CA2397738C - Organometal catalyst compositions - Google Patents

Organometal catalyst compositions Download PDF

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Publication number
CA2397738C
CA2397738C CA002397738A CA2397738A CA2397738C CA 2397738 C CA2397738 C CA 2397738C CA 002397738 A CA002397738 A CA 002397738A CA 2397738 A CA2397738 A CA 2397738A CA 2397738 C CA2397738 C CA 2397738C
Authority
CA
Canada
Prior art keywords
group
substituted
combination
aliphatic
cyclic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CA002397738A
Other languages
English (en)
French (fr)
Other versions
CA2397738A1 (en
Inventor
Max P. Mcdaniel
Joseph S. Shveima
James L. Smith
Kathy S. Collins
Elizabeth A. Benham
Anthony P. Eaton
Michael D. Jensen
Joel L. Martin
Gil R. Hawley
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Phillips Petroleum Co
Original Assignee
Phillips Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/564,293 external-priority patent/US6632894B1/en
Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co
Publication of CA2397738A1 publication Critical patent/CA2397738A1/en
Application granted granted Critical
Publication of CA2397738C publication Critical patent/CA2397738C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/16—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of silicon, germanium, tin, lead, titanium, zirconium or hafnium
    • C08F4/18—Oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C08F4/025—Metal oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/49—Hafnium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Catalysts (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Polymerization Catalysts (AREA)
CA002397738A 1999-12-30 2000-12-28 Organometal catalyst compositions Expired - Lifetime CA2397738C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US17404599P 1999-12-30 1999-12-30
US60/174,045 1999-12-30
US09/564,293 US6632894B1 (en) 1999-12-30 2000-05-03 Organometal catalyst compositions
US09/564,293 2000-05-03
PCT/US2000/035493 WO2001049747A1 (en) 1999-12-30 2000-12-28 Organometal catalyst compositions

Publications (2)

Publication Number Publication Date
CA2397738A1 CA2397738A1 (en) 2001-07-12
CA2397738C true CA2397738C (en) 2008-07-22

Family

ID=26869806

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002397738A Expired - Lifetime CA2397738C (en) 1999-12-30 2000-12-28 Organometal catalyst compositions

Country Status (12)

Country Link
EP (1) EP1268569B1 (no)
JP (1) JP2003519252A (no)
KR (1) KR20020061016A (no)
CN (1) CN1267191C (no)
AR (1) AR029427A1 (no)
AU (1) AU2741601A (no)
CA (1) CA2397738C (no)
HU (1) HUP0203909A3 (no)
MX (1) MXPA02006520A (no)
NO (1) NO20023162L (no)
RU (1) RU2002120193A (no)
TW (1) TW514649B (no)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100473757C (zh) * 2002-12-23 2009-04-01 应用薄膜公司 磷酸铝涂层
DE102005012638A1 (de) * 2005-03-18 2006-09-21 Süd-Chemie AG Granulate aus natürlichen Schichtmineralien und Verfahren zu deren Herstellung
KR100979541B1 (ko) * 2008-07-16 2010-09-02 삼성전기주식회사 프리프레그, 프리프레그 제조방법 및 이를 이용한동박적층판
CN102558401B (zh) * 2012-02-15 2014-07-02 中国科学院长春应用化学研究所 一种遥爪聚合物的制备方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3652457A (en) * 1968-09-30 1972-03-28 Chevron Res Hydrothermal method of manufacturing a hydrocarbon conversion catalyst containing at least one hydrogenating component and the catalyst so manufactured
JP2507903B2 (ja) * 1991-02-01 1996-06-19 工業技術院長 任意の層間隔を有する層間架橋粘土の製造法
BE1007148A3 (fr) * 1993-05-17 1995-04-11 Solvay Support pour catalyseurs, procede pour la fabrication d'un gel precurseur d'un support pour catalyseurs, procede de preparation d'un support pour catalyseurs, catalyseur pour la polymerisation d'olefines et procede pour la polymerisation d'olefines au moyen de ce catalyseur.
US5726113A (en) * 1996-03-19 1998-03-10 Board Of Trustees Operating Michigan State University Porous clay heterostructures prepared by gallery templated synthesis
DE69801299T2 (de) * 1997-04-25 2002-04-18 Mitsubishi Chemical Corp., Tokio/Tokyo Phyllosilikat-geträgerter Katalysator für die Olefinenpolymerisation
WO2000043123A1 (fr) * 1999-01-21 2000-07-27 Idemitsu Petrochemical Co., Ltd. CATALYSEURS DESTINES A LA PRODUCTION DE α-OLEFINE ET PROCEDES DE FABRICATION DE α-OLEFINE
ID28180A (id) * 1999-06-11 2001-05-10 Idemitsu Petrochemical Co Katalis untuk memproduksi alva-olefin dan metoda untuk memproduksi alva olefin
KR100796103B1 (ko) * 1999-08-11 2008-01-21 아크조 노벨 엔.브이. 내마모성의 성형된 음이온성 클레이-함유 결정체
AU3434001A (en) * 1999-10-07 2001-05-08 Dow Chemical Company, The Nanocomposite polymers

Also Published As

Publication number Publication date
CA2397738A1 (en) 2001-07-12
TW514649B (en) 2002-12-21
HUP0203909A2 (hu) 2003-03-28
RU2002120193A (ru) 2004-01-10
AR029427A1 (es) 2003-06-25
HUP0203909A3 (en) 2006-07-28
EP1268569B1 (en) 2014-07-02
AU2741601A (en) 2001-07-16
MXPA02006520A (es) 2002-12-09
NO20023162L (no) 2002-08-23
CN1301600A (zh) 2001-07-04
EP1268569A4 (en) 2006-06-21
NO20023162D0 (no) 2002-06-28
JP2003519252A (ja) 2003-06-17
KR20020061016A (ko) 2002-07-20
CN1267191C (zh) 2006-08-02
EP1268569A1 (en) 2003-01-02

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