CA2670725A1 - Highly elastic flexible polyurethane foams - Google Patents
Highly elastic flexible polyurethane foams Download PDFInfo
- Publication number
- CA2670725A1 CA2670725A1 CA002670725A CA2670725A CA2670725A1 CA 2670725 A1 CA2670725 A1 CA 2670725A1 CA 002670725 A CA002670725 A CA 002670725A CA 2670725 A CA2670725 A CA 2670725A CA 2670725 A1 CA2670725 A1 CA 2670725A1
- Authority
- CA
- Canada
- Prior art keywords
- flexible polyurethane
- polyurethane foam
- hyperbranched
- groups
- polyester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 229920005830 Polyurethane Foam Polymers 0.000 title claims abstract description 57
- 239000011496 polyurethane foam Substances 0.000 title claims abstract description 57
- 239000004417 polycarbonate Substances 0.000 claims abstract description 50
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 49
- 239000003054 catalyst Substances 0.000 claims abstract description 30
- 229920000728 polyester Polymers 0.000 claims abstract description 23
- 239000005056 polyisocyanate Substances 0.000 claims abstract description 23
- 229920001228 polyisocyanate Polymers 0.000 claims abstract description 23
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 17
- 239000000654 additive Substances 0.000 claims abstract description 14
- 238000004519 manufacturing process Methods 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 230000000399 orthopedic effect Effects 0.000 claims abstract description 3
- 150000003077 polyols Chemical class 0.000 claims description 68
- 229920005862 polyol Polymers 0.000 claims description 67
- 238000006243 chemical reaction Methods 0.000 claims description 63
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 56
- 229920006150 hyperbranched polyester Polymers 0.000 claims description 43
- 150000001298 alcohols Chemical class 0.000 claims description 39
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 38
- 239000000047 product Substances 0.000 claims description 31
- 238000000034 method Methods 0.000 claims description 25
- 239000002253 acid Substances 0.000 claims description 23
- 125000005587 carbonate group Chemical group 0.000 claims description 23
- 239000007859 condensation product Substances 0.000 claims description 22
- 239000012948 isocyanate Substances 0.000 claims description 19
- 150000002513 isocyanates Chemical class 0.000 claims description 19
- 239000002904 solvent Substances 0.000 claims description 19
- 108090000790 Enzymes Proteins 0.000 claims description 16
- 102000004190 Enzymes Human genes 0.000 claims description 16
- 150000001991 dicarboxylic acids Chemical class 0.000 claims description 16
- 125000000524 functional group Chemical group 0.000 claims description 16
- 239000004604 Blowing Agent Substances 0.000 claims description 15
- 230000008569 process Effects 0.000 claims description 15
- 150000002009 diols Chemical class 0.000 claims description 14
- 239000003377 acid catalyst Substances 0.000 claims description 13
- 125000001931 aliphatic group Chemical group 0.000 claims description 13
- 125000004432 carbon atom Chemical group C* 0.000 claims description 13
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 13
- 239000011541 reaction mixture Substances 0.000 claims description 12
- 239000004970 Chain extender Substances 0.000 claims description 11
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 11
- 150000007513 acids Chemical class 0.000 claims description 9
- 230000009257 reactivity Effects 0.000 claims description 9
- 239000004971 Cross linker Substances 0.000 claims description 8
- 125000003118 aryl group Chemical group 0.000 claims description 8
- 150000002605 large molecules Chemical class 0.000 claims description 8
- 150000003628 tricarboxylic acids Chemical class 0.000 claims description 8
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 claims description 7
- 150000007524 organic acids Chemical class 0.000 claims description 7
- 230000008030 elimination Effects 0.000 claims description 6
- 238000003379 elimination reaction Methods 0.000 claims description 6
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 claims description 5
- 238000007306 functionalization reaction Methods 0.000 claims description 5
- 150000005677 organic carbonates Chemical class 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 4
- HCUYBXPSSCRKRF-UHFFFAOYSA-N diphosgene Chemical compound ClC(=O)OC(Cl)(Cl)Cl HCUYBXPSSCRKRF-UHFFFAOYSA-N 0.000 claims description 4
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 4
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims description 4
- UCPYLLCMEDAXFR-UHFFFAOYSA-N triphosgene Chemical compound ClC(Cl)(Cl)OC(=O)OC(Cl)(Cl)Cl UCPYLLCMEDAXFR-UHFFFAOYSA-N 0.000 claims description 4
- 239000003153 chemical reaction reagent Substances 0.000 claims description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 claims description 2
- 229920001169 thermoplastic Polymers 0.000 claims description 2
- 239000000306 component Substances 0.000 claims 8
- 229920001730 Moisture cure polyurethane Polymers 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 abstract description 24
- 239000003795 chemical substances by application Substances 0.000 abstract description 7
- 239000003431 cross linking reagent Substances 0.000 abstract 1
- 239000003380 propellant Substances 0.000 abstract 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 69
- -1 uretonimine Chemical compound 0.000 description 56
- 239000000203 mixture Substances 0.000 description 52
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 42
- 239000006260 foam Substances 0.000 description 26
- 235000011118 potassium hydroxide Nutrition 0.000 description 23
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 18
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 18
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 18
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 16
- 238000006068 polycondensation reaction Methods 0.000 description 16
- 239000007858 starting material Substances 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 14
- 229920000642 polymer Polymers 0.000 description 14
- 150000002148 esters Chemical class 0.000 description 12
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 11
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 11
- 235000019589 hardness Nutrition 0.000 description 11
- 150000003254 radicals Chemical class 0.000 description 11
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 10
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 10
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 10
- 230000001588 bifunctional effect Effects 0.000 description 10
- 229920000570 polyether Polymers 0.000 description 10
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 8
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- 239000004721 Polyphenylene oxide Substances 0.000 description 8
- 239000001361 adipic acid Substances 0.000 description 8
- 235000011037 adipic acid Nutrition 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 229920002635 polyurethane Polymers 0.000 description 8
- 239000004814 polyurethane Substances 0.000 description 8
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 7
- 238000013016 damping Methods 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- ARXKVVRQIIOZGF-UHFFFAOYSA-N 1,2,4-butanetriol Chemical compound OCCC(O)CO ARXKVVRQIIOZGF-UHFFFAOYSA-N 0.000 description 6
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 6
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 6
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 6
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 6
- 125000002947 alkylene group Chemical group 0.000 description 6
- 238000009835 boiling Methods 0.000 description 6
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 6
- 238000009833 condensation Methods 0.000 description 6
- 230000005494 condensation Effects 0.000 description 6
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 6
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 5
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
- 150000001412 amines Chemical class 0.000 description 5
- 230000005540 biological transmission Effects 0.000 description 5
- 238000000354 decomposition reaction Methods 0.000 description 5
- 239000000412 dendrimer Substances 0.000 description 5
- 229920000736 dendritic polymer Polymers 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 5
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 5
- 239000004926 polymethyl methacrylate Substances 0.000 description 5
- 230000035484 reaction time Effects 0.000 description 5
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 150000005846 sugar alcohols Chemical class 0.000 description 5
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 4
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 4
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- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 4
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- 125000000582 cycloheptyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 4
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- 238000005809 transesterification reaction Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
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- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 1
- YFHICDDUDORKJB-UHFFFAOYSA-N trimethylene carbonate Chemical compound O=C1OCCCO1 YFHICDDUDORKJB-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
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- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3271—Hydroxyamines
- C08G18/3275—Hydroxyamines containing two hydroxy groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
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- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4072—Mixtures of compounds of group C08G18/63 with other macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
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- C08G18/40—High-molecular-weight compounds
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- C08G18/4236—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
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- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/44—Polycarbonates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/4833—Polyethers containing oxyethylene units
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6633—Compounds of group C08G18/42
- C08G18/6637—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6648—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3225 or C08G18/3271 and/or polyamines of C08G18/38
- C08G18/6655—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3225 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3271
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2205/00—Foams characterised by their properties
- C08J2205/06—Flexible foams
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Polyesters Or Polycarbonates (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06125824.0 | 2006-12-11 | ||
| EP06125824 | 2006-12-11 | ||
| PCT/EP2007/063445 WO2008071622A1 (de) | 2006-12-11 | 2007-12-06 | Hochelastische polyurethanweichschaumstoffe |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2670725A1 true CA2670725A1 (en) | 2008-06-19 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002670725A Abandoned CA2670725A1 (en) | 2006-12-11 | 2007-12-06 | Highly elastic flexible polyurethane foams |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20100036008A1 (enExample) |
| EP (1) | EP2099841B1 (enExample) |
| JP (1) | JP2010512439A (enExample) |
| KR (1) | KR20090097915A (enExample) |
| CN (1) | CN101600748A (enExample) |
| AT (1) | ATE499395T1 (enExample) |
| CA (1) | CA2670725A1 (enExample) |
| DE (1) | DE502007006564D1 (enExample) |
| ES (1) | ES2359855T3 (enExample) |
| MX (1) | MX2009006142A (enExample) |
| WO (1) | WO2008071622A1 (enExample) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CA2670987C (en) | 2006-12-15 | 2016-07-19 | Basf Se | Polymer dispersions comprising highly branched polycarbonates |
| RU2452742C2 (ru) * | 2007-01-30 | 2012-06-10 | ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи | Инициированные аминами полиолы и жесткие полиуретановые пенопласты, изготовленные из них |
| EP2225337B1 (de) * | 2007-11-19 | 2017-08-23 | Basf Se | Verwendung hochverzweigter polymere in polymerdispersionen für glanzfarben |
| KR20100100891A (ko) * | 2007-11-19 | 2010-09-15 | 바스프 에스이 | 향상된 냉동/해동 안정성을 갖는 중합체 분산액을 제조하기 위한 고도-분지형 중합체의 용도 |
| ES2524258T3 (es) | 2008-03-14 | 2014-12-04 | Basf Se | Elastómeros de poliuretano de celda gruesa |
| US8604094B2 (en) | 2008-12-23 | 2013-12-10 | Basf Se | Flexible polyurethane foam and method of producing same |
| MX2011007402A (es) | 2009-01-12 | 2011-08-03 | Basf Se | Espumas de poliuretano flexibles, altamente elasticas. |
| US20110257284A1 (en) * | 2010-04-15 | 2011-10-20 | Basf Se | Process for producing flame-retardant pu foams |
| US9023908B2 (en) | 2010-05-27 | 2015-05-05 | Basf Se | Oil-absorbent polyurethane sponges with good mechanical properties |
| EP2390275A1 (de) | 2010-05-27 | 2011-11-30 | Basf Se | Ölaufnehmende Polyurethanschwämme mit guten mechanischen Eigenschaften |
| US9453100B2 (en) | 2011-07-25 | 2016-09-27 | Novomer, Inc. | Polymer compositions and methods |
| KR101909320B1 (ko) | 2011-08-25 | 2018-10-17 | 다우 글로벌 테크놀로지스 엘엘씨 | 이중 금속 시아니드 촉매의 존재 하에 에틸렌 카르보네이트의 중합에 의한 옥시에틸렌 단위를 갖는 폴리에테르 알콜의 제조 방법 |
| ES2404734B2 (es) | 2011-10-05 | 2014-01-29 | Centro Tecnológico De Grupo Copo, S.L.U. | Composición química para obtención de poliuretano. |
| CN102516491B (zh) * | 2011-11-18 | 2013-10-02 | 宁波继峰汽车零部件股份有限公司 | 一种低回弹头枕泡沫及其制备方法 |
| JP6932038B2 (ja) * | 2012-08-16 | 2021-09-08 | 株式会社ポリシス | 軟質ポリウレタン樹脂、それを用いた防振性、制振性及び衝撃吸収性に優れた軟質ポリウレタン樹脂部材 |
| JP2014037488A (ja) * | 2012-08-16 | 2014-02-27 | Polysis:Kk | 軟質ポリウレタン樹脂、それを用いた防振性、制振性及び衝撃吸収性に優れた軟質ポリウレタン樹脂部材 |
| EP2917257B1 (en) * | 2012-11-07 | 2019-09-11 | Saudi Aramco Technologies Company | High strength polyurethane foam compositions and methods |
| KR101645117B1 (ko) * | 2015-01-02 | 2016-08-12 | 한국가스공사 | 경질 우레탄 폼 제조용 조성물 및 이의 제조 방법 |
| CN105820303B (zh) * | 2015-01-06 | 2018-08-21 | 上海延锋金桥汽车饰件系统有限公司 | 低密度汽车仪表板用聚氨酯泡沫及其制备方法和应用 |
| US20180044464A1 (en) * | 2015-02-27 | 2018-02-15 | Covestro Deutschland Ag | Viscoelastic flexible polyurethane foams based on polyether carbonate polyols |
| CN105131231A (zh) * | 2015-09-29 | 2015-12-09 | 东莞赛诺家居用品有限公司 | 记忆棉 |
| KR102075716B1 (ko) | 2017-05-18 | 2020-02-10 | (주)동림케미칼 | 낮은 경도 및 탄성을 가지는 발포체용 조성물 |
| CN109851749A (zh) * | 2019-01-21 | 2019-06-07 | 东莞市腾崴塑胶制品有限公司 | 一种硬棕海绵及制备方法 |
| JP2020152802A (ja) * | 2019-03-20 | 2020-09-24 | 三菱ケミカル株式会社 | 樹脂組成物、塗料組成物及び塗装物 |
| EP4255949A4 (en) * | 2020-12-03 | 2024-10-23 | Huntsman International LLC | POLYURETHANE FOAM COMPOSITION COMPRISING AN AROMATIC POLYESTER POLYOL COMPOUND AND PRODUCTS MADE THEREFROM |
| CN113583214A (zh) * | 2021-08-16 | 2021-11-02 | 吉林省华裕汽车零部件有限公司 | 一种慢回弹高阻尼软质聚氨酯泡沫及其制备方法 |
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| FI963254L (fi) * | 1994-12-21 | 1996-10-18 | Showa Denko Kk | Alifaattinen polyesterihartsi ja menetelmä sen valmistamiseksi |
| JP3490431B2 (ja) * | 2000-06-13 | 2004-01-26 | 東洋ゴム工業株式会社 | ポリウレタン発泡体の製造方法、ポリウレタン発泡体及び研磨シート |
| EP1248809B1 (en) * | 2000-07-28 | 2010-03-10 | Woodbridge Foam Corporation | Foamed isocyanate-based polymer having improved hardness properties and process for production thereof |
| KR20070100879A (ko) * | 2004-10-15 | 2007-10-12 | 대니스코 에이/에스 | 발포 이소시아네이트계 중합체, 이를 제조하기 위한 믹스및 이의 제조방법 |
| DE102005009166A1 (de) * | 2005-02-25 | 2006-08-31 | Basf Ag | Hochfunktionelle, hoch- oder hyperverzweigte Polycarbonate sowie deren Herstellung und Verwendung |
| JP4705803B2 (ja) * | 2005-04-18 | 2011-06-22 | 伊藤製油株式会社 | ポリカーボネートポリオール組成物及びそれを用いてなるポリウレタン樹脂 |
| KR101455878B1 (ko) * | 2006-11-15 | 2014-11-03 | 바스프 에스이 | 연질 폴리우레탄 발포체의 제조 방법 |
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2007
- 2007-12-06 ES ES07847918T patent/ES2359855T3/es active Active
- 2007-12-06 KR KR1020097014262A patent/KR20090097915A/ko not_active Ceased
- 2007-12-06 CN CNA200780051165XA patent/CN101600748A/zh active Pending
- 2007-12-06 CA CA002670725A patent/CA2670725A1/en not_active Abandoned
- 2007-12-06 EP EP07847918A patent/EP2099841B1/de not_active Not-in-force
- 2007-12-06 AT AT07847918T patent/ATE499395T1/de active
- 2007-12-06 US US12/518,668 patent/US20100036008A1/en not_active Abandoned
- 2007-12-06 MX MX2009006142A patent/MX2009006142A/es active IP Right Grant
- 2007-12-06 WO PCT/EP2007/063445 patent/WO2008071622A1/de not_active Ceased
- 2007-12-06 JP JP2009540725A patent/JP2010512439A/ja active Pending
- 2007-12-06 DE DE502007006564T patent/DE502007006564D1/de active Active
Also Published As
| Publication number | Publication date |
|---|---|
| ES2359855T3 (es) | 2011-05-27 |
| DE502007006564D1 (de) | 2011-04-07 |
| JP2010512439A (ja) | 2010-04-22 |
| WO2008071622A1 (de) | 2008-06-19 |
| KR20090097915A (ko) | 2009-09-16 |
| CN101600748A (zh) | 2009-12-09 |
| ATE499395T1 (de) | 2011-03-15 |
| MX2009006142A (es) | 2009-06-18 |
| EP2099841B1 (de) | 2011-02-23 |
| US20100036008A1 (en) | 2010-02-11 |
| EP2099841A1 (de) | 2009-09-16 |
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Legal Events
| Date | Code | Title | Description |
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| EEER | Examination request | ||
| EEER | Examination request |
Effective date: 20121205 |
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| FZDE | Discontinued |
Effective date: 20150320 |