CA2010248A1 - Recuperation d'un catalyseur complexe a base de cyanure metallique double dans un polymere - Google Patents

Recuperation d'un catalyseur complexe a base de cyanure metallique double dans un polymere

Info

Publication number
CA2010248A1
CA2010248A1 CA2010248A CA2010248A CA2010248A1 CA 2010248 A1 CA2010248 A1 CA 2010248A1 CA 2010248 A CA2010248 A CA 2010248A CA 2010248 A CA2010248 A CA 2010248A CA 2010248 A1 CA2010248 A1 CA 2010248A1
Authority
CA
Canada
Prior art keywords
polymer
catalyst
metal cyanide
double metal
cyanide complex
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2010248A
Other languages
English (en)
Other versions
CA2010248C (fr
Inventor
Jonathan L. Schuchardt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lyondell Chemical Technology LP
Original Assignee
Arco Chemical Technology LP
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arco Chemical Technology LP filed Critical Arco Chemical Technology LP
Publication of CA2010248A1 publication Critical patent/CA2010248A1/fr
Application granted granted Critical
Publication of CA2010248C publication Critical patent/CA2010248C/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/68—Liquid treating or treating in liquid phase, e.g. dissolved or suspended including substantial dissolution or chemical precipitation of a catalyst component in the ultimate reconstitution of the catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/28—Regeneration or reactivation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2663—Metal cyanide catalysts, i.e. DMC's
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/30—Post-polymerisation treatment, e.g. recovery, purification, drying
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Toxicology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Polyethers (AREA)
CA002010248A 1989-02-27 1990-02-16 Recuperation d'un catalyseur complexe a base de cyanure metallique double dans un polymere Expired - Fee Related CA2010248C (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/315,662 US5010047A (en) 1989-02-27 1989-02-27 Recovery of double metal cyanide complex catalyst from a polymer
US07/315,662 1989-02-27

Publications (2)

Publication Number Publication Date
CA2010248A1 true CA2010248A1 (fr) 1990-08-27
CA2010248C CA2010248C (fr) 2000-04-18

Family

ID=23225495

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002010248A Expired - Fee Related CA2010248C (fr) 1989-02-27 1990-02-16 Recuperation d'un catalyseur complexe a base de cyanure metallique double dans un polymere

Country Status (10)

Country Link
US (1) US5010047A (fr)
EP (1) EP0385619B1 (fr)
JP (1) JP2969275B2 (fr)
KR (1) KR0147818B1 (fr)
AU (1) AU631188B2 (fr)
BR (1) BR9000872A (fr)
CA (1) CA2010248C (fr)
DE (1) DE69030776T2 (fr)
MX (1) MX168836B (fr)
SG (1) SG46691A1 (fr)

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US5712216A (en) * 1995-05-15 1998-01-27 Arco Chemical Technology, L.P. Highly active double metal cyanide complex catalysts
US5470813A (en) * 1993-11-23 1995-11-28 Arco Chemical Technology, L.P. Double metal cyanide complex catalysts
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US5426081A (en) * 1993-12-23 1995-06-20 Arco Chemical Technology, L.P. Polyurethane foam-supported double metal cyanide catalysts for polyol synthesis
CA2138063C (fr) * 1993-12-23 2007-02-20 Bi Le-Khac Catalyseurs a base de cyanure de metal double sur support de mousse de polyurethane pour la synthese des polyols
US5416241A (en) * 1994-01-27 1995-05-16 Arco Chemical Technology, L.P. Method for purifying polyether polyols made with double metal cyanide catalysts
US5482908A (en) * 1994-09-08 1996-01-09 Arco Chemical Technology, L.P. Highly active double metal cyanide catalysts
US5811829A (en) * 1995-08-10 1998-09-22 Arco Chemical Technology, L.P. Viscosity stable isocyanate-terminated prepolymers and polyoxyalkylene polyether polyols having improved storage stability
US5688861A (en) * 1995-11-30 1997-11-18 Arco Chemical Technology, L.P. Process for the preparation of polyol polymer dispersions
US5767323A (en) * 1995-12-22 1998-06-16 Arco Chemical Technology, L.P. Process for preparing polyoxyalkylene polyether polyols having low levels of transition metals through double metal cyanide complex polyoxyalkylation
US5900384A (en) * 1996-07-18 1999-05-04 Arco Chemical Technology L.P. Double metal cyanide catalysts
DE19730467A1 (de) * 1997-07-16 1999-01-21 Bayer Ag Neue Zink/Metall-Hexacyanocobaltat-Katalysatoren für die Herstellung von Polyetherpolyolen
DE19903274A1 (de) 1999-01-28 2000-08-03 Basf Ag Verfahren zur Herstellung von Polyetherpolyolen
US6800583B2 (en) 1999-06-02 2004-10-05 Basf Aktiengesellschaft Suspension of multimetal cyanide compounds, their preparation and their use
US6613714B2 (en) 1999-06-02 2003-09-02 Basf Aktiengesellschaft Multimetal cyanide compounds, their preparation and their use
CO5160375A1 (es) * 1999-07-09 2002-05-30 Dow Chemical Co Metodo para fraccionar poli(oxido de etileno) formado usando un catalizador de cianuro metalico
AU2001255735A1 (en) 2000-04-28 2001-11-12 Synuthane International, Inc. Double metal cyanide catalysts containing polyglycol ether complexing agents
EP1370600B1 (fr) * 2000-11-22 2004-10-13 Basf Aktiengesellschaft Procede de traitement d'alcools de polyether
ES2199666B1 (es) * 2002-02-25 2005-06-01 Repsol Quimica, S.A. Procedimiento de produccion de polioleteres.
US6806348B2 (en) 2003-02-11 2004-10-19 Basf Corporation Process for removing and regenerating a double metal cyanide (DMC) catalyst from a polymer polyol
EP1493769B1 (fr) * 2003-06-30 2007-11-21 Repsol Quimica S.A. Procédé pour épuration des polyetherpolyoles
DE102007045230A1 (de) * 2007-09-21 2009-04-09 Clariant International Limited Polycarboxylatether als Dispergiermittel für anorganische Pigmentformulierungen
CN101925631B (zh) 2008-01-25 2013-01-16 株式会社钟化 聚环氧烷烃的制造方法
CN102164987B (zh) 2008-08-22 2015-07-08 诺沃梅尔公司 用于合成聚合物的催化剂和方法
WO2012005897A1 (fr) 2010-06-29 2012-01-12 Dow Global Technologies Llc Tensioactifs de type alkoxylate d'alcools secondaires ramifiés et leur procédé de fabrication
CN103270012A (zh) 2010-11-23 2013-08-28 陶氏环球技术有限责任公司 支链仲醇烷氧基化物表面活性剂及制备它们的方法
ES2525022T3 (es) 2010-12-20 2014-12-16 Bayer Intellectual Property Gmbh Procedimiento para la preparación de polioléteres
KR20140007822A (ko) 2010-12-20 2014-01-20 바이엘 인텔렉쳐 프로퍼티 게엠베하 폴리에테르 에스테르 폴리올의 제조 방법
ES2537891T3 (es) 2011-06-30 2015-06-15 Bayer Intellectual Property Gmbh Procedimiento para la preparación de polieterpolioles de peso molecular alto
CN108570140A (zh) 2011-12-20 2018-09-25 阿德希西斯医疗有限公司 用于生物可降解组织粘合剂的异氰酸酯官能的预聚物
SG10201604976RA (en) 2011-12-20 2016-08-30 Bayer Ip Gmbh Hydroxy-aminopolymers and method for producing same
ES2560031T3 (es) 2011-12-20 2016-02-17 Medical Adhesive Revolution Gmbh Polímero de hidroxi-amino y su uso en adhesivos para tejido de poliurea-poliuretano
CN104169327A (zh) * 2012-04-18 2014-11-26 旭硝子株式会社 聚醚类的制造方法
EP2671893A1 (fr) 2012-06-06 2013-12-11 Bayer MaterialScience AG Procédé de fabrication d'oméga-hydroxy-aminopolymères
EP2876121A1 (fr) 2013-11-22 2015-05-27 Bayer MaterialScience AG Utilisation d'alcools d'uréthane pour la fabrication de polyétherpolyols
EP2886572A1 (fr) 2013-12-17 2015-06-24 Bayer MaterialScience AG Utilisation d'alcools d'uréthane pour la fabrication de polyéthercarbonatepolyols
CN106414532B (zh) 2014-04-07 2019-11-01 科思创德国股份有限公司 制造聚甲醛嵌段共聚物的方法
US9527958B2 (en) * 2014-05-02 2016-12-27 Covestro Llc Process for purification of polyether carbonate polyols
US20160244549A1 (en) 2015-02-25 2016-08-25 Bayer Materialscience Llc Alkoxysilane-group modified polyurethanes and low modulus sealants formed therefrom
EP3098252A1 (fr) 2015-05-26 2016-11-30 Covestro Deutschland AG Utilisation d'alcools, comprenant au moins deux groupes uréthane, destinés à la production de polyols de carbonate de polyéther
EP3098251A1 (fr) 2015-05-26 2016-11-30 Covestro Deutschland AG Utilisation d'alcools, comprenant au moins deux groupes uréthane, destinés à la production de polyols de polyéther
CN107922607B (zh) 2015-08-26 2020-05-19 科思创德国股份有限公司 制备高分子量聚氧化烯多元醇的方法
KR20190008212A (ko) 2016-05-13 2019-01-23 코베스트로 도이칠란트 아게 폴리옥시알킬렌 폴리올의 제조 방법
KR101869707B1 (ko) 2017-01-20 2018-06-21 제룡산업 주식회사 활선작업용 검전기능을 갖는 단말캡
US20190119444A1 (en) 2017-10-25 2019-04-25 Covestro Llc Process to remove dmc catalysts from polyether carbonate polyols
EP3533815A1 (fr) 2018-02-28 2019-09-04 Covestro Deutschland AG Mousses souples de polyuréthane à base de copolymères blocs de polyoxyalkylène-polyoxymethylène
EP3567067A1 (fr) 2018-05-08 2019-11-13 Covestro Deutschland AG Séparation d'un catalyseur à cyanure de métal double
KR20210020916A (ko) 2018-06-19 2021-02-24 헨켈 아게 운트 코. 카게아아 고 활성 이중 금속 시아나이드 화합물
EP3656797A1 (fr) 2018-11-22 2020-05-27 Covestro Deutschland AG Procédé de production de copolymères séquencés de polyalkylène-oxyde-polyoxyméthylène
BR112021015225A2 (pt) 2019-02-19 2021-09-28 Dow Global Technologies Llc Composição de aditivo de reservatório de óleo com arenito, e, método de recuperação melhorada de óleo de um reservatório com arenito
WO2020173568A1 (fr) 2019-02-28 2020-09-03 Covestro Intellectual Property Gmbh & Co. Kg Prépolymères à terminaison isocyanate destinés à la production de mousses intégrées de polyuréthane
EP3747927A1 (fr) 2019-06-05 2020-12-09 Covestro Deutschland AG Procédé de fabrication continue de polyols polyoxyalkylènes
KR102624002B1 (ko) 2019-09-30 2024-01-12 주식회사 엘지화학 폴리알킬렌 카보네이트 중합 용액으로부터 유기 아연 촉매를 분리하는 방법
EP3960783A1 (fr) 2020-09-01 2022-03-02 Covestro Deutschland AG Prépolymères à terminaison isocyanate à base de copolymères séquencés polyoxyméthylène-polyoxyalkylène, leur procédé de fabrication et leur utilisation

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Also Published As

Publication number Publication date
EP0385619A3 (fr) 1991-09-11
BR9000872A (pt) 1991-02-13
EP0385619B1 (fr) 1997-05-28
KR0147818B1 (ko) 1998-08-17
JP2969275B2 (ja) 1999-11-02
MX168836B (es) 1993-06-10
DE69030776D1 (de) 1997-07-03
CA2010248C (fr) 2000-04-18
DE69030776T2 (de) 1997-09-11
SG46691A1 (en) 1998-02-20
JPH02265903A (ja) 1990-10-30
AU5051490A (en) 1990-08-30
EP0385619A2 (fr) 1990-09-05
KR900012681A (ko) 1990-09-01
US5010047A (en) 1991-04-23
AU631188B2 (en) 1992-11-19

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Effective date: 20070216