CA2193989C - Process for preparing carboxylic acid salts and catalysts useful in such process - Google Patents

Process for preparing carboxylic acid salts and catalysts useful in such process Download PDF

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Publication number
CA2193989C
CA2193989C CA002193989A CA2193989A CA2193989C CA 2193989 C CA2193989 C CA 2193989C CA 002193989 A CA002193989 A CA 002193989A CA 2193989 A CA2193989 A CA 2193989A CA 2193989 C CA2193989 C CA 2193989C
Authority
CA
Canada
Prior art keywords
catalyst
metal
copper
anchor metal
carboxylic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA002193989A
Other languages
English (en)
French (fr)
Other versions
CA2193989A1 (en
Inventor
Jerry Rudolph Ebner
Thaddeus Stephan Franczyk
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Technology LLC
Original Assignee
Monsanto Technology LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Technology LLC filed Critical Monsanto Technology LLC
Publication of CA2193989A1 publication Critical patent/CA2193989A1/en
Application granted granted Critical
Publication of CA2193989C publication Critical patent/CA2193989C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C227/02—Formation of carboxyl groups in compounds containing amino groups, e.g. by oxidation of amino alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0217—Pretreatment of the substrate before coating
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/41—Preparation of salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Biochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CA002193989A 1994-07-01 1995-05-26 Process for preparing carboxylic acid salts and catalysts useful in such process Expired - Fee Related CA2193989C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US26971894A 1994-07-01 1994-07-01
US08/269,718 1994-07-01
US08/407,723 1995-03-20
US08/407,723 US5689000A (en) 1994-07-01 1995-03-20 Process for preparing carboxylic acid salts and catalysts useful in such process
PCT/US1995/006754 WO1996001146A1 (en) 1994-07-01 1995-05-26 Process for preparing carboxylic acid salts and catalysts useful in such process

Publications (2)

Publication Number Publication Date
CA2193989A1 CA2193989A1 (en) 1996-01-18
CA2193989C true CA2193989C (en) 2006-11-14

Family

ID=26953850

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002193989A Expired - Fee Related CA2193989C (en) 1994-07-01 1995-05-26 Process for preparing carboxylic acid salts and catalysts useful in such process

Country Status (23)

Country Link
US (2) US5689000A (enExample)
EP (1) EP0768917B1 (enExample)
JP (1) JPH10501728A (enExample)
KR (1) KR970703816A (enExample)
CN (1) CN1091649C (enExample)
AT (1) ATE173956T1 (enExample)
AU (1) AU711349B2 (enExample)
BR (1) BR9508163A (enExample)
CA (1) CA2193989C (enExample)
DE (1) DE69506412T2 (enExample)
DK (1) DK0768917T3 (enExample)
ES (1) ES2126290T3 (enExample)
GR (1) GR3029541T3 (enExample)
HU (1) HUT76751A (enExample)
IL (1) IL114412A (enExample)
MX (1) MX206593B (enExample)
MY (1) MY112727A (enExample)
NZ (1) NZ288027A (enExample)
PL (1) PL179923B1 (enExample)
RU (1) RU2157727C2 (enExample)
TW (1) TW449502B (enExample)
UA (1) UA46736C2 (enExample)
WO (1) WO1996001146A1 (enExample)

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US6232494B1 (en) 1998-02-12 2001-05-15 Monsanto Company Process for the preparation of N-(phosphonomethyl)glycine by oxidizing N-substituted N-(phosphonomethyl)glycine
AU719152B2 (en) * 1998-02-12 2000-05-04 Monsanto Technology Llc Process for making glyphosate by oxidizing N-substituted glyphosates
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ITTO980249A1 (it) * 1998-03-23 1999-09-23 Finchimica Srl Procedimento per la preparazione di sali di acidi carbossilici
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ES2238582T5 (es) * 2001-07-03 2010-05-26 Facultes Universitaires Notre-Dame De La Paix Soportes de catalizador y nanotubos de carbono producidos sobre dichos soportes.
AU2002362929B2 (en) 2001-10-18 2007-08-09 Monsanto Technology Llc Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts
US7196033B2 (en) 2001-12-14 2007-03-27 Huntsman Petrochemical Corporation Advances in amination catalysis
DE10161674A1 (de) * 2001-12-14 2003-06-26 Basf Ag Katalysatoren zur Herstellung von Carbonsäuresalzen
US7390920B2 (en) * 2002-02-14 2008-06-24 Monsanto Technology Llc Oxidation catalyst and process
CA2476255C (en) * 2002-02-14 2012-07-31 Monsanto Technology Llc Oxidation catalyst and process for its preparation and process for oxidation using it
EP1551755A1 (en) * 2002-10-18 2005-07-13 Monsanto Technology LLC Use of metal supported copper catalysts for reforming alcohols
US6992039B2 (en) * 2003-03-13 2006-01-31 General Motors Corporation Method for making monodispersed noble metal nanoparticles supported on oxide substrates
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BRPI0413856A (pt) * 2003-08-22 2006-10-24 Monsato Techology Llc processo para a preparação de n-fosfono-metilglicina e derivados deste
DE10349095A1 (de) 2003-10-17 2005-05-19 Basf Ag Verfahren zur Herstellung von Aminen
US20050100493A1 (en) * 2003-11-06 2005-05-12 George Yaluris Ferrierite compositions for reducing NOx emissions during fluid catalytic cracking
US20050100494A1 (en) * 2003-11-06 2005-05-12 George Yaluris Ferrierite compositions for reducing NOx emissions during fluid catalytic cracking
US20050232839A1 (en) * 2004-04-15 2005-10-20 George Yaluris Compositions and processes for reducing NOx emissions during fluid catalytic cracking
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US8703639B2 (en) * 2004-09-15 2014-04-22 Monsanto Technology Llc Oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
JP2006142137A (ja) * 2004-11-16 2006-06-08 Nissan Motor Co Ltd 排ガス浄化用触媒及びその製造方法
EP1858642A2 (en) 2005-02-17 2007-11-28 Monsanto Technology, LLC Transition metal-containing catalysts and catalyst combinations including transition metal-containing catalysts and processes for their preparation and use as oxidation catalysts
KR101382014B1 (ko) 2005-04-27 2014-04-04 더블유.알. 그레이스 앤드 캄파니-콘. 유동상 접촉 분해 중의 ＮＯｘ 방출 감소를 위한 조성물 및공정
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BRPI0708081A2 (pt) * 2006-02-17 2011-05-17 Monsanto Technology Llc catalisadores contendo metal de transição e processos para a sua preparação e uso como catalisadores de pilha termoelétrica
RU2451800C2 (ru) * 2006-06-13 2012-05-27 МОНСАНТО ТЕКНОЛОДЖИ ЭлЭлСи Способ получения механической или электрической энергии из топлива, содержащего спирт
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US8309759B2 (en) 2010-02-19 2012-11-13 Basf Se Preparing ether carboxylates
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Also Published As

Publication number Publication date
DK0768917T3 (da) 1999-08-16
PL179923B1 (pl) 2000-11-30
US5627125A (en) 1997-05-06
ATE173956T1 (de) 1998-12-15
EP0768917A1 (en) 1997-04-23
HU9603630D0 (en) 1997-02-28
GR3029541T3 (en) 1999-06-30
DE69506412T2 (de) 1999-06-24
AU2692695A (en) 1996-01-25
TW449502B (en) 2001-08-11
IL114412A0 (en) 1995-10-31
CA2193989A1 (en) 1996-01-18
HUT76751A (en) 1997-11-28
ES2126290T3 (es) 1999-03-16
RU2157727C2 (ru) 2000-10-20
CN1156419A (zh) 1997-08-06
EP0768917B1 (en) 1998-12-02
JPH10501728A (ja) 1998-02-17
AU711349B2 (en) 1999-10-14
KR970703816A (enExample) 1997-08-09
MX9700060A (es) 1997-04-30
MX206593B (es) 2002-02-08
CN1091649C (zh) 2002-10-02
UA46736C2 (uk) 2002-06-17
PL317849A1 (en) 1997-04-28
IL114412A (en) 1999-06-20
US5689000A (en) 1997-11-18
WO1996001146A1 (en) 1996-01-18
NZ288027A (en) 1998-11-25
MY112727A (en) 2001-08-30
BR9508163A (pt) 1997-12-23
DE69506412D1 (de) 1999-01-14

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