CA2167350C - Stabilizer combination - Google Patents

Info

Publication number

CA2167350C

CA2167350C CA002167350A CA2167350A CA2167350C CA 2167350 C CA2167350 C CA 2167350C CA 002167350 A CA002167350 A CA 002167350A CA 2167350 A CA2167350 A CA 2167350A CA 2167350 C CA2167350 C CA 2167350C

Authority

CA

Canada

Prior art keywords

substituted

phenyl

c18alkyl

formula

tert

Prior art date

1995-01-18

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired - Fee Related

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• 239000003381 stabilizer Substances 0.000 title claims description 38
• 239000000203 mixture Substances 0.000 claims abstract description 111
• 150000001875 compounds Chemical class 0.000 claims abstract description 79
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 54
• 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 41
• 239000001257 hydrogen Substances 0.000 claims abstract description 38
• 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims abstract description 34
• 150000002367 halogens Chemical class 0.000 claims abstract description 33
• 229910052736 halogen Inorganic materials 0.000 claims abstract description 32
• 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims abstract description 20
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 19
• 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims abstract description 13
• 150000002431 hydrogen Chemical group 0.000 claims abstract description 13
• 239000011368 organic material Substances 0.000 claims abstract description 12
• 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims abstract description 11
• 125000000882 C2-C6 alkenyl group Chemical group 0.000 claims abstract description 9
• 230000000087 stabilizing effect Effects 0.000 claims abstract description 7
• 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims abstract description 7
• 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 4
• 125000005336 allyloxy group Chemical group 0.000 claims abstract description 3
• 125000004642 (C1-C12) alkoxy group Chemical group 0.000 claims abstract 4
• -1 phenylene, tolylene Chemical group 0.000 claims description 134
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 66
• 229910052760 oxygen Inorganic materials 0.000 claims description 21
• 239000011230 binding agent Substances 0.000 claims description 18
• 238000000576 coating method Methods 0.000 claims description 17
• 239000001301 oxygen Substances 0.000 claims description 15
• 150000001412 amines Chemical class 0.000 claims description 14
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 14
• 238000000034 method Methods 0.000 claims description 11
• 229920001169 thermoplastic Polymers 0.000 claims description 11
• 239000004611 light stabiliser Substances 0.000 claims description 10
• 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 9
• 239000000463 material Substances 0.000 claims description 8
• 125000003944 tolyl group Chemical group 0.000 claims description 7
• 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
• 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 6
• 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 5
• 239000000654 additive Substances 0.000 claims description 5
• 125000000229 (C1-C4)alkoxy group Chemical group 0.000 claims description 4
• 229910052801 chlorine Inorganic materials 0.000 claims description 4
• NIHNNTQXNPWCJQ-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 claims description 4
• 125000001624 naphthyl group Chemical group 0.000 claims description 4
• 125000006839 xylylene group Chemical group 0.000 claims description 4
• FJGQBLRYBUAASW-UHFFFAOYSA-N 2-(benzotriazol-2-yl)phenol Chemical compound OC1=CC=CC=C1N1N=C2C=CC=CC2=N1 FJGQBLRYBUAASW-UHFFFAOYSA-N 0.000 claims description 3
• 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 3
• 125000005184 naphthylamino group Chemical group C1(=CC=CC2=CC=CC=C12)N* 0.000 claims description 3
• RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims description 3
• 125000002933 cyclohexyloxy group Chemical group C1(CCCCC1)O* 0.000 claims description 2
• 229910052731 fluorine Inorganic materials 0.000 claims description 2
• 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 2
• 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 2
• 229920005613 synthetic organic polymer Polymers 0.000 claims description 2
• 125000006729 (C2-C5) alkenyl group Chemical group 0.000 claims 1
• 125000006834 (C4-C20) alkylene group Chemical group 0.000 claims 1
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 48
• 229920000642 polymer Polymers 0.000 description 35
• 229920001577 copolymer Polymers 0.000 description 34
• 229940044603 styrene Drugs 0.000 description 26
• 239000004952 Polyamide Substances 0.000 description 20
• 239000008199 coating composition Substances 0.000 description 20
• 239000003973 paint Substances 0.000 description 20
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 19
• 229920002647 polyamide Polymers 0.000 description 18
• 229920005989 resin Polymers 0.000 description 17
• 239000011347 resin Substances 0.000 description 17
• 229910052751 metal Inorganic materials 0.000 description 16
• 239000002184 metal Substances 0.000 description 16
• 125000000217 alkyl group Chemical group 0.000 description 14
• 239000003054 catalyst Substances 0.000 description 14
• NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 13
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
• 229920006324 polyoxymethylene Polymers 0.000 description 12
• IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 11
• ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 11
• 150000001252 acrylic acid derivatives Chemical class 0.000 description 11
• 229910052757 nitrogen Inorganic materials 0.000 description 11
• 239000004417 polycarbonate Substances 0.000 description 11
• 150000003254 radicals Chemical class 0.000 description 11
• NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 10
• VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 10
• 239000005977 Ethylene Substances 0.000 description 10
• 239000004743 Polypropylene Substances 0.000 description 10
• MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 10
• 229920001971 elastomer Polymers 0.000 description 10
• 150000002148 esters Chemical class 0.000 description 10
• 229920000728 polyester Polymers 0.000 description 10
• 239000000758 substrate Substances 0.000 description 10
• 239000006096 absorbing agent Substances 0.000 description 9
• 229920001684 low density polyethylene Polymers 0.000 description 9
• 239000004702 low-density polyethylene Substances 0.000 description 9
• 229920000877 Melamine resin Polymers 0.000 description 8
• 239000005062 Polybutadiene Substances 0.000 description 8
• 239000004721 Polyphenylene oxide Substances 0.000 description 8
• KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 8
• GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 8
• 229920002857 polybutadiene Polymers 0.000 description 8
• 229920000515 polycarbonate Polymers 0.000 description 8
• 239000004698 Polyethylene Substances 0.000 description 7
• IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 7
• 239000003795 chemical substances by application Substances 0.000 description 7
• 238000001723 curing Methods 0.000 description 7
• 239000004700 high-density polyethylene Substances 0.000 description 7
• 239000000243 solution Substances 0.000 description 7
• WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
• 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 6
• WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 6
• 239000011248 coating agent Substances 0.000 description 6
• 239000000806 elastomer Substances 0.000 description 6
• 229920001903 high density polyethylene Polymers 0.000 description 6
• 229920000647 polyepoxide Polymers 0.000 description 6
• 229920000570 polyether Polymers 0.000 description 6
• 229920000573 polyethylene Polymers 0.000 description 6
• 239000005056 polyisocyanate Substances 0.000 description 6
• 229920001228 polyisocyanate Polymers 0.000 description 6
• 229920000098 polyolefin Polymers 0.000 description 6
• 229920006380 polyphenylene oxide Polymers 0.000 description 6
• 229920001155 polypropylene Polymers 0.000 description 6
• 239000004814 polyurethane Substances 0.000 description 6
• 229920000915 polyvinyl chloride Polymers 0.000 description 6
• 239000004800 polyvinyl chloride Substances 0.000 description 6
• 239000007787 solid Substances 0.000 description 6
• 229920002554 vinyl polymer Polymers 0.000 description 6
• 239000004925 Acrylic resin Substances 0.000 description 5
• 125000001931 aliphatic group Chemical group 0.000 description 5
• 150000008064 anhydrides Chemical class 0.000 description 5
• 125000003118 aryl group Chemical group 0.000 description 5
• 150000001991 dicarboxylic acids Chemical class 0.000 description 5
• 150000001993 dienes Chemical class 0.000 description 5
• 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
• 239000012948 isocyanate Substances 0.000 description 5
• 150000002739 metals Chemical class 0.000 description 5
• 229940059574 pentaerithrityl Drugs 0.000 description 5
• WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 5
• 239000000049 pigment Substances 0.000 description 5
• 229920000058 polyacrylate Polymers 0.000 description 5
• 150000005846 sugar alcohols Polymers 0.000 description 5
• 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 5
• 239000004416 thermosoftening plastic Substances 0.000 description 5
• 239000002966 varnish Substances 0.000 description 5
• KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 5
• DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 4
• BPXVHIRIPLPOPT-UHFFFAOYSA-N 1,3,5-tris(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound OCCN1C(=O)N(CCO)C(=O)N(CCO)C1=O BPXVHIRIPLPOPT-UHFFFAOYSA-N 0.000 description 4
• ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical compound OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 4
• YEWBOZCFGXOUQW-UHFFFAOYSA-N 2,6,7-trioxa-1-phosphabicyclo[2.2.2]octan-4-ylmethanol Chemical compound C1OP2OCC1(CO)CO2 YEWBOZCFGXOUQW-UHFFFAOYSA-N 0.000 description 4
• KXPXKNBDCUOENF-UHFFFAOYSA-N 2-(Octylthio)ethanol Chemical compound CCCCCCCCSCCO KXPXKNBDCUOENF-UHFFFAOYSA-N 0.000 description 4
• ZPIRWAHWDCHWLM-UHFFFAOYSA-N 2-dodecylsulfanylethanol Chemical compound CCCCCCCCCCCCSCCO ZPIRWAHWDCHWLM-UHFFFAOYSA-N 0.000 description 4
• CKPKHTKLLYPGFM-UHFFFAOYSA-N 6,6-dimethylheptane-1,1-diol Chemical compound CC(CCCCC(O)O)(C)C CKPKHTKLLYPGFM-UHFFFAOYSA-N 0.000 description 4
• CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
• 229920002943 EPDM rubber Polymers 0.000 description 4
• LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
• CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
• 229920002396 Polyurea Polymers 0.000 description 4
• ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
• 101100054666 Streptomyces halstedii sch3 gene Proteins 0.000 description 4
• KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
• ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 4
• 239000007983 Tris buffer Substances 0.000 description 4
• 229920000180 alkyd Polymers 0.000 description 4
• 239000003963 antioxidant agent Substances 0.000 description 4
• 235000006708 antioxidants Nutrition 0.000 description 4
• FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 4
• 125000004432 carbon atom Chemical group C* 0.000 description 4
• XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 4
• DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 4
• 238000001035 drying Methods 0.000 description 4
• 150000002170 ethers Chemical class 0.000 description 4
• 239000010408 film Substances 0.000 description 4
• 125000005842 heteroatom Chemical group 0.000 description 4
• NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 4
• XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 4
• 238000010348 incorporation Methods 0.000 description 4
• 229910052740 iodine Inorganic materials 0.000 description 4
• 229920000554 ionomer Polymers 0.000 description 4
• ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 4
• 229910052748 manganese Inorganic materials 0.000 description 4
• 239000011572 manganese Substances 0.000 description 4
• 239000000178 monomer Substances 0.000 description 4
• DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 4
• FPQJEXTVQZHURJ-UHFFFAOYSA-N n,n'-bis(2-hydroxyethyl)oxamide Chemical compound OCCNC(=O)C(=O)NCCO FPQJEXTVQZHURJ-UHFFFAOYSA-N 0.000 description 4
• SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 4
• 150000002815 nickel Chemical class 0.000 description 4
• 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 4
• 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 4
• QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
• 235000013772 propylene glycol Nutrition 0.000 description 4
• 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
• 239000005060 rubber Substances 0.000 description 4
• 150000003839 salts Chemical class 0.000 description 4
• YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 description 4
• 239000011732 tocopherol Substances 0.000 description 4
• ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 4
• 229940113165 trimethylolpropane Drugs 0.000 description 4
• 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
• 239000008096 xylene Substances 0.000 description 4
• RMSGQZDGSZOJMU-UHFFFAOYSA-N 1-butyl-2-phenylbenzene Chemical group CCCCC1=CC=CC=C1C1=CC=CC=C1 RMSGQZDGSZOJMU-UHFFFAOYSA-N 0.000 description 3
• RXFCIXRFAJRBSG-UHFFFAOYSA-N 3,2,3-tetramine Chemical compound NCCCNCCNCCCN RXFCIXRFAJRBSG-UHFFFAOYSA-N 0.000 description 3
• GGUFVZFOCZNPEG-UHFFFAOYSA-N 4,5,6-triphenyltriazine Chemical class C1=CC=CC=C1C1=NN=NC(C=2C=CC=CC=2)=C1C1=CC=CC=C1 GGUFVZFOCZNPEG-UHFFFAOYSA-N 0.000 description 3
• 229920000089 Cyclic olefin copolymer Polymers 0.000 description 3
• 239000004593 Epoxy Substances 0.000 description 3
• IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
• SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
• 239000004734 Polyphenylene sulfide Substances 0.000 description 3
• 239000002253 acid Substances 0.000 description 3
• 150000007513 acids Chemical class 0.000 description 3
• 239000001361 adipic acid Substances 0.000 description 3
• 235000011037 adipic acid Nutrition 0.000 description 3
• 125000003342 alkenyl group Chemical group 0.000 description 3
• 229910052782 aluminium Inorganic materials 0.000 description 3
• 239000002585 base Substances 0.000 description 3
• XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 description 3
• 229920001400 block copolymer Polymers 0.000 description 3
• MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 3
• 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
• 150000004649 carbonic acid derivatives Chemical class 0.000 description 3
• 150000004985 diamines Chemical class 0.000 description 3
• ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 3
• HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 3
• 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 3
• 239000005038 ethylene vinyl acetate Substances 0.000 description 3
• 230000009931 harmful effect Effects 0.000 description 3
• 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
• 239000003446 ligand Substances 0.000 description 3
• JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 3
• UKJARPDLRWBRAX-UHFFFAOYSA-N n,n'-bis(2,2,6,6-tetramethylpiperidin-4-yl)hexane-1,6-diamine Chemical compound C1C(C)(C)NC(C)(C)CC1NCCCCCCNC1CC(C)(C)NC(C)(C)C1 UKJARPDLRWBRAX-UHFFFAOYSA-N 0.000 description 3
• 239000003921 oil Substances 0.000 description 3
• 150000002902 organometallic compounds Chemical class 0.000 description 3
• 125000004430 oxygen atom Chemical group O* 0.000 description 3
• AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 3
• 229920003023 plastic Polymers 0.000 description 3
• 239000004033 plastic Substances 0.000 description 3
• 229920001707 polybutylene terephthalate Polymers 0.000 description 3
• 229920001225 polyester resin Polymers 0.000 description 3
• 229920000069 polyphenylene sulfide Polymers 0.000 description 3
• 229920001451 polypropylene glycol Polymers 0.000 description 3
• 229920002635 polyurethane Polymers 0.000 description 3
• 238000012545 processing Methods 0.000 description 3
• 238000007493 shaping process Methods 0.000 description 3
• 239000002904 solvent Substances 0.000 description 3
• KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 3
• 229920001897 terpolymer Polymers 0.000 description 3
• 150000003568 thioethers Chemical class 0.000 description 3
• 229960001295 tocopherol Drugs 0.000 description 3
• 125000005023 xylyl group Chemical group 0.000 description 3
• 229910052725 zinc Inorganic materials 0.000 description 3
• 239000011701 zinc Substances 0.000 description 3
• 229910052726 zirconium Inorganic materials 0.000 description 3
• GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
• ZQMPWXFHAUDENN-UHFFFAOYSA-N 1,2-bis[(2-methylphenyl)amino]ethane Natural products CC1=CC=CC=C1NCCNC1=CC=CC=C1C ZQMPWXFHAUDENN-UHFFFAOYSA-N 0.000 description 2
• YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 2
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