CA2321611A1 - Composition catalytique comprenant un compose de titane, une amine et un compose phosphore, leur preparation et leur utilisation - Google Patents

Composition catalytique comprenant un compose de titane, une amine et un compose phosphore, leur preparation et leur utilisation Download PDF

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Publication number
CA2321611A1
CA2321611A1 CA002321611A CA2321611A CA2321611A1 CA 2321611 A1 CA2321611 A1 CA 2321611A1 CA 002321611 A CA002321611 A CA 002321611A CA 2321611 A CA2321611 A CA 2321611A CA 2321611 A1 CA2321611 A1 CA 2321611A1
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CA
Canada
Prior art keywords
acid
group
combinations
glycol
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002321611A
Other languages
English (en)
Inventor
Donald Edward Putzig
Edward Francis Mcbride
Hiep Quang Do
James Arthur Trainham
Hermann Ludwig Jaeger
Heiner Schulte
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/291,960 external-priority patent/US6066714A/en
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of CA2321611A1 publication Critical patent/CA2321611A1/fr
Abandoned legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0212—Alkoxylates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255—Phosphorus containing compounds
    • B01J31/0257—Phosphorus acids or phosphorus acid esters
    • B01J31/0258—Phosphoric acid mono-, di- or triesters ((RO)(R'O)2P=O), i.e. R= C, R'= C, H
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/14—Other (co) polymerisation, e.g. of lactides, epoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

L'invention se rapporte à une composition catalytique qui comprend un composé à base de titane, un composé à base de phosphore, une amine, un solvant et éventuellement un cocatalyseur dans lequel le composé phosphoré possède une formule sélectionnée dans un groupe comprenant (R?1¿O)¿x?(PO)(OH)¿3-x?, (R?1¿O)¿y?(P¿2?O¿3?)(OH)¿4-y? et leurs combinaisons, l'amine étant une amine tertiaire, chaque R?1¿ se présentant indépendamment comme un radical d'alkyle linéaire ou ramifié qui contient entre un et vingt atomes de carbone par radical; x est 1 ou 2; et y est 1, 2 ou 3. Le cocatalyseur peut être un catalyseur à base de cobalt/d'aluminium, un composé à base d'antimoine ou leurs combinaisons. L'invention concerne également un procédé pour fabriquer cette composition. Le procédé consiste à combiner un composé à base de titane, un composé à base de phosphore, un solvant, une amine et éventuellement un cocatalyseur. Le composé à base de phosphore, le solvant et l'amine sont les mêmes que décrits ci-dessus. L'invention concerne en outre un process pour utiliser cette composition qui consiste à mettre en contact un composé carbonylé, en présence de la composition, avec un alcool, et ce dans des conditions propices à l'estérification, à la transestérification, à la polymérisation ou à leurs combinaisons.
CA002321611A 1998-04-17 1999-04-16 Composition catalytique comprenant un compose de titane, une amine et un compose phosphore, leur preparation et leur utilisation Abandoned CA2321611A1 (fr)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US6246398A 1998-04-17 1998-04-17
US09/062,463 1999-04-15
US09/291,960 US6066714A (en) 1998-04-17 1999-04-15 Titanium-containing catalyst composition and processes therefor and therewith
US09/291,960 1999-04-15
PCT/US1999/008338 WO1999054040A1 (fr) 1998-04-17 1999-04-16 Composition catalytique comprenant un compose de titane, une amine et un compose phosphore, leur preparation et leur utilisation

Publications (1)

Publication Number Publication Date
CA2321611A1 true CA2321611A1 (fr) 1999-10-28

Family

ID=26742291

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002321611A Abandoned CA2321611A1 (fr) 1998-04-17 1999-04-16 Composition catalytique comprenant un compose de titane, une amine et un compose phosphore, leur preparation et leur utilisation

Country Status (10)

Country Link
EP (1) EP1071510A1 (fr)
JP (1) JP2002512267A (fr)
CN (1) CN1297376A (fr)
AU (1) AU3565199A (fr)
BR (1) BR9908410A (fr)
CA (1) CA2321611A1 (fr)
ID (1) ID26040A (fr)
PL (1) PL343600A1 (fr)
TR (1) TR200002988T2 (fr)
WO (1) WO1999054040A1 (fr)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6350895B1 (en) 1999-03-26 2002-02-26 E. I. Du Pont De Nemours And Company Transesterification process using yttrium and samarium compound catalystis
GB9912210D0 (en) * 1999-05-25 1999-07-28 Acma Ltd Esterification catalysts
US6255442B1 (en) 2000-02-08 2001-07-03 E. I. Du Pont De Nemours And Company Esterification process
BR0017106B1 (pt) 2000-02-11 2010-07-27 processo contìnuo para a produção do poli(trimetileno tereftalato).
US6951954B1 (en) 2000-02-11 2005-10-04 E.I. Du Pont De Nemours And Company Continuous process for producing bis(3-hydroxypropyl) terephthalate
EP1183409B1 (fr) 2000-03-03 2005-11-16 E.I. Du Pont De Nemours And Company Fil poly(trimethylene terephthalate)
US6914107B2 (en) * 2001-01-24 2005-07-05 E. I. Du Pont De Nemours And Company Catalyst composition and process therewith
US6489433B2 (en) * 2001-02-23 2002-12-03 E. I. Du Pont De Nemours And Company Metal-containing composition and process therewith
JP4329427B2 (ja) 2003-06-26 2009-09-09 東レ株式会社 ポリエステル組成物及びそれからなる繊維
JP2005139247A (ja) * 2003-11-05 2005-06-02 Toray Ind Inc ポリエステル重合用触媒及びそれを用いたポリエステルの製造方法
JP5326741B2 (ja) * 2008-09-29 2013-10-30 東レ株式会社 ポリエステル重合触媒およびそれを用いるポリエステルの製造方法
WO2014022197A1 (fr) * 2012-07-30 2014-02-06 Sabic Innovative Plastics Ip B.V. Procédé de préparation de poly(alkylène téréphtalate) modifié employant un complexe de catalyseur contenant du titane
US9944773B2 (en) * 2014-01-28 2018-04-17 Sabic Global Technologies B.V. Modified endcapped poly(alkylene terephthalate) prepared by employing an in situ titanium-containing catalyst and compositions derived therefrom
CN109666447A (zh) * 2019-01-16 2019-04-23 江西奋发科技有限公司 一种单组份脱醇型硅橡胶密封剂及其制备方法
JP7132979B2 (ja) * 2019-07-26 2022-09-07 三洋化成工業株式会社 トナー用ポリエステル樹脂及びトナーの製造方法
CN116589670A (zh) * 2023-06-30 2023-08-15 浙江大学 一种耐高温水解醇钛有机碱催化剂及其制备方法和应用

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0102115B1 (fr) * 1982-08-17 1987-06-10 Akzo N.V. Polyester-esteruréthane
CA1228195A (fr) * 1984-08-03 1987-10-13 Takayuki Nakano Copolyester aromatique derive d'un acide aromatique dicarboxylique et d'un diol aromatique
JPS62225523A (ja) * 1986-03-28 1987-10-03 Toray Ind Inc 高重合度ポリブチレンテレフタレ−ト系重合体の製造法
FR2653036B1 (fr) * 1989-10-17 1992-01-10 Inst Francais Du Petrole Composition catalytique comprenant du titane et du phosphore, sa preparation et son utilisation pour la condensation d'un epoxyde sur un anhydride d'acide carboxylique.

Also Published As

Publication number Publication date
WO1999054040A1 (fr) 1999-10-28
AU3565199A (en) 1999-11-08
EP1071510A1 (fr) 2001-01-31
TR200002988T2 (tr) 2001-02-21
BR9908410A (pt) 2000-12-26
CN1297376A (zh) 2001-05-30
ID26040A (id) 2000-11-16
JP2002512267A (ja) 2002-04-23
PL343600A1 (en) 2001-08-27

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