CA2274774C - Uv protected syndiotactic polystyrene overlay films - Google Patents
Uv protected syndiotactic polystyrene overlay films Download PDFInfo
- Publication number
- CA2274774C CA2274774C CA002274774A CA2274774A CA2274774C CA 2274774 C CA2274774 C CA 2274774C CA 002274774 A CA002274774 A CA 002274774A CA 2274774 A CA2274774 A CA 2274774A CA 2274774 C CA2274774 C CA 2274774C
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- CA
- Canada
- Prior art keywords
- film
- sps
- films
- layer
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 229920010524 Syndiotactic polystyrene Polymers 0.000 title claims abstract description 107
- 238000000576 coating method Methods 0.000 claims abstract description 53
- 239000011248 coating agent Substances 0.000 claims abstract description 47
- 229920000642 polymer Polymers 0.000 claims abstract description 24
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000000758 substrate Substances 0.000 claims description 45
- 239000000178 monomer Substances 0.000 claims description 31
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 30
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 30
- 239000000463 material Substances 0.000 claims description 21
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 18
- 229920001577 copolymer Polymers 0.000 claims description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- -1 unsaturated silyl ester Chemical class 0.000 claims description 12
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 9
- 150000002148 esters Chemical class 0.000 claims description 9
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 7
- 125000003118 aryl group Chemical group 0.000 claims description 7
- BCHZICNRHXRCHY-UHFFFAOYSA-N 2h-oxazine Chemical group N1OC=CC=C1 BCHZICNRHXRCHY-UHFFFAOYSA-N 0.000 claims description 6
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- 239000003086 colorant Substances 0.000 claims description 5
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- 239000000377 silicon dioxide Substances 0.000 claims description 3
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 2
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
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- 241001168730 Simo Species 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 230000006750 UV protection Effects 0.000 description 2
- 238000007754 air knife coating Methods 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
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- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
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- 238000002211 ultraviolet spectrum Methods 0.000 description 2
- 229910052724 xenon Inorganic materials 0.000 description 2
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 2
- SJHPCNCNNSSLPL-CSKARUKUSA-N (4e)-4-(ethoxymethylidene)-2-phenyl-1,3-oxazol-5-one Chemical compound O1C(=O)C(=C/OCC)\N=C1C1=CC=CC=C1 SJHPCNCNNSSLPL-CSKARUKUSA-N 0.000 description 1
- VDVUCLWJZJHFAV-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidin-4-ol Chemical compound CC1(C)CC(O)CC(C)(C)N1 VDVUCLWJZJHFAV-UHFFFAOYSA-N 0.000 description 1
- PMNLUUOXGOOLSP-UHFFFAOYSA-N 2-mercaptopropanoic acid Chemical compound CC(S)C(O)=O PMNLUUOXGOOLSP-UHFFFAOYSA-N 0.000 description 1
- LPIQIQPLUVLISR-UHFFFAOYSA-N 2-prop-1-en-2-yl-4,5-dihydro-1,3-oxazole Chemical compound CC(=C)C1=NCCO1 LPIQIQPLUVLISR-UHFFFAOYSA-N 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- 229910000968 Chilled casting Inorganic materials 0.000 description 1
- 229940123457 Free radical scavenger Drugs 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
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- 125000000129 anionic group Chemical group 0.000 description 1
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- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
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- 239000008393 encapsulating agent Substances 0.000 description 1
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- XPNLOZNCOBKRNJ-UHFFFAOYSA-N ethyl prop-2-enoate;methyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C=C.COC(=O)C(C)=C XPNLOZNCOBKRNJ-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- B32B27/00—Layered products comprising a layer of synthetic resin
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/302—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
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- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
- Y10T428/31913—Monoolefin polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
- Y10T428/31928—Ester, halide or nitrile of addition polymer
Landscapes
- Laminated Bodies (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/761,912 US5981076A (en) | 1996-12-09 | 1996-12-09 | UV protected syndiotactic polystyrene overlay films |
| US08/761912 | 1996-12-09 | ||
| PCT/US1997/006992 WO1998025763A1 (en) | 1996-12-09 | 1997-04-25 | Uv protected syndiotactic polystyrene overlay films |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2274774A1 CA2274774A1 (en) | 1998-06-18 |
| CA2274774C true CA2274774C (en) | 2005-08-23 |
Family
ID=25063588
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002274774A Expired - Fee Related CA2274774C (en) | 1996-12-09 | 1997-04-25 | Uv protected syndiotactic polystyrene overlay films |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US5981076A (enExample) |
| EP (1) | EP0942830B1 (enExample) |
| JP (2) | JP4060371B2 (enExample) |
| KR (1) | KR20000057453A (enExample) |
| CN (1) | CN1096939C (enExample) |
| AU (1) | AU2992697A (enExample) |
| CA (1) | CA2274774C (enExample) |
| DE (1) | DE69723098T2 (enExample) |
| WO (1) | WO1998025763A1 (enExample) |
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| DE10010416A1 (de) * | 2000-03-03 | 2001-09-13 | Basf Coatings Ag | Pysikalisch oder thermisch und/oder mit aktinischer Strahlung härtbarer Beschichtungsstoff und seine Verwendung |
| US6316531B1 (en) * | 2000-11-15 | 2001-11-13 | Shashikant B Garware | Process for dyeing UV stabilized polyester film |
| US7057805B2 (en) * | 2001-10-22 | 2006-06-06 | Commonwealth Laminating & Coating, Inc. | Solar control film containing carbon black and process for preparing the solar control film |
| US7358301B2 (en) | 2002-12-17 | 2008-04-15 | Hewlett-Packard Development Company, L.P. | Latex particles having incorporated image stabilizers |
| FR2856677B1 (fr) * | 2003-06-27 | 2006-12-01 | Saint Gobain | Substrat revetu d'une couche dielectrique et procede pour sa fabrication |
| FR2857467B1 (fr) * | 2003-07-09 | 2005-08-19 | Saint Gobain | Dispositif electrocommandable a proprietes optiques et/ou energetiques variables |
| DE10354652A1 (de) * | 2003-11-22 | 2005-07-07 | Clariant Gmbh | Verfahren zur Veresterung von Alkoholen mit olefinisch ungesättigten Carbonsäuren |
| TWI247830B (en) * | 2004-02-17 | 2006-01-21 | Taiwan Textile Res Inst | Structure of textile featuring light transmission and thermal insulation and method of manufacturing the same |
| CN100340873C (zh) * | 2004-07-29 | 2007-10-03 | 长兴化学工业股份有限公司 | 抗紫外线的光学膜 |
| KR20070053267A (ko) * | 2004-08-20 | 2007-05-23 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 반투명 보호 필름을 갖는 경피 약물 전달 장치 |
| US7642303B2 (en) * | 2004-10-15 | 2010-01-05 | Shakely Thomas L | Thermoplastic articles for packaging UV sensitive materials, processes for the articles production and use and novel UV absorbers |
| US7329465B2 (en) | 2004-10-29 | 2008-02-12 | 3M Innovative Properties Company | Optical films incorporating cyclic olefin copolymers |
| EP2218111A2 (en) * | 2007-11-06 | 2010-08-18 | Ming-Liang Shiao | Photovoltaic roofing elements including tie layer systems, and roofs using them, and methods for making them |
| US9178465B2 (en) | 2007-11-06 | 2015-11-03 | Certainteed Corporation | Photovoltaic roofing elements including tie layer systems and roofs using them |
| US20090229655A1 (en) * | 2008-03-13 | 2009-09-17 | Chen-Sheng Lee | Solar Cell |
| DE102010038288A1 (de) * | 2010-07-22 | 2012-01-26 | Evonik Röhm Gmbh | Transparente, witterungsbeständige Barrierefolie mit verbesserter Barrierewirkung und Kratzfesteigenschaften |
| DE102011006321A1 (de) * | 2011-03-29 | 2012-10-04 | Siemens Aktiengesellschaft | Photovoltaik-Modul mit selbstheilender Schutzschicht, Verfahren zum Herstellen des Photovoltaik-Moduls, Verfahren zum Heilen einer Schadstelle der Schutzschicht des Photovoltaik-Moduls und Verwendung des Photoviltaik-Moduls |
| KR101960557B1 (ko) * | 2011-06-30 | 2019-03-20 | 제이엔씨 주식회사 | 내후성 적층 필름 |
| JP6702720B2 (ja) | 2012-05-03 | 2020-06-03 | スリーエム イノベイティブ プロパティズ カンパニー | 耐久性ソーラーミラーフィルム |
| WO2013165965A1 (en) * | 2012-05-03 | 2013-11-07 | 3M Innovative Properties Company | Durable solar mirror films |
| JP7111558B2 (ja) * | 2018-08-27 | 2022-08-02 | 日東電工株式会社 | 積層体 |
| CN111826103A (zh) * | 2019-11-06 | 2020-10-27 | 深圳科诺桥科技股份有限公司 | 透明覆盖膜及其制备方法和柔性电路板以及led透明屏 |
| CN114716263A (zh) * | 2021-01-04 | 2022-07-08 | 奉节县文物保护管理中心 | 一种石碑类文物的保护方法 |
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-
1996
- 1996-12-09 US US08/761,912 patent/US5981076A/en not_active Expired - Fee Related
-
1997
- 1997-04-25 CN CN97181241A patent/CN1096939C/zh not_active Expired - Fee Related
- 1997-04-25 DE DE69723098T patent/DE69723098T2/de not_active Expired - Fee Related
- 1997-04-25 KR KR1019990705086A patent/KR20000057453A/ko not_active Withdrawn
- 1997-04-25 AU AU29926/97A patent/AU2992697A/en not_active Abandoned
- 1997-04-25 CA CA002274774A patent/CA2274774C/en not_active Expired - Fee Related
- 1997-04-25 JP JP52661098A patent/JP4060371B2/ja not_active Expired - Fee Related
- 1997-04-25 EP EP97924524A patent/EP0942830B1/en not_active Expired - Lifetime
- 1997-04-25 WO PCT/US1997/006992 patent/WO1998025763A1/en not_active Ceased
-
1998
- 1998-06-18 US US09/098,965 patent/US6120901A/en not_active Expired - Fee Related
-
2006
- 2006-09-07 JP JP2006242850A patent/JP2007045158A/ja not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| DE69723098T2 (de) | 2004-05-06 |
| KR20000057453A (ko) | 2000-09-15 |
| WO1998025763A1 (en) | 1998-06-18 |
| EP0942830A1 (en) | 1999-09-22 |
| EP0942830B1 (en) | 2003-06-25 |
| JP2001505835A (ja) | 2001-05-08 |
| JP4060371B2 (ja) | 2008-03-12 |
| US5981076A (en) | 1999-11-09 |
| DE69723098D1 (de) | 2003-07-31 |
| CN1244156A (zh) | 2000-02-09 |
| AU2992697A (en) | 1998-07-03 |
| JP2007045158A (ja) | 2007-02-22 |
| CN1096939C (zh) | 2002-12-25 |
| CA2274774A1 (en) | 1998-06-18 |
| US6120901A (en) | 2000-09-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |