CA2092184C - Detergent compositions containing anionic surfactants, polyhydroxy fatty acid amides and magnesium - Google Patents
Detergent compositions containing anionic surfactants, polyhydroxy fatty acid amides and magnesiumInfo
- Publication number
- CA2092184C CA2092184C CA002092184A CA2092184A CA2092184C CA 2092184 C CA2092184 C CA 2092184C CA 002092184 A CA002092184 A CA 002092184A CA 2092184 A CA2092184 A CA 2092184A CA 2092184 C CA2092184 C CA 2092184C
- Authority
- CA
- Canada
- Prior art keywords
- alkyl
- fatty acid
- weight
- composition
- sulfonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 276
- 239000003599 detergent Substances 0.000 title claims abstract description 100
- 235000014113 dietary fatty acids Nutrition 0.000 title claims abstract description 95
- 239000000194 fatty acid Substances 0.000 title claims abstract description 95
- 229930195729 fatty acid Natural products 0.000 title claims abstract description 95
- 150000004665 fatty acids Chemical class 0.000 title claims abstract description 92
- 239000011777 magnesium Substances 0.000 title claims abstract description 37
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 229910052749 magnesium Inorganic materials 0.000 title claims abstract description 36
- 239000003945 anionic surfactant Substances 0.000 title claims description 16
- 239000004094 surface-active agent Substances 0.000 claims abstract description 97
- -1 2-hydroxy propyl Chemical group 0.000 claims abstract description 94
- 238000000034 method Methods 0.000 claims abstract description 49
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 45
- 125000000129 anionic group Chemical group 0.000 claims abstract description 32
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 29
- 125000001183 hydrocarbyl group Chemical group 0.000 claims abstract description 11
- 238000004140 cleaning Methods 0.000 claims abstract description 10
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 9
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 claims abstract description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 62
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 58
- 238000006243 chemical reaction Methods 0.000 claims description 47
- 239000007788 liquid Substances 0.000 claims description 44
- 239000000047 product Substances 0.000 claims description 42
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 42
- 125000004432 carbon atom Chemical group C* 0.000 claims description 40
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 28
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 26
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 26
- 239000008103 glucose Substances 0.000 claims description 25
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 23
- 239000007859 condensation product Substances 0.000 claims description 21
- 239000002736 nonionic surfactant Substances 0.000 claims description 20
- 150000001412 amines Chemical class 0.000 claims description 16
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 claims description 15
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 claims description 15
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 claims description 15
- 239000002562 thickening agent Substances 0.000 claims description 15
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 13
- 229960003237 betaine Drugs 0.000 claims description 13
- 239000003752 hydrotrope Substances 0.000 claims description 13
- 150000001720 carbohydrates Chemical group 0.000 claims description 12
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims description 10
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 9
- 230000002209 hydrophobic effect Effects 0.000 claims description 9
- 239000011591 potassium Substances 0.000 claims description 9
- 229910052700 potassium Inorganic materials 0.000 claims description 9
- 125000003342 alkenyl group Chemical group 0.000 claims description 8
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims description 8
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 7
- 150000004676 glycans Chemical class 0.000 claims description 7
- 229940079842 sodium cumenesulfonate Drugs 0.000 claims description 7
- QEKATQBVVAZOAY-UHFFFAOYSA-M sodium;4-propan-2-ylbenzenesulfonate Chemical compound [Na+].CC(C)C1=CC=C(S([O-])(=O)=O)C=C1 QEKATQBVVAZOAY-UHFFFAOYSA-M 0.000 claims description 7
- 238000009833 condensation Methods 0.000 claims description 5
- 230000005494 condensation Effects 0.000 claims description 5
- 150000002016 disaccharides Chemical class 0.000 claims description 5
- 125000001165 hydrophobic group Chemical group 0.000 claims description 5
- 229920001282 polysaccharide Polymers 0.000 claims description 5
- 239000005017 polysaccharide Substances 0.000 claims description 5
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 claims description 4
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 4
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 4
- 150000002772 monosaccharides Chemical class 0.000 claims description 4
- 229920001155 polypropylene Polymers 0.000 claims description 4
- GHKGUEZUGFJUEJ-UHFFFAOYSA-M potassium;4-methylbenzenesulfonate Chemical compound [K+].CC1=CC=C(S([O-])(=O)=O)C=C1 GHKGUEZUGFJUEJ-UHFFFAOYSA-M 0.000 claims description 4
- 229940117986 sulfobetaine Drugs 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 3
- ZZXDRXVIRVJQBT-UHFFFAOYSA-M Xylenesulfonate Chemical compound CC1=CC=CC(S([O-])(=O)=O)=C1C ZZXDRXVIRVJQBT-UHFFFAOYSA-M 0.000 claims description 3
- 229910001425 magnesium ion Inorganic materials 0.000 claims description 3
- 229920001748 polybutylene Polymers 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 229940048842 sodium xylenesulfonate Drugs 0.000 claims description 3
- 229940071104 xylenesulfonate Drugs 0.000 claims description 3
- VUGIQPRQXKWKGX-UHFFFAOYSA-K [K+].[K+].[K+].[O-]C(=O)CC(C([O-])=O)S([O-])(=O)=O Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(C([O-])=O)S([O-])(=O)=O VUGIQPRQXKWKGX-UHFFFAOYSA-K 0.000 claims description 2
- 150000002989 phenols Chemical class 0.000 claims description 2
- MYGBBCKCTXSGOB-UHFFFAOYSA-M potassium;2-propan-2-ylbenzenesulfonate Chemical compound [K+].CC(C)C1=CC=CC=C1S([O-])(=O)=O MYGBBCKCTXSGOB-UHFFFAOYSA-M 0.000 claims description 2
- KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical group [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 claims 1
- ZXGOACRTCPRVON-UHFFFAOYSA-K trisodium;2-sulfonatobutanedioate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(C([O-])=O)S([O-])(=O)=O ZXGOACRTCPRVON-UHFFFAOYSA-K 0.000 claims 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 54
- 235000019441 ethanol Nutrition 0.000 description 40
- 235000001055 magnesium Nutrition 0.000 description 30
- 239000000463 material Substances 0.000 description 29
- 239000000243 solution Substances 0.000 description 28
- 229920002125 Sokalan® Polymers 0.000 description 25
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 24
- 235000001727 glucose Nutrition 0.000 description 23
- 229910052708 sodium Inorganic materials 0.000 description 23
- 244000060011 Cocos nucifera Species 0.000 description 22
- 239000003054 catalyst Substances 0.000 description 22
- 235000000346 sugar Nutrition 0.000 description 22
- 235000013162 Cocos nucifera Nutrition 0.000 description 21
- 239000011734 sodium Substances 0.000 description 21
- 235000015424 sodium Nutrition 0.000 description 21
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 20
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 20
- 239000003795 chemical substances by application Substances 0.000 description 20
- 235000020357 syrup Nutrition 0.000 description 20
- 239000006188 syrup Substances 0.000 description 20
- 240000008042 Zea mays Species 0.000 description 19
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 19
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 19
- 235000005822 corn Nutrition 0.000 description 19
- 150000008051 alkyl sulfates Chemical class 0.000 description 17
- 150000001875 compounds Chemical class 0.000 description 16
- 230000008569 process Effects 0.000 description 16
- 239000002253 acid Substances 0.000 description 15
- 238000004851 dishwashing Methods 0.000 description 15
- 238000009472 formulation Methods 0.000 description 15
- 229920000642 polymer Polymers 0.000 description 15
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 14
- 150000003839 salts Chemical class 0.000 description 14
- 229920005646 polycarboxylate Polymers 0.000 description 13
- 239000011541 reaction mixture Substances 0.000 description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
- 229960002160 maltose Drugs 0.000 description 12
- 239000002304 perfume Substances 0.000 description 12
- 239000003760 tallow Substances 0.000 description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 11
- 150000001408 amides Chemical class 0.000 description 11
- 239000004744 fabric Substances 0.000 description 11
- 238000002156 mixing Methods 0.000 description 11
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 10
- 150000001298 alcohols Chemical class 0.000 description 10
- 239000004615 ingredient Substances 0.000 description 10
- 229910000029 sodium carbonate Inorganic materials 0.000 description 10
- 235000017550 sodium carbonate Nutrition 0.000 description 10
- 239000002904 solvent Substances 0.000 description 10
- MBBZMMPHUWSWHV-BDVNFPICSA-N N-methylglucamine Chemical compound CNC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO MBBZMMPHUWSWHV-BDVNFPICSA-N 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
- 229910021536 Zeolite Inorganic materials 0.000 description 9
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 9
- 239000000975 dye Substances 0.000 description 9
- 239000001257 hydrogen Substances 0.000 description 9
- 229910052739 hydrogen Inorganic materials 0.000 description 9
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 9
- 150000004702 methyl esters Chemical class 0.000 description 9
- 239000012188 paraffin wax Substances 0.000 description 9
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 9
- 239000007787 solid Substances 0.000 description 9
- 150000003871 sulfonates Chemical class 0.000 description 9
- 239000010457 zeolite Substances 0.000 description 9
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 8
- 230000008901 benefit Effects 0.000 description 8
- 150000002148 esters Chemical class 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 8
- 235000007686 potassium Nutrition 0.000 description 8
- 229960003975 potassium Drugs 0.000 description 8
- 239000000376 reactant Substances 0.000 description 8
- GHPCICSQWQDZLM-UHFFFAOYSA-N 1-(4-chlorophenyl)sulfonyl-1-methyl-3-propylurea Chemical compound CCCNC(=O)N(C)S(=O)(=O)C1=CC=C(Cl)C=C1 GHPCICSQWQDZLM-UHFFFAOYSA-N 0.000 description 7
- RKWGIWYCVPQPMF-UHFFFAOYSA-N Chloropropamide Chemical compound CCCNC(=O)NS(=O)(=O)C1=CC=C(Cl)C=C1 RKWGIWYCVPQPMF-UHFFFAOYSA-N 0.000 description 7
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 7
- 238000007792 addition Methods 0.000 description 7
- 125000001931 aliphatic group Chemical group 0.000 description 7
- 150000004996 alkyl benzenes Chemical class 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 229940096386 coconut alcohol Drugs 0.000 description 7
- 238000007046 ethoxylation reaction Methods 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- 239000003605 opacifier Substances 0.000 description 7
- 229920005862 polyol Polymers 0.000 description 7
- 159000000000 sodium salts Chemical class 0.000 description 7
- 239000002689 soil Substances 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 6
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 229930006000 Sucrose Natural products 0.000 description 6
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 6
- 239000006227 byproduct Substances 0.000 description 6
- 239000007795 chemical reaction product Substances 0.000 description 6
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 6
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 6
- 150000002194 fatty esters Chemical class 0.000 description 6
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 6
- 150000003077 polyols Chemical class 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 239000002002 slurry Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 239000005720 sucrose Substances 0.000 description 6
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 229920002472 Starch Polymers 0.000 description 5
- 239000002585 base Substances 0.000 description 5
- NZUPCNDJBJXXRF-UHFFFAOYSA-O bethanechol Chemical compound C[N+](C)(C)CC(C)OC(N)=O NZUPCNDJBJXXRF-UHFFFAOYSA-O 0.000 description 5
- 239000004927 clay Substances 0.000 description 5
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 229920001296 polysiloxane Polymers 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 239000000523 sample Substances 0.000 description 5
- 235000019698 starch Nutrition 0.000 description 5
- 125000001424 substituent group Chemical group 0.000 description 5
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 4
- 239000004721 Polyphenylene oxide Substances 0.000 description 4
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 4
- 125000002252 acyl group Chemical group 0.000 description 4
- 150000001336 alkenes Chemical class 0.000 description 4
- 229940077388 benzenesulfonate Drugs 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 230000001965 increasing effect Effects 0.000 description 4
- 239000002563 ionic surfactant Substances 0.000 description 4
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical class OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 4
- 239000000347 magnesium hydroxide Substances 0.000 description 4
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 4
- 239000000395 magnesium oxide Substances 0.000 description 4
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
- 229920000570 polyether Polymers 0.000 description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000010992 reflux Methods 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 238000005201 scrubbing Methods 0.000 description 4
- 239000000741 silica gel Substances 0.000 description 4
- 229910002027 silica gel Inorganic materials 0.000 description 4
- 229940083542 sodium Drugs 0.000 description 4
- 239000008107 starch Substances 0.000 description 4
- 150000008163 sugars Chemical class 0.000 description 4
- FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 description 4
- 230000008719 thickening Effects 0.000 description 4
- 239000002888 zwitterionic surfactant Substances 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- QZXSMBBFBXPQHI-UHFFFAOYSA-N N-(dodecanoyl)ethanolamine Chemical compound CCCCCCCCCCCC(=O)NCCO QZXSMBBFBXPQHI-UHFFFAOYSA-N 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 125000005227 alkyl sulfonate group Chemical group 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
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- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 125000005480 straight-chain fatty acid group Chemical group 0.000 description 1
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- AABMAPVNIQIMKZ-UHFFFAOYSA-J tetrapotassium 2-(1,2-dicarboxylatoethoxy)butanedioate Chemical class [K+].[K+].[K+].[K+].[O-]C(=O)CC(C([O-])=O)OC(C([O-])=O)CC([O-])=O AABMAPVNIQIMKZ-UHFFFAOYSA-J 0.000 description 1
- JZBRFIUYUGTUGG-UHFFFAOYSA-J tetrapotassium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [K+].[K+].[K+].[K+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O JZBRFIUYUGTUGG-UHFFFAOYSA-J 0.000 description 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-M toluenesulfonate group Chemical class C=1(C(=CC=CC1)S(=O)(=O)[O-])C LBLYYCQCTBFVLH-UHFFFAOYSA-M 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
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- 125000005457 triglyceride group Chemical group 0.000 description 1
- TWQULNDIKKJZPH-UHFFFAOYSA-K trilithium;phosphate Chemical compound [Li+].[Li+].[Li+].[O-]P([O-])([O-])=O TWQULNDIKKJZPH-UHFFFAOYSA-K 0.000 description 1
- 235000015870 tripotassium citrate Nutrition 0.000 description 1
- 235000019798 tripotassium phosphate Nutrition 0.000 description 1
- 229910000404 tripotassium phosphate Inorganic materials 0.000 description 1
- 150000004043 trisaccharides Chemical class 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 229940038773 trisodium citrate Drugs 0.000 description 1
- 235000019263 trisodium citrate Nutrition 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
- 238000001665 trituration Methods 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 239000011345 viscous material Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/65—Mixtures of anionic with cationic compounds
- C11D1/652—Mixtures of anionic compounds with carboxylic amides or alkylol amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/18—Sulfonic acids or sulfuric acid esters; Salts thereof derived from amino alcohols
- C11D1/20—Fatty acid condensates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/42—Amino alcohols or amino ethers
- C11D1/44—Ethers of polyoxyalkylenes with amino alcohols; Condensation products of epoxyalkanes with amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US59061790A | 1990-09-28 | 1990-09-28 | |
| US590,617 | 1990-09-28 | ||
| US75590591A | 1991-09-06 | 1991-09-06 | |
| US755,905 | 1991-09-06 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2092184A1 CA2092184A1 (en) | 1992-03-29 |
| CA2092184C true CA2092184C (en) | 1998-06-30 |
Family
ID=27080893
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002092184A Expired - Fee Related CA2092184C (en) | 1990-09-28 | 1991-09-25 | Detergent compositions containing anionic surfactants, polyhydroxy fatty acid amides and magnesium |
Country Status (24)
| Country | Link |
|---|---|
| EP (1) | EP0551410B1 (cs) |
| JP (1) | JPH06505032A (cs) |
| CN (1) | CN1029010C (cs) |
| AU (1) | AU8768891A (cs) |
| BR (1) | BR9106933A (cs) |
| CA (1) | CA2092184C (cs) |
| CZ (1) | CZ281623B6 (cs) |
| DE (1) | DE69113057T2 (cs) |
| DK (1) | DK0551410T3 (cs) |
| EG (1) | EG19743A (cs) |
| ES (1) | ES2077250T3 (cs) |
| FI (1) | FI931368L (cs) |
| GR (1) | GR3018284T3 (cs) |
| HU (1) | HU214048B (cs) |
| IE (1) | IE913418A1 (cs) |
| MA (1) | MA22304A1 (cs) |
| MX (1) | MX9101364A (cs) |
| MY (1) | MY131214A (cs) |
| NO (1) | NO931021L (cs) |
| NZ (1) | NZ240040A (cs) |
| PT (1) | PT99101B (cs) |
| SK (1) | SK21893A3 (cs) |
| TR (1) | TR26011A (cs) |
| WO (1) | WO1992006156A1 (cs) |
Families Citing this family (51)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| HUT68189A (en) * | 1991-09-06 | 1995-05-29 | Procter & Gamble | Detergent compositions containing calcium and polyhydroxy fatty acid amide |
| JPH08500388A (ja) * | 1992-08-21 | 1996-01-16 | ザ、プロクター、エンド、ギャンブル、カンパニー | アルキルエーテルサルフェートを含んでなる濃縮液体洗剤組成物および製法 |
| US5545354A (en) * | 1992-09-01 | 1996-08-13 | The Procter & Gamble Company | Liquid or gel dishwashing detergent containing a polyhydroxy fatty acid amide, calcium ions and an alkylpolyethoxypolycarboxylate |
| US5580849A (en) * | 1992-09-01 | 1996-12-03 | The Procter & Gamble Company | Liquid or gel detergent compositions containing calcium and stabilizing agent thereof |
| CZ53895A3 (en) * | 1992-09-01 | 1995-11-15 | Procter & Gamble | Liquid or jellylike detergents containing calcium and agents for their stabilization |
| WO1994005769A1 (en) * | 1992-09-01 | 1994-03-17 | The Procter & Gamble Company | Liquid or gel dishwashing detergent containing alkyl ethoxy carboxylate, divalent ions and alkylpolyethoxypolycarboxylate |
| DE4229442A1 (de) * | 1992-09-03 | 1994-03-10 | Henkel Kgaa | Dispergiermittel |
| AU5540994A (en) * | 1992-11-04 | 1994-05-24 | Procter & Gamble Company, The | Detergent gels |
| EP0670886A1 (en) * | 1992-11-30 | 1995-09-13 | The Procter & Gamble Company | Detergent compositions containing polyhydroxy fatty acid amide, sulfated polyhydroxy fatty acid amide and soap |
| US5318728A (en) * | 1992-11-30 | 1994-06-07 | The Procter & Gamble Company | Low sudsing polyhydroxy fatty acid amide detergents |
| AU5678294A (en) * | 1992-11-30 | 1994-06-22 | Procter & Gamble Company, The | Cleaning with low-sudsing mixed polyhydroxy fatty acid amide nonionic/anionic surfactants |
| EP0670885B1 (en) * | 1992-11-30 | 1997-08-20 | The Procter & Gamble Company | High sudsing detergent compositions with specially selected soaps |
| JPH08509757A (ja) * | 1993-04-08 | 1996-10-15 | ザ、プロクター、エンド、ギャンブル、カンパニー | ポリヒドロキシ脂肪酸アミドを有する洗剤組成物中の第二級（２，３）アルキルサルフェート界面活性剤 |
| DE4323253C1 (de) * | 1993-07-12 | 1995-01-05 | Henkel Kgaa | Verwendung von Fettsäure-N-alkylpolyhydroxyalkylamiden als Klarspülmittel für die maschinelle Reinigung harter Oberflächen |
| DE4331297A1 (de) * | 1993-09-15 | 1995-03-16 | Henkel Kgaa | Stückseifen |
| EP1707624A3 (en) | 1993-10-08 | 2007-01-03 | Novozymes A/S | Amylase variants |
| DE69423225T2 (de) * | 1993-10-12 | 2000-06-21 | Stepan Co., Northfield | Alpha sulfonierte methyl- oder ethylfettsäureestersalze und anionische oberflächenaktive mittel enthaltende flüssigwaschmittelzusammensetzungen |
| DE4400632C1 (de) * | 1994-01-12 | 1995-03-23 | Henkel Kgaa | Tensidgemische und diese enthaltende Mittel |
| DE4409321A1 (de) * | 1994-03-18 | 1995-09-21 | Henkel Kgaa | Detergensgemische |
| CA2189544C (en) * | 1994-05-06 | 2000-06-13 | Kenneth Michael Kemen | Liquid detergent containing polyhydroxy fatty acid amide and toluene sulfonate salt |
| GB2292155A (en) * | 1994-08-11 | 1996-02-14 | Procter & Gamble | Handwash laundry detergent composition comprising three surfactants |
| DE19533539A1 (de) | 1995-09-11 | 1997-03-13 | Henkel Kgaa | O/W-Emulgatoren |
| WO1997012022A1 (en) * | 1995-09-29 | 1997-04-03 | The Procter & Gamble Company | Stable aqueous laundry detergent compositions comprising quaternary surfactants and amine oxides and having improved suspension properties |
| DE19544422A1 (de) * | 1995-11-29 | 1997-06-05 | Hoechst Ag | Sulfonsuccinate von Polyhydroxyamiden |
| DE19544710C2 (de) | 1995-11-30 | 1998-11-26 | Henkel Kgaa | Verdickungsmittel |
| US5932535A (en) * | 1995-12-21 | 1999-08-03 | Henkel Kommanditgesellschaft Auf Aktien | Process for the production of light-colored, low-viscosity surfactant concentrates |
| DE19548068C1 (de) | 1995-12-21 | 1997-06-19 | Henkel Kgaa | Verfahren zur Herstellung hellfarbiger, niedrigviskoser Tensidkonzentrate |
| US5965508A (en) * | 1997-10-21 | 1999-10-12 | Stepan Company | Soap bar compositions comprising alpha sulfonated fatty acid alkyl esters and long chain fatty acids |
| JP2000073085A (ja) * | 1998-08-31 | 2000-03-07 | Lion Corp | 洗浄剤組成物 |
| DE19840342A1 (de) * | 1998-09-04 | 2000-03-09 | Clariant Gmbh | Feste Tensidmischungen enthaltend Fettsäurepolyhydroxyamide |
| US6387870B1 (en) | 1999-03-29 | 2002-05-14 | Ecolab Inc. | Solid pot and pan detergent |
| DE10018812A1 (de) | 2000-04-15 | 2001-10-25 | Cognis Deutschland Gmbh | Verfahren zur Herstellung von nichtionischen Tensidgranulaten |
| DE102004017112B4 (de) * | 2004-04-07 | 2007-06-28 | Henkel Kgaa | Verwendung von Pudermittel |
| DE102005025933B3 (de) | 2005-06-06 | 2006-07-13 | Centrotherm Photovoltaics Gmbh + Co. Kg | Dotiergermisch für die Dotierung von Halbleitern |
| JP4795298B2 (ja) * | 2007-04-12 | 2011-10-19 | 花王株式会社 | 液体洗浄剤組成物 |
| CN102686715B (zh) | 2009-10-21 | 2014-05-07 | 斯特潘公司 | 含有磺化脂肪酸、其酯或其盐以及甜菜碱或磺基甜菜碱的粘性液体清洁组合物 |
| KR101218398B1 (ko) * | 2010-12-02 | 2013-01-03 | 애경산업(주) | 액체 세정제용 조성물 |
| AU2010365414B2 (en) | 2010-12-13 | 2014-07-10 | Colgate-Palmolive Company | Dilutable concentrated cleaning composition |
| EP2854950B1 (de) * | 2012-05-30 | 2016-12-14 | Clariant International Ltd | Verwendung von n-methyl-n-acylglucaminen als kältestabilisatoren in tensidlösungen |
| CN103860398A (zh) * | 2012-12-17 | 2014-06-18 | 江苏华艺服饰有限公司 | 一种去染料洗手液 |
| BR112017015300B1 (pt) | 2015-01-15 | 2022-09-13 | Ecolab Usa Inc | Composição de limpeza espumante aquosa para removersujeira em baixas temperaturas de uma superfície a ser limpa, composição de espuma, método para remover sujeira de uma superfície a ser limpa e uso da referida composição |
| JP6688613B2 (ja) * | 2016-01-15 | 2020-04-28 | 株式会社ニイタカ | 液体洗浄剤組成物 |
| JP6646512B2 (ja) * | 2016-04-15 | 2020-02-14 | 花王株式会社 | 食器用液体洗浄剤組成物 |
| DE102019207890A1 (de) * | 2019-05-29 | 2020-12-03 | Henkel Ag & Co. Kgaa | Schaumstabilisierung durch spezifisches Tensidgemisch |
| DE102019207891A1 (de) * | 2019-05-29 | 2020-12-03 | Henkel Ag & Co. Kgaa | Schaumstabilisierung durch spezifisches Tensidgemisch |
| US20230034095A1 (en) | 2021-07-16 | 2023-02-02 | The Procter & Gamble Company | Liquid hand dishwashing cleaning composition |
| US20230029458A1 (en) | 2021-07-16 | 2023-02-02 | The Procter & Gamble Company | Liquid hand dishwashing cleaning composition |
| US20230018865A1 (en) | 2021-07-16 | 2023-01-19 | The Procter & Gamble Company | Liquid hand dishwashing cleaning composition |
| EP4194533B1 (en) * | 2021-12-08 | 2024-06-05 | The Procter & Gamble Company | Liquid hand dishwashing detergent composition |
| CA3239561A1 (en) * | 2021-12-22 | 2023-06-29 | Integrity Bio-Chemicals, Llc | Compositions comprising reaction products of saccharide polymers and fatty acids or fatty esters formulated with an amide-based neutral surfactant |
| CN115678690B (zh) * | 2022-12-14 | 2024-12-17 | 山东宙雨消防科技股份有限公司 | 一种氢氧化镁清洁剂及其制备方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1072347B (cs) * | 1956-05-14 | |||
| DK130418A (cs) * | 1967-07-19 | |||
| JPS5950200B2 (ja) * | 1978-02-17 | 1984-12-06 | ライオン株式会社 | 改良された液体洗浄剤組成物 |
| GB2058823B (en) * | 1979-09-17 | 1983-06-22 | Unilever Ltd | Dishwashing compositions |
| DE3370164D1 (en) * | 1982-10-28 | 1987-04-16 | Procter & Gamble | Liquid detergent compositions |
| IE58219B1 (en) * | 1984-11-07 | 1993-08-11 | Procter & Gamble | Liquid detergent compositions |
| DE3538451A1 (de) * | 1985-10-29 | 1987-05-07 | Sueddeutsche Zucker Ag | Fettsaeureamide von aminopolyolen als nichtionogene tenside |
| DE3711776A1 (de) * | 1987-04-08 | 1988-10-27 | Huels Chemische Werke Ag | Verwendung von n-polyhydroxyalkylfettsaeureamiden als verdickungsmittel fuer fluessige waessrige tensidsysteme |
-
1991
- 1991-09-25 EP EP91918975A patent/EP0551410B1/en not_active Expired - Lifetime
- 1991-09-25 WO PCT/US1991/006982 patent/WO1992006156A1/en active IP Right Grant
- 1991-09-25 SK SK21893A patent/SK21893A3/sk unknown
- 1991-09-25 ES ES91918975T patent/ES2077250T3/es not_active Expired - Lifetime
- 1991-09-25 DE DE69113057T patent/DE69113057T2/de not_active Expired - Fee Related
- 1991-09-25 DK DK91918975.3T patent/DK0551410T3/da active
- 1991-09-25 BR BR919106933A patent/BR9106933A/pt not_active IP Right Cessation
- 1991-09-25 AU AU87688/91A patent/AU8768891A/en not_active Abandoned
- 1991-09-25 JP JP3517270A patent/JPH06505032A/ja active Pending
- 1991-09-25 CZ CZ93323A patent/CZ281623B6/cs not_active IP Right Cessation
- 1991-09-25 CA CA002092184A patent/CA2092184C/en not_active Expired - Fee Related
- 1991-09-25 FI FI931368A patent/FI931368L/fi unknown
- 1991-09-25 HU HU9300765A patent/HU214048B/hu not_active IP Right Cessation
- 1991-09-27 MA MA22587A patent/MA22304A1/fr unknown
- 1991-09-27 PT PT99101A patent/PT99101B/pt not_active IP Right Cessation
- 1991-09-27 IE IE341891A patent/IE913418A1/en not_active Application Discontinuation
- 1991-09-27 CN CN91108489.4A patent/CN1029010C/zh not_active Expired - Fee Related
- 1991-09-28 EG EG58891A patent/EG19743A/xx active
- 1991-09-28 MY MYPI91001786A patent/MY131214A/en unknown
- 1991-09-30 MX MX9101364A patent/MX9101364A/es unknown
- 1991-09-30 TR TR91/0938A patent/TR26011A/xx unknown
- 1991-09-30 NZ NZ240040A patent/NZ240040A/en unknown
-
1993
- 1993-03-22 NO NO93931021A patent/NO931021L/no unknown
-
1995
- 1995-12-05 GR GR950403402T patent/GR3018284T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| HU214048B (en) | 1997-12-29 |
| BR9106933A (pt) | 1993-08-17 |
| MX9101364A (es) | 1992-05-04 |
| MY131214A (en) | 2007-07-31 |
| MA22304A1 (fr) | 1992-04-01 |
| HUT64378A (en) | 1993-12-28 |
| CN1061036A (zh) | 1992-05-13 |
| ES2077250T3 (es) | 1995-11-16 |
| AU8768891A (en) | 1992-04-28 |
| FI931368A7 (fi) | 1993-04-26 |
| CA2092184A1 (en) | 1992-03-29 |
| CN1029010C (zh) | 1995-06-21 |
| WO1992006156A1 (en) | 1992-04-16 |
| NO931021L (no) | 1993-05-12 |
| SK21893A3 (en) | 1993-07-07 |
| GR3018284T3 (en) | 1996-03-31 |
| DK0551410T3 (da) | 1996-02-05 |
| CZ281623B6 (cs) | 1996-11-13 |
| PT99101B (pt) | 1999-02-26 |
| EP0551410B1 (en) | 1995-09-13 |
| FI931368L (fi) | 1993-04-26 |
| FI931368A0 (fi) | 1993-03-26 |
| EP0551410A1 (en) | 1993-07-21 |
| CZ32393A3 (en) | 1994-03-16 |
| EG19743A (en) | 1996-01-31 |
| DE69113057T2 (de) | 1996-05-30 |
| NZ240040A (en) | 1995-05-26 |
| NO931021D0 (no) | 1993-03-22 |
| IE913418A1 (en) | 1992-04-08 |
| TR26011A (tr) | 1993-11-01 |
| JPH06505032A (ja) | 1994-06-09 |
| PT99101A (pt) | 1992-08-31 |
| HU9300765D0 (en) | 1993-07-28 |
| DE69113057D1 (de) | 1995-10-19 |
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