CA2669471C - Metal-rich siliceous compositions and methods of producing same - Google Patents

Metal-rich siliceous compositions and methods of producing same Download PDF

Info

Publication number
CA2669471C
CA2669471C CA2669471A CA2669471A CA2669471C CA 2669471 C CA2669471 C CA 2669471C CA 2669471 A CA2669471 A CA 2669471A CA 2669471 A CA2669471 A CA 2669471A CA 2669471 C CA2669471 C CA 2669471C
Authority
CA
Canada
Prior art keywords
metal
colloidal silica
silica particles
colloidal
silicic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CA2669471A
Other languages
English (en)
French (fr)
Other versions
CA2669471A1 (en
Inventor
Brian T. Holland
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ChampionX LLC
Original Assignee
Nalco Co LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nalco Co LLC filed Critical Nalco Co LLC
Publication of CA2669471A1 publication Critical patent/CA2669471A1/en
Application granted granted Critical
Publication of CA2669471C publication Critical patent/CA2669471C/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/103Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16Alumino-silicates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/32Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3234Inorganic material layers
    • B01J20/3236Inorganic material layers containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44Palladium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66Silver or gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06Halogens; Compounds thereof
    • B01J27/128Halogens; Compounds thereof with iron group metals or platinum group metals
    • B01J27/13Platinum group metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/049Pillared clays
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/20Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
    • B01J35/23Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a colloidal state
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45Nanoparticles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/03Precipitation; Co-precipitation
    • B01J37/031Precipitation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04Mixing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00Silicon; Compounds thereof
    • C01B33/113Silicon oxides; Hydrates thereof
    • C01B33/12Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/14Colloidal silica, e.g. dispersions, gels, sols
    • C01B33/141Preparation of hydrosols or aqueous dispersions
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00Silicon; Compounds thereof
    • C01B33/113Silicon oxides; Hydrates thereof
    • C01B33/12Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/14Colloidal silica, e.g. dispersions, gels, sols
    • C01B33/146After-treatment of sols
    • C01B33/151After-treatment of sols by progressively adding a sol to a different sol, i.e. "build-up" of particles using a "heel"
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G55/00Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/70Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/64Nanometer sized, i.e. from 1-100 nanometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/12Surface area
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/14Pore volume

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Nanotechnology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Composite Materials (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Physics & Mathematics (AREA)
  • Catalysts (AREA)
  • Powder Metallurgy (AREA)
  • Silicon Compounds (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)
CA2669471A 2006-11-08 2007-11-08 Metal-rich siliceous compositions and methods of producing same Active CA2669471C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/557,548 US20080108497A1 (en) 2006-11-08 2006-11-08 Metal-rich siliceous compositions and methods of producing same
US11/557,548 2006-11-08
PCT/US2007/084095 WO2008058240A2 (en) 2006-11-08 2007-11-08 Metal-rich siliceous compositions and methods of producing same

Publications (2)

Publication Number Publication Date
CA2669471A1 CA2669471A1 (en) 2008-05-15
CA2669471C true CA2669471C (en) 2015-03-10

Family

ID=39360386

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2669471A Active CA2669471C (en) 2006-11-08 2007-11-08 Metal-rich siliceous compositions and methods of producing same

Country Status (6)

Country Link
US (2) US20080108497A1 (enExample)
EP (1) EP2079546B1 (enExample)
JP (1) JP5389660B2 (enExample)
CN (1) CN101534944B (enExample)
CA (1) CA2669471C (enExample)
WO (1) WO2008058240A2 (enExample)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060116865A1 (en) 1999-09-17 2006-06-01 Www.Uniscape.Com E-services translation utilizing machine translation and translation memory
US10227238B2 (en) * 2006-04-04 2019-03-12 Ecolab Usa Inc. Production and use of polysilicate particulate materials
US8450236B2 (en) * 2010-04-13 2013-05-28 Cristal Usa Inc. Supported precious metal catalysts via hydrothermal deposition
US8764974B2 (en) 2010-04-16 2014-07-01 Nalco Company Processing aids to improve the bitumen recovery and froth quality in oil sands extraction processes
BR112015002164A2 (pt) 2012-08-01 2017-07-04 Oxane Mat Inc pluralidade de propantes cerâmicos sinterizados, método para fabricar um propante cerâmico sinterizado, propante, propante cerâmico, propante cerâmico sinterizado e método para fabricar um propante cerâmico
US10087081B2 (en) 2013-03-08 2018-10-02 Ecolab Usa Inc. Process for producing high solids colloidal silica
CA2849415C (en) 2013-04-24 2017-02-28 Robert D. Skala Methods for fracturing subterranean formations
US9561473B2 (en) 2014-02-28 2017-02-07 Pall Corporation Charged hollow fiber membrane having hexagonal voids
US9446355B2 (en) 2014-02-28 2016-09-20 Pall Corporation Porous polymeric membrane with high void volume
US9610548B2 (en) 2014-02-28 2017-04-04 Pall Corporation Composite porous polymeric membrane with high void volume
US9302228B2 (en) 2014-02-28 2016-04-05 Pall Corporation Charged porous polymeric membrane with high void volume
US9737860B2 (en) 2014-02-28 2017-08-22 Pall Corporation Hollow fiber membrane having hexagonal voids
US9764292B2 (en) 2014-02-28 2017-09-19 Pall Corporation Porous polymeric membrane with high void volume
US9776142B2 (en) 2014-02-28 2017-10-03 Pall Corporation Porous polymeric membrane with high void volume
US9309126B2 (en) 2014-02-28 2016-04-12 Pall Corporation Rapidly dissolvable nanoparticles
US9868902B2 (en) * 2014-07-17 2018-01-16 Soulbrain Co., Ltd. Composition for etching
US10421059B2 (en) * 2014-10-24 2019-09-24 Samsung Electronics Co., Ltd. Gas-adsorbing material and vacuum insulation material including the same
KR101589953B1 (ko) * 2014-10-29 2016-01-29 한국원자력연구원 알루미늄을 함유하는 핵분열생성 몰리브덴 생성 공정에서의 침전여과법을 이용한 알루미늄의 제거방법
EP3325590B1 (en) 2015-07-18 2020-09-30 Ecolab USA Inc. Chemical additives to improve oil separation in stillage process operations
US10227525B2 (en) 2016-01-05 2019-03-12 Baker Hughes, A Ge Company, Llc Rare earth materials to enhance properties of ceramic particles
SA117380521B1 (ar) * 2017-03-26 2022-02-06 مدينة الملك عبدالعزيز للعلوم والتقنية عملية لتحضير حفاز حبيبات البلاديوم النانونية المدعمه بالسيليكا واستخدامه في عملية تحضير الانيلينات البنزيلية
CN110482559B (zh) * 2019-09-16 2021-03-30 广东惠和硅制品有限公司 一种铝改性酸性硅溶胶及其制备方法和应用
PH12019050291A1 (en) * 2019-11-20 2021-08-23 Univ Of The Philippines Los Ba¤Os Modified Nanostructured Silica Materials for Heavy Metal Removal from Contaminated Water and the Methods of Production Thereof
CN111908951B (zh) * 2020-08-14 2024-02-09 云浮市豪野材料科技有限公司 一种耐高温阻燃建筑复合石材的生产工艺
CN115212877A (zh) * 2022-06-28 2022-10-21 深圳市添金利新材料科技有限公司 一种耐热性纳米催化剂及其光化学驱动制备方法

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2892797A (en) * 1956-02-17 1959-06-30 Du Pont Process for modifying the properties of a silica sol and product thereof
US3637819A (en) * 1967-12-30 1972-01-25 Knapsack Ag Process for the manufacture of unsaturated esters of carboxylic acids
US3575888A (en) * 1969-04-28 1971-04-20 Shell Oil Co Silver catalyst
DE1964085A1 (de) * 1969-12-22 1971-07-22 Knapsack Ag Verfahren zur Herstellung von Methallylacetat
US3745126A (en) * 1971-04-22 1973-07-10 Du Pont Stable positively charged alumina coated silica sols
US3864142A (en) * 1971-04-26 1975-02-04 Nalco Chemical Co Metal oxide sols
JPS514097A (en) * 1974-07-02 1976-01-13 Tokuyama Soda Kk Kasankasuisono seizohoho
US3954496A (en) * 1974-10-09 1976-05-04 E. I. Du Pont De Nemours And Company Preparation of dense silica-encapsulated aluminum flake pigment treated with a carboxylic chromic chloride
JPS5271000A (en) * 1975-12-10 1977-06-13 Tokuyama Soda Co Ltd Production of hydrogen peroxide
US4451388A (en) * 1981-11-02 1984-05-29 Nalco Chemical Company Preparation of aluminum oxide coated silica sols using ultrafiltration
NO300125B1 (no) * 1988-03-16 1997-04-14 Nissan Chemical Ind Ltd Stabil væskeformig silikasol, samt fremgangsmåte ved fremstilling derav
US5015453A (en) * 1989-04-28 1991-05-14 W. R. Grace & Co.-Conn. Crystalline group IVA metal-containing molecular sieve compositions
US5188660A (en) * 1991-10-16 1993-02-23 E. I. Du Pont De Nemours And Company Process for making finely divided particles of silver metals
ATE280750T1 (de) * 1995-07-18 2004-11-15 Asahi Kasei Chemicals Corp Verfahren zur herstellung von carbonsäureestern
US6051672A (en) * 1998-08-24 2000-04-18 Dow Corning Corporation Method for making hydrophobic non-aggregated colloidal silica
US6358882B1 (en) * 1998-12-08 2002-03-19 The Standard Oil Company Fluid bed vinyl acetate catalyst
CN1312233C (zh) * 1999-01-11 2007-04-25 昭和电工株式会社 化妆料、表面疏水化二氧化硅被覆金属氧化物粒子、二氧化硅被覆金属氧化物溶胶、以及它们的制法
EP1456313A1 (en) 2001-12-20 2004-09-15 AKZO Nobel N.V. Cerium oxide coated silica particles and method for production thereof
US6916514B2 (en) * 2003-07-18 2005-07-12 Eastman Kodak Company Cationic shelled particle
US20050234136A1 (en) * 2004-04-19 2005-10-20 Holland Brian T Colloidal compositions and methods of preparing same
DE102005021623A1 (de) * 2005-05-04 2006-11-09 Sasol Germany Gmbh Verfahren zur Herstellung eines temperaturstabilen TiO2/SiO2 - Mischoxids und dessen Verwendung als Katalysatorträger

Also Published As

Publication number Publication date
US8003707B2 (en) 2011-08-23
JP2010509496A (ja) 2010-03-25
WO2008058240A3 (en) 2008-08-14
US20100074974A1 (en) 2010-03-25
WO2008058240A2 (en) 2008-05-15
EP2079546B1 (en) 2020-08-12
CN101534944A (zh) 2009-09-16
EP2079546A2 (en) 2009-07-22
EP2079546A4 (en) 2012-08-29
JP5389660B2 (ja) 2014-01-15
US20080108497A1 (en) 2008-05-08
CN101534944B (zh) 2013-01-16
CA2669471A1 (en) 2008-05-15

Similar Documents

Publication Publication Date Title
CA2669471C (en) Metal-rich siliceous compositions and methods of producing same
EP1744825B1 (en) Colloidal compositions and methods of preparing same
EP2074061B1 (en) Silica-coated metal oxide sols having variable metal oxide to silica ration
KR101417004B1 (ko) 폴리실리케이트 미립자 물질의 제조 및 이용
US8658127B2 (en) Method of manufacturing mesoporous zeolite agglomerates
JP6379273B2 (ja) ゼオライト及びゼオタイプに金属ナノ粒子を組み入れる一般的方法
da Silva et al. Functionalization methods of SBA-15 mesoporous molecular sieve: A brief overview
JP2004528158A (ja) ナノメートル寸法の粒子を組み込んだメソ構造触媒
JP5021395B2 (ja) 複合シリカ粒子
CN105377424A (zh) 生产沸石包封的纳米颗粒的方法
KR20110073443A (ko) 가변성의 기공도 및 표면 모폴로지를 갖는 실리카질 물질 및 이의 합성방법
JP2008239801A (ja) 貴金属微粒子担持固体高分子材料、その調製方法および触媒
KR101995857B1 (ko) 주름이 형성된 실리카 나노입자 코어와 금 레이어 쉘을 포함하는 나노입자, 이의 생산방법 및 응용
JP7449123B2 (ja) マイクロ孔を有する物質で被覆された遷移金属担持体およびその製造方法
JP2008246392A (ja) 微粒子含有複合体及びその製造方法
JP4496630B2 (ja) 金属細線触媒
JP5057021B2 (ja) 球状シリカ系メソ多孔体及びその製造方法、並びにそれを用いた塩基性色素吸着材
CN116174012B (zh) 金属元素与分子筛复合催化材料及其制备方法和应用
WO2025002974A1 (en) Hydrogenation catalyst for the manufacture of hydrogen peroxide
CN115485062A (zh) 负载型过渡金属纳米颗粒催化剂及其作为加氢催化剂的用途

Legal Events

Date Code Title Description
EEER Examination request