CA2503025C - Complex hydrides for hydrogen storage - Google Patents
Complex hydrides for hydrogen storage Download PDFInfo
- Publication number
- CA2503025C CA2503025C CA2503025A CA2503025A CA2503025C CA 2503025 C CA2503025 C CA 2503025C CA 2503025 A CA2503025 A CA 2503025A CA 2503025 A CA2503025 A CA 2503025A CA 2503025 C CA2503025 C CA 2503025C
- Authority
- CA
- Canada
- Prior art keywords
- hydride
- hydrogen
- complex hydride
- complex
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 125
- 239000001257 hydrogen Substances 0.000 title claims abstract description 107
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 107
- 150000004678 hydrides Chemical class 0.000 title claims abstract description 67
- 238000003860 storage Methods 0.000 title description 29
- 238000000034 method Methods 0.000 claims abstract description 34
- 239000011232 storage material Substances 0.000 claims abstract description 32
- 230000008569 process Effects 0.000 claims abstract description 27
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000010936 titanium Substances 0.000 claims abstract description 23
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 22
- 239000000203 mixture Substances 0.000 claims description 42
- 239000002019 doping agent Substances 0.000 claims description 37
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 26
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 20
- 238000002844 melting Methods 0.000 claims description 19
- 230000008018 melting Effects 0.000 claims description 19
- -1 sodium aluminum hydride Chemical compound 0.000 claims description 18
- 229910052742 iron Chemical group 0.000 claims description 13
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 12
- 229910052726 zirconium Inorganic materials 0.000 claims description 12
- 229910052746 lanthanum Inorganic materials 0.000 claims description 10
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 10
- 229910052759 nickel Inorganic materials 0.000 claims description 10
- 230000002441 reversible effect Effects 0.000 claims description 10
- 229910017052 cobalt Inorganic materials 0.000 claims description 9
- 239000010941 cobalt Substances 0.000 claims description 9
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 9
- 229910052720 vanadium Inorganic materials 0.000 claims description 9
- SIAPCJWMELPYOE-UHFFFAOYSA-N lithium hydride Chemical compound [LiH] SIAPCJWMELPYOE-UHFFFAOYSA-N 0.000 claims description 8
- 229910000103 lithium hydride Inorganic materials 0.000 claims description 8
- 229910000104 sodium hydride Inorganic materials 0.000 claims description 8
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 claims description 5
- 239000012312 sodium hydride Substances 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical group [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- 229910052796 boron Chemical group 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 239000011575 calcium Chemical group 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 239000011777 magnesium Chemical group 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 4
- 239000000463 material Substances 0.000 abstract description 30
- 238000003795 desorption Methods 0.000 abstract description 14
- 229910052751 metal Inorganic materials 0.000 abstract description 8
- 239000002184 metal Substances 0.000 abstract description 8
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 abstract description 6
- 239000000047 product Substances 0.000 description 30
- 238000000498 ball milling Methods 0.000 description 10
- 239000003054 catalyst Substances 0.000 description 9
- 229910052723 transition metal Inorganic materials 0.000 description 9
- 150000003624 transition metals Chemical class 0.000 description 9
- 238000001179 sorption measurement Methods 0.000 description 8
- 239000007795 chemical reaction product Substances 0.000 description 7
- 229910052987 metal hydride Inorganic materials 0.000 description 6
- 150000004681 metal hydrides Chemical class 0.000 description 6
- 238000011068 loading method Methods 0.000 description 5
- 239000004570 mortar (masonry) Substances 0.000 description 5
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 230000004927 fusion Effects 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000000523 sample Substances 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 3
- 239000013068 control sample Substances 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 238000002411 thermogravimetry Methods 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000001351 cycling effect Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 125000002524 organometallic group Chemical group 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000002336 sorption--desorption measurement Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 230000004580 weight loss Effects 0.000 description 2
- SDTMFDGELKWGFT-UHFFFAOYSA-N 2-methylpropan-2-olate Chemical compound CC(C)(C)[O-] SDTMFDGELKWGFT-UHFFFAOYSA-N 0.000 description 1
- 229910002335 LaNi5 Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910000102 alkali metal hydride Inorganic materials 0.000 description 1
- 150000008046 alkali metal hydrides Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000009388 chemical precipitation Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000011876 fused mixture Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000012279 sodium borohydride Substances 0.000 description 1
- 229910000033 sodium borohydride Inorganic materials 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0031—Intermetallic compounds; Metal alloys; Treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
- C01B6/06—Hydrides of aluminium, gallium, indium, thallium, germanium, tin, lead, arsenic, antimony, bismuth or polonium; Monoborane; Diborane; Addition complexes thereof
- C01B6/10—Monoborane; Diborane; Addition complexes thereof
- C01B6/13—Addition complexes of monoborane or diborane, e.g. with phosphine, arsine or hydrazine
- C01B6/15—Metal borohydrides; Addition complexes thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
- C01B6/24—Hydrides containing at least two metals; Addition complexes thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
- Fuel Cell (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US42317202P | 2002-11-01 | 2002-11-01 | |
| US60/423,172 | 2002-11-01 | ||
| PCT/US2003/034980 WO2004041717A1 (en) | 2002-11-01 | 2003-11-03 | Complex hydrides for hydrogen storage |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2503025A1 CA2503025A1 (en) | 2004-05-21 |
| CA2503025C true CA2503025C (en) | 2011-01-04 |
Family
ID=32312615
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2503025A Expired - Fee Related CA2503025C (en) | 2002-11-01 | 2003-11-03 | Complex hydrides for hydrogen storage |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7094387B2 (enExample) |
| EP (1) | EP1558520B1 (enExample) |
| JP (1) | JP4584716B2 (enExample) |
| AT (1) | ATE496865T1 (enExample) |
| AU (1) | AU2003286873A1 (enExample) |
| CA (1) | CA2503025C (enExample) |
| DE (1) | DE60335896D1 (enExample) |
| WO (1) | WO2004041717A1 (enExample) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10163697A1 (de) * | 2001-12-21 | 2003-07-03 | Studiengesellschaft Kohle Mbh | Reversible Speicherung von Wasserstoff mit Hilfe von dotierten Alkalimetallaluminiumhydriden |
| EP1558520B1 (en) | 2002-11-01 | 2011-01-26 | Savannah River Nuclear Solutions, LLC | Complex hydrides for hydrogen storage |
| US7384574B2 (en) * | 2003-07-17 | 2008-06-10 | Westinghouse Savannah River Co. | Hydrogen storage material and process using graphite additive with metal-doped complex hydrides |
| US20070014683A1 (en) * | 2003-09-30 | 2007-01-18 | General Electric Company | Hydrogen storage composition, and associated article and method |
| US7175826B2 (en) * | 2003-12-29 | 2007-02-13 | General Electric Company | Compositions and methods for hydrogen storage and recovery |
| US8124558B2 (en) * | 2004-08-27 | 2012-02-28 | Savannah River Nuclear Solutions, Llc | Catalyzed borohydrides for hydrogen storage |
| US8124559B2 (en) * | 2004-08-27 | 2012-02-28 | Toyota Motor Engineering & Manufacturing North America, Inc. | Destabilized and catalyzed borohydride for reversible hydrogen storage |
| US8105974B2 (en) * | 2004-08-27 | 2012-01-31 | Toyota Motor Engineering & Manufacturing North America, Inc. | Destabilized and catalyzed borohydride for reversible hydrogen storage |
| US20060194695A1 (en) * | 2004-08-27 | 2006-08-31 | Westinghouse Savannah River Co., Llc | Destabilized and catalyzed borohydrided for reversible hydrogen storage |
| JP4427643B2 (ja) * | 2004-08-27 | 2010-03-10 | 国立大学法人室蘭工業大学 | 活性化アルミニウム微粒子の乾燥及び保存方法 |
| US20110180753A1 (en) * | 2008-02-22 | 2011-07-28 | Toyota Motor Engineering & Manufacturing North America, Inc. | Destabilized and catalyzed borohydride for reversible hydrogen storage |
| ES2387989T3 (es) * | 2004-12-07 | 2012-10-05 | Hydrexia Pty Ltd | Aleaciones de magnesio para el almacenamiento de hidrógeno |
| CA2529427C (en) * | 2004-12-17 | 2011-03-15 | University Of New Brunswick | Synthesis, recharging and processing of hydrogen storage materials using supercritical fluids |
| US20070092395A1 (en) * | 2005-10-03 | 2007-04-26 | General Electric Company | Hydrogen storage material and method for making |
| US8883371B2 (en) * | 2007-10-16 | 2014-11-11 | Motorola Mobility Llc | Hydrogen storage materials and hydrogen fuel cells |
| EP2257494B1 (en) | 2008-02-12 | 2012-10-03 | Ilika Technologies Ltd | Doped hydrogen storage material |
| US7754641B2 (en) * | 2008-02-14 | 2010-07-13 | General Electric Company | Hydrogen storage material and related processes |
| US8153020B1 (en) | 2008-03-19 | 2012-04-10 | University Of South Florida | Hydrogen-storing hydride complexes |
| KR100984718B1 (ko) * | 2008-08-11 | 2010-10-01 | 한화케미칼 주식회사 | 수소 저장물질로써 아릴 또는 알킬을 포함하는 유기-전이 금속 하이드라이드의 보다 개선된 제조방법 |
| US20100233076A1 (en) * | 2008-09-18 | 2010-09-16 | Ford Global Technologies, Llc | Hydrogen Storage Materials |
| CN102782390B (zh) | 2010-02-24 | 2015-05-13 | 海德瑞克斯亚股份有限公司 | 排出氢的系统,递送氢供应的系统以及供应氢的方法 |
| RU2466929C1 (ru) * | 2011-03-24 | 2012-11-20 | Федеральное государственное унитарное предприятие "Российский Федеральный ядерный центр - Всероссийский научно-исследовательский институт экспериментальной физики" (ФГУП "РФЯЦ-ВНИИЭФ") | Способ обработки гидрида титана |
| HUE061845T2 (hu) | 2011-12-15 | 2023-08-28 | Hydro Quebec | Új fém hibridek és felhasználásuk hidrogéntárolási alkalmazásokban |
| RU2507150C1 (ru) * | 2012-07-03 | 2014-02-20 | Федеральное государственное унитарное предприятие "Российский Федеральный ядерный центр-Всероссийский научно-исследовательский институт экспериментальной физики" (ФГУП "РФЯЦ-ВНИИЭФ") | Способ получения порошкообразного гидрида титана |
| EP3008011B1 (en) | 2013-06-14 | 2023-07-26 | USW Commercial Services Ltd. | Synthesis and hydrogen storage properties of manganese hydrides |
| DK3154901T3 (da) | 2014-06-13 | 2023-12-18 | Usw Commercial Services Ltd | Syntese-og hydrogenlagringsegenskaber for hidtil ukendte metalhydrider |
| CA2991310C (en) | 2015-07-23 | 2023-08-08 | Hydrexia Pty Ltd | Mg-based alloy for hydrogen storage |
| US11267702B1 (en) | 2017-06-08 | 2022-03-08 | National Technology & Engineering Solutions Of Sandia, Llc | Solid state synthesis of metal borohydrides |
| US11192783B1 (en) * | 2017-06-08 | 2021-12-07 | National Technology & Engineering Solutions Of Sandia, Llc | Ternary borides and borohydrides for hydrogen storage and method of synthesis |
| US11002255B2 (en) | 2019-08-20 | 2021-05-11 | Lowry Inheritors Trust | Carbon negative clean fuel production system |
| US11976235B2 (en) | 2020-10-27 | 2024-05-07 | Battelle Savannah River Alliance, Llc | High temperature thermochemical energy storage materials |
| CN114735643B (zh) * | 2022-05-07 | 2023-10-27 | 瀚锐氢能科技集团有限公司 | 一种有机液态储氢材料及其性能调控方法和应用 |
Family Cites Families (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3720752A (en) * | 1967-04-11 | 1973-03-13 | Houten R Van | Massive metal hydride structures and methods for their preparation |
| DE1909732A1 (de) * | 1968-06-21 | 1970-02-19 | Grosse Aristid Victor | Verfahren und Vorrichtung zur Herstellung und Lagerung von Wasserstoff |
| US4360569A (en) * | 1980-03-12 | 1982-11-23 | The United States Of America As Represented By The United States Department Of Energy | Porous metal hydride composite and preparation and uses thereof |
| US4790985A (en) * | 1986-10-16 | 1988-12-13 | Ethyl Corporation | Synthesis of sodium aluminum hydride |
| US4948423A (en) * | 1989-07-21 | 1990-08-14 | Energy Conversion Devices, Inc. | Alloy preparation of hydrogen storage materials |
| US5411928A (en) * | 1993-05-24 | 1995-05-02 | The United States Of America As Represented By The United States Department Of Energy | Composition for absorbing hydrogen |
| DE4343321A1 (de) * | 1993-12-18 | 1995-06-22 | Varta Batterie | Elektrischer Akkumulator |
| US5460745A (en) * | 1994-02-07 | 1995-10-24 | The United States Of America As Represented By The United States Department Of Energy | Hydride compositions |
| DE69608182T2 (de) * | 1995-07-18 | 2000-10-05 | Matsushita Electric Industrial Co., Ltd. | Wasserstoffspeichernde Legierung und Elektrode daraus |
| DE19526434A1 (de) * | 1995-07-19 | 1997-01-23 | Studiengesellschaft Kohle Mbh | Verfahren zur reversilben Speicherung von Wasserstoff |
| JP3843459B2 (ja) * | 1996-09-26 | 2006-11-08 | トヨタ自動車株式会社 | チタン系水素吸蔵合金粉末の製造方法 |
| US6074453A (en) * | 1996-10-30 | 2000-06-13 | Iowa State University Research Foundation, Inc. | Ultrafine hydrogen storage powders |
| US6277519B1 (en) * | 1997-01-27 | 2001-08-21 | Shin-Etsu Chemical Co., Ltd. | Method for making hydrogen storage alloy powder and electrode comprising the alloy powder |
| SE9702189D0 (sv) * | 1997-06-06 | 1997-06-06 | Hoeganaes Ab | Powder composition and process for the preparation thereof |
| CA2218271A1 (en) * | 1997-10-10 | 1999-04-10 | Mcgill University | Method of fabrication of complex alkali mental hydrides |
| CA2220503A1 (en) * | 1997-11-07 | 1999-05-07 | Leszek Zaluski | Hydrogen storage composition |
| DE19758384C2 (de) * | 1997-12-23 | 2002-08-01 | Geesthacht Gkss Forschung | Verfahren zur Herstellung nanokristalliner Metallhydride |
| JP3528599B2 (ja) * | 1998-05-21 | 2004-05-17 | トヨタ自動車株式会社 | 水素吸蔵合金 |
| US6471935B2 (en) * | 1998-08-06 | 2002-10-29 | University Of Hawaii | Hydrogen storage materials and method of making by dry homogenation |
| WO2000007930A1 (en) * | 1998-08-06 | 2000-02-17 | University Of Hawaii | Novel hydrogen storage materials and method of making by dry homogenation |
| CA2345955A1 (en) * | 1998-10-07 | 2000-04-13 | Mcgill University | Lithium-based hydrogen storage compositions |
| ES2178264T3 (es) * | 1998-10-07 | 2002-12-16 | Univ Mcgill | Composicion reversible para almacenamiento de hidrogeno. |
| US6268077B1 (en) * | 1999-03-01 | 2001-07-31 | Motorola, Inc. | Portable fuel cell power supply |
| US6305442B1 (en) * | 1999-11-06 | 2001-10-23 | Energy Conversion Devices, Inc. | Hydrogen-based ecosystem |
| DE10012794A1 (de) | 2000-03-16 | 2001-09-20 | Studiengesellschaft Kohle Mbh | Verfahren zur reversiblen Speicherung von Wasserstoff auf der Basis von Alkalimetallen und Aluminium |
| US6680042B1 (en) * | 2000-11-07 | 2004-01-20 | Hydro-Quebec | Method of rapidly carrying out a hydrogenation of a hydrogen storage material |
| US6596055B2 (en) * | 2000-11-22 | 2003-07-22 | Air Products And Chemicals, Inc. | Hydrogen storage using carbon-metal hybrid compositions |
| TWI260344B (en) * | 2001-01-12 | 2006-08-21 | Safe Hydrogen Llc | A method of operating a hydrogen-fueled device |
| US6773692B2 (en) * | 2001-08-02 | 2004-08-10 | Iowa State University Research Foundation, Inc. | Method of production of pure hydrogen near room temperature from aluminum-based hydride materials |
| US6680043B2 (en) * | 2001-11-29 | 2004-01-20 | General Motors Corporation | Process for enhancing the kinetics of hydrogenation/dehydrogenation of MAIH4 and MBH4 metal hydrides for reversible hydrogen storage |
| US20030165423A1 (en) * | 2002-01-29 | 2003-09-04 | Gross Karl J. | Direct synthesis of hydride compounds using a titanium aluminate dopant |
| US6793909B2 (en) * | 2002-01-29 | 2004-09-21 | Sandia National Laboratories | Direct synthesis of catalyzed hydride compounds |
| US7011768B2 (en) * | 2002-07-10 | 2006-03-14 | Fuelsell Technologies, Inc. | Methods for hydrogen storage using doped alanate compositions |
| EP1558520B1 (en) | 2002-11-01 | 2011-01-26 | Savannah River Nuclear Solutions, LLC | Complex hydrides for hydrogen storage |
-
2003
- 2003-11-03 EP EP03778089A patent/EP1558520B1/en not_active Expired - Lifetime
- 2003-11-03 AT AT03778089T patent/ATE496865T1/de not_active IP Right Cessation
- 2003-11-03 JP JP2004550428A patent/JP4584716B2/ja not_active Expired - Fee Related
- 2003-11-03 DE DE60335896T patent/DE60335896D1/de not_active Expired - Lifetime
- 2003-11-03 WO PCT/US2003/034980 patent/WO2004041717A1/en not_active Ceased
- 2003-11-03 US US10/700,001 patent/US7094387B2/en not_active Expired - Fee Related
- 2003-11-03 CA CA2503025A patent/CA2503025C/en not_active Expired - Fee Related
- 2003-11-03 AU AU2003286873A patent/AU2003286873A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| WO2004041717A1 (en) | 2004-05-21 |
| EP1558520A4 (en) | 2009-03-18 |
| EP1558520A1 (en) | 2005-08-03 |
| EP1558520B1 (en) | 2011-01-26 |
| AU2003286873A1 (en) | 2004-06-07 |
| JP4584716B2 (ja) | 2010-11-24 |
| US20040105805A1 (en) | 2004-06-03 |
| ATE496865T1 (de) | 2011-02-15 |
| DE60335896D1 (enExample) | 2011-03-10 |
| JP2006504616A (ja) | 2006-02-09 |
| CA2503025A1 (en) | 2004-05-21 |
| US7094387B2 (en) | 2006-08-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2503025C (en) | Complex hydrides for hydrogen storage | |
| JP2006504616A5 (enExample) | ||
| Lin et al. | Recent advances in metastable alloys for hydrogen storage: a review | |
| KR100567426B1 (ko) | 마그네슘 수소화물의 기계적인 분쇄를 통해 제조되고 활성화된 경계면을 갖는 나노합성물과, 이를 제조하는 방법 | |
| US20060194695A1 (en) | Destabilized and catalyzed borohydrided for reversible hydrogen storage | |
| US8193113B2 (en) | Hydrogen storage material and related processes | |
| CA2218271A1 (en) | Method of fabrication of complex alkali mental hydrides | |
| Song et al. | Thermodynamics study of hydrogen storage materials | |
| CN113148956B (zh) | 一种石墨烯负载的纳米片状过渡金属氢化物的制备方法和储氢材料 | |
| CN101920936A (zh) | 金属锂基复合储氢材料及其制备方法与用途 | |
| JP5491041B2 (ja) | 可逆的な水素吸蔵用の不安定化触媒化ホウ水素化物 | |
| US20090142258A1 (en) | Physiochemical pathway to reversible hydrogen storage | |
| CA2471362A1 (en) | Reversible storage of hydrogen using doped alkali metal aluminum hydrides | |
| KR100904403B1 (ko) | 스캐폴드된 보라잔-리튬 하이드리드 수소 저장 물질 | |
| US8105974B2 (en) | Destabilized and catalyzed borohydride for reversible hydrogen storage | |
| CA2640453C (en) | Adjusting the stability of complex metal hydrides | |
| US8124559B2 (en) | Destabilized and catalyzed borohydride for reversible hydrogen storage | |
| Lee et al. | The substitution of NaMgH3 for MgH2 greatly enhancing the hydrogen storage performance and mechanism of Li-Mg-NH system | |
| KR20230099283A (ko) | 염화물계 촉매를 이용한 고체수소저장소재 제조방법 | |
| Zidan et al. | Development and characterization of novel complex hydrides synthesized via Molten state processing | |
| Niaz et al. | Improved hydrogen desorption kinetics of MgH2 nanoparticles by using TiC nanocatalyst | |
| Guo | Light metal borohydrides and Mg-based hydrides for hydrogen storage | |
| CN109553069A (zh) | 一种双阳离子双配位阴离子氢化物及其制备方法 | |
| KR20170131037A (ko) | 수소저장재료의 제조방법 | |
| Deavin | Thermodynamic tuning of lithium borohydride using various metallic sources |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20141103 |