CA2091299C - Compositions of random copolymers of propene containing an .alpha.-olefin as comonomer - Google Patents
Compositions of random copolymers of propene containing an .alpha.-olefin as comonomerInfo
- Publication number
- CA2091299C CA2091299C CA002091299A CA2091299A CA2091299C CA 2091299 C CA2091299 C CA 2091299C CA 002091299 A CA002091299 A CA 002091299A CA 2091299 A CA2091299 A CA 2091299A CA 2091299 C CA2091299 C CA 2091299C
- Authority
- CA
- Canada
- Prior art keywords
- fraction
- alpha
- olefin
- weight
- percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 50
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title claims abstract description 35
- 229920005604 random copolymer Polymers 0.000 title claims abstract description 9
- 210000002196 fr. b Anatomy 0.000 claims abstract description 16
- 210000003918 fraction a Anatomy 0.000 claims abstract description 13
- 238000007789 sealing Methods 0.000 claims abstract description 11
- 229920000098 polyolefin Polymers 0.000 claims abstract description 10
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000008096 xylene Substances 0.000 claims abstract description 8
- 238000002844 melting Methods 0.000 claims abstract description 6
- 230000008018 melting Effects 0.000 claims abstract description 6
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 19
- 239000003054 catalyst Substances 0.000 claims description 18
- 239000011777 magnesium Substances 0.000 claims description 16
- 229910052749 magnesium Inorganic materials 0.000 claims description 15
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 13
- 238000006116 polymerization reaction Methods 0.000 claims description 11
- 239000012071 phase Substances 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 8
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 4
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 4
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims description 4
- 239000000178 monomer Substances 0.000 claims description 4
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 239000007791 liquid phase Substances 0.000 claims description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 2
- 230000000707 stereoselective effect Effects 0.000 claims description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 17
- 150000001875 compounds Chemical class 0.000 description 14
- -1 polypropylene Polymers 0.000 description 14
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 12
- 229920001577 copolymer Polymers 0.000 description 11
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 10
- 229910003074 TiCl4 Inorganic materials 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 9
- 239000007789 gas Substances 0.000 description 8
- 229910001629 magnesium chloride Inorganic materials 0.000 description 8
- 239000007787 solid Substances 0.000 description 7
- 239000011949 solid catalyst Substances 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 5
- 239000005977 Ethylene Substances 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 239000010936 titanium Substances 0.000 description 5
- UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N anhydrous n-heptane Natural products CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 150000003609 titanium compounds Chemical class 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 3
- 238000002083 X-ray spectrum Methods 0.000 description 3
- 238000013019 agitation Methods 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 3
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 125000005843 halogen group Chemical group 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 3
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidine Chemical compound CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 150000005840 aryl radicals Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000001273 butane Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 150000002680 magnesium Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 150000003377 silicon compounds Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229940099259 vaseline Drugs 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- LTMRRSWNXVJMBA-UHFFFAOYSA-L 2,2-diethylpropanedioate Chemical compound CCC(CC)(C([O-])=O)C([O-])=O LTMRRSWNXVJMBA-UHFFFAOYSA-L 0.000 description 1
- POWUJINVZSHIGY-UHFFFAOYSA-N 2,6-di(propan-2-yl)piperidine Chemical compound CC(C)C1CCCC(C(C)C)N1 POWUJINVZSHIGY-UHFFFAOYSA-N 0.000 description 1
- PVWCLOAAEFMTLH-UHFFFAOYSA-N 4,4-bis(methoxymethyl)-2,6-dimethylheptane Chemical compound COCC(COC)(CC(C)C)CC(C)C PVWCLOAAEFMTLH-UHFFFAOYSA-N 0.000 description 1
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- DKMROQRQHGEIOW-UHFFFAOYSA-N Diethyl succinate Chemical compound CCOC(=O)CCC(=O)OCC DKMROQRQHGEIOW-UHFFFAOYSA-N 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Chemical compound CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- XMYDKOZNENQEHO-UHFFFAOYSA-N [1-methoxy-2-(methoxymethyl)-3-methylbutan-2-yl]cyclopentane Chemical compound COCC(COC)(C(C)C)C1CCCC1 XMYDKOZNENQEHO-UHFFFAOYSA-N 0.000 description 1
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical group [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 159000000032 aromatic acids Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- UXXXZMDJQLPQPH-UHFFFAOYSA-N bis(2-methylpropyl) carbonate Chemical compound CC(C)COC(=O)OCC(C)C UXXXZMDJQLPQPH-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003426 co-catalyst Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 1
- DWNAQMUDCDVSLT-UHFFFAOYSA-N diphenyl phthalate Chemical compound C=1C=CC=C(C(=O)OC=2C=CC=CC=2)C=1C(=O)OC1=CC=CC=C1 DWNAQMUDCDVSLT-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- YCNSGSUGQPDYTK-UHFFFAOYSA-N ethyl phenyl carbonate Chemical compound CCOC(=O)OC1=CC=CC=C1 YCNSGSUGQPDYTK-UHFFFAOYSA-N 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical class ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
- C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
- Medicinal Preparation (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI92A000545 | 1992-03-10 | ||
| ITMI920545A IT1254244B (it) | 1992-03-10 | 1992-03-10 | Composizioni di copolimeri random del propene contenenti una alfa- olefina come comonomero |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2091299A1 CA2091299A1 (en) | 1993-09-11 |
| CA2091299C true CA2091299C (en) | 2001-06-12 |
Family
ID=11362346
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002091299A Expired - Fee Related CA2091299C (en) | 1992-03-10 | 1993-03-09 | Compositions of random copolymers of propene containing an .alpha.-olefin as comonomer |
Country Status (16)
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1269307B (it) * | 1994-03-09 | 1997-03-26 | Himont Inc | Film o lastre di polimeri olefinici |
| EP0679686B1 (en) * | 1994-04-28 | 1998-07-22 | Sumitomo Chemical Company Limited | Polypropylene composition for laminated and oriented film and laminated and oriented film thereof |
| CA2164461C (en) * | 1994-12-06 | 2000-08-08 | Tatsuya Tanizaki | Polypropylene composition and uses thereof |
| SG38896A1 (en) * | 1994-12-22 | 1997-04-17 | Sumitomo Chemical Co | Polypropylene composition and laminated and oriented film therefrom |
| US6106938A (en) * | 1994-12-22 | 2000-08-22 | Sumitomo Chemical Company, Ltd. | Polypropylene composition and laminated and oriented film therefrom |
| CN1076282C (zh) * | 1995-03-02 | 2001-12-19 | 三井化学株式会社 | 聚丙烯复合膜 |
| KR20040111719A (ko) * | 1996-05-06 | 2004-12-31 | 바셀 테크놀로지 캄파니 비이브이 | 조절된 박리 강도를 갖는 열-봉합성 필름용 폴리올레핀조성물 |
| ATE248892T1 (de) | 1998-08-20 | 2003-09-15 | Basell Poliolefine Spa | Kristalline propylene-copolymerzusammensetzungen mit heissversiegelungseigenschaften, optischen eigenschaften und reduzierter löslichkeit |
| AU778145B2 (en) * | 1999-12-16 | 2004-11-18 | Baselltech Usa Inc. | Compositions of random copolymers of propene containing an alpha-olefin as comonomer |
| DE10030879A1 (de) * | 2000-06-23 | 2002-01-03 | Wolff Walsrode Ag | Peelfähige, siegelbare polyolefinische Mehrschichtfolie und deren Verwendung als Verpackungsfolie |
| JP4655344B2 (ja) * | 2000-08-30 | 2011-03-23 | 住友化学株式会社 | プロピレン系共重合体とその製造方法およびそのプロピレン系共重合体からなるフィルム |
| DE60129939T2 (de) | 2001-06-27 | 2008-05-15 | Borealis Technology Oy | Verfahren zur Herstellung einer Polymerfolie die ein statistisches Propylencopolymer enthält |
| MY132768A (en) * | 2001-10-09 | 2007-10-31 | Basell Poliolefine Italia Spa | Crystalline propylene copolymer compositions having improved sealability and optical properties and reduced solubility. |
| JP2008524414A (ja) | 2004-12-21 | 2008-07-10 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | ヒートシール可能なポリオレフィンフィルム |
| JP2006350725A (ja) * | 2005-06-16 | 2006-12-28 | Alps Electric Co Ltd | カード装着装置 |
| CN101903083B (zh) * | 2007-12-18 | 2015-07-22 | 巴塞尔聚烯烃意大利有限责任公司 | 膜 |
| CN102666680B (zh) | 2009-09-24 | 2015-06-24 | 巴塞尔聚烯烃意大利有限责任公司 | 热封聚烯烃膜 |
| WO2011039314A1 (en) | 2009-09-29 | 2011-04-07 | Basell Poliolefine Italia Srl | Heat-sealable polyolefin films |
| WO2011061087A1 (en) | 2009-11-17 | 2011-05-26 | Basell Poliolefine Italia S.R.L. | Soft polyolefin compositions with improved processability |
| WO2011064131A1 (en) | 2009-11-24 | 2011-06-03 | Basell Poliolefine Italia S.R.L. | Polyolefin compositions having improved sealability |
| ES2385142T3 (es) * | 2010-04-21 | 2012-07-18 | Borealis Ag | Composición de copolímero o propileno/1-hexeno con ventana de sellado amplia |
| BR112012026909B1 (pt) * | 2010-04-21 | 2020-03-10 | Borealis Ag | Composição de copolímero propileno/1-hexeno com baixa temperatura de selamento, seu processo de preparação, película, e substrato revestido por extrusão |
| BR112013005308B1 (pt) | 2010-09-06 | 2020-02-04 | Basell Poliolefine Italia Srl | composições de poliolefina e filmes ou folhas mono ou multicamadas |
| EP2487203B2 (en) * | 2011-02-14 | 2020-11-25 | Borealis AG | Sealing propylene copolymer |
| ES2462004T3 (es) * | 2011-06-27 | 2014-05-22 | Borealis Ag | Película polímera multicapa orientada biaxialmente |
| EP2540497B1 (en) * | 2011-06-27 | 2014-08-06 | Borealis AG | Multi-layer cast film |
| EP2540496B1 (en) * | 2011-06-27 | 2014-04-23 | Borealis AG | Multi-layer blown film |
| ES2663345T3 (es) * | 2015-03-02 | 2018-04-12 | Borealis Ag | Composición de copolímeros aleatorios C2C3 con un equilibrio mejorado entre la temperatura de inicio del sellado y el punto de fusión |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1495776A (en) * | 1975-06-11 | 1977-12-21 | Ici Ltd | Film-forming olefin polymer compositions |
| US4211852A (en) * | 1977-09-26 | 1980-07-08 | Mitsui Petrochemical Industries Ltd. | Thermoplastic olefin resin composition and laminated film or sheet thereof |
| JPS56139520A (en) * | 1980-04-02 | 1981-10-31 | Mitsui Petrochem Ind Ltd | Preparation of block copolymer |
| JPS58162620A (ja) * | 1982-03-23 | 1983-09-27 | Mitsubishi Petrochem Co Ltd | オレフイン系ブロツク共重合体 |
| KR920000173B1 (ko) * | 1986-10-09 | 1992-01-09 | 미쓰이세끼유 가가꾸고오교오 가부시끼가이샤 | 저결정성 프로필렌계 랜덤 공중합체 조성물, 그 제조방법 및 폴리프로필렌 복합 적층체 |
| DE4004087A1 (de) * | 1990-02-10 | 1991-08-14 | Basf Ag | Copolymerisate des propylens |
-
1992
- 1992-03-10 IT ITMI920545A patent/IT1254244B/it active
-
1993
- 1993-03-09 RU RU93004809A patent/RU2104289C1/ru active
- 1993-03-09 CA CA002091299A patent/CA2091299C/en not_active Expired - Fee Related
- 1993-03-09 FI FI931040A patent/FI112245B/fi not_active IP Right Cessation
- 1993-03-09 BR BR9301113A patent/BR9301113A/pt not_active IP Right Cessation
- 1993-03-09 NO NO930863A patent/NO301771B1/no not_active IP Right Cessation
- 1993-03-10 DE DE69310961T patent/DE69310961T2/de not_active Expired - Lifetime
- 1993-03-10 MX MX9301317A patent/MX9301317A/es unknown
- 1993-03-10 EP EP93103846A patent/EP0560326B1/en not_active Expired - Lifetime
- 1993-03-10 ES ES93103846T patent/ES2103990T3/es not_active Expired - Lifetime
- 1993-03-10 AT AT93103846T patent/ATE153683T1/de not_active IP Right Cessation
- 1993-03-10 JP JP07611393A patent/JP3452601B2/ja not_active Expired - Fee Related
- 1993-03-10 KR KR1019930003573A patent/KR100253015B1/ko not_active Expired - Fee Related
- 1993-03-10 CN CN93104322A patent/CN1082979C/zh not_active Expired - Fee Related
- 1993-03-10 AU AU35138/93A patent/AU664598B2/en not_active Ceased
- 1993-05-14 TW TW082101774A patent/TW281681B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| EP0560326B1 (en) | 1997-05-28 |
| KR930019750A (ko) | 1993-10-18 |
| DE69310961T2 (de) | 1997-11-27 |
| MX9301317A (es) | 1993-09-01 |
| FI931040A0 (fi) | 1993-03-09 |
| ITMI920545A0 (it) | 1992-03-10 |
| AU3513893A (en) | 1993-09-16 |
| FI931040L (fi) | 1993-09-11 |
| ATE153683T1 (de) | 1997-06-15 |
| NO301771B1 (no) | 1997-12-08 |
| RU2104289C1 (ru) | 1998-02-10 |
| BR9301113A (pt) | 1993-09-14 |
| ES2103990T3 (es) | 1997-10-01 |
| ITMI920545A1 (it) | 1993-09-10 |
| CA2091299A1 (en) | 1993-09-11 |
| CN1076937A (zh) | 1993-10-06 |
| IT1254244B (it) | 1995-09-14 |
| KR100253015B1 (ko) | 2000-04-15 |
| FI112245B (fi) | 2003-11-14 |
| CN1082979C (zh) | 2002-04-17 |
| JPH0693146A (ja) | 1994-04-05 |
| EP0560326A1 (en) | 1993-09-15 |
| JP3452601B2 (ja) | 2003-09-29 |
| NO930863D0 (no) | 1993-03-09 |
| NO930863L (no) | 1993-09-13 |
| TW281681B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1996-07-21 |
| AU664598B2 (en) | 1995-11-23 |
| DE69310961D1 (de) | 1997-07-03 |
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| EEER | Examination request | ||
| MKLA | Lapsed |