CA2126351C - Removable pressure-sensitive adhesives for recyclable substrates - Google Patents
Removable pressure-sensitive adhesives for recyclable substrates Download PDFInfo
- Publication number
- CA2126351C CA2126351C CA002126351A CA2126351A CA2126351C CA 2126351 C CA2126351 C CA 2126351C CA 002126351 A CA002126351 A CA 002126351A CA 2126351 A CA2126351 A CA 2126351A CA 2126351 C CA2126351 C CA 2126351C
- Authority
- CA
- Canada
- Prior art keywords
- weight
- percent
- pressure
- polymer
- sensitive adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000004820 Pressure-sensitive adhesive Substances 0.000 title claims abstract description 38
- 239000000758 substrate Substances 0.000 title claims description 45
- 229920000642 polymer Polymers 0.000 claims abstract description 62
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 49
- 239000000203 mixture Substances 0.000 claims abstract description 45
- 239000004094 surface-active agent Substances 0.000 claims abstract description 42
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 32
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 32
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000003513 alkali Substances 0.000 claims abstract description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 46
- 239000000178 monomer Substances 0.000 claims description 29
- 239000004908 Emulsion polymer Substances 0.000 claims description 21
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 20
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 18
- 125000004432 carbon atom Chemical group C* 0.000 claims description 17
- 239000002253 acid Substances 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 13
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 11
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 11
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 10
- 150000005690 diesters Chemical class 0.000 claims description 9
- 229920001971 elastomer Polymers 0.000 claims description 9
- 239000005060 rubber Substances 0.000 claims description 9
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 claims description 8
- 229920001567 vinyl ester resin Polymers 0.000 claims description 8
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims description 6
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 6
- ROPXFXOUUANXRR-YPKPFQOOSA-N bis(2-ethylhexyl) (z)-but-2-enedioate Chemical compound CCCCC(CC)COC(=O)\C=C/C(=O)OCC(CC)CCCC ROPXFXOUUANXRR-YPKPFQOOSA-N 0.000 claims description 6
- 239000002174 Styrene-butadiene Substances 0.000 claims description 5
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 5
- 230000009477 glass transition Effects 0.000 claims description 5
- 239000011115 styrene butadiene Substances 0.000 claims description 5
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 4
- ROPXFXOUUANXRR-BUHFOSPRSA-N bis(2-ethylhexyl) (e)-but-2-enedioate Chemical compound CCCCC(CC)COC(=O)\C=C\C(=O)OCC(CC)CCCC ROPXFXOUUANXRR-BUHFOSPRSA-N 0.000 claims description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 3
- 229920005604 random copolymer Polymers 0.000 claims description 3
- 239000002023 wood Substances 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 2
- 239000000654 additive Substances 0.000 claims description 2
- 229940117927 ethylene oxide Drugs 0.000 claims description 2
- 239000000839 emulsion Substances 0.000 abstract description 12
- 230000002378 acidificating effect Effects 0.000 abstract description 8
- 230000001070 adhesive effect Effects 0.000 description 54
- 239000000853 adhesive Substances 0.000 description 51
- 229920005989 resin Polymers 0.000 description 35
- 239000011347 resin Substances 0.000 description 35
- -1 2-ethyl Chemical group 0.000 description 15
- 239000004698 Polyethylene Substances 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 239000011521 glass Substances 0.000 description 12
- 229920000573 polyethylene Polymers 0.000 description 12
- 229910001220 stainless steel Inorganic materials 0.000 description 11
- 239000010935 stainless steel Substances 0.000 description 11
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 10
- 229920000728 polyester Polymers 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- VLTOSDJJTWPWLS-UHFFFAOYSA-N pent-2-ynal Chemical compound CCC#CC=O VLTOSDJJTWPWLS-UHFFFAOYSA-N 0.000 description 9
- 239000007787 solid Substances 0.000 description 9
- 229920002554 vinyl polymer Polymers 0.000 description 9
- 229920001577 copolymer Polymers 0.000 description 8
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 8
- 239000006185 dispersion Substances 0.000 description 7
- 150000002148 esters Chemical class 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 238000009472 formulation Methods 0.000 description 6
- 229920005601 base polymer Polymers 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 5
- 210000003813 thumb Anatomy 0.000 description 5
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 4
- 239000004793 Polystyrene Substances 0.000 description 4
- 239000012670 alkaline solution Substances 0.000 description 4
- 239000000908 ammonium hydroxide Substances 0.000 description 4
- 239000003945 anionic surfactant Substances 0.000 description 4
- 239000003518 caustics Substances 0.000 description 4
- 239000003599 detergent Substances 0.000 description 4
- 239000012528 membrane Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229920002223 polystyrene Polymers 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 239000002998 adhesive polymer Substances 0.000 description 3
- 238000013019 agitation Methods 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical compound CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- 125000005396 acrylic acid ester group Chemical group 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920002432 poly(vinyl methyl ether) polymer Polymers 0.000 description 2
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- MNCGMVDMOKPCSQ-UHFFFAOYSA-M sodium;2-phenylethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=CC1=CC=CC=C1 MNCGMVDMOKPCSQ-UHFFFAOYSA-M 0.000 description 2
- BWYYYTVSBPRQCN-UHFFFAOYSA-M sodium;ethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=C BWYYYTVSBPRQCN-UHFFFAOYSA-M 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- ORJDWQVKIMZEMX-UHFFFAOYSA-N (2-nonylphenyl) hydrogen sulfate Chemical class CCCCCCCCCC1=CC=CC=C1OS(O)(=O)=O ORJDWQVKIMZEMX-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- IEPRKVQEAMIZSS-UHFFFAOYSA-N Di-Et ester-Fumaric acid Natural products CCOC(=O)C=CC(=O)OCC IEPRKVQEAMIZSS-UHFFFAOYSA-N 0.000 description 1
- IEPRKVQEAMIZSS-WAYWQWQTSA-N Diethyl maleate Chemical compound CCOC(=O)\C=C/C(=O)OCC IEPRKVQEAMIZSS-WAYWQWQTSA-N 0.000 description 1
- 241001644893 Entandrophragma utile Species 0.000 description 1
- 239000013032 Hydrocarbon resin Substances 0.000 description 1
- 244000089486 Phragmites australis subsp australis Species 0.000 description 1
- 235000014676 Phragmites communis Nutrition 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- IAXXETNIOYFMLW-COPLHBTASA-N [(1s,3s,4s)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl] 2-methylprop-2-enoate Chemical compound C1C[C@]2(C)[C@@H](OC(=O)C(=C)C)C[C@H]1C2(C)C IAXXETNIOYFMLW-COPLHBTASA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003522 acrylic cement Substances 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- QVFWZNCVPCJQOP-UHFFFAOYSA-N chloralodol Chemical compound CC(O)(C)CC(C)OC(O)C(Cl)(Cl)Cl QVFWZNCVPCJQOP-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- WNMORWGTPVWAIB-UHFFFAOYSA-N ethenyl 2-methylpropanoate Chemical compound CC(C)C(=O)OC=C WNMORWGTPVWAIB-UHFFFAOYSA-N 0.000 description 1
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
- BLZSRIYYOIZLJL-UHFFFAOYSA-N ethenyl pentanoate Chemical compound CCCCC(=O)OC=C BLZSRIYYOIZLJL-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 229940063583 high-density polyethylene Drugs 0.000 description 1
- 229920006270 hydrocarbon resin Polymers 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000005457 ice water Substances 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 229940119545 isobornyl methacrylate Drugs 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000005395 methacrylic acid group Chemical class 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229920000847 nonoxynol Polymers 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical group CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical class OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- 210000002706 plastid Anatomy 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 150000003839 salts Chemical group 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- JBJWASZNUJCEKT-UHFFFAOYSA-M sodium;hydroxide;hydrate Chemical compound O.[OH-].[Na+] JBJWASZNUJCEKT-UHFFFAOYSA-M 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
- C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/385—Acrylic polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/26—Natural polymers, natural resins or derivatives thereof according to C08L1/00 - C08L5/00, C08L89/00, C08L93/00, C08L97/00 or C08L99/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L93/00—Compositions of natural resins; Compositions of derivatives thereof
- C08L93/04—Rosin
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US813,354 | 1991-12-24 | ||
| US07/813,354 US5183841A (en) | 1991-12-24 | 1991-12-24 | Removable pressure-sensitive adhesives for recyclable substrates |
| PCT/US1992/011161 WO1993013181A1 (en) | 1991-12-24 | 1992-12-22 | Removable pressure-sensitive adhesives for recyclable substrates |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2126351A1 CA2126351A1 (en) | 1993-07-08 |
| CA2126351C true CA2126351C (en) | 2003-10-21 |
Family
ID=25212144
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002126351A Expired - Fee Related CA2126351C (en) | 1991-12-24 | 1992-12-22 | Removable pressure-sensitive adhesives for recyclable substrates |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US5183841A (enExample) |
| EP (1) | EP0618947B1 (enExample) |
| JP (1) | JPH07506126A (enExample) |
| KR (1) | KR100255497B1 (enExample) |
| AU (1) | AU672381B2 (enExample) |
| BR (1) | BR9206986A (enExample) |
| CA (1) | CA2126351C (enExample) |
| DE (1) | DE69226653T2 (enExample) |
| MX (1) | MX9207556A (enExample) |
| TW (1) | TW316277B (enExample) |
| WO (1) | WO1993013181A1 (enExample) |
Families Citing this family (82)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5405889A (en) * | 1991-10-31 | 1995-04-11 | Dow Corning Toray Silicone Co., Ltd. | Room-temperature-curable organopolysiloxane composition |
| US5183841A (en) * | 1991-12-24 | 1993-02-02 | Avery Dennison Corporation | Removable pressure-sensitive adhesives for recyclable substrates |
| US5319020A (en) * | 1993-04-21 | 1994-06-07 | National Starch And Chemical Investment Holding Corporation | Redispersible waterborne pressure sensitive adhesive polymer |
| US6077895A (en) * | 1993-07-15 | 2000-06-20 | Ato Findley, Inc. | pH sensitive thermoplastic binder |
| EP0710264B1 (en) * | 1993-07-20 | 2001-06-13 | Findley Adhesives Inc. | Water sensitive hot melt adhesive composition |
| US5508367A (en) * | 1993-11-29 | 1996-04-16 | Adhesives Research, Inc. | Water-soluble pressure sensitive adhesive |
| US5395907A (en) * | 1993-11-29 | 1995-03-07 | Adhesive Research, Inc. | Water-soluble pressure sensitive adhesive |
| US5550181A (en) * | 1994-03-07 | 1996-08-27 | Avery Dennison Corporation | Repulpable splicing tape |
| US5833622A (en) * | 1994-04-04 | 1998-11-10 | Graphic Controls Corporation | Non-invasive fetal probe having improved mechanical and electrical properties |
| US5474065A (en) * | 1994-04-04 | 1995-12-12 | Graphic Controls Corporation | Non-invasive fetal probe |
| US5726250A (en) * | 1994-07-11 | 1998-03-10 | Adhesives Research, Inc. | Covalently crosslinked water-absorbent graft copolymer |
| US5846653A (en) * | 1995-12-21 | 1998-12-08 | Minnesota Mining And Manufacturing Company | Poly(α-olefin) pressure sensitive adhesvie tape with a priming layer |
| US6121508A (en) * | 1995-12-29 | 2000-09-19 | 3M Innovative Properties Company | Polar, lipophilic pressure-sensitive adhesive compositions and medical devices using same |
| DE19707181A1 (de) * | 1997-02-22 | 1998-08-27 | Beiersdorf Ag | Repulpierbares Klebeband |
| US6162848A (en) * | 1997-03-14 | 2000-12-19 | Omnova Solutions Inc. | Carpet latex compound |
| US6132829A (en) * | 1997-05-28 | 2000-10-17 | Avery Dennison Corporation | Articles useful security printing and methods of making the same |
| US6394499B1 (en) * | 1997-05-28 | 2002-05-28 | Unicover Corporation | Self-adhesive stamp construction |
| US6136903A (en) * | 1997-10-09 | 2000-10-24 | Avery Dennison Corporation | Repulpable, pressure-sensitive adhesive compositions |
| US6525129B1 (en) | 1999-12-20 | 2003-02-25 | Avery Dennison Corporation | Water-soluble pressure-sensitive adhesives |
| AU2000257574A1 (en) * | 2000-06-21 | 2002-01-02 | National Starch And Chemical Investment Holding Corporation | Water based bottle labeling adhesives |
| SG125066A1 (en) * | 2001-04-19 | 2006-09-29 | Lintec Corp | Adhesive sheet for precision electronic member |
| US6927267B1 (en) | 2002-03-07 | 2005-08-09 | Basf Ag | High solids dispersion for wide temperature, pressure sensitive adhesive applications |
| DE10229733A1 (de) * | 2002-07-02 | 2004-01-22 | Basf Ag | Haftklebstoffe für Träger aus Weich-PVC |
| CA2406432C (en) * | 2002-10-03 | 2011-11-29 | Bayer Inc. | Adhesive compounds of butyl-type rubber |
| DE10308046A1 (de) * | 2003-02-26 | 2004-09-23 | Asiral Industriereiniger Gmbh | Bifunktioneller Etikettenleim |
| US7691925B2 (en) | 2004-03-08 | 2010-04-06 | Nitto Denko Corporation | Pressure-sensitive adhesive composition, pressure-sensitive adhesive sheets and surface protecting film |
| JP3765497B2 (ja) * | 2004-03-17 | 2006-04-12 | 日東電工株式会社 | アクリル系粘着剤組成物および粘着テープ |
| CN1294221C (zh) * | 2004-05-17 | 2007-01-10 | 四维企业股份有限公司 | 乳化丙烯酸感压粘着剂 |
| TWI388640B (zh) * | 2004-06-01 | 2013-03-11 | Nitto Denko Corp | 壓敏黏合劑組成物、壓敏黏合片及表面保護膜 |
| TWI387629B (zh) * | 2004-07-26 | 2013-03-01 | Nitto Denko Corp | 壓感黏合劑組成物、壓感黏合片及表面保護膜 |
| JP4804007B2 (ja) * | 2005-01-13 | 2011-10-26 | 日東電工株式会社 | 粘着製品 |
| JP4358190B2 (ja) * | 2005-03-16 | 2009-11-04 | 日東電工株式会社 | 粘着剤組成物、粘着シート類および表面保護フィルム |
| EP1884547B1 (en) * | 2005-05-20 | 2010-12-15 | Nitto Denko Corporation | Pressure sensitive adhesive composition, pressure sensitive adhesive sheet and surface protective film |
| EP1939263B1 (en) * | 2005-09-05 | 2012-08-01 | Nitto Denko Corporation | Adhesive composition, adhesive sheet, and surface protective film |
| US20070135542A1 (en) * | 2005-12-08 | 2007-06-14 | Boonstra Lykele J | Emulsifiers for use in water-based tackifier dispersions |
| US20070249759A1 (en) * | 2006-04-21 | 2007-10-25 | Peter James Miller | Tackifier dispersions with improved humid age performance |
| US20070254985A1 (en) * | 2006-04-21 | 2007-11-01 | Maas Joost H | Resin dispersions with low surfactant concentrations |
| FR2912153B1 (fr) * | 2007-02-02 | 2009-04-17 | Bostik S A Sa | Composition adhesive pour etiquette auto-adhesive decollable |
| US8282754B2 (en) * | 2007-04-05 | 2012-10-09 | Avery Dennison Corporation | Pressure sensitive shrink label |
| AU2008237210B2 (en) * | 2007-04-05 | 2012-08-16 | Avery Dennison Corporation | Pressure sensitive shrink label |
| US20110198024A1 (en) * | 2007-04-05 | 2011-08-18 | Avery Dennison Corporation | Systems and Processes for Applying Heat Transfer Labels |
| DE102007030407A1 (de) * | 2007-06-29 | 2009-01-02 | Henkel Ag & Co. Kgaa | Etiketten mit wasserlösbaren UV-härtenden Klebstoffen |
| FR2918069B1 (fr) * | 2007-06-29 | 2009-09-04 | Bostik S A Sa | Hmpsa pour etiquette auto-adhesive decollable |
| US20090119175A1 (en) * | 2007-11-07 | 2009-05-07 | John Richardson | Tape sealant |
| US20090162595A1 (en) * | 2007-12-19 | 2009-06-25 | Chan Ko | Striped adhesive construction and method and die for making same |
| WO2009127601A1 (de) * | 2008-04-16 | 2009-10-22 | Basf Se | Verfahren zur herstellung von selbstklebenden artikeln |
| KR101733021B1 (ko) | 2009-04-27 | 2017-05-08 | 애버리 데니슨 코포레이션 | 요구에 따라 운반 및 디본딩하기 위한 시스템, 방법 및 재료 |
| US8957277B2 (en) | 2009-04-27 | 2015-02-17 | Avery Dennison Corporation | Disruptable adhesive layer for fluid activated debonding |
| JP4966398B2 (ja) * | 2009-08-05 | 2012-07-04 | ローム アンド ハース カンパニー | ウォッシュオフラベル |
| WO2011036349A1 (en) * | 2009-09-25 | 2011-03-31 | Upm Raflatac Oy | Removable label with a double-layer adhesive |
| BR122014017823A2 (pt) | 2010-01-28 | 2019-07-16 | Avery Dennison Corporation | Sistema e método para aplicação de rótulos em artigos |
| WO2014018077A1 (en) | 2012-07-24 | 2014-01-30 | Avery Dennison Corporation | Silicone/acrylic hybrid adhesives |
| FR2959996B1 (fr) | 2010-05-11 | 2012-05-11 | Bostik Sa | Hmpsa pour etiquette auto-adhesive decollable |
| AU2011299165A1 (en) | 2010-09-08 | 2013-05-02 | Avery Dennison Corporation | Thermoform labeling |
| WO2012054719A2 (en) | 2010-10-20 | 2012-04-26 | Avery Dennison Corporation | Labeling of preformed articles, labels, inks, and related methods |
| WO2013025699A1 (en) | 2011-08-17 | 2013-02-21 | Avery Dennison Corporation | Multiple step forming and labeling process |
| KR102427702B1 (ko) * | 2011-08-31 | 2022-08-03 | 애버리 데니슨 코포레이션 | 접착성 아크릴레이트-올레핀 코폴리머, 이것의 제조방법, 및 이것을 사용하는 조성물 |
| WO2013066401A1 (en) | 2011-10-31 | 2013-05-10 | Avery Dennison Corporation | Disruptable adhesive layer for fluid activated debonding |
| US20130225021A1 (en) * | 2012-02-29 | 2013-08-29 | E.I. Du Pont De Nemours And Company | Highly viscous ionomer-poly(vinylalcohol) coatings |
| US20130289196A1 (en) | 2012-04-30 | 2013-10-31 | Shurtape Technologies, Llc | Film forming formulation for textured surfaces |
| WO2014039796A2 (en) | 2012-09-07 | 2014-03-13 | Avery Dennison Corporation | Labels compatible with recycling |
| CN104870567B (zh) | 2012-10-22 | 2018-09-07 | 艾利丹尼森公司 | 分散在胶黏剂中的交联的微凝胶颗粒的杂化材料 |
| US9633581B2 (en) | 2012-12-21 | 2017-04-25 | Avery Dennison Corporation | Recycling processes and labels and adhesives and use therein |
| CN105246995A (zh) * | 2013-06-14 | 2016-01-13 | 阿利桑那化学公司 | 用于压敏粘合剂的松香酯增粘剂 |
| CN103755863B (zh) * | 2013-12-26 | 2016-06-15 | 中国林业科学研究院林产化学工业研究所 | 一种松香基复合纳米聚合物微球的制备方法 |
| MX2016013233A (es) | 2014-04-07 | 2017-04-27 | Avery Dennison Corp | Composiciones para etiquetas extraibles. |
| WO2019213475A1 (en) | 2018-05-03 | 2019-11-07 | Avery Dennison Corporation | Adhesive laminates and method for making adhesive laminates |
| KR102262503B1 (ko) * | 2018-12-17 | 2021-06-08 | 주식회사 엘지화학 | 아크릴계 에멀젼 수지의 제조 방법 |
| US20240318051A1 (en) | 2021-07-15 | 2024-09-26 | Basf Se | Aqueous pressure-sensitive adhesive composition for recycling-compatible pressure-sensitive adhesive labels |
| WO2024121662A1 (en) | 2022-12-06 | 2024-06-13 | Avery Dennison Corporation | Method for patterning an adhesive layer |
| WO2024157155A1 (en) | 2023-01-26 | 2024-08-02 | Avery Dennison Corporation | Hotmelt adhesive |
| CN120752143A (zh) | 2023-03-09 | 2025-10-03 | 艾利丹尼森公司 | 用于生产装饰性层压件的系统和方法 |
| WO2024224335A1 (en) | 2023-04-26 | 2024-10-31 | Avery Dennison Corporation | Washable laminate and methods of adhesive isolation |
| WO2024231878A1 (en) | 2023-05-11 | 2024-11-14 | Avery Dennison Corporation | Patterned adhesives for use with transfer printing |
| WO2024261643A2 (en) | 2023-06-22 | 2024-12-26 | Avery Dennison Corporation | Systems and methods for depositing and identifying patterned coatings |
| WO2024261645A1 (en) | 2023-06-22 | 2024-12-26 | Avery Dennison Corporation | Systems and methods for depositing and identifying dendritic shapes |
| WO2025003924A1 (en) | 2023-06-30 | 2025-01-02 | Avery Dennison Retail Information Services Llc | Recyclable wireless constructions |
| WO2025003922A1 (en) | 2023-06-30 | 2025-01-02 | Avery Dennison Retail Information Services Llc | Recyclable wireless constructions |
| WO2025003923A1 (en) | 2023-06-30 | 2025-01-02 | Avery Dennison Retail Information Services Llc | Recyclable wireless constructions |
| WO2025074306A1 (en) | 2023-10-05 | 2025-04-10 | Avery Dennison Corporation | Adhesive article with patterned microstructure release |
| WO2025186706A1 (en) | 2024-03-04 | 2025-09-12 | Avery Dennison Corporation | Adhesive composition |
| WO2025191532A2 (en) | 2024-03-15 | 2025-09-18 | The Penn State Research Foundation | Smart battery labels of state of health indication |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4167433A (en) * | 1977-11-03 | 1979-09-11 | Gulf Oil Corporation | Adhesive composition and process for bonding |
| US4189419A (en) * | 1978-08-14 | 1980-02-19 | Avery International Corporation | Pressure-sensitive adhesives based on carboxylated SBR emulsion |
| CA1203335A (en) * | 1981-04-28 | 1986-04-15 | Polysar Limited | Pressure sensitive adhesives |
| US4548845A (en) * | 1983-04-21 | 1985-10-22 | Avery International Corp. | Reduced build-up pressure-sensitive adhesives |
| US4564664A (en) * | 1983-08-12 | 1986-01-14 | Avery International Corporation | Emulsion-acrylic pressure-sensitive adhesives formed in two step polymerization |
| US4670505A (en) * | 1985-08-23 | 1987-06-02 | Hercules Incorporated | Polyacrylate dispersions |
| JP2684046B2 (ja) * | 1988-01-26 | 1997-12-03 | ニチバン株式会社 | 粘着剤組成物 |
| CA2044169C (en) * | 1989-08-14 | 2002-02-26 | Margaret M. Bernard | Emulsion pressure-sensitive adhesive polymers exhibiting excellent room and low-temperature performance |
| JP2915455B2 (ja) * | 1989-12-04 | 1999-07-05 | 三菱化学ビーエーエスエフ株式会社 | アクリル系樹脂水性エマルジョン組成物 |
| ATE160814T1 (de) * | 1991-10-15 | 1997-12-15 | Avery Dennison Corp | Verbesserungen an wiederaufbereitbaren zusammensetzungen mit druckempfindlichen klebstoff |
| US5183841A (en) * | 1991-12-24 | 1993-02-02 | Avery Dennison Corporation | Removable pressure-sensitive adhesives for recyclable substrates |
-
1991
- 1991-12-24 US US07/813,354 patent/US5183841A/en not_active Expired - Lifetime
-
1992
- 1992-12-22 DE DE69226653T patent/DE69226653T2/de not_active Expired - Fee Related
- 1992-12-22 EP EP93902716A patent/EP0618947B1/en not_active Expired - Lifetime
- 1992-12-22 AU AU34190/93A patent/AU672381B2/en not_active Ceased
- 1992-12-22 KR KR1019940702215A patent/KR100255497B1/ko not_active Expired - Fee Related
- 1992-12-22 CA CA002126351A patent/CA2126351C/en not_active Expired - Fee Related
- 1992-12-22 BR BR9206986A patent/BR9206986A/pt not_active Application Discontinuation
- 1992-12-22 WO PCT/US1992/011161 patent/WO1993013181A1/en not_active Ceased
- 1992-12-22 JP JP5511867A patent/JPH07506126A/ja active Pending
- 1992-12-23 US US07/996,019 patent/US5385965A/en not_active Expired - Lifetime
- 1992-12-24 MX MX9207556A patent/MX9207556A/es not_active IP Right Cessation
-
1993
- 1993-01-04 TW TW082100017A patent/TW316277B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| MX9207556A (es) | 1994-05-31 |
| AU672381B2 (en) | 1996-10-03 |
| TW316277B (enExample) | 1997-09-21 |
| DE69226653T2 (de) | 1998-12-24 |
| US5183841A (en) | 1993-02-02 |
| DE69226653D1 (de) | 1998-09-17 |
| EP0618947B1 (en) | 1998-08-12 |
| JPH07506126A (ja) | 1995-07-06 |
| KR940703899A (ko) | 1994-12-12 |
| KR100255497B1 (ko) | 2000-05-01 |
| US5385965A (en) | 1995-01-31 |
| BR9206986A (pt) | 1995-09-12 |
| CA2126351A1 (en) | 1993-07-08 |
| AU3419093A (en) | 1993-07-28 |
| EP0618947A4 (en) | 1995-05-31 |
| EP0618947A1 (en) | 1994-10-12 |
| WO1993013181A1 (en) | 1993-07-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2126351C (en) | Removable pressure-sensitive adhesives for recyclable substrates | |
| CA1156776A (en) | Surfactant free process for production of pressure sensitive adhesive latexes | |
| US5196504A (en) | Repulpable pressure-sensitive adhesive compositions | |
| TW593614B (en) | Rubber-acrylic adhesive formulation | |
| EP0690886B1 (en) | Pressure-sensitive adhesives based on emulsion polymers | |
| KR102256572B1 (ko) | 다상 폴리머 조성물 | |
| JP2012522853A (ja) | 苛性アルカリ除去能を有するホットメルト接着剤配合物 | |
| US5221706A (en) | Tackifiable acrylic emulsion pressure-sensitive adhesive having excellent low-temperature performance | |
| US6525129B1 (en) | Water-soluble pressure-sensitive adhesives | |
| JPH06207151A (ja) | アクリル系感圧接着剤組成物及び両面テープ | |
| JP3670049B2 (ja) | ディレードタック型粘着剤組成物 | |
| JP3046067B2 (ja) | 優れた低温性能を有する粘着性アクリル系エマルション型感圧接着剤 | |
| JP4559084B2 (ja) | ゴム‐アクリル接着剤配合物 | |
| JP2003313528A (ja) | 水性感圧型粘着剤組成物 | |
| JP2001089730A (ja) | 感圧性接着剤組成物およびそれを用いた感圧性接着シート | |
| US6242552B1 (en) | Stamp adhesive | |
| JPH07188629A (ja) | 粘着剤組成物 | |
| JP2001200235A (ja) | 感熱性粘着剤組成物およびその製造方法ならびに感熱性粘着シート又はラベル | |
| WO2002010306A2 (en) | Pressure sensitive adhesive and surfactant composition | |
| JPH03217478A (ja) | 静電植毛用接着剤 | |
| JPS60179480A (ja) | 接着剤組成物 | |
| JPH0713220B2 (ja) | 感圧接着剤組成物 | |
| JPS5861160A (ja) | 感圧接着剤組成物 | |
| JPH09241600A (ja) | 粘接着剤用樹脂水性分散液 | |
| US20040131873A1 (en) | Pressure sensitive adhesive composition containing ethylene/vinyl ester functional copolymers having high ethylene content |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |