JP4584716B2 - 水素貯蔵用複合水素化物 - Google Patents

水素貯蔵用複合水素化物 Download PDF

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Publication number
JP4584716B2
JP4584716B2 JP2004550428A JP2004550428A JP4584716B2 JP 4584716 B2 JP4584716 B2 JP 4584716B2 JP 2004550428 A JP2004550428 A JP 2004550428A JP 2004550428 A JP2004550428 A JP 2004550428A JP 4584716 B2 JP4584716 B2 JP 4584716B2
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hydrogen
hydride
hydrogen storage
titanium
pressure
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Japanese (ja)
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JP2006504616A (ja
JP2006504616A5 (enExample
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ジダン ラゲイー
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サバンナ リバー ヌークリア ソリューションズ リミテッド ライアビリティ カンパニー
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
    • C01B3/0031—Intermetallic compounds; Metal alloys; Treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
    • C01B6/06—Hydrides of aluminium, gallium, indium, thallium, germanium, tin, lead, arsenic, antimony, bismuth or polonium; Monoborane; Diborane; Addition complexes thereof
    • C01B6/10—Monoborane; Diborane; Addition complexes thereof
    • C01B6/13—Addition complexes of monoborane or diborane, e.g. with phosphine, arsine or hydrazine
    • C01B6/15—Metal borohydrides; Addition complexes thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
    • C01B6/24—Hydrides containing at least two metals; Addition complexes thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Fuel Cell (AREA)
JP2004550428A 2002-11-01 2003-11-03 水素貯蔵用複合水素化物 Expired - Fee Related JP4584716B2 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US42317202P 2002-11-01 2002-11-01
PCT/US2003/034980 WO2004041717A1 (en) 2002-11-01 2003-11-03 Complex hydrides for hydrogen storage

Publications (3)

Publication Number Publication Date
JP2006504616A JP2006504616A (ja) 2006-02-09
JP2006504616A5 JP2006504616A5 (enExample) 2010-01-28
JP4584716B2 true JP4584716B2 (ja) 2010-11-24

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JP2004550428A Expired - Fee Related JP4584716B2 (ja) 2002-11-01 2003-11-03 水素貯蔵用複合水素化物

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US (1) US7094387B2 (enExample)
EP (1) EP1558520B1 (enExample)
JP (1) JP4584716B2 (enExample)
AT (1) ATE496865T1 (enExample)
AU (1) AU2003286873A1 (enExample)
CA (1) CA2503025C (enExample)
DE (1) DE60335896D1 (enExample)
WO (1) WO2004041717A1 (enExample)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10163697A1 (de) * 2001-12-21 2003-07-03 Studiengesellschaft Kohle Mbh Reversible Speicherung von Wasserstoff mit Hilfe von dotierten Alkalimetallaluminiumhydriden
US7094387B2 (en) 2002-11-01 2006-08-22 Washington Savannah River Company Llc Complex hydrides for hydrogen storage
US7384574B2 (en) * 2003-07-17 2008-06-10 Westinghouse Savannah River Co. Hydrogen storage material and process using graphite additive with metal-doped complex hydrides
US7175826B2 (en) * 2003-12-29 2007-02-13 General Electric Company Compositions and methods for hydrogen storage and recovery
US20070014683A1 (en) * 2003-09-30 2007-01-18 General Electric Company Hydrogen storage composition, and associated article and method
US8124559B2 (en) * 2004-08-27 2012-02-28 Toyota Motor Engineering & Manufacturing North America, Inc. Destabilized and catalyzed borohydride for reversible hydrogen storage
US8105974B2 (en) * 2004-08-27 2012-01-31 Toyota Motor Engineering & Manufacturing North America, Inc. Destabilized and catalyzed borohydride for reversible hydrogen storage
US20110180753A1 (en) * 2008-02-22 2011-07-28 Toyota Motor Engineering & Manufacturing North America, Inc. Destabilized and catalyzed borohydride for reversible hydrogen storage
US20060194695A1 (en) * 2004-08-27 2006-08-31 Westinghouse Savannah River Co., Llc Destabilized and catalyzed borohydrided for reversible hydrogen storage
JP4427643B2 (ja) * 2004-08-27 2010-03-10 国立大学法人室蘭工業大学 活性化アルミニウム微粒子の乾燥及び保存方法
US8124558B2 (en) * 2004-08-27 2012-02-28 Savannah River Nuclear Solutions, Llc Catalyzed borohydrides for hydrogen storage
DK1838887T3 (da) * 2004-12-07 2012-07-09 Hydrexia Pty Ltd Magnesiumlegeringer til hydrogenlagring
CA2529427C (en) * 2004-12-17 2011-03-15 University Of New Brunswick Synthesis, recharging and processing of hydrogen storage materials using supercritical fluids
US20070092395A1 (en) * 2005-10-03 2007-04-26 General Electric Company Hydrogen storage material and method for making
US8883371B2 (en) * 2007-10-16 2014-11-11 Motorola Mobility Llc Hydrogen storage materials and hydrogen fuel cells
JP5174188B2 (ja) 2008-02-12 2013-04-03 イリカ テクノロジーズ リミテッド ドープされた水素貯蔵材料
US7754641B2 (en) * 2008-02-14 2010-07-13 General Electric Company Hydrogen storage material and related processes
US8153020B1 (en) 2008-03-19 2012-04-10 University Of South Florida Hydrogen-storing hydride complexes
KR100984718B1 (ko) * 2008-08-11 2010-10-01 한화케미칼 주식회사 수소 저장물질로써 아릴 또는 알킬을 포함하는 유기-전이 금속 하이드라이드의 보다 개선된 제조방법
US20100233076A1 (en) * 2008-09-18 2010-09-16 Ford Global Technologies, Llc Hydrogen Storage Materials
CA2790561C (en) 2010-02-24 2018-08-28 Hydrexia Pty Ltd Hydrogen release system
RU2466929C1 (ru) * 2011-03-24 2012-11-20 Федеральное государственное унитарное предприятие "Российский Федеральный ядерный центр - Всероссийский научно-исследовательский институт экспериментальной физики" (ФГУП "РФЯЦ-ВНИИЭФ") Способ обработки гидрида титана
JP6285869B2 (ja) 2011-12-15 2018-02-28 ユニヴァーシティー オブ サウス ウェールズ コマーシャル サービシズ リミテッド 新規な金属水素化物及び水素貯蔵用途におけるその使用
RU2507150C1 (ru) * 2012-07-03 2014-02-20 Федеральное государственное унитарное предприятие "Российский Федеральный ядерный центр-Всероссийский научно-исследовательский институт экспериментальной физики" (ФГУП "РФЯЦ-ВНИИЭФ") Способ получения порошкообразного гидрида титана
FI3008011T3 (fi) 2013-06-14 2023-09-21 Usw Commercial Services Ltd Mangaanihydridien synteesi ja vetyvarastointiominaisuudet
KR20220156661A (ko) 2014-06-13 2022-11-25 유에스더블유 커머셜 서비시스 리미티드 신규한 금속 수소화물의 합성 및 수소 저장 특성
EP3325190A4 (en) 2015-07-23 2019-08-14 Hydrexia Pty Ltd MG-BASED ALLOY FOR HYDROGEN STORAGE
US11267702B1 (en) 2017-06-08 2022-03-08 National Technology & Engineering Solutions Of Sandia, Llc Solid state synthesis of metal borohydrides
US11192783B1 (en) * 2017-06-08 2021-12-07 National Technology & Engineering Solutions Of Sandia, Llc Ternary borides and borohydrides for hydrogen storage and method of synthesis
US11002255B2 (en) 2019-08-20 2021-05-11 Lowry Inheritors Trust Carbon negative clean fuel production system
US11976235B2 (en) 2020-10-27 2024-05-07 Battelle Savannah River Alliance, Llc High temperature thermochemical energy storage materials
CN114735643B (zh) * 2022-05-07 2023-10-27 瀚锐氢能科技集团有限公司 一种有机液态储氢材料及其性能调控方法和应用

Family Cites Families (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3720752A (en) * 1967-04-11 1973-03-13 Houten R Van Massive metal hydride structures and methods for their preparation
DE1909732A1 (de) * 1968-06-21 1970-02-19 Grosse Aristid Victor Verfahren und Vorrichtung zur Herstellung und Lagerung von Wasserstoff
US4360569A (en) * 1980-03-12 1982-11-23 The United States Of America As Represented By The United States Department Of Energy Porous metal hydride composite and preparation and uses thereof
US4790985A (en) * 1986-10-16 1988-12-13 Ethyl Corporation Synthesis of sodium aluminum hydride
US4948423A (en) * 1989-07-21 1990-08-14 Energy Conversion Devices, Inc. Alloy preparation of hydrogen storage materials
US5411928A (en) * 1993-05-24 1995-05-02 The United States Of America As Represented By The United States Department Of Energy Composition for absorbing hydrogen
DE4343321A1 (de) * 1993-12-18 1995-06-22 Varta Batterie Elektrischer Akkumulator
US5460745A (en) * 1994-02-07 1995-10-24 The United States Of America As Represented By The United States Department Of Energy Hydride compositions
DE69608182T2 (de) * 1995-07-18 2000-10-05 Matsushita Electric Industrial Co., Ltd. Wasserstoffspeichernde Legierung und Elektrode daraus
DE19526434A1 (de) * 1995-07-19 1997-01-23 Studiengesellschaft Kohle Mbh Verfahren zur reversilben Speicherung von Wasserstoff
CA2266474C (en) * 1996-09-26 2003-05-13 Toyota Jidosha Kabushiki Kaisha Hydrogen absorbing alloy powder and method of producing hydrogen absorbing alloy powder
US6074453A (en) * 1996-10-30 2000-06-13 Iowa State University Research Foundation, Inc. Ultrafine hydrogen storage powders
JPH10265802A (ja) * 1997-01-27 1998-10-06 Shin Etsu Chem Co Ltd 水素吸蔵合金粉末の製造方法及び水素吸蔵合金電極
SE9702189D0 (sv) * 1997-06-06 1997-06-06 Hoeganaes Ab Powder composition and process for the preparation thereof
CA2218271A1 (en) * 1997-10-10 1999-04-10 Mcgill University Method of fabrication of complex alkali mental hydrides
CA2220503A1 (en) * 1997-11-07 1999-05-07 Leszek Zaluski Hydrogen storage composition
DE19758384C2 (de) * 1997-12-23 2002-08-01 Geesthacht Gkss Forschung Verfahren zur Herstellung nanokristalliner Metallhydride
JP3528599B2 (ja) * 1998-05-21 2004-05-17 トヨタ自動車株式会社 水素吸蔵合金
CA2339656A1 (en) * 1998-08-06 2000-02-17 Ragaiy A. Zidan Novel hydrogen storage materials and method of making by dry homogenation
US6471935B2 (en) * 1998-08-06 2002-10-29 University Of Hawaii Hydrogen storage materials and method of making by dry homogenation
HK1041249B (en) * 1998-10-07 2003-04-17 Mcgill University Reversible hydrogen storage composition
DE69806649T2 (de) * 1998-10-07 2003-03-13 Mcgill University, Montreal Lithiumhaltiger wasserstoffspeicher
US6268077B1 (en) * 1999-03-01 2001-07-31 Motorola, Inc. Portable fuel cell power supply
US6305442B1 (en) * 1999-11-06 2001-10-23 Energy Conversion Devices, Inc. Hydrogen-based ecosystem
DE10012794A1 (de) * 2000-03-16 2001-09-20 Studiengesellschaft Kohle Mbh Verfahren zur reversiblen Speicherung von Wasserstoff auf der Basis von Alkalimetallen und Aluminium
US6680042B1 (en) * 2000-11-07 2004-01-20 Hydro-Quebec Method of rapidly carrying out a hydrogenation of a hydrogen storage material
US6596055B2 (en) * 2000-11-22 2003-07-22 Air Products And Chemicals, Inc. Hydrogen storage using carbon-metal hybrid compositions
TWI260344B (en) * 2001-01-12 2006-08-21 Safe Hydrogen Llc A method of operating a hydrogen-fueled device
US6773692B2 (en) * 2001-08-02 2004-08-10 Iowa State University Research Foundation, Inc. Method of production of pure hydrogen near room temperature from aluminum-based hydride materials
US6680043B2 (en) * 2001-11-29 2004-01-20 General Motors Corporation Process for enhancing the kinetics of hydrogenation/dehydrogenation of MAIH4 and MBH4 metal hydrides for reversible hydrogen storage
US6793909B2 (en) * 2002-01-29 2004-09-21 Sandia National Laboratories Direct synthesis of catalyzed hydride compounds
US20030165423A1 (en) * 2002-01-29 2003-09-04 Gross Karl J. Direct synthesis of hydride compounds using a titanium aluminate dopant
US7011768B2 (en) * 2002-07-10 2006-03-14 Fuelsell Technologies, Inc. Methods for hydrogen storage using doped alanate compositions
US7094387B2 (en) 2002-11-01 2006-08-22 Washington Savannah River Company Llc Complex hydrides for hydrogen storage

Also Published As

Publication number Publication date
JP2006504616A (ja) 2006-02-09
US7094387B2 (en) 2006-08-22
DE60335896D1 (enExample) 2011-03-10
CA2503025C (en) 2011-01-04
EP1558520A1 (en) 2005-08-03
WO2004041717A1 (en) 2004-05-21
ATE496865T1 (de) 2011-02-15
CA2503025A1 (en) 2004-05-21
EP1558520A4 (en) 2009-03-18
US20040105805A1 (en) 2004-06-03
AU2003286873A1 (en) 2004-06-07
EP1558520B1 (en) 2011-01-26

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