CA2510872A1 - Process for removal of nitrogen containing contaminants from gas oil feedstreams - Google Patents
Process for removal of nitrogen containing contaminants from gas oil feedstreams Download PDFInfo
- Publication number
- CA2510872A1 CA2510872A1 CA002510872A CA2510872A CA2510872A1 CA 2510872 A1 CA2510872 A1 CA 2510872A1 CA 002510872 A CA002510872 A CA 002510872A CA 2510872 A CA2510872 A CA 2510872A CA 2510872 A1 CA2510872 A1 CA 2510872A1
- Authority
- CA
- Canada
- Prior art keywords
- adsorbent
- silica
- adsorption
- petroleum
- nitrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000000034 method Methods 0.000 title claims abstract description 122
- 230000008569 process Effects 0.000 title claims abstract description 45
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 title claims description 31
- 239000000356 contaminant Substances 0.000 title description 20
- 239000007789 gas Substances 0.000 title description 9
- 239000003463 adsorbent Substances 0.000 claims abstract description 170
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 140
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 82
- 239000003208 petroleum Substances 0.000 claims abstract description 53
- 229910052751 metal Inorganic materials 0.000 claims abstract description 50
- 239000002184 metal Substances 0.000 claims abstract description 50
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 48
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 41
- 150000001875 compounds Chemical class 0.000 claims abstract description 34
- 239000011159 matrix material Substances 0.000 claims abstract description 32
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000011593 sulfur Substances 0.000 claims abstract description 25
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 25
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 15
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 14
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 10
- 239000000446 fuel Substances 0.000 claims abstract description 10
- 230000003197 catalytic effect Effects 0.000 claims abstract description 7
- 238000004821 distillation Methods 0.000 claims abstract description 7
- 238000001179 sorption measurement Methods 0.000 claims description 79
- 239000000463 material Substances 0.000 claims description 70
- 239000000203 mixture Substances 0.000 claims description 40
- 239000000017 hydrogel Substances 0.000 claims description 35
- 239000002245 particle Substances 0.000 claims description 35
- 239000002841 Lewis acid Substances 0.000 claims description 32
- 150000007517 lewis acids Chemical class 0.000 claims description 31
- 239000011148 porous material Substances 0.000 claims description 30
- 239000002243 precursor Substances 0.000 claims description 26
- 238000003795 desorption Methods 0.000 claims description 17
- 229910017464 nitrogen compound Inorganic materials 0.000 claims description 17
- 150000002830 nitrogen compounds Chemical class 0.000 claims description 17
- 239000007788 liquid Substances 0.000 claims description 16
- 229910052726 zirconium Inorganic materials 0.000 claims description 16
- 239000002904 solvent Substances 0.000 claims description 13
- -1 cycloalkyl alcohols Chemical class 0.000 claims description 11
- 229910002028 silica xerogel Inorganic materials 0.000 claims description 10
- 229910052719 titanium Inorganic materials 0.000 claims description 10
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 9
- 229910052742 iron Inorganic materials 0.000 claims description 9
- 239000002002 slurry Substances 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- 238000009826 distribution Methods 0.000 claims description 6
- 239000011236 particulate material Substances 0.000 claims description 6
- 230000000737 periodic effect Effects 0.000 claims description 6
- 230000002829 reductive effect Effects 0.000 claims description 6
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 5
- 229910052746 lanthanum Inorganic materials 0.000 claims description 5
- 229910052749 magnesium Inorganic materials 0.000 claims description 5
- 150000004706 metal oxides Chemical class 0.000 claims description 5
- 229910052725 zinc Inorganic materials 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 150000002576 ketones Chemical class 0.000 claims description 4
- 229910044991 metal oxide Inorganic materials 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 229910052733 gallium Inorganic materials 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 238000004231 fluid catalytic cracking Methods 0.000 claims description 2
- 229910052735 hafnium Inorganic materials 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 229910052758 niobium Inorganic materials 0.000 claims description 2
- 229910052706 scandium Inorganic materials 0.000 claims description 2
- 229910052712 strontium Inorganic materials 0.000 claims description 2
- 229910052721 tungsten Inorganic materials 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- 229910052727 yttrium Inorganic materials 0.000 claims description 2
- 239000004965 Silica aerogel Substances 0.000 claims 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 239000002131 composite material Substances 0.000 claims 1
- 239000003054 catalyst Substances 0.000 abstract description 23
- 238000005336 cracking Methods 0.000 abstract description 7
- 239000012530 fluid Substances 0.000 abstract description 2
- 239000012535 impurity Substances 0.000 abstract description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 1
- APVPOHHVBBYQAV-UHFFFAOYSA-N n-(4-aminophenyl)sulfonyloctadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NS(=O)(=O)C1=CC=C(N)C=C1 APVPOHHVBBYQAV-UHFFFAOYSA-N 0.000 abstract 1
- 235000019647 acidic taste Nutrition 0.000 description 38
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 32
- 239000000499 gel Substances 0.000 description 31
- 229910002027 silica gel Inorganic materials 0.000 description 26
- 239000000741 silica gel Substances 0.000 description 26
- 239000000047 product Substances 0.000 description 25
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 21
- 239000002283 diesel fuel Substances 0.000 description 20
- 239000000523 sample Substances 0.000 description 19
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 18
- 230000015572 biosynthetic process Effects 0.000 description 17
- 238000009835 boiling Methods 0.000 description 13
- 239000000243 solution Substances 0.000 description 13
- 125000004429 atom Chemical group 0.000 description 12
- 238000005054 agglomeration Methods 0.000 description 11
- 230000002776 aggregation Effects 0.000 description 11
- 238000003801 milling Methods 0.000 description 10
- 238000002156 mixing Methods 0.000 description 10
- 239000003921 oil Substances 0.000 description 10
- 239000011230 binding agent Substances 0.000 description 9
- 239000003209 petroleum derivative Substances 0.000 description 9
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 9
- 238000005406 washing Methods 0.000 description 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 8
- 230000000704 physical effect Effects 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- 238000012545 processing Methods 0.000 description 8
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- 230000032683 aging Effects 0.000 description 7
- 239000011324 bead Substances 0.000 description 7
- 229910052681 coesite Inorganic materials 0.000 description 7
- 229910052906 cristobalite Inorganic materials 0.000 description 7
- 238000013461 design Methods 0.000 description 7
- 229910052682 stishovite Inorganic materials 0.000 description 7
- 229910052905 tridymite Inorganic materials 0.000 description 7
- 239000004964 aerogel Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000010936 titanium Substances 0.000 description 6
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 5
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 5
- 235000011114 ammonium hydroxide Nutrition 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000000470 constituent Substances 0.000 description 5
- 125000005842 heteroatom Chemical group 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 4
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 4
- 239000001569 carbon dioxide Substances 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- 239000003344 environmental pollutant Substances 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 231100000719 pollutant Toxicity 0.000 description 4
- 230000008929 regeneration Effects 0.000 description 4
- 238000011069 regeneration method Methods 0.000 description 4
- 150000003464 sulfur compounds Chemical class 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- 239000004115 Sodium Silicate Substances 0.000 description 3
- 239000002250 absorbent Substances 0.000 description 3
- 230000002745 absorbent Effects 0.000 description 3
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 3
- 229960000892 attapulgite Drugs 0.000 description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 3
- 238000004523 catalytic cracking Methods 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 238000010924 continuous production Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 238000005470 impregnation Methods 0.000 description 3
- 229910052809 inorganic oxide Inorganic materials 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 229910052625 palygorskite Inorganic materials 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229910052814 silicon oxide Inorganic materials 0.000 description 3
- 229910052911 sodium silicate Inorganic materials 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- PFCHFHIRKBAQGU-UHFFFAOYSA-N 3-hexanone Chemical compound CCCC(=O)CC PFCHFHIRKBAQGU-UHFFFAOYSA-N 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical class N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- 239000004113 Sepiolite Substances 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
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- 239000007864 aqueous solution Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
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- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 239000007863 gel particle Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
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- 125000001477 organic nitrogen group Chemical group 0.000 description 2
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- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- 238000005453 pelletization Methods 0.000 description 2
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- 229910052815 sulfur oxide Inorganic materials 0.000 description 2
- JPJOOTWNILDNAW-UHFFFAOYSA-N 1-cyclobutylethanone Chemical compound CC(=O)C1CCC1 JPJOOTWNILDNAW-UHFFFAOYSA-N 0.000 description 1
- HVCFCNAITDHQFX-UHFFFAOYSA-N 1-cyclopropylethanone Chemical compound CC(=O)C1CC1 HVCFCNAITDHQFX-UHFFFAOYSA-N 0.000 description 1
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- WSMYVTOQOOLQHP-UHFFFAOYSA-N Malondialdehyde Chemical compound O=CCC=O WSMYVTOQOOLQHP-UHFFFAOYSA-N 0.000 description 1
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- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
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- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
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- 238000007493 shaping process Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 239000002594 sorbent Substances 0.000 description 1
- 238000002336 sorption--desorption measurement Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000013077 target material Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 150000003754 zirconium Chemical class 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/103—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
- C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
- C10G67/06—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including a sorption process as the refining step in the absence of hydrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
- C10G25/02—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material
- C10G25/03—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material with crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/322,417 | 2002-12-19 | ||
| US10/322,417 US7087156B2 (en) | 2002-12-19 | 2002-12-19 | Process for removal of nitrogen containing contaminants from gas oil feedstreams |
| PCT/US2003/040322 WO2004058923A1 (en) | 2002-12-19 | 2003-12-12 | Process for removal of nitrogen containing contaminants from gas oil feedstreams |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2510872A1 true CA2510872A1 (en) | 2004-07-15 |
Family
ID=32592989
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002510872A Abandoned CA2510872A1 (en) | 2002-12-19 | 2003-12-12 | Process for removal of nitrogen containing contaminants from gas oil feedstreams |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US7087156B2 (de) |
| EP (1) | EP1576075A1 (de) |
| JP (1) | JP2006511647A (de) |
| KR (1) | KR20050091742A (de) |
| CN (1) | CN1748020A (de) |
| AR (1) | AR042637A1 (de) |
| AU (1) | AU2003299681A1 (de) |
| BR (1) | BR0317619A (de) |
| CA (1) | CA2510872A1 (de) |
| MX (1) | MXPA05006469A (de) |
| NO (1) | NO20053381L (de) |
| TW (1) | TWI264464B (de) |
| WO (1) | WO2004058923A1 (de) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005523370A (ja) * | 2002-04-17 | 2005-08-04 | ビーピー・コーポレーション・ノース・アメリカ・インコーポレーテッド | 精製方法 |
| US7473349B2 (en) * | 2004-12-30 | 2009-01-06 | Bp Corporation North America Inc. | Process for removal of sulfur from components for blending of transportation fuels |
| US7842181B2 (en) * | 2006-12-06 | 2010-11-30 | Saudi Arabian Oil Company | Composition and process for the removal of sulfur from middle distillate fuels |
| FR2913235B1 (fr) * | 2007-03-02 | 2011-02-25 | Inst Francais Du Petrole | Procede ameliore de desulfuration et de deazotation d'une coupe hydrocarbonee de type gazole contenant des composes azotes. |
| US7780847B2 (en) * | 2007-10-01 | 2010-08-24 | Saudi Arabian Oil Company | Method of producing low sulfur, high octane gasoline |
| US7749377B2 (en) * | 2007-11-14 | 2010-07-06 | Uop Llc | Methods of denitrogenating diesel fuel |
| US20090145808A1 (en) * | 2007-11-30 | 2009-06-11 | Saudi Arabian Oil Company | Catalyst to attain low sulfur diesel |
| US8142646B2 (en) | 2007-11-30 | 2012-03-27 | Saudi Arabian Oil Company | Process to produce low sulfur catalytically cracked gasoline without saturation of olefinic compounds |
| EP2250129A2 (de) | 2008-02-21 | 2010-11-17 | Saudi Arabian Oil Company | Katalysator zum erhalt von schwefelarmem benzin |
| US8187991B2 (en) * | 2008-06-11 | 2012-05-29 | General Electric Company | Methods for regeneration of adsorbent material |
| US8088277B2 (en) * | 2008-06-11 | 2012-01-03 | General Electric Company | Methods and system for removing impurities from heavy fuel |
| JP5492204B2 (ja) * | 2008-08-15 | 2014-05-14 | エクソンモービル リサーチ アンド エンジニアリング カンパニー | 極性成分をプロセスストリームから除去して熱損失を防止する方法 |
| US9005432B2 (en) | 2010-06-29 | 2015-04-14 | Saudi Arabian Oil Company | Removal of sulfur compounds from petroleum stream |
| JP5599522B2 (ja) * | 2011-01-10 | 2014-10-01 | コチ・ウニヴェルシテシ | 表面開始光重合を介するｐｅｇヒドロゲルでの被包化疎水性および親水性エアロゲル |
| US8535518B2 (en) | 2011-01-19 | 2013-09-17 | Saudi Arabian Oil Company | Petroleum upgrading and desulfurizing process |
| CN106102869B (zh) * | 2014-01-21 | 2019-02-05 | 卡博特公司 | 细小粒径的活性炭 |
| CN106607005B (zh) * | 2015-10-21 | 2019-07-05 | 中国石油化工股份有限公司 | 含氮化合物固体吸附剂及其制备方法 |
| US11084021B2 (en) | 2015-10-27 | 2021-08-10 | W.R. Grace & Co.—Conn | Acid-resistant catalyst supports and catalysts |
| WO2017079550A2 (en) * | 2015-11-07 | 2017-05-11 | Entegris, Inc. | Adsorbents and fluid supply packages and apparatus comprising same |
| US10752847B2 (en) | 2017-03-08 | 2020-08-25 | Saudi Arabian Oil Company | Integrated hydrothermal process to upgrade heavy oil |
| US10703999B2 (en) | 2017-03-14 | 2020-07-07 | Saudi Arabian Oil Company | Integrated supercritical water and steam cracking process |
| CN108102693B (zh) * | 2017-12-28 | 2020-02-28 | 辽宁石油化工大学 | 钴镍双金属离子改性硅胶脱除页岩油中碱性氮化物的方法 |
| US10526552B1 (en) | 2018-10-12 | 2020-01-07 | Saudi Arabian Oil Company | Upgrading of heavy oil for steam cracking process |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2384315A (en) * | 1942-08-06 | 1945-09-04 | Standard Oil Dev Co | Process for cracking crude hydrocarbon oil |
| US2744053A (en) * | 1951-04-26 | 1956-05-01 | Union Oil Co | Hydrocarbon conversion process, including preliminary nitrogen removal by adsorption |
| US3189539A (en) * | 1962-05-14 | 1965-06-15 | California Research Corp | Removal of nitrogen compounds from hydrocarbon oils by adsorption on cracking catalyst |
| US3649528A (en) * | 1970-03-16 | 1972-03-14 | Exxon Research Engineering Co | Denitrogenation by distillation in presence of alkali metals |
| US4708786A (en) * | 1986-03-26 | 1987-11-24 | Union Oil Company Of California | Process for the catalytic cracking of nitrogen-containing feedstocks |
| US5051163A (en) * | 1990-01-11 | 1991-09-24 | Chevron Research Company | Nitrogen-tolerant cracking process |
| ES2089792T3 (es) * | 1992-01-23 | 1996-10-01 | Procter & Gamble | Composiciones detergentes liquidas para superficies duras que contienen tensioactivos hibridos y cationicos y monoetanolamina y/o beta-aminoalcanol. |
| DE4207191C2 (de) * | 1992-03-06 | 2001-03-08 | Intevep Sa | Verfahren zum Herstellen eines etherreichen Additivs |
| US5300218A (en) * | 1992-06-23 | 1994-04-05 | Shell Oil Company | Reduction of diesel engine particulate emissions by contacting diesel fuel with a carbon molecular sieve adsorbent |
| US5414183A (en) * | 1992-12-24 | 1995-05-09 | Uop | Nitrogen removal from light hydrocarbon feed in olefin isomerization and etherication process |
| US5376608A (en) * | 1993-01-27 | 1994-12-27 | W. R. Grace & Co.-Conn. | Sulfur reduction in FCC gasoline |
| GB9403260D0 (en) * | 1994-02-21 | 1994-04-13 | Ici Plc | Absorbents |
| EP0671455A3 (de) * | 1994-03-11 | 1996-01-17 | Standard Oil Co Ohio | Verfahren zur selektiven Entfernung von stickstoffenthaltenden Verbindungen aus Kohlenwasserstoffgemischen. |
| US5770047A (en) * | 1994-05-23 | 1998-06-23 | Intevep, S.A. | Process for producing reformulated gasoline by reducing sulfur, nitrogen and olefin |
| DE19505579A1 (de) * | 1995-02-18 | 1996-08-22 | Sued Chemie Ag | Adsorbens zur Behandlung von Ölen und/oder Fetten |
| US5942650A (en) * | 1995-09-20 | 1999-08-24 | Uop Llc | Process for the removal of nitrogen compounds from an aromatic stream |
| US5744686A (en) * | 1995-09-20 | 1998-04-28 | Uop | Process for the removal of nitrogen compounds from an aromatic hydrocarbon stream |
| IT1283626B1 (it) | 1996-04-22 | 1998-04-22 | Snam Progetti | Procedimento per rimuovere contaminanti azotati e solforati da correnti idrocarburiche |
| US6150300A (en) * | 1996-08-14 | 2000-11-21 | Phillips Petroleum Company | Process to produce sorbents |
| US6118037A (en) * | 1997-04-22 | 2000-09-12 | Snamprogetti S.P.A. | Process for the removal of contaminant compounds containing one or more heteroatoms of sulfur, nitrogen and/or oxygen from hydrocarbon streams |
| US6099619A (en) * | 1997-10-09 | 2000-08-08 | Uop Llc | Purification of carbon dioxide |
| AU2350299A (en) * | 1998-01-30 | 1999-08-16 | E.I. Du Pont De Nemours And Company | Desulfurization of petroleum products |
| US6248230B1 (en) * | 1998-06-25 | 2001-06-19 | Sk Corporation | Method for manufacturing cleaner fuels |
| KR100557586B1 (ko) | 1999-04-24 | 2006-03-03 | 에스케이 주식회사 | 석유계 탄화수소내의 헤테로화합물을 제거 또는 농축시키기 위한 액상 흡탈착공정 |
| EP1057879A3 (de) * | 1999-06-02 | 2001-07-04 | Haldor Topsoe A/S | Kombiniertes Verfahren für die Wasserstoffbehandlung von Dieselbrennstoffen |
| US6358302B1 (en) | 1999-11-18 | 2002-03-19 | The Boc Group, Inc. | Purification of gases using multi-composite adsorbent |
-
2002
- 2002-12-19 US US10/322,417 patent/US7087156B2/en not_active Expired - Fee Related
-
2003
- 2003-12-12 JP JP2004563739A patent/JP2006511647A/ja not_active Withdrawn
- 2003-12-12 KR KR1020057011650A patent/KR20050091742A/ko not_active Application Discontinuation
- 2003-12-12 BR BR0317619-3A patent/BR0317619A/pt not_active IP Right Cessation
- 2003-12-12 CA CA002510872A patent/CA2510872A1/en not_active Abandoned
- 2003-12-12 MX MXPA05006469A patent/MXPA05006469A/es unknown
- 2003-12-12 WO PCT/US2003/040322 patent/WO2004058923A1/en active Application Filing
- 2003-12-12 CN CNA2003801097771A patent/CN1748020A/zh active Pending
- 2003-12-12 EP EP03799965A patent/EP1576075A1/de not_active Withdrawn
- 2003-12-12 AU AU2003299681A patent/AU2003299681A1/en not_active Abandoned
- 2003-12-17 TW TW092135729A patent/TWI264464B/zh not_active IP Right Cessation
- 2003-12-19 AR ARP030104759A patent/AR042637A1/es not_active Application Discontinuation
-
2005
- 2005-07-12 NO NO20053381A patent/NO20053381L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| WO2004058923A1 (en) | 2004-07-15 |
| BR0317619A (pt) | 2005-11-29 |
| TW200422393A (en) | 2004-11-01 |
| EP1576075A1 (de) | 2005-09-21 |
| MXPA05006469A (es) | 2005-08-26 |
| NO20053381D0 (no) | 2005-07-12 |
| NO20053381L (no) | 2005-09-19 |
| US20040118748A1 (en) | 2004-06-24 |
| US7087156B2 (en) | 2006-08-08 |
| TWI264464B (en) | 2006-10-21 |
| AU2003299681A1 (en) | 2004-07-22 |
| KR20050091742A (ko) | 2005-09-15 |
| CN1748020A (zh) | 2006-03-15 |
| AR042637A1 (es) | 2005-06-29 |
| JP2006511647A (ja) | 2006-04-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued |