CA2305795C - Method for increasing light olefin yield by conversion of a heavy hydrocarbon fraction of a product to light olefins - Google Patents
Method for increasing light olefin yield by conversion of a heavy hydrocarbon fraction of a product to light olefins Download PDFInfo
- Publication number
- CA2305795C CA2305795C CA002305795A CA2305795A CA2305795C CA 2305795 C CA2305795 C CA 2305795C CA 002305795 A CA002305795 A CA 002305795A CA 2305795 A CA2305795 A CA 2305795A CA 2305795 C CA2305795 C CA 2305795C
- Authority
- CA
- Canada
- Prior art keywords
- reactor
- hydrocarbon fraction
- heavy hydrocarbon
- whsv
- sapo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 76
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 76
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 68
- 238000000034 method Methods 0.000 title claims abstract description 65
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 51
- 239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 48
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title abstract description 14
- 239000003054 catalyst Substances 0.000 claims abstract description 52
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000002808 molecular sieve Substances 0.000 claims abstract description 23
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 20
- 239000005977 Ethylene Substances 0.000 claims description 20
- 239000011148 porous material Substances 0.000 claims description 11
- 239000010457 zeolite Substances 0.000 claims description 11
- 229910021536 Zeolite Inorganic materials 0.000 claims description 6
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 6
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 6
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 5
- 238000004064 recycling Methods 0.000 claims description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 36
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 25
- 241000269350 Anura Species 0.000 description 12
- 239000003085 diluting agent Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- -1 aliphatic alcohols Chemical class 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 239000003208 petroleum Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229910001868 water Inorganic materials 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000004939 coking Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000012808 vapor phase Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000000571 coke Substances 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- GHOKWGTUZJEAQD-ZETCQYMHSA-N (D)-(+)-Pantothenic acid Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCC(O)=O GHOKWGTUZJEAQD-ZETCQYMHSA-N 0.000 description 1
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
- QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 description 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 1
- XOBKSJJDNFUZPF-UHFFFAOYSA-N Methoxyethane Chemical compound CCOC XOBKSJJDNFUZPF-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 235000013844 butane Nutrition 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000001728 carbonyl compounds Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- LJSQFQKUNVCTIA-UHFFFAOYSA-N diethyl sulfide Chemical compound CCSCC LJSQFQKUNVCTIA-UHFFFAOYSA-N 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229960003750 ethyl chloride Drugs 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical class CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 125000004817 pentamethylene group Chemical class [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 238000005120 petroleum cracking Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003463 sulfur Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
- C10G3/44—Catalytic treatment characterised by the catalyst used
- C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
- C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/82—Phosphates
- C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
- C07C2529/85—Silicoaluminophosphates (SAPO compounds)
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4025—Yield
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/20—C2-C4 olefins
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/40—Ethylene production
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/943,399 US6455749B1 (en) | 1997-10-03 | 1997-10-03 | Method for increasing light olefin yield by conversion of a heavy hydrocarbon fraction of a product to light olefins |
| US08/943,399 | 1997-10-03 | ||
| PCT/US1998/020070 WO1999018055A1 (en) | 1997-10-03 | 1998-09-25 | Method for increasing light olefin yield by conversion of a heavy hydrocarbon fraction of a product to light olefins |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2305795A1 CA2305795A1 (en) | 1999-04-15 |
| CA2305795C true CA2305795C (en) | 2007-10-30 |
Family
ID=25479583
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002305795A Expired - Fee Related CA2305795C (en) | 1997-10-03 | 1998-09-25 | Method for increasing light olefin yield by conversion of a heavy hydrocarbon fraction of a product to light olefins |
Country Status (17)
| Country | Link |
|---|---|
| US (2) | US6455749B1 (https=) |
| EP (1) | EP1025068B1 (https=) |
| JP (1) | JP2001519321A (https=) |
| KR (1) | KR100549878B1 (https=) |
| CN (1) | CN1138731C (https=) |
| AR (1) | AR015944A1 (https=) |
| AT (1) | ATE230387T1 (https=) |
| AU (1) | AU757031B2 (https=) |
| BR (1) | BR9812710A (https=) |
| CA (1) | CA2305795C (https=) |
| DE (1) | DE69810506T2 (https=) |
| ES (1) | ES2190111T3 (https=) |
| MY (1) | MY129560A (https=) |
| SA (1) | SA98190717B1 (https=) |
| TW (1) | TW400373B (https=) |
| WO (1) | WO1999018055A1 (https=) |
| ZA (1) | ZA988960B (https=) |
Families Citing this family (56)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6552240B1 (en) | 1997-07-03 | 2003-04-22 | Exxonmobil Chemical Patents Inc. | Method for converting oxygenates to olefins |
| RO114524B1 (ro) | 1997-10-02 | 1999-05-28 | Sc Zecasin Sa | Procedeu de fabricare a oleofinelor cu greutate moleculara mica prin conversia catalitica in strat fluidizat a metanolului |
| US6455749B1 (en) * | 1997-10-03 | 2002-09-24 | Exxonmobil Chemical Patents, Inc. | Method for increasing light olefin yield by conversion of a heavy hydrocarbon fraction of a product to light olefins |
| US6444868B1 (en) * | 1999-02-17 | 2002-09-03 | Exxon Mobil Chemical Patents Inc. | Process to control conversion of C4+ and heavier stream to lighter products in oxygenate conversion reactions |
| US6437208B1 (en) * | 1999-09-29 | 2002-08-20 | Exxonmobil Chemical Patents Inc. | Making an olefin product from an oxygenate |
| DE60014454T2 (de) * | 2000-05-09 | 2005-11-24 | Exxonmobil Chemical Patents Inc., Baytown | Verfahren zur umwandlung von oygenaten zu olefinen |
| US7247764B2 (en) | 2002-08-14 | 2007-07-24 | Exxonmobil Chemical Patents Inc. | Conversion process |
| US7317133B2 (en) * | 2002-11-21 | 2008-01-08 | Uop Llc | Process for enhanced olefin production |
| US7084319B2 (en) | 2003-12-05 | 2006-08-01 | Exxonmobil Chemical Patents Inc. | Catalyst fluidization in oxygenate to olefin reaction systems |
| US7663012B2 (en) * | 2004-06-25 | 2010-02-16 | Uop Llc | Conversion of dimethylether to propylene using moving bed technology |
| US7371915B1 (en) | 2004-06-25 | 2008-05-13 | Uop Llc | Conversion of oxygenate to propylene using moving bed technology |
| US7371916B1 (en) | 2004-09-16 | 2008-05-13 | Uop Llc | Conversion of an alcoholic oxygenate to propylene using moving bed technology and an etherification step |
| US7405337B2 (en) * | 2004-09-21 | 2008-07-29 | Uop Llc | Conversion of oxygenate to propylene with selective hydrogen treatment of heavy olefin recycle stream |
| US7408092B2 (en) * | 2004-11-12 | 2008-08-05 | Uop Llc | Selective conversion of oxygenate to propylene using moving bed technology and a hydrothermally stabilized dual-function catalyst |
| US7414167B2 (en) * | 2005-01-14 | 2008-08-19 | Uop Llc | Conversion of oxygenate to propylene using moving bed technology and a separate heavy olefin interconversion step |
| EP1846156B1 (en) | 2005-01-31 | 2018-08-08 | ExxonMobil Chemical Patents Inc. | Molecular sieve catalyst compositions, its making and use in coversion processes |
| DE102005029399B4 (de) * | 2005-06-24 | 2015-03-05 | Air Liquide Global E&C Solutions Germany Gmbh | Verfahren und Anlage zur Herstellung von C2-C4-Olefinen aus Methanol und/oder Dimethylether mit erhöhter Ausbeute |
| US7687671B2 (en) * | 2005-12-05 | 2010-03-30 | Uop Llc | Integrated oxygenate conversion and product cracking |
| EP2004776A1 (en) * | 2006-03-31 | 2008-12-24 | ExxonMobil Chemical Patents Inc. | Product recovery in gas-solids reactors |
| US7744746B2 (en) | 2006-03-31 | 2010-06-29 | Exxonmobil Research And Engineering Company | FCC catalyst stripper configuration |
| US7582268B1 (en) | 2006-07-12 | 2009-09-01 | Uop Llc | Reactor system with interstage product removal |
| CN101104576B (zh) * | 2006-07-13 | 2010-08-25 | 中国石油化工股份有限公司 | 一种有机含氧化合物和烃类的联合催化转化方法 |
| US7722825B1 (en) | 2006-07-31 | 2010-05-25 | Uop Llc | Preparing a light-olefin containing product stream from an oxygenate-containing feed stream using reactors directing a flow of a fluidized dual-function catalyst system |
| US20080081936A1 (en) * | 2006-09-29 | 2008-04-03 | Bozzano Andrea G | Integrated processing of methanol to olefins |
| CN101165022B (zh) * | 2006-10-20 | 2011-07-20 | 中国石油化工股份有限公司 | 提高乙烯及丙烯收率的方法 |
| CN101165024B (zh) * | 2006-10-20 | 2010-06-16 | 中国石油化工股份有限公司 | 提高丙烯选择性及收率的方法 |
| CN101165023B (zh) * | 2006-10-20 | 2010-12-01 | 中国石油化工股份有限公司 | 提高乙烯、丙烯选择性及收率的方法 |
| CN101177374B (zh) * | 2006-11-07 | 2011-06-01 | 中国科学院大连化学物理研究所 | 一种由甲醇或二甲醚生产丙烯的方法 |
| US7935650B2 (en) | 2006-12-18 | 2011-05-03 | Uop Llc | Neutralization of quench stream in a process for handling catalyst from an oxygenate-to-olefin reaction |
| US7998246B2 (en) | 2006-12-18 | 2011-08-16 | Uop Llc | Gas separations using high performance mixed matrix membranes |
| US7815712B2 (en) | 2006-12-18 | 2010-10-19 | Uop Llc | Method of making high performance mixed matrix membranes using suspensions containing polymers and polymer stabilized molecular sieves |
| CN101157593B (zh) * | 2007-03-07 | 2010-09-22 | 中国科学院大连化学物理研究所 | 由甲醇或/和二甲醚生产低碳烯烃的方法 |
| CN101279877B (zh) * | 2007-04-04 | 2011-07-20 | 中国石油化工股份有限公司 | 含氧化合物转化过程中提高乙烯、丙烯收率的方法 |
| CN101417914B (zh) * | 2007-10-26 | 2012-05-30 | 中国石油化工股份有限公司 | 一种以烃类为部分原料的甲醇制备丙烯方法 |
| AU2009211370A1 (en) * | 2008-02-07 | 2009-08-13 | Total Petrochemicals Research Feluy | Dehydration of alcohols in the presence of an inert component |
| WO2009156435A2 (en) * | 2008-06-25 | 2009-12-30 | Total Petrochemicals Research Feluy | Process to make olefins and aromatics from organics |
| CN102076636B (zh) * | 2008-06-25 | 2014-04-16 | 道达尔石油化学产品研究弗吕公司 | 由含氧化合物制造烯烃的方法 |
| US8957273B2 (en) * | 2008-06-25 | 2015-02-17 | Total Research & Technology Feluy | Process to make olefins from organics |
| EA020577B1 (ru) * | 2008-06-25 | 2014-12-30 | Тотал Ресерч Энд Текнолоджи Фелюи | Способ получения олефинов из оксигенатов |
| CN102666794B (zh) | 2009-11-10 | 2015-12-02 | 国际壳牌研究有限公司 | 用于制备低级烯烃产品的方法 |
| BR112012011078A2 (pt) * | 2009-11-10 | 2016-07-05 | Shell Int Research | processo para produção de olefinas |
| EP2499219A2 (en) * | 2009-11-10 | 2012-09-19 | Shell Internationale Research Maatschappij B.V. | Process for producing olefins |
| BR112012010865A2 (pt) * | 2009-11-10 | 2019-09-24 | Shell International Res Maatshappij B V | "processo para a produção de óxido de etileno". |
| AU2010318050B2 (en) | 2009-11-10 | 2013-12-12 | Shell Internationale Research Maatschappij B.V. | Process and integrated system for the preparation of a lower olefin product |
| CN101723778B (zh) * | 2009-11-27 | 2013-10-16 | 清华大学 | 一种用醇或醚制备烯烃与烷烃脱氢的耦合工艺方法 |
| CN102372547B (zh) * | 2010-08-23 | 2013-12-25 | 中国石油化工股份有限公司 | 含氧化合物脱水制低碳烯烃的方法 |
| CN102372574A (zh) * | 2010-08-27 | 2012-03-14 | 中国石油化工股份有限公司 | 一种加入甲醇和/或二甲醚的c4烯烃裂解制丙烯方法 |
| US20120083634A1 (en) * | 2010-09-30 | 2012-04-05 | Uop Llc | Adsorbent Regeneration in Light Olefin Recovery Process |
| US9133077B2 (en) | 2011-12-27 | 2015-09-15 | Shell Oil Company | Process for the preparation of a lower olefin product |
| BR112014015701A8 (pt) | 2011-12-27 | 2017-07-04 | Shell Int Research | processo para a preparação de um produto de olefina |
| US9221726B2 (en) | 2011-12-27 | 2015-12-29 | Shell Oil Company | Integrated process for the preparation of an aromatic product |
| CN104010995A (zh) * | 2011-12-27 | 2014-08-27 | 国际壳牌研究有限公司 | 制备烯烃的方法 |
| RU2014131094A (ru) * | 2011-12-27 | 2016-02-20 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ получения этилена и/или пропилена |
| CN103804110B (zh) * | 2012-11-13 | 2015-11-11 | 神华集团有限责任公司 | 有机含氧化合物制低碳烯烃与c5+烃催化裂解耦合工艺 |
| US10626062B2 (en) | 2016-10-19 | 2020-04-21 | Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences | Method and device for manufacturing propene and C4 hydrocarbon |
| WO2018072142A1 (zh) * | 2016-10-19 | 2018-04-26 | 中国科学院大连化学物理研究所 | 一种制备丙烯、c4烃类的方法及其装置 |
Family Cites Families (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4138440A (en) | 1974-08-14 | 1979-02-06 | Mobil Oil Corporation | Conversion of liquid alcohols and ethers with a fluid mass of ZSM-5 type catalyst |
| US4071573A (en) | 1974-09-23 | 1978-01-31 | Mobil Oil Corporation | Prolonging zeolite catalyst life in methanol conversion to gasoline by disposing of exothermic reaction heat |
| DE2909927A1 (de) | 1979-03-14 | 1980-09-25 | Basf Ag | Verfahren zur herstellung von olefinen aus rohmethanol |
| US4338475A (en) | 1979-10-30 | 1982-07-06 | Mobil Oil Corporation | Converting alcohols to hydrocarbons |
| US4423274A (en) | 1980-10-03 | 1983-12-27 | Mobil Oil Corporation | Method for converting alcohols to hydrocarbons |
| BR8101487A (pt) | 1981-03-13 | 1982-10-26 | Petroleo Brasileiro Sa | Processo de desidratacao de um alcool de baixo peso molecular |
| DE3135618A1 (de) | 1981-09-09 | 1983-03-17 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von olefinen aus methanol und/oder dimethylether |
| CA1196031A (en) | 1982-02-05 | 1985-10-29 | Wooyoung Lee | Process for converting alcohols into olefins |
| DE3209223A1 (de) | 1982-03-13 | 1983-09-15 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von olefinen aus methanol und/oder dimethylether |
| US4440871A (en) | 1982-07-26 | 1984-04-03 | Union Carbide Corporation | Crystalline silicoaluminophosphates |
| US4677243A (en) | 1982-10-04 | 1987-06-30 | Union Carbide Corporation | Production of light olefins from aliphatic hetero compounds |
| US4527001A (en) | 1983-11-15 | 1985-07-02 | Union Carbide Corporation | Small olefin interconversions |
| JPS6124526A (ja) | 1984-07-14 | 1986-02-03 | Agency Of Ind Science & Technol | 低級オレフインの製造法 |
| US4590320A (en) | 1984-08-31 | 1986-05-20 | Mobil Oil Corporation | Conversion of methanol to olefins in a tubular reactor with light olefin co-feeding |
| US4547616A (en) | 1984-12-28 | 1985-10-15 | Mobil Oil Corporation | Conversion of oxygenates to lower olefins in a turbulent fluidized catalyst bed |
| US4579999A (en) * | 1985-01-17 | 1986-04-01 | Mobil Oil Corporation | Multistage process for converting oxygenates to liquid hydrocarbons with aliphatic recycle |
| FR2577549B1 (fr) | 1985-02-15 | 1987-03-20 | Inst Francais Du Petrole | Procede de conversion de methanol ou de dimethylether en olefines |
| US4752651A (en) | 1986-06-16 | 1988-06-21 | Union Carbide Corporation | Production of light olefins |
| US5028400A (en) | 1987-04-29 | 1991-07-02 | Mobil Oil Corporation | Feedstock preparation and reactor system for conversion to oxygenates to olefins |
| US4861938A (en) | 1987-07-07 | 1989-08-29 | Uop | Chemical conversion process |
| US4973792A (en) | 1987-07-07 | 1990-11-27 | Uop | Chemical conversion process |
| US4873390A (en) | 1987-07-07 | 1989-10-10 | Uop | Chemical conversion process |
| US5157181A (en) | 1990-12-03 | 1992-10-20 | Uop | Moving bed hydrocarbon conversion process |
| US5177283A (en) | 1992-02-03 | 1993-01-05 | Uop | Hydrocarbon conversion process |
| US5744680A (en) | 1995-08-10 | 1998-04-28 | Uop | Process for producing light olefins |
| DE19723363A1 (de) | 1997-06-04 | 1998-12-10 | Metallgesellschaft Ag | Verfahren zum Erzeugen von Ethylen, Propylen und wahlweise auch Butenisomeren aus Methanol- und/oder Dimethylether |
| US5914433A (en) | 1997-07-22 | 1999-06-22 | Uop Lll | Process for producing polymer grade olefins |
| US6455749B1 (en) * | 1997-10-03 | 2002-09-24 | Exxonmobil Chemical Patents, Inc. | Method for increasing light olefin yield by conversion of a heavy hydrocarbon fraction of a product to light olefins |
-
1997
- 1997-10-03 US US08/943,399 patent/US6455749B1/en not_active Expired - Lifetime
-
1998
- 1998-09-25 AU AU96659/98A patent/AU757031B2/en not_active Ceased
- 1998-09-25 CN CNB988103192A patent/CN1138731C/zh not_active Expired - Lifetime
- 1998-09-25 KR KR1020007003569A patent/KR100549878B1/ko not_active Expired - Lifetime
- 1998-09-25 ES ES98950676T patent/ES2190111T3/es not_active Expired - Lifetime
- 1998-09-25 WO PCT/US1998/020070 patent/WO1999018055A1/en not_active Ceased
- 1998-09-25 AT AT98950676T patent/ATE230387T1/de not_active IP Right Cessation
- 1998-09-25 JP JP2000514868A patent/JP2001519321A/ja active Pending
- 1998-09-25 EP EP98950676A patent/EP1025068B1/en not_active Revoked
- 1998-09-25 DE DE69810506T patent/DE69810506T2/de not_active Revoked
- 1998-09-25 BR BR9812710-1A patent/BR9812710A/pt not_active Application Discontinuation
- 1998-09-25 CA CA002305795A patent/CA2305795C/en not_active Expired - Fee Related
- 1998-09-29 MY MYPI98004463A patent/MY129560A/en unknown
- 1998-10-01 ZA ZA988960A patent/ZA988960B/xx unknown
- 1998-10-01 AR ARP980104911A patent/AR015944A1/es active IP Right Grant
- 1998-10-02 TW TW087116448A patent/TW400373B/zh not_active IP Right Cessation
- 1998-11-04 SA SA98190717A patent/SA98190717B1/ar unknown
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- 2002-05-13 US US10/144,604 patent/US6809227B2/en not_active Expired - Fee Related
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| AU757031B2 (en) | 2003-01-30 |
| EP1025068B1 (en) | 2003-01-02 |
| ZA988960B (en) | 1999-04-06 |
| AR015944A1 (es) | 2001-05-30 |
| EP1025068A1 (en) | 2000-08-09 |
| WO1999018055A1 (en) | 1999-04-15 |
| US20020161270A1 (en) | 2002-10-31 |
| DE69810506T2 (de) | 2003-10-02 |
| US6455749B1 (en) | 2002-09-24 |
| ATE230387T1 (de) | 2003-01-15 |
| SA98190717B1 (ar) | 2006-09-19 |
| CN1138731C (zh) | 2004-02-18 |
| US6809227B2 (en) | 2004-10-26 |
| TW400373B (en) | 2000-08-01 |
| BR9812710A (pt) | 2000-08-22 |
| JP2001519321A (ja) | 2001-10-23 |
| CA2305795A1 (en) | 1999-04-15 |
| ES2190111T3 (es) | 2003-07-16 |
| MY129560A (en) | 2007-04-30 |
| AU9665998A (en) | 1999-04-27 |
| CN1276775A (zh) | 2000-12-13 |
| KR100549878B1 (ko) | 2006-02-06 |
| DE69810506D1 (de) | 2003-02-06 |
| KR20010030877A (ko) | 2001-04-16 |
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