CA2679322C - Prepolymers with dangling polysiloxane-containing polymer chains - Google Patents

Prepolymers with dangling polysiloxane-containing polymer chains Download PDF

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Publication number
CA2679322C
CA2679322C CA2679322A CA2679322A CA2679322C CA 2679322 C CA2679322 C CA 2679322C CA 2679322 A CA2679322 A CA 2679322A CA 2679322 A CA2679322 A CA 2679322A CA 2679322 C CA2679322 C CA 2679322C
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CA
Canada
Prior art keywords
polysiloxane
groups
prepolymer
group
units derived
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA2679322A
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English (en)
French (fr)
Other versions
CA2679322A1 (en
Inventor
Jian S. Zhou
Dawn A. Smith
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Alcon Inc
Original Assignee
Novartis AG
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Publication of CA2679322A1 publication Critical patent/CA2679322A1/en
Application granted granted Critical
Publication of CA2679322C publication Critical patent/CA2679322C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/12—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/08—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated side groups
    • C08F290/14—Polymers provided for in subclass C08G
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D11/00—Producing optical elements, e.g. lenses or prisms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • C08F290/068—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42—Block-or graft-polymers containing polysiloxane sequences
    • C08G77/442—Block-or graft-polymers containing polysiloxane sequences containing vinyl polymer sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/08—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
    • C08L51/085—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds on to polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/10—Block- or graft-copolymers containing polysiloxane sequences
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • G02B1/041—Lenses
    • G02B1/043—Contact lenses
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C08G77/18—Polysiloxanes containing silicon bound to oxygen-containing groups to alkoxy or aryloxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C08G77/24—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen halogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C08G77/26—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen nitrogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/70—Siloxanes defined by use of the MDTQ nomenclature

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Ophthalmology & Optometry (AREA)
  • Mechanical Engineering (AREA)
  • Eyeglasses (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Silicon Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CA2679322A 2007-03-22 2008-03-21 Prepolymers with dangling polysiloxane-containing polymer chains Expired - Fee Related CA2679322C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US89632507P 2007-03-22 2007-03-22
US60/896,325 2007-03-22
PCT/US2008/057774 WO2008116131A2 (en) 2007-03-22 2008-03-21 Prepolymers with dangling polysiloxane-containing polymer chains

Publications (2)

Publication Number Publication Date
CA2679322A1 CA2679322A1 (en) 2008-09-25
CA2679322C true CA2679322C (en) 2015-02-10

Family

ID=39766782

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2679322A Expired - Fee Related CA2679322C (en) 2007-03-22 2008-03-21 Prepolymers with dangling polysiloxane-containing polymer chains

Country Status (12)

Country Link
US (2) US8071658B2 (enExample)
EP (1) EP2129513B1 (enExample)
JP (1) JP5484916B2 (enExample)
KR (1) KR101482808B1 (enExample)
CN (1) CN101641206B (enExample)
AU (1) AU2008228760B2 (enExample)
BR (1) BRPI0809271A2 (enExample)
CA (1) CA2679322C (enExample)
MX (1) MX2009010116A (enExample)
RU (1) RU2462361C2 (enExample)
WO (1) WO2008116131A2 (enExample)
ZA (1) ZA200904884B (enExample)

Families Citing this family (96)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9056880B2 (en) 2006-09-29 2015-06-16 Johnson & Johnson Vision Care, Inc. Process for producing hydrolysis-resistant silicone compounds
US7838698B2 (en) 2006-09-29 2010-11-23 Johnson & Johnson Vision Care, Inc. Hydrolysis-resistant silicone compounds
JP5600863B2 (ja) * 2006-09-29 2014-10-08 東レ株式会社 シリコーンポリマー、眼用レンズおよびコンタクトレンズ
AU2008228761B2 (en) * 2007-03-22 2011-11-24 Novartis Ag Silicone-containing prepolymers with hydrophilic polymeric chains
US20100302628A1 (en) 2007-08-07 2010-12-02 Nikon Corporation Microscope
US8119753B2 (en) * 2007-10-23 2012-02-21 Bausch & Lomb Incorporated Silicone hydrogels with amino surface groups
WO2009085902A1 (en) * 2007-12-20 2009-07-09 Novartis Ag Method for making contact lenses
US20090168013A1 (en) * 2007-12-27 2009-07-02 Kunzler Jay F Trimethylsilyl-Capped Polysiloxane Macromonomers Containing Polar Fluorinated Side-Chains
US7897654B2 (en) * 2007-12-27 2011-03-01 Johnson & Johnson Vision Care Inc. Silicone prepolymer solutions
CN101939347B (zh) * 2008-02-06 2013-03-06 大金工业株式会社 氟硅氧烷和含氟和硅的表面处理剂
WO2010011492A1 (en) 2008-07-21 2010-01-28 Novartis Ag Silicone hydrogel contact lenses with convertible comfort agents
US8079703B2 (en) * 2008-07-21 2011-12-20 Novartis Ag Silicone-containing polymeric materials with hydrolyzable groups
US8470906B2 (en) 2008-09-30 2013-06-25 Johnson & Johnson Vision Care, Inc. Ionic silicone hydrogels having improved hydrolytic stability
US20130203812A1 (en) 2008-09-30 2013-08-08 Johnson & Johnson Vision Care, Inc. Ionic silicone hydrogels comprising pharmaceutical and/or nutriceutical components and having improved hydrolytic stability
CA2739102C (en) * 2008-11-13 2016-06-21 Novartis Ag Silicone hydrogel materials with chemically bound wetting agents
WO2010056686A1 (en) * 2008-11-13 2010-05-20 Novartis Ag Polysiloxane copolymers with terminal hydrophilic polymer chains
TWI506333B (zh) * 2008-12-05 2015-11-01 Novartis Ag 用以傳遞疏水性舒適劑之眼用裝置及其製造方法
CA2747355C (en) * 2008-12-18 2014-10-21 Novartis Ag Method for making silicone hydrogel contact lenses
WO2010078001A1 (en) 2008-12-30 2010-07-08 Novartis Ag Tri-functional uv-absorbing compounds and use thereof
CA2761218C (en) 2009-05-22 2016-06-28 Novartis Ag Actinically-crosslinkable siloxane-containing copolymers
WO2010133680A1 (en) * 2009-05-22 2010-11-25 Novartis Ag Actinically-crosslinkable siloxane-containing copolymers
US8083348B2 (en) * 2009-06-16 2011-12-27 Bausch & Lomb Incorporated Biomedical devices
CN102498431A (zh) * 2009-09-15 2012-06-13 诺瓦提斯公司 适于制造紫外吸收接触透镜的预聚物
WO2011071790A1 (en) * 2009-12-07 2011-06-16 Novartis Ag Methods for increasing the ion permeability of contact lenses
TWI483996B (zh) 2009-12-08 2015-05-11 Novartis Ag 具有共價貼合塗層之聚矽氧水凝膠鏡片
US9005492B2 (en) * 2009-12-14 2015-04-14 Novartis Ag Methods for making silicone hydrogel lenses from water-based lens formulations
JP5720103B2 (ja) * 2010-03-18 2015-05-20 東レ株式会社 シリコーンハイドロゲル、眼用レンズおよびコンタクトレンズ
CN103052364B (zh) 2010-07-30 2015-12-02 诺华股份有限公司 具有富水表面的硅水凝胶透镜
JP5860461B2 (ja) 2010-07-30 2016-02-16 ノバルティス アーゲー Ｕｖ吸収性眼用レンズの製造方法
BR112013002154A2 (pt) * 2010-07-30 2016-05-31 Novartis Ag pré-polímeros anfifílicos de polissiloxano e seus usos
BR112013008221B1 (pt) 2010-10-06 2020-02-11 Alcon Inc. Pré-polímero processável em água, lente de contato de hidrogel de silicone e seu método de fabricação
WO2012047969A1 (en) 2010-10-06 2012-04-12 Novartis Ag Water-processable silicone-containing prepolymers and uses thereof
HUE044765T2 (hu) 2010-10-06 2019-11-28 Novartis Ag Polimerizálható hosszabbított láncú polisziloxánok hidrofil oldalcsoportokkal
US9156215B2 (en) 2010-12-06 2015-10-13 Novartis Ag Method for making silicone hydrogel contact lenses
EP2652532B1 (en) 2010-12-13 2016-06-08 Novartis AG Ophthalmic lenses modified with functional groups and methods of making thereof
CA2831659C (en) * 2011-04-01 2016-01-05 Novartis Ag Composition for forming a contact lens
WO2012170603A1 (en) 2011-06-09 2012-12-13 Novartis Ag Silicone hydrogel lenses with nano-textured surfaces
CN103917899B (zh) 2011-10-12 2018-04-03 诺华股份有限公司 通过涂布制备uv吸收性眼用透镜的方法
US9140825B2 (en) 2011-12-23 2015-09-22 Johnson & Johnson Vision Care, Inc. Ionic silicone hydrogels
US8937110B2 (en) 2011-12-23 2015-01-20 Johnson & Johnson Vision Care, Inc. Silicone hydrogels having a structure formed via controlled reaction kinetics
US9156934B2 (en) 2011-12-23 2015-10-13 Johnson & Johnson Vision Care, Inc. Silicone hydrogels comprising n-vinyl amides and hydroxyalkyl (meth)acrylates or (meth)acrylamides
US9588258B2 (en) 2011-12-23 2017-03-07 Johnson & Johnson Vision Care, Inc. Silicone hydrogels formed from zero diluent reactive mixtures
US8937111B2 (en) 2011-12-23 2015-01-20 Johnson & Johnson Vision Care, Inc. Silicone hydrogels comprising desirable water content and oxygen permeability
US9125808B2 (en) 2011-12-23 2015-09-08 Johnson & Johnson Vision Care, Inc. Ionic silicone hydrogels
TWI488892B (zh) * 2011-12-29 2015-06-21 Pegavision Corp 親水性矽膠預聚物之製造方法
WO2013142061A1 (en) 2012-03-22 2013-09-26 Momentive Performance Materials Inc. Hydrophilic macromers and hydrogels comprising the same
AU2013235656A1 (en) * 2012-03-22 2014-10-09 Momentive Performance Materials Inc. Organo-modified silicone polymers and hydrogels comprising the same
US9395468B2 (en) 2012-08-27 2016-07-19 Ocular Dynamics, Llc Contact lens with a hydrophilic layer
US8937133B2 (en) 2012-09-25 2015-01-20 National Chiao Tung University Dissoluble PDMS-modified p(HEMA-MAA) amphiphilic copolymer and method for fabricating the same
KR102172116B1 (ko) 2012-09-27 2020-10-30 로디아 오퍼레이션스 은 나노구조의 제조 방법 및 그러한 방법에 유용한 코폴리머
CN103819610B (zh) * 2012-11-16 2015-12-02 江南大学 一种pH敏感型无机高聚物杂化水凝胶的制备方法
EP2931790B1 (en) 2012-12-14 2017-02-15 Novartis AG Actinically-crosslinkable amphiphilic prepolymers
CA2889891C (en) * 2012-12-14 2017-10-24 Novartis Ag Amphiphilic siloxane-containing vinylic monomers and uses thereof
WO2014093764A1 (en) 2012-12-14 2014-06-19 Novartis Ag Amphiphilic siloxane-containing (meth)acrylamides and uses thereof
JP6065988B2 (ja) 2012-12-14 2017-01-25 ノバルティス アーゲー トリス（トリメチルシロキシ）シランビニル系モノマー及びその用途
CN104871036B (zh) 2012-12-17 2019-12-10 诺华股份有限公司 制备改进的uv吸收性眼用透镜的方法
US10053597B2 (en) 2013-01-18 2018-08-21 Basf Se Acrylic dispersion-based coating compositions
US20140268028A1 (en) * 2013-03-15 2014-09-18 Johnson & Johnson Vision Care, Inc. Silicone-containing contact lens having clay treatment applied thereto
MX347214B (es) * 2013-04-30 2017-04-19 Coopervision Int Holding Co Lp Lentes de contacto de hidrogel de silicona que contienen aminas primarias y composiciones y metodos relacionados.
TWI610951B (zh) * 2013-09-10 2018-01-11 國立交通大學 有機－無機混成矽氧烷水膠組成物之製備方法
CN105555816B (zh) * 2013-09-30 2018-05-18 诺华股份有限公司 具有相对长的热稳定性的硅酮水凝胶透镜
US9568645B2 (en) 2013-09-30 2017-02-14 Novartis Ag Silicone hydrogel lenses with relatively-long thermal stability
HUE045140T2 (hu) 2013-09-30 2019-12-30 Novartis Ag Eljárás UV-abszorbáló szemészeti lencsék elõállítására
US9919456B2 (en) 2013-10-31 2018-03-20 Novartis Ag Method for producing ophthalmic lenses
CN105917270A (zh) 2013-11-15 2016-08-31 视觉力学有限责任公司 具有亲水层的接触透镜
CN105793022B (zh) 2013-12-13 2017-09-19 诺华股份有限公司 用于制备接触镜片的方法
MY180543A (en) 2013-12-17 2020-12-01 Novartis Ag A silicone hydrogel lens with a crosslinked hydrophilic coating
CN103951797B (zh) * 2014-03-17 2017-05-03 江苏诺飞新材料科技有限公司 一种有机硅接枝共聚物及其制备方法和应用
AU2015201321A1 (en) 2014-03-31 2015-10-15 Johnson & Johnson Vision Care, Inc. Silicone acrylamide copolymer
JP6355821B2 (ja) 2014-04-25 2018-07-11 ノバルティス アーゲー カルボシロキサンビニル系モノマー
CA2940207C (en) 2014-04-25 2019-09-10 Novartis Ag Hydrophilized carbosiloxane vinylic monomers
CN106715101B (zh) 2014-08-26 2019-11-05 诺华股份有限公司 用于在硅酮水凝胶接触镜片上施用稳定的涂层的方法
MX380774B (es) 2014-09-26 2025-03-12 Alcon Inc Polisiloxanos polimerizables con sustituyentes hidrófilos.
US10160141B2 (en) 2014-11-25 2018-12-25 Novartis Ag Molds for making contact lenses
JP6774947B2 (ja) 2014-12-09 2020-10-28 タンジブル サイエンス インコーポレイテッド 生体適合性層を有する医療デバイスコーティング
US9851472B2 (en) 2015-03-27 2017-12-26 Momentive Performance Materials Inc. Silicone-based hydrophilic copolymer and hydrogel compositions comprising the same
CN104945570B (zh) * 2015-07-03 2017-06-09 东南大学 一种硅凝胶接触透镜及其表面反转处理方法
US10640649B2 (en) * 2015-07-23 2020-05-05 The University Of North Carolina At Chapel Hill Solvent-free supersoft and superelastic materials
WO2017073807A1 (ko) * 2015-10-28 2017-05-04 (주)엘지하우시스 첨가제용 내오염성 아크릴계 수지
CN108369291B (zh) 2015-12-15 2021-07-20 爱尔康公司 用于将稳定的涂层施加在硅酮水凝胶接触镜片上的方法
US10138316B2 (en) 2015-12-15 2018-11-27 Novartis Ag Amphiphilic branched polydiorganosiloxane macromers
WO2017145024A1 (en) 2016-02-22 2017-08-31 Novartis Ag Uv-absorbing vinylic monomers and uses thereof
WO2017145022A1 (en) 2016-02-22 2017-08-31 Novartis Ag Uv/visible-absorbing vinylic monomers and uses thereof
WO2018078543A1 (en) 2016-10-26 2018-05-03 Novartis Ag Amphiphilic branched polydiorganosiloxane macromers
ES2678773B1 (es) * 2017-01-16 2019-06-12 Consejo Superior Investigacion Recubrimientos tipo hidrogel en base vinil-lactamas
US10906258B2 (en) 2017-08-29 2021-02-02 Alcon Inc. Cast-molding process for producing contact lenses
US11256003B2 (en) 2017-12-13 2022-02-22 Alcon Inc. Weekly and monthly disposable water gradient contact lenses
US11111327B2 (en) 2018-01-22 2021-09-07 Alcon Inc. Cast-molding process for producing UV-absorbing contact lenses
US11459479B2 (en) 2018-12-03 2022-10-04 Alcon Inc. Method for making coated silicone hydrogel contact lenses
HUE062555T2 (hu) 2018-12-03 2023-11-28 Alcon Inc Eljárás bevonatos szilikonhidrogél-kontaktlencsék elõállítására
HUE061330T2 (hu) 2018-12-14 2023-06-28 Alcon Inc Eljárás szilikon hidrogél kontaktlencsék elõállítására
SG11202108875UA (en) 2019-04-10 2021-10-28 Alcon Inc Method for producing coated contact lenses
SG11202111038UA (en) 2019-05-28 2021-12-30 Alcon Inc Pad transfer printing instrument and method for making colored contact lenses
TWI859401B (zh) 2020-01-27 2024-10-21 新加坡商科萊博新加坡私人有限公司 光化可交聯的聚矽氧烷－聚甘油嵌段共聚物及其製造和使用方法
US20220365427A1 (en) * 2021-04-30 2022-11-17 Taiwan Semiconductor Manufacturing Company, Ltd. Photoresist composition and method for manufacturing a semiconductor device
CN116496501B (zh) * 2023-04-04 2024-03-29 浙江精一新材料科技有限公司 一种具有内酰胺基团的液态聚硅氧烷及光阀

Family Cites Families (82)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4042552A (en) 1972-09-19 1977-08-16 Warner-Lambert Company Composition for hydrophilic lens blank and method of casting
US4045547A (en) 1974-11-21 1977-08-30 Warner-Lambert Company Fabrication of soft contact lens and composition therefor
FR2385763A1 (fr) * 1977-03-31 1978-10-27 Essilor Int Procede de preparation de copolymeres greffes de silicones
US4136250A (en) * 1977-07-20 1979-01-23 Ciba-Geigy Corporation Polysiloxane hydrogels
US4312575A (en) 1979-09-18 1982-01-26 Peyman Gholam A Soft corneal contact lens with tightly cross-linked polymer coating and method of making same
US4444711A (en) 1981-12-21 1984-04-24 Husky Injection Molding Systems Ltd. Method of operating a two-shot injection-molding machine
US4460534A (en) 1982-09-07 1984-07-17 International Business Machines Corporation Two-shot injection molding
US4543398A (en) * 1983-04-28 1985-09-24 Minnesota Mining And Manufacturing Company Ophthalmic devices fabricated from urethane acrylates of polysiloxane alcohols
JPS60163901A (ja) 1984-02-04 1985-08-26 Japan Synthetic Rubber Co Ltd プラズマ重合処理方法
EP0216074B1 (en) 1985-07-31 1993-06-16 Ciba-Geigy Ag Polyvinyl alcohol derivatives and crosslinked hydrogel contact lenses made therefrom
DE3708308A1 (de) * 1986-04-10 1987-10-22 Bayer Ag Kontaktoptische gegenstaende
US4780515A (en) * 1987-02-05 1988-10-25 Bausch & Lomb Incorporated Continuous-wear lenses having improved physical properties
DE3710343A1 (de) * 1987-03-28 1988-10-06 Basf Lacke & Farben Verzweigtes acrylatcopolymerisat mit polisierbaren doppelbindungen und verfahren zur herstellung des acrylatcopolymerisats
US5070169A (en) * 1988-02-26 1991-12-03 Ciba-Geigy Corporation Wettable, flexible, oxygen permeable contact lens containing block copolymer polysiloxane-polyoxyalkylene backbone units and use thereof
US4859780A (en) 1988-02-26 1989-08-22 Ciba-Geigy Corporation Hydrophilic modifier monomers
US5070170A (en) * 1988-02-26 1991-12-03 Ciba-Geigy Corporation Wettable, rigid gas permeable, substantially non-swellable contact lens containing block copolymer polysiloxane-polyoxyalkylene backbone units, and use thereof
JP2802287B2 (ja) * 1988-05-31 1998-09-24 ピルキングトン ビジョンケア インコーポレイテッド コンタクトレンズ材料とその製法
US5070215A (en) * 1989-05-02 1991-12-03 Bausch & Lomb Incorporated Novel vinyl carbonate and vinyl carbamate contact lens material monomers
US5063139A (en) * 1989-06-19 1991-11-05 Fuji Photo Film Co., Ltd. Silver halide color photographic light-sensitive material capable of being processed at ultrahigh speed and process for the formation of color images using thereof
US5036139A (en) * 1989-09-29 1991-07-30 E. I. Du Pont De Nemours And Company Hybrid acrylic star polymers with polysiloxane cores
US5314960A (en) * 1990-04-10 1994-05-24 Permeable Technologies, Inc. Silicone-containing polymers, oxygen permeable hydrophilic contact lenses and methods for making these lenses and treating patients with visual impairment
US5244981A (en) * 1990-04-10 1993-09-14 Permeable Technologies, Inc. Silicone-containing contact lens polymers, oxygen permeable contact lenses and methods for making these lenses and treating patients with visual impairment
US5314961A (en) * 1990-10-11 1994-05-24 Permeable Technologies, Inc. Silicone-containing polymers, compositions and improved oxygen permeable hydrophilic contact lenses
US5158717A (en) 1990-11-27 1992-10-27 Bausch & Lomb Incorporated Method of molding shaped polymeric articles
US5219965A (en) * 1990-11-27 1993-06-15 Bausch & Lomb Incorporated Surface modification of polymer objects
AU647880B2 (en) 1991-02-28 1994-03-31 Ciba-Geigy Ag Contact lenses made from thermoformable material
WO1992018548A1 (en) 1991-04-18 1992-10-29 Optical Research, Inc. Novel composition for contact lenses
US6743878B2 (en) * 1991-07-05 2004-06-01 Biocompatibles Uk Limited Polymeric surface coatings
US5196458A (en) * 1991-10-15 1993-03-23 Johnson & Johnson Vision Products, Inc. Soft, high oxygen permeability ophthalmic lens
US5310779A (en) 1991-11-05 1994-05-10 Bausch & Lomb Incorporated UV curable crosslinking agents useful in copolymerization
JPH05310837A (ja) 1992-05-14 1993-11-22 Japan Synthetic Rubber Co Ltd 酸素透過性高分子材料の製造方法
US5358995A (en) * 1992-05-15 1994-10-25 Bausch & Lomb Incorporated Surface wettable silicone hydrogels
US5336797A (en) * 1992-12-30 1994-08-09 Bausch & Lomb Incorporated Siloxane macromonomers
TW328535B (en) 1993-07-02 1998-03-21 Novartis Ag Functional photoinitiators and their manufacture
TW272976B (enExample) 1993-08-06 1996-03-21 Ciba Geigy Ag
US5712356A (en) 1993-11-26 1998-01-27 Ciba Vision Corporation Cross-linkable copolymers and hydrogels
US5894002A (en) 1993-12-13 1999-04-13 Ciba Vision Corporation Process and apparatus for the manufacture of a contact lens
US5387633A (en) * 1994-03-08 1995-02-07 W. R. Grace & Co.-Conn. Styrene sodium styrene sulfonate copolymer for plastisol sealant
US5843346A (en) 1994-06-30 1998-12-01 Polymer Technology Corporation Method of cast molding contact lenses
US5760100B1 (en) * 1994-09-06 2000-11-14 Ciba Vision Corp Extended wear ophthalmic lens
US6342570B1 (en) 1994-11-14 2002-01-29 Novartis Ag Cross-linkable copolymers and hydrogels
US5665840A (en) * 1994-11-18 1997-09-09 Novartis Corporation Polymeric networks from water-soluble prepolymers
JP3785599B2 (ja) 1995-02-03 2006-06-14 ノバルティス アクチエンゲゼルシャフト エステル又はアミド基を含む架橋ポリマー
TW349967B (en) 1995-02-03 1999-01-11 Novartis Ag Process for producing contact lenses and a cross-linkable polyvinylalcohol used therefor
TW393498B (en) * 1995-04-04 2000-06-11 Novartis Ag The preparation and use of Polysiloxane-comprising perfluoroalkyl ethers
US5807944A (en) * 1996-06-27 1998-09-15 Ciba Vision Corporation Amphiphilic, segmented copolymer of controlled morphology and ophthalmic devices including contact lenses made therefrom
JP2001502734A (ja) 1996-10-21 2001-02-27 ノバルティス アクチエンゲゼルシャフト 架橋性ポリマー
AU7533696A (en) 1996-12-13 1998-06-18 Ciba-Geigy Ag New materials
US5708094A (en) * 1996-12-17 1998-01-13 Bausch & Lomb Incorporated Polybutadiene-based compositions for contact lenses
TW425403B (en) 1997-02-04 2001-03-11 Novartis Ag Branched polyurethane (meth)acrylate prepolymers, opthal-mic mouldings derived therefrom and processes for their manufacture
EP0867456A1 (de) 1997-02-04 1998-09-30 Novartis AG Ophthalmischer Formkörper
ATE216501T1 (de) 1997-02-21 2002-05-15 Novartis Erfind Verwalt Gmbh Opthalmische formmasse
AU9743298A (en) 1997-09-16 1999-04-05 Novartis Ag Crosslinkable polyurea polymers
TW429327B (en) 1997-10-21 2001-04-11 Novartis Ag Single mould alignment
US5981669A (en) * 1997-12-29 1999-11-09 Bausch & Lomb Incorporated Silicone-containing prepolymers and low water materials
US6451871B1 (en) 1998-11-25 2002-09-17 Novartis Ag Methods of modifying surface characteristics
US6943203B2 (en) * 1998-03-02 2005-09-13 Johnson & Johnson Vision Care, Inc. Soft contact lenses
US7052131B2 (en) * 2001-09-10 2006-05-30 J&J Vision Care, Inc. Biomedical devices containing internal wetting agents
US5998498A (en) * 1998-03-02 1999-12-07 Johnson & Johnson Vision Products, Inc. Soft contact lenses
US6822016B2 (en) * 2001-09-10 2004-11-23 Johnson & Johnson Vision Care, Inc. Biomedical devices containing internal wetting agents
US6367929B1 (en) 1998-03-02 2002-04-09 Johnson & Johnson Vision Care, Inc. Hydrogel with internal wetting agent
JP3771711B2 (ja) * 1998-03-31 2006-04-26 互応化学工業株式会社 フォトソルダーレジストインクの製造方法
EP1095076A4 (en) 1998-07-08 2002-11-06 Sunsoft Corp INTERMEDIATE POLYMERS NETWORK OF HYDROPHILIC HYDROGELS FOR CONTACT LENSES
JP2000034326A (ja) * 1998-07-21 2000-02-02 Shinnakamura Kagaku Kogyo Kk シロキサン共重合体およびその製造方法
US6039913A (en) * 1998-08-27 2000-03-21 Novartis Ag Process for the manufacture of an ophthalmic molding
EP1002807A1 (en) 1998-11-20 2000-05-24 Novartis AG Functionalized resin derived from polyallylamine
US5981675A (en) * 1998-12-07 1999-11-09 Bausch & Lomb Incorporated Silicone-containing macromonomers and low water materials
US6444776B1 (en) * 1998-12-21 2002-09-03 Novartis Ag Organic polymers
JP4489975B2 (ja) 1999-03-30 2010-06-23 ノバルティス アーゲー 有機化合物
WO2001007523A1 (en) * 1999-07-27 2001-02-01 Bausch & Lomb Incorporated Contact lens material
US6793973B2 (en) 2000-02-04 2004-09-21 Novartis Ag Single-dip process for achieving a layer-by-layer-like coating
US6719929B2 (en) 2000-02-04 2004-04-13 Novartis Ag Method for modifying a surface
AR029901A1 (es) * 2000-03-24 2003-07-23 Novartis Ag Prepolimeros reticulables o polimerizables, y un proceso para la fabricacion de articulos moldeados ''biomedicos'' ''
AU2733102A (en) * 2000-11-03 2002-05-15 Johnson & Johnson Vision Care Solvents useful in the preparation of polymers containing hydrophilic and hydrophobic monomers
US6811805B2 (en) 2001-05-30 2004-11-02 Novatis Ag Method for applying a coating
US6995192B2 (en) 2002-08-14 2006-02-07 Novartis Ag Radiation-curable prepolymers
US6896926B2 (en) 2002-09-11 2005-05-24 Novartis Ag Method for applying an LbL coating onto a medical device
US7025131B2 (en) * 2003-09-05 2006-04-11 Baugh Benton F Electrical tubing control and remediation apparatus and method of use
US7977430B2 (en) 2003-11-25 2011-07-12 Novartis Ag Crosslinkable polyurea prepolymers
MXPA06012125A (es) * 2004-04-21 2007-01-17 Novartis Ag Tintas de color curables para fabricar lentes de hidrogel de silicona coloreados.
US7249848B2 (en) * 2004-09-30 2007-07-31 Johnson & Johnson Vision Care, Inc. Wettable hydrogels comprising reactive, hydrophilic, polymeric internal wetting agents
US7858000B2 (en) 2006-06-08 2010-12-28 Novartis Ag Method of making silicone hydrogel contact lenses

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