CA2591396A1

CA2591396A1 - Use of sub-micron copper salt particles in wood preservation

Use of sub-micron copper salt particles in wood preservation Download PDF

Info

Publication number: CA2591396A1
Authority: CA; Canada
Prior art keywords: copper; particles; wood; slurry; hydroxide
Prior art date: 2004-12-13
Legal status : Abandoned

Application number

CA002591396A

Other languages

English (en)

French (fr)

Inventor

H. Wayne Richardson

Robert L. Hodge

Current Assignee

Phibro Tech Inc

Original Assignee

Individual

Priority date

2004-12-13

Filing date

2005-12-12

Publication date

2006-06-22

2005-12-12 Application filed by Individual filed Critical Individual

2006-06-22 Publication of CA2591396A1 publication Critical patent/CA2591396A1/en

Status Abandoned legal-status Critical Current

Links

239000002245 particle Substances 0.000 title claims abstract description 432
239000002023 wood Substances 0.000 title claims abstract description 227
150000001879 copper Chemical class 0.000 title claims abstract description 78
238000004321 preservation Methods 0.000 title description 6
239000002002 slurry Substances 0.000 claims abstract description 182
JJLJMEJHUUYSSY-UHFFFAOYSA-L Copper hydroxide Chemical compound [OH-].[OH-].[Cu+2] JJLJMEJHUUYSSY-UHFFFAOYSA-L 0.000 claims abstract description 167
229910001956 copper hydroxide Inorganic materials 0.000 claims abstract description 136
239000005750 Copper hydroxide Substances 0.000 claims abstract description 133
238000000034 method Methods 0.000 claims abstract description 93
239000003139 biocide Substances 0.000 claims abstract description 89
239000002270 dispersing agent Substances 0.000 claims abstract description 79
230000003115 biocidal effect Effects 0.000 claims abstract description 53
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 34
GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 claims abstract description 31
229940116318 copper carbonate Drugs 0.000 claims abstract description 29
239000005752 Copper oxychloride Substances 0.000 claims abstract description 15
125000000129 anionic group Chemical group 0.000 claims abstract description 15
LITQZINTSYBKIU-UHFFFAOYSA-F tetracopper;hexahydroxide;sulfate Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Cu+2].[Cu+2].[Cu+2].[Cu+2].[O-]S([O-])(=O)=O LITQZINTSYBKIU-UHFFFAOYSA-F 0.000 claims abstract description 14
HKMOPYJWSFRURD-UHFFFAOYSA-N chloro hypochlorite;copper Chemical compound [Cu].ClOCl HKMOPYJWSFRURD-UHFFFAOYSA-N 0.000 claims abstract description 13
239000005848 Tribasic copper sulfate Substances 0.000 claims abstract description 12
DOVLHZIEMGDZIW-UHFFFAOYSA-N [Cu+3].[O-]B([O-])[O-] Chemical compound [Cu+3].[O-]B([O-])[O-] DOVLHZIEMGDZIW-UHFFFAOYSA-N 0.000 claims abstract description 9
RAOSIAYCXKBGFE-UHFFFAOYSA-K [Cu+3].[O-]P([O-])([O-])=O Chemical compound [Cu+3].[O-]P([O-])([O-])=O RAOSIAYCXKBGFE-UHFFFAOYSA-K 0.000 claims abstract description 7
XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 claims abstract description 5
ZZBBCSFCMKWYQR-UHFFFAOYSA-N copper;dioxido(oxo)silane Chemical compound [Cu+2].[O-][Si]([O-])=O ZZBBCSFCMKWYQR-UHFFFAOYSA-N 0.000 claims abstract description 4
239000010949 copper Substances 0.000 claims description 227
229910052802 copper Inorganic materials 0.000 claims description 222
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 219
239000000463 material Substances 0.000 claims description 136
238000003801 milling Methods 0.000 claims description 95
239000011777 magnesium Substances 0.000 claims description 50
229910052749 magnesium Inorganic materials 0.000 claims description 47
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 46
239000011701 zinc Substances 0.000 claims description 31
229910052725 zinc Inorganic materials 0.000 claims description 30
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical group [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 27
150000001412 amines Chemical class 0.000 claims description 23
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 23
229910019142 PO4 Inorganic materials 0.000 claims description 22
238000001238 wet grinding Methods 0.000 claims description 21
238000000576 coating method Methods 0.000 claims description 20
QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 19
239000011248 coating agent Substances 0.000 claims description 19
239000010452 phosphate Substances 0.000 claims description 19
239000005751 Copper oxide Substances 0.000 claims description 17
229910000431 copper oxide Inorganic materials 0.000 claims description 17
238000006243 chemical reaction Methods 0.000 claims description 15
239000007788 liquid Substances 0.000 claims description 14
239000003795 chemical substances by application Substances 0.000 claims description 12
UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 claims description 4
239000003979 granulating agent Substances 0.000 claims description 3
229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 3
229910021511 zinc hydroxide Inorganic materials 0.000 claims description 3
229940007718 zinc hydroxide Drugs 0.000 claims description 3
BAERPNBPLZWCES-UHFFFAOYSA-N (2-hydroxy-1-phosphonoethyl)phosphonic acid Chemical compound OCC(P(O)(O)=O)P(O)(O)=O BAERPNBPLZWCES-UHFFFAOYSA-N 0.000 claims description 2
229940091250 magnesium supplement Drugs 0.000 claims 5
239000000203 mixture Substances 0.000 description 61
239000003755 preservative agent Substances 0.000 description 50
-1 copper amines Chemical class 0.000 description 46
239000000047 product Substances 0.000 description 46
150000003839 salts Chemical class 0.000 description 38
238000009826 distribution Methods 0.000 description 30
PXMNMQRDXWABCY-UHFFFAOYSA-N 1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-ylmethyl)pentan-3-ol Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)CCC1=CC=C(Cl)C=C1 PXMNMQRDXWABCY-UHFFFAOYSA-N 0.000 description 29
239000005839 Tebuconazole Substances 0.000 description 29
238000011282 treatment Methods 0.000 description 24
230000002335 preservative effect Effects 0.000 description 23
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 22
239000012141 concentrate Substances 0.000 description 20
239000007924 injection Substances 0.000 description 20
238000002347 injection Methods 0.000 description 20
235000021317 phosphate Nutrition 0.000 description 20
238000002386 leaching Methods 0.000 description 18
239000003171 wood protecting agent Substances 0.000 description 18
238000004090 dissolution Methods 0.000 description 16
239000008187 granular material Substances 0.000 description 16
239000010875 treated wood Substances 0.000 description 16
230000000694 effects Effects 0.000 description 15
239000004094 surface-active agent Substances 0.000 description 15
GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 15
238000009472 formulation Methods 0.000 description 14
239000000243 solution Substances 0.000 description 14
238000005054 agglomeration Methods 0.000 description 13
230000002776 aggregation Effects 0.000 description 13
AEJIMXVJZFYIHN-UHFFFAOYSA-N copper;dihydrate Chemical compound O.O.[Cu] AEJIMXVJZFYIHN-UHFFFAOYSA-N 0.000 description 13
239000000839 emulsion Substances 0.000 description 13
230000008569 process Effects 0.000 description 13
238000011068 loading method Methods 0.000 description 12
238000004519 manufacturing process Methods 0.000 description 12
229920000058 polyacrylate Polymers 0.000 description 12
150000001875 compounds Chemical class 0.000 description 11
239000002105 nanoparticle Substances 0.000 description 11
239000011148 porous material Substances 0.000 description 11
238000012360 testing method Methods 0.000 description 11
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
230000006870 function Effects 0.000 description 10
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 10
239000003381 stabilizer Substances 0.000 description 10
239000012530 fluid Substances 0.000 description 9
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 9
239000000080 wetting agent Substances 0.000 description 9
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
239000003513 alkali Substances 0.000 description 8
230000000052 comparative effect Effects 0.000 description 8
239000003085 diluting agent Substances 0.000 description 8
229910052751 metal Inorganic materials 0.000 description 8
239000002184 metal Substances 0.000 description 8
239000003921 oil Substances 0.000 description 8
238000001556 precipitation Methods 0.000 description 8
239000002253 acid Substances 0.000 description 7
150000008044 alkali metal hydroxides Chemical class 0.000 description 7
150000001450 anions Chemical class 0.000 description 7
239000002585 base Substances 0.000 description 7
125000001477 organic nitrogen group Chemical group 0.000 description 7
230000035515 penetration Effects 0.000 description 7
229920000642 polymer Polymers 0.000 description 7
150000003852 triazoles Chemical group 0.000 description 7
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 6
239000005747 Chlorothalonil Substances 0.000 description 6
125000004429 atom Chemical group 0.000 description 6
239000011324 bead Substances 0.000 description 6
CRQQGFGUEAVUIL-UHFFFAOYSA-N chlorothalonil Chemical compound ClC1=C(Cl)C(C#N)=C(Cl)C(C#N)=C1Cl CRQQGFGUEAVUIL-UHFFFAOYSA-N 0.000 description 6
239000011159 matrix material Substances 0.000 description 6
RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 6
239000012071 phase Substances 0.000 description 6
230000002829 reductive effect Effects 0.000 description 6
229910001928 zirconium oxide Inorganic materials 0.000 description 6
229910000831 Steel Inorganic materials 0.000 description 5
239000000654 additive Substances 0.000 description 5
239000002518 antifoaming agent Substances 0.000 description 5
VEMKTZHHVJILDY-UXHICEINSA-N bioresmethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-UXHICEINSA-N 0.000 description 5
150000001768 cations Chemical class 0.000 description 5
230000003247 decreasing effect Effects 0.000 description 5
YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 5
XWPZUHJBOLQNMN-UHFFFAOYSA-N metconazole Chemical compound C1=NC=NN1CC1(O)C(C)(C)CCC1CC1=CC=C(Cl)C=C1 XWPZUHJBOLQNMN-UHFFFAOYSA-N 0.000 description 5
229910052757 nitrogen Inorganic materials 0.000 description 5
239000002244 precipitate Substances 0.000 description 5
241000894007 species Species 0.000 description 5
239000010959 steel Substances 0.000 description 5
239000000126 substance Substances 0.000 description 5
239000000725 suspension Substances 0.000 description 5
239000005906 Imidacloprid Substances 0.000 description 4
239000005868 Metconazole Substances 0.000 description 4
239000005822 Propiconazole Substances 0.000 description 4
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
229910052783 alkali metal Inorganic materials 0.000 description 4
229910021529 ammonia Inorganic materials 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
TWFZGCMQGLPBSX-UHFFFAOYSA-N carbendazim Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 description 4
239000002738 chelating agent Substances 0.000 description 4
238000004040 coloring Methods 0.000 description 4
230000007797 corrosion Effects 0.000 description 4
238000005260 corrosion Methods 0.000 description 4
239000013530 defoamer Substances 0.000 description 4
239000000835 fiber Substances 0.000 description 4
239000000945 filler Substances 0.000 description 4
150000004679 hydroxides Chemical class 0.000 description 4
229940056881 imidacloprid Drugs 0.000 description 4
239000010410 layer Substances 0.000 description 4
238000002156 mixing Methods 0.000 description 4
150000002823 nitrates Chemical class 0.000 description 4
IZUPBVBPLAPZRR-UHFFFAOYSA-N pentachlorophenol Chemical compound OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IZUPBVBPLAPZRR-UHFFFAOYSA-N 0.000 description 4
229920000193 polymethacrylate Polymers 0.000 description 4
STJLVHWMYQXCPB-UHFFFAOYSA-N propiconazole Chemical compound O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 STJLVHWMYQXCPB-UHFFFAOYSA-N 0.000 description 4
239000003352 sequestering agent Substances 0.000 description 4
239000007787 solid Substances 0.000 description 4
239000002904 solvent Substances 0.000 description 4
238000010561 standard procedure Methods 0.000 description 4
ZMYFCFLJBGAQRS-IAGOWNOFSA-N (2S,3R)-epoxiconazole Chemical compound C1=CC(F)=CC=C1[C@]1(CN2N=CN=C2)[C@@H](C=2C(=CC=CC=2)Cl)O1 ZMYFCFLJBGAQRS-IAGOWNOFSA-N 0.000 description 3
YTOPFCCWCSOHFV-UHFFFAOYSA-N 2,6-dimethyl-4-tridecylmorpholine Chemical compound CCCCCCCCCCCCCN1CC(C)OC(C)C1 YTOPFCCWCSOHFV-UHFFFAOYSA-N 0.000 description 3
STMIIPIFODONDC-UHFFFAOYSA-N 2-(2,4-dichlorophenyl)-1-(1H-1,2,4-triazol-1-yl)hexan-2-ol Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(O)(CCCC)CN1C=NC=N1 STMIIPIFODONDC-UHFFFAOYSA-N 0.000 description 3
UFNOUKDBUJZYDE-UHFFFAOYSA-N 2-(4-chlorophenyl)-3-cyclopropyl-1-(1H-1,2,4-triazol-1-yl)butan-2-ol Chemical compound C1=NC=NN1CC(O)(C=1C=CC(Cl)=CC=1)C(C)C1CC1 UFNOUKDBUJZYDE-UHFFFAOYSA-N 0.000 description 3
RQDJADAKIFFEKQ-UHFFFAOYSA-N 4-(4-chlorophenyl)-2-phenyl-2-(1,2,4-triazol-1-ylmethyl)butanenitrile Chemical compound C1=CC(Cl)=CC=C1CCC(C=1C=CC=CC=1)(C#N)CN1N=CN=C1 RQDJADAKIFFEKQ-UHFFFAOYSA-N 0.000 description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
239000005757 Cyproconazole Substances 0.000 description 3
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 3
230000002378 acidificating effect Effects 0.000 description 3
229910001854 alkali hydroxide Inorganic materials 0.000 description 3
229910052782 aluminium Inorganic materials 0.000 description 3
AKNQMEBLVAMSNZ-UHFFFAOYSA-N azaconazole Chemical compound ClC1=CC(Cl)=CC=C1C1(CN2N=CN=C2)OCCO1 AKNQMEBLVAMSNZ-UHFFFAOYSA-N 0.000 description 3
229950000294 azaconazole Drugs 0.000 description 3
150000003851 azoles Chemical class 0.000 description 3
230000008901 benefit Effects 0.000 description 3
150000001556 benzimidazoles Chemical class 0.000 description 3
239000000872 buffer Substances 0.000 description 3
150000004649 carbonic acid derivatives Chemical class 0.000 description 3
230000015556 catabolic process Effects 0.000 description 3
210000004027 cell Anatomy 0.000 description 3
239000013078 crystal Substances 0.000 description 3
238000006731 degradation reaction Methods 0.000 description 3
230000001419 dependent effect Effects 0.000 description 3
FWBOFUGDKHMVPI-UHFFFAOYSA-K dicopper;2-oxidopropane-1,2,3-tricarboxylate Chemical compound [Cu+2].[Cu+2].[O-]C(=O)CC([O-])(C([O-])=O)CC([O-])=O FWBOFUGDKHMVPI-UHFFFAOYSA-K 0.000 description 3
OAEGRYMCJYIXQT-UHFFFAOYSA-N dithiooxamide Chemical compound NC(=S)C(N)=S OAEGRYMCJYIXQT-UHFFFAOYSA-N 0.000 description 3
238000001035 drying Methods 0.000 description 3
239000012065 filter cake Substances 0.000 description 3
239000007972 injectable composition Substances 0.000 description 3
230000000670 limiting effect Effects 0.000 description 3
229910001425 magnesium ion Inorganic materials 0.000 description 3
239000004530 micro-emulsion Substances 0.000 description 3
150000002780 morpholines Chemical class 0.000 description 3
125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 3
150000003013 phosphoric acid derivatives Chemical class 0.000 description 3
MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 description 3
238000003860 storage Methods 0.000 description 3
231100000419 toxicity Toxicity 0.000 description 3
230000001988 toxicity Effects 0.000 description 3
RYAUSSKQMZRMAI-ALOPSCKCSA-N (2S,6R)-4-[3-(4-tert-butylphenyl)-2-methylpropyl]-2,6-dimethylmorpholine Chemical compound C=1C=C(C(C)(C)C)C=CC=1CC(C)CN1C[C@H](C)O[C@H](C)C1 RYAUSSKQMZRMAI-ALOPSCKCSA-N 0.000 description 2
PPDBOQMNKNNODG-NTEUORMPSA-N (5E)-5-(4-chlorobenzylidene)-2,2-dimethyl-1-(1,2,4-triazol-1-ylmethyl)cyclopentanol Chemical compound C1=NC=NN1CC1(O)C(C)(C)CC\C1=C/C1=CC=C(Cl)C=C1 PPDBOQMNKNNODG-NTEUORMPSA-N 0.000 description 2
QNBTYORWCCMPQP-JXAWBTAJSA-N (Z)-dimethomorph Chemical compound C1=C(OC)C(OC)=CC=C1C(\C=1C=CC(Cl)=CC=1)=C/C(=O)N1CCOCC1 QNBTYORWCCMPQP-JXAWBTAJSA-N 0.000 description 2
JLHMJWHSBYZWJJ-UHFFFAOYSA-N 1,2-thiazole 1-oxide Chemical class O=S1C=CC=N1 JLHMJWHSBYZWJJ-UHFFFAOYSA-N 0.000 description 2
TUBQDCKAWGHZPF-UHFFFAOYSA-N 1,3-benzothiazol-2-ylsulfanylmethyl thiocyanate Chemical compound C1=CC=C2SC(SCSC#N)=NC2=C1 TUBQDCKAWGHZPF-UHFFFAOYSA-N 0.000 description 2
YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 2
JWUCHKBSVLQQCO-UHFFFAOYSA-N 1-(2-fluorophenyl)-1-(4-fluorophenyl)-2-(1H-1,2,4-triazol-1-yl)ethanol Chemical compound C=1C=C(F)C=CC=1C(C=1C(=CC=CC=1)F)(O)CN1C=NC=N1 JWUCHKBSVLQQCO-UHFFFAOYSA-N 0.000 description 2
WURBVZBTWMNKQT-UHFFFAOYSA-N 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-one Chemical compound C1=NC=NN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 WURBVZBTWMNKQT-UHFFFAOYSA-N 0.000 description 2
VGPIBGGRCVEHQZ-UHFFFAOYSA-N 1-(biphenyl-4-yloxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-ol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC(C=C1)=CC=C1C1=CC=CC=C1 VGPIBGGRCVEHQZ-UHFFFAOYSA-N 0.000 description 2
LQDARGUHUSPFNL-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)-3-(1,1,2,2-tetrafluoroethoxy)propyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(COC(F)(F)C(F)F)CN1C=NC=N1 LQDARGUHUSPFNL-UHFFFAOYSA-N 0.000 description 2
WKBPZYKAUNRMKP-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)pentyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(CCC)CN1C=NC=N1 WKBPZYKAUNRMKP-UHFFFAOYSA-N 0.000 description 2
PZBPKYOVPCNPJY-UHFFFAOYSA-N 1-[2-(allyloxy)-2-(2,4-dichlorophenyl)ethyl]imidazole Chemical compound ClC1=CC(Cl)=CC=C1C(OCC=C)CN1C=NC=C1 PZBPKYOVPCNPJY-UHFFFAOYSA-N 0.000 description 2
MGNFYQILYYYUBS-UHFFFAOYSA-N 1-[3-(4-tert-butylphenyl)-2-methylpropyl]piperidine Chemical compound C=1C=C(C(C)(C)C)C=CC=1CC(C)CN1CCCCC1 MGNFYQILYYYUBS-UHFFFAOYSA-N 0.000 description 2
HZJKXKUJVSEEFU-UHFFFAOYSA-N 2-(4-chlorophenyl)-2-(1H-1,2,4-triazol-1-ylmethyl)hexanenitrile Chemical compound C=1C=C(Cl)C=CC=1C(CCCC)(C#N)CN1C=NC=N1 HZJKXKUJVSEEFU-UHFFFAOYSA-N 0.000 description 2
WNZQDUSMALZDQF-UHFFFAOYSA-N 2-benzofuran-1(3H)-one Chemical compound C1=CC=C2C(=O)OCC2=C1 WNZQDUSMALZDQF-UHFFFAOYSA-N 0.000 description 2
TXNSZCSYBXHETP-UHFFFAOYSA-N 2-chloro-n-(hydroxymethyl)acetamide Chemical compound OCNC(=O)CCl TXNSZCSYBXHETP-UHFFFAOYSA-N 0.000 description 2
IQUPABOKLQSFBK-UHFFFAOYSA-N 2-nitrophenol Chemical class OC1=CC=CC=C1[N+]([O-])=O IQUPABOKLQSFBK-UHFFFAOYSA-N 0.000 description 2
CFKMVGJGLGKFKI-UHFFFAOYSA-N 4-chloro-m-cresol Chemical compound CC1=CC(O)=CC=C1Cl CFKMVGJGLGKFKI-UHFFFAOYSA-N 0.000 description 2
239000005725 8-Hydroxyquinoline Substances 0.000 description 2
241000251468 Actinopterygii Species 0.000 description 2
239000004135 Bone phosphate Substances 0.000 description 2
239000005741 Bromuconazole Substances 0.000 description 2
239000005746 Carboxin Substances 0.000 description 2
239000005749 Copper compound Substances 0.000 description 2
JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 2
JGFDZZLUDWMUQH-UHFFFAOYSA-N Didecyldimethylammonium Chemical class CCCCCCCCCC[N+](C)(C)CCCCCCCCCC JGFDZZLUDWMUQH-UHFFFAOYSA-N 0.000 description 2
239000005761 Dimethomorph Substances 0.000 description 2
239000005765 Dodemorph Substances 0.000 description 2
DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical class OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 2
239000005775 Fenbuconazole Substances 0.000 description 2
239000005778 Fenpropimorph Substances 0.000 description 2
239000005785 Fluquinconazole Substances 0.000 description 2
239000005786 Flutolanil Substances 0.000 description 2
239000005787 Flutriafol Substances 0.000 description 2
239000005791 Fuberidazole Substances 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
239000005795 Imazalil Substances 0.000 description 2
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