CA2614591C - Electrocatalysts and additives for the oxidation of solid fuels - Google Patents

Electrocatalysts and additives for the oxidation of solid fuels Download PDF

Info

Publication number
CA2614591C
CA2614591C CA2614591A CA2614591A CA2614591C CA 2614591 C CA2614591 C CA 2614591C CA 2614591 A CA2614591 A CA 2614591A CA 2614591 A CA2614591 A CA 2614591A CA 2614591 C CA2614591 C CA 2614591C
Authority
CA
Canada
Prior art keywords
coal
electrolytic cell
anode
oxidation
cell
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CA2614591A
Other languages
English (en)
French (fr)
Other versions
CA2614591A1 (en
Inventor
Gerardine Botte
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ohio University
Original Assignee
Ohio University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ohio University filed Critical Ohio University
Publication of CA2614591A1 publication Critical patent/CA2614591A1/en
Application granted granted Critical
Publication of CA2614591C publication Critical patent/CA2614591C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/06Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/091Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
    • C25B11/097Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds comprising two or more noble metals or noble metal alloys
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B5/00Electrogenerative processes, i.e. processes for producing compounds in which electricity is generated simultaneously
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90Selection of catalytic material
    • H01M4/92Metals of platinum group
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90Selection of catalytic material
    • H01M4/92Metals of platinum group
    • H01M4/925Metals of platinum group supported on carriers, e.g. powder carriers
    • H01M4/926Metals of platinum group supported on carriers, e.g. powder carriers on carbon or graphite
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/08Fuel cells with aqueous electrolytes
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06Integration with other chemical processes
    • C01B2203/066Integration with other chemical processes with fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Sustainable Energy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
  • Catalysts (AREA)
CA2614591A 2005-05-06 2006-05-08 Electrocatalysts and additives for the oxidation of solid fuels Expired - Lifetime CA2614591C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US67872505P 2005-05-06 2005-05-06
US60/678,725 2005-05-06
PCT/US2006/017641 WO2006121981A2 (en) 2005-05-06 2006-05-08 Electrocatalysts and additives for the oxidation of solid fuels

Publications (2)

Publication Number Publication Date
CA2614591A1 CA2614591A1 (en) 2006-11-16
CA2614591C true CA2614591C (en) 2013-12-31

Family

ID=37397180

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2614591A Expired - Lifetime CA2614591C (en) 2005-05-06 2006-05-08 Electrocatalysts and additives for the oxidation of solid fuels

Country Status (6)

Country Link
US (1) US8758951B2 (https=)
EP (1) EP1889317B1 (https=)
JP (2) JP5241488B2 (https=)
CN (1) CN101496208B (https=)
CA (1) CA2614591C (https=)
WO (1) WO2006121981A2 (https=)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5241488B2 (ja) * 2005-05-06 2013-07-17 オハイオ ユニバーシティ 固体燃料スラリーから水素を生成する方法
US8303781B2 (en) 2007-10-15 2012-11-06 Ohio University Electrolytic cells and methods for the production of ammonia and hydrogen
US7883802B2 (en) 2008-06-16 2011-02-08 Robert Danziger Systems and methods for electrochemical power generation
US8029759B2 (en) * 2009-03-27 2011-10-04 Ohio University Pretreatment method for the synthesis of carbon nanotubes and carbon nanostructures from coal and carbon chars
WO2010120882A1 (en) 2009-04-14 2010-10-21 Ohio University Removal of metals from water
FR2950365B1 (fr) * 2009-09-21 2012-07-06 Commissariat Energie Atomique Procede de depot d'un metal sur une couche en carbone poreux
KR101800476B1 (ko) 2010-04-02 2017-11-22 오하이오 유니버시티 우레아의 전기분해를 통한 선택적 촉매 환원
US8562929B2 (en) 2010-04-02 2013-10-22 Ohio University Selective catalytic reduction via electrolysis of urea
KR20140012016A (ko) * 2010-07-28 2014-01-29 마그네토 스페셜 아노즈 비. 브이. 전극촉매
JP2015523944A (ja) * 2012-04-09 2015-08-20 ナノコンプ テクノロジーズ,インク. 導電性を増加させるために導電性堆積物を有しているナノチューブ材料
CN103132100B (zh) * 2013-03-22 2015-06-17 上海交通大学 一种从煤生产纯净氢气和二氧化碳的工艺方法
JP6797685B2 (ja) 2013-10-25 2020-12-09 オハイオ・ユニバーシティ グラフェンで覆われた電極を含む電気化学セル
CN110804739A (zh) * 2019-10-22 2020-02-18 国电新能源技术研究院有限公司 一种电解低质煤直接制氢的系统及方法
CN114806659B (zh) * 2021-01-19 2023-08-08 中国科学院上海硅酸盐研究所 煤制甲烷电化学合成器及方法
CN114134511A (zh) * 2022-01-04 2022-03-04 哈尔滨工业大学 一种两步法电解水煤浆制氢的方法

Family Cites Families (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3650838A (en) * 1965-09-30 1972-03-21 United Aircraft Corp Electrochemical cell with platinum-ruthenium electrode and method of using with ammonia
US4141801A (en) * 1977-12-15 1979-02-27 The United States Of America As Represented By The Secretary Of The Army Fuel cell anode electrode, method of making the fuel cell anode electrode, and fuel cell containing the fuel cell anode electrode
US4226683A (en) * 1979-08-09 1980-10-07 Vaseen Vesper A Method and apparatus for hydrogen production in an absorber liquid by electrochemical of coal and water
US4430175A (en) * 1981-12-22 1984-02-07 Rutgerswerke Aktiengesellschaft Process for the electrochemical conversion of coal and use of the reaction products
US4388162A (en) * 1982-02-08 1983-06-14 Institute Of Gas Technology Continuous flow electrochemical cell and process
US4541989A (en) * 1983-01-27 1985-09-17 Oxytech, Inc. Process and device for the generation of ozone via the anodic oxidation of water
US4453594A (en) * 1983-04-25 1984-06-12 The United States Of America As Represented By The Secretary Of The Interior Solution mining of coal by electrolysis
US4608137A (en) * 1983-05-23 1986-08-26 Chevron Research Company Production of hydrogen at the cathode of an electrolytic cell
DE3583170D1 (de) 1984-04-02 1991-07-18 Hitachi Ltd Elektrode fuer brennstoffzelle, verfahren zu ihrer herstellung und diese elektrode verwendende brennstoffzelle.
JPS60262989A (ja) * 1984-06-08 1985-12-26 Mitsui Eng & Shipbuild Co Ltd 電解槽
US4643809A (en) * 1985-10-25 1987-02-17 The United States Of America As Represented By The United States Department Of Energy Process for electrochemically gasifying coal using electromagnetism
US4752364A (en) * 1986-05-19 1988-06-21 Delphi Research, Inc. Method for treating organic waste material and a catalyst/cocatalyst composition useful therefor
US6683783B1 (en) * 1997-03-07 2004-01-27 William Marsh Rice University Carbon fibers formed from single-wall carbon nanotubes
US7098163B2 (en) * 1998-08-27 2006-08-29 Cabot Corporation Method of producing membrane electrode assemblies for use in proton exchange membrane and direct methanol fuel cells
GB2348209B (en) * 1999-03-24 2001-05-09 Ionex Ltd Water purification process
JP3601673B2 (ja) * 1999-04-23 2004-12-15 栗田工業株式会社 被酸化性汚染物質含有水の電解処理方法及び電解処理用電極
DE19944989A1 (de) * 1999-09-20 2001-03-22 Basf Ag Verfahren zur elektrolytischen Umwandlung von Furanderivaten
DE10037072A1 (de) 2000-07-29 2002-02-14 Omg Ag & Co Kg Membran-Elektrodeneinheit für Polymerelektrolyt-Brennstoffzellen und Verfahren zu ihrer Herstellung
US6444337B1 (en) 2000-09-26 2002-09-03 Energetics, Inc. Fuel cell with low cathodic polarization and high power density
DE10196986T5 (de) 2000-11-30 2004-05-06 Rmg Services Pty. Ltd. Elektrolytische kommerzielle Herstellung von Wasserstoff aus Kohlenwasserstoffverbindungen
US6627035B2 (en) * 2001-01-24 2003-09-30 Gas Technology Institute Gas diffusion electrode manufacture and MEA fabrication
US6670301B2 (en) * 2001-03-19 2003-12-30 Brookhaven Science Associates Llc Carbon monoxide tolerant electrocatalyst with low platinum loading and a process for its preparation
JP3981565B2 (ja) * 2001-03-21 2007-09-26 守信 遠藤 触媒金属を担持した気相成長法による炭素繊維
CN1181583C (zh) * 2001-04-10 2004-12-22 大连新源动力股份有限公司 一种质子交换膜燃料电池用抗co复合催化层及其制备
US6695963B2 (en) * 2001-07-05 2004-02-24 Asahi Kasei Kabushiki Kaisha Organic electrolysis reactor for performing an electrolytic oxidation reaction and method for producing a chemical compound by using the same
TW200304503A (en) * 2002-03-20 2003-10-01 Asahi Chemical Ind Electrode for generation of hydrogen
JP3637392B2 (ja) * 2002-04-08 2005-04-13 独立行政法人産業技術総合研究所 燃料電池
US7144476B2 (en) * 2002-04-12 2006-12-05 Sgl Carbon Ag Carbon fiber electrode substrate for electrochemical cells
JP4746263B2 (ja) 2002-10-11 2011-08-10 勇 内田 エタノール酸化用電極触媒およびそれを用いた直接エタノール型燃料電池、電子機器
US7105148B2 (en) * 2002-11-26 2006-09-12 General Motors Corporation Methods for producing hydrogen from a fuel
AU2003300048A1 (en) * 2002-12-31 2004-07-29 Northern Illinois University Metal-coated carbon surfaces for use in fuel cells
CN1274044C (zh) * 2003-05-31 2006-09-06 中国科学院大连化学物理研究所 一种用于燃料电池的多孔气体扩散电极及电极的制备方法
US20050112450A1 (en) * 2003-09-08 2005-05-26 Intematix Corporation Low platinum fuel cell catalysts and method for preparing the same
US7485211B2 (en) 2003-10-10 2009-02-03 Ohio University Electro-catalysts for the oxidation of ammonia in alkaline media
NO325620B1 (no) 2003-10-21 2008-06-30 Revolt Technology Ltd Elektrode, fremgangsmate for fremstilling derav, metall/luft-brenselcelle og metallhydrid-battericelle
US7309480B2 (en) * 2004-04-16 2007-12-18 H2Gen Innovations, Inc. Catalyst for hydrogen generation through steam reforming of hydrocarbons
JP5241488B2 (ja) * 2005-05-06 2013-07-17 オハイオ ユニバーシティ 固体燃料スラリーから水素を生成する方法

Also Published As

Publication number Publication date
CA2614591A1 (en) 2006-11-16
WO2006121981A3 (en) 2009-04-23
US20090145750A1 (en) 2009-06-11
US8758951B2 (en) 2014-06-24
EP1889317A2 (en) 2008-02-20
JP5241488B2 (ja) 2013-07-17
EP1889317A4 (en) 2009-11-04
CN101496208A (zh) 2009-07-29
JP2008542527A (ja) 2008-11-27
EP1889317B1 (en) 2017-09-06
JP2013136838A (ja) 2013-07-11
WO2006121981A2 (en) 2006-11-16
CN101496208B (zh) 2012-06-13

Similar Documents

Publication Publication Date Title
Chen et al. NiCoP nanoleaves array for electrocatalytic alkaline H2 evolution and overall water splitting
JP2013136838A (ja) 固体燃料の酸化のための電解触媒および添加剤
Jiang et al. Partial sulfidation strategy to NiCo-LDH@ NiCoS coupled with NiFe-LDH for highly efficient overall water splitting
Patil et al. Electrooxidation of coal slurries on different electrode materials
Ghahremani et al. Simultaneous hydrogen evolution and lignin depolymerization using NiSn electrocatalysts in a biomass-depolarized electrolyzer
Yu et al. Bimetallic platinum–iron electrocatalyst supported on carbon fibers for coal electrolysis
Liu et al. Green fabrication of nanostructured Ni (OH) 2/Ni/Carbon felt electrodes with water-containing deep eutectic solvent for enhanced water electrolysis performance
Lan et al. Enhancing oxygen reduction reaction in microbial fuel cell by Cu-metal organic framework@ Fe-metal organic framework (Cu-MOF@ Fe-MOF) as cathode catalyst
Du et al. Cu-based hollow nanotubes with enhanced surface roughness and Chloridion-Enriched environment for Seawater-Splitting
Lv et al. Ultrafine IrNi nanoparticles supported onto titanium nitride as low-iridium and highly active OER electrocatalysts for proton exchange membrane water electrolysis
Zhao et al. Ni3S2/Co9S8 directly grown on nickel foam as an environmentally friendly electrocatalyst for seawater splitting
Pan et al. Self-supported Fe, Mn-co-doped NiCo2Se4 nanorods on nickel foam for enhanced electrocatalytic performance in wide pH range
Fetohi et al. Nickel sulfide–transition metal sulfides bi-electrocatalyst supported on Nickel Foam for water splitting
Shaarawy et al. Green hydrogen generation in alkaline solution using electrodeposited Ni-Co-nano-graphene thin film cathode
Du et al. 1D Copper-based nanowire decorated with trimetallic nanoparticles affording abundant edges toward hydrogen generation in wide pH range
Wang et al. Ni2P (O)–Fe2P (O)/CeOx as high effective bifunctional catalyst for overall water splitting
Fathi et al. The enhancement of TiO2 nanotubes performance towards methanol oxidation after surface functionalization with exfoliated graphene and nickel oxide
Zhang et al. Cation-anion dual doping monolithic anode for high-stable intermittent anion exchange membrane water electrolysis
Liu et al. Vanadium-doped Ni3S2 nanosheets for low-overpotential hydrogen evolution and sulfide removal
Fan et al. Enhanced Hydrogen Production via Water Electrolysis Using Fe‐Loaded Biomass‐Derived Self‐Supporting Sacrificial Anode
Ma et al. Interfacial anchoring versus surface exposure: tuning IrOx–Co3O4 interaction for stable industrial water splitting
Santos et al. Towards the hydrogen economy—a review of the parameters that influence the efficiency of alkaline water electrolyzers. Energies 2021; 14: 3193
Li et al. CeOx implantation into NiFe-LDH induced intermediate adsorption and desorption route modulation endowing 17.06% STH in long-term solar-driven water electrolysis
Nayak et al. Recycling waste plastics and biowaste into high-performance NiCo-MOF/activated carbon electrocatalyst for overall water splitting
Xu et al. Enhancing the trifunctional electrocatalytic activity of Fe-Co-Ni multi-component alloys using a zinc dealloying strategy

Legal Events

Date Code Title Description
EEER Examination request
MPN Maintenance fee for patent paid

Free format text: FEE DESCRIPTION TEXT: MF (PATENT, 19TH ANNIV.) - STANDARD

Year of fee payment: 19

U00 Fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U00-U101 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE REQUEST RECEIVED

Effective date: 20250502

U11 Full renewal or maintenance fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-U102 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE FEE PAYMENT PAID IN FULL

Effective date: 20250502