CA2420346A1 - Low cost, corrosion and heat resistant alloy for diesel engine valves - Google Patents
Low cost, corrosion and heat resistant alloy for diesel engine valves Download PDFInfo
- Publication number
- CA2420346A1 CA2420346A1 CA002420346A CA2420346A CA2420346A1 CA 2420346 A1 CA2420346 A1 CA 2420346A1 CA 002420346 A CA002420346 A CA 002420346A CA 2420346 A CA2420346 A CA 2420346A CA 2420346 A1 CA2420346 A1 CA 2420346A1
- Authority
- CA
- Canada
- Prior art keywords
- alloy
- diesel engine
- alloys
- weight percent
- corrosion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 96
- 239000000956 alloy Substances 0.000 title claims abstract description 96
- 230000007797 corrosion Effects 0.000 title claims abstract description 19
- 238000005260 corrosion Methods 0.000 title claims abstract description 19
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 14
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 11
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 11
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 9
- 239000012535 impurity Substances 0.000 claims abstract description 9
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 8
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 8
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000010955 niobium Substances 0.000 description 33
- 239000010936 titanium Substances 0.000 description 18
- 150000001247 metal acetylides Chemical class 0.000 description 14
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 14
- 239000011651 chromium Substances 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 13
- 238000012360 testing method Methods 0.000 description 12
- 238000005299 abrasion Methods 0.000 description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
- 229910000990 Ni alloy Inorganic materials 0.000 description 5
- 239000011572 manganese Substances 0.000 description 5
- 238000001556 precipitation Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 229910000601 superalloy Inorganic materials 0.000 description 4
- 238000005275 alloying Methods 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 229910052796 boron Inorganic materials 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 230000008092 positive effect Effects 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 238000005098 hot rolling Methods 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 229910001235 nimonic Inorganic materials 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 238000005728 strengthening Methods 0.000 description 2
- 230000035882 stress Effects 0.000 description 2
- 229910052715 tantalum Inorganic materials 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910018487 Ni—Cr Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052925 anhydrite Inorganic materials 0.000 description 1
- 229910001566 austenite Inorganic materials 0.000 description 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Inorganic materials [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 230000003467 diminishing effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000009661 fatigue test Methods 0.000 description 1
- 238000005552 hardfacing Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- VSZWPYCFIRKVQL-UHFFFAOYSA-N selanylidenegallium;selenium Chemical compound [Se].[Se]=[Ga].[Se]=[Ga] VSZWPYCFIRKVQL-UHFFFAOYSA-N 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/03—Alloys based on nickel or cobalt based on nickel
- C22C19/05—Alloys based on nickel or cobalt based on nickel with chromium
- C22C19/058—Alloys based on nickel or cobalt based on nickel with chromium without Mo and W
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C30/00—Alloys containing less than 50% by weight of each constituent
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01L—CYCLICALLY OPERATING VALVES FOR MACHINES OR ENGINES
- F01L3/00—Lift-valve, i.e. cut-off apparatus with closure members having at least a component of their opening and closing motion perpendicular to the closing faces; Parts or accessories thereof
- F01L3/02—Selecting particular materials for valve-members or valve-seats; Valve-members or valve-seats composed of two or more materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Heat Treatment Of Steel (AREA)
- Cylinder Crankcases Of Internal Combustion Engines (AREA)
- Powder Metallurgy (AREA)
- Pressure Welding/Diffusion-Bonding (AREA)
- Exhaust Silencers (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US22770000P | 2000-08-24 | 2000-08-24 | |
| US60/227,700 | 2000-08-24 | ||
| US66348900A | 2000-09-18 | 2000-09-18 | |
| US09/663,489 | 2000-09-18 | ||
| PCT/US2001/026277 WO2002016661A2 (en) | 2000-08-24 | 2001-08-23 | Low cost, corrosion and heat resistant alloy for diesel engine valves |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2420346A1 true CA2420346A1 (en) | 2002-02-28 |
Family
ID=26921676
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002420346A Abandoned CA2420346A1 (en) | 2000-08-24 | 2001-08-23 | Low cost, corrosion and heat resistant alloy for diesel engine valves |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6372181B1 (enExample) |
| EP (1) | EP1313888B1 (enExample) |
| JP (1) | JP3905034B2 (enExample) |
| AT (1) | ATE267271T1 (enExample) |
| AU (1) | AU2001285211A1 (enExample) |
| CA (1) | CA2420346A1 (enExample) |
| DE (1) | DE60103410T2 (enExample) |
| WO (1) | WO2002016661A2 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111074131A (zh) * | 2019-12-26 | 2020-04-28 | 西北工业大学 | 一种共晶高熵合金的热机械处理方法 |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7651575B2 (en) * | 2006-07-07 | 2010-01-26 | Eaton Corporation | Wear resistant high temperature alloy |
| US7744813B2 (en) * | 2007-01-04 | 2010-06-29 | Ut-Battelle, Llc | Oxidation resistant high creep strength austenitic stainless steel |
| US7754144B2 (en) * | 2007-01-04 | 2010-07-13 | Ut-Battelle, Llc | High Nb, Ta, and Al creep- and oxidation-resistant austenitic stainless steel |
| US7754305B2 (en) * | 2007-01-04 | 2010-07-13 | Ut-Battelle, Llc | High Mn austenitic stainless steel |
| US20090081073A1 (en) * | 2007-06-07 | 2009-03-26 | Celso Antonio Barbosa | Alloys with high corrosion resistance for engine valve applications |
| US20090081074A1 (en) * | 2007-06-07 | 2009-03-26 | Celso Antonio Barbosa | Wear resistant alloy for high temprature applications |
| JP5769204B2 (ja) * | 2012-12-28 | 2015-08-26 | 株式会社日本製鋼所 | 高温特性および耐水素脆化特性に優れたＦｅ−Ｎｉ基合金およびその製造方法 |
| US9540714B2 (en) | 2013-03-15 | 2017-01-10 | Ut-Battelle, Llc | High strength alloys for high temperature service in liquid-salt cooled energy systems |
| US9683280B2 (en) | 2014-01-10 | 2017-06-20 | Ut-Battelle, Llc | Intermediate strength alloys for high temperature service in liquid-salt cooled energy systems |
| US9683279B2 (en) | 2014-05-15 | 2017-06-20 | Ut-Battelle, Llc | Intermediate strength alloys for high temperature service in liquid-salt cooled energy systems |
| US9605565B2 (en) | 2014-06-18 | 2017-03-28 | Ut-Battelle, Llc | Low-cost Fe—Ni—Cr alloys for high temperature valve applications |
| JP6688598B2 (ja) * | 2015-11-11 | 2020-04-28 | 三菱日立パワーシステムズ株式会社 | オーステナイト鋼およびそれを用いたオーステナイト鋼鋳造品 |
| JP2019516011A (ja) | 2016-04-20 | 2019-06-13 | アーコニック インコーポレイテッドＡｒｃｏｎｉｃ Ｉｎｃ． | アルミニウム、コバルト、鉄、及びニッケルのｆｃｃ材料、並びにそれを用いた製品 |
| WO2017184778A1 (en) | 2016-04-20 | 2017-10-26 | Arconic Inc. | Fcc materials of aluminum, cobalt and nickel, and products made therefrom |
| US11866809B2 (en) | 2021-01-29 | 2024-01-09 | Ut-Battelle, Llc | Creep and corrosion-resistant cast alumina-forming alloys for high temperature service in industrial and petrochemical applications |
| US11479836B2 (en) | 2021-01-29 | 2022-10-25 | Ut-Battelle, Llc | Low-cost, high-strength, cast creep-resistant alumina-forming alloys for heat-exchangers, supercritical CO2 systems and industrial applications |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1419078A (fr) * | 1964-04-15 | 1965-11-26 | Special Metals Corp | Alliage perfectionné de résistance élevée, à base de nickel |
| JPS5620148A (en) * | 1979-07-25 | 1981-02-25 | Daido Steel Co Ltd | Alloy for exhaust valve |
| US4379120B1 (en) | 1980-07-28 | 1999-08-24 | Crs Holdings Inc | Sulfidation resistant nickel-iron base alloy |
| JPS60211028A (ja) | 1984-04-03 | 1985-10-23 | Daido Steel Co Ltd | 排気バルブ用合金 |
| JPS60234938A (ja) * | 1984-05-02 | 1985-11-21 | Aichi Steel Works Ltd | 高温特性の優れた排気弁用合金 |
| JPS61119640A (ja) | 1984-11-16 | 1986-06-06 | Honda Motor Co Ltd | 排気バルブ用合金 |
| JPS61130464A (ja) | 1984-11-30 | 1986-06-18 | Nippon Steel Corp | 高耐食性高強度ドリルカラ−用非磁性鋼 |
| US4867116A (en) | 1988-05-23 | 1989-09-19 | Inco Alloys International, Inc. | Aircraft exhaust valves |
| JPH04304337A (ja) * | 1991-04-01 | 1992-10-27 | Hitachi Metals Ltd | エンジンバルブ用耐熱合金 |
| JP3058794B2 (ja) * | 1993-08-19 | 2000-07-04 | 日立金属株式会社 | Ｆｅ−Ｎｉ−Ｃｒ基超耐熱合金、エンジンバルブおよび排ガス触媒用ニットメッシュ |
| JP2963842B2 (ja) | 1994-06-15 | 1999-10-18 | 大同特殊鋼株式会社 | 排気バルブ用合金 |
| JPH09279309A (ja) | 1996-04-12 | 1997-10-28 | Daido Steel Co Ltd | Ｆｅ−Ｃｒ−Ｎｉ系耐熱合金 |
| DE69710409T2 (de) | 1996-10-25 | 2002-11-07 | Daido Tokushuko K.K., Nagoya | Hitzebeständige Legierung für Auslassventile und Verfahren zur Herstellung derartiger Auslassventile |
| JPH10219377A (ja) | 1997-02-07 | 1998-08-18 | Daido Steel Co Ltd | ディーゼルエンジンの高耐食性吸排気バルブ用合金及び吸排気バルブの製造方法 |
| JPH11117019A (ja) * | 1997-10-09 | 1999-04-27 | Daido Steel Co Ltd | 耐熱部品の製造方法 |
-
2001
- 2001-08-22 US US09/934,892 patent/US6372181B1/en not_active Expired - Lifetime
- 2001-08-23 EP EP01964346A patent/EP1313888B1/en not_active Expired - Lifetime
- 2001-08-23 AT AT01964346T patent/ATE267271T1/de active
- 2001-08-23 AU AU2001285211A patent/AU2001285211A1/en not_active Abandoned
- 2001-08-23 CA CA002420346A patent/CA2420346A1/en not_active Abandoned
- 2001-08-23 WO PCT/US2001/026277 patent/WO2002016661A2/en not_active Ceased
- 2001-08-23 DE DE60103410T patent/DE60103410T2/de not_active Expired - Lifetime
- 2001-08-23 JP JP2002522331A patent/JP3905034B2/ja not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111074131A (zh) * | 2019-12-26 | 2020-04-28 | 西北工业大学 | 一种共晶高熵合金的热机械处理方法 |
| CN111074131B (zh) * | 2019-12-26 | 2021-07-20 | 西北工业大学 | 一种共晶高熵合金的热机械处理方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE60103410D1 (de) | 2004-06-24 |
| ATE267271T1 (de) | 2004-06-15 |
| EP1313888B1 (en) | 2004-05-19 |
| US6372181B1 (en) | 2002-04-16 |
| DE60103410T2 (de) | 2005-06-30 |
| WO2002016661A2 (en) | 2002-02-28 |
| JP3905034B2 (ja) | 2007-04-18 |
| JP2004512428A (ja) | 2004-04-22 |
| EP1313888A2 (en) | 2003-05-28 |
| AU2001285211A1 (en) | 2002-03-04 |
| WO2002016661A3 (en) | 2002-06-06 |
| US20020044882A1 (en) | 2002-04-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Discontinued |