CA1329782C - Process for purifying crude glycerol - Google Patents
Process for purifying crude glycerolInfo
- Publication number
- CA1329782C CA1329782C CA 607783 CA607783A CA1329782C CA 1329782 C CA1329782 C CA 1329782C CA 607783 CA607783 CA 607783 CA 607783 A CA607783 A CA 607783A CA 1329782 C CA1329782 C CA 1329782C
- Authority
- CA
- Canada
- Prior art keywords
- process according
- crude glycerol
- filter material
- crude
- microfiltration
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title claims abstract 16
- 239000000463 material Substances 0.000 claims abstract 9
- 238000001471 micro-filtration Methods 0.000 claims abstract 5
- 239000000919 ceramic Substances 0.000 claims abstract 3
- 238000000108 ultra-filtration Methods 0.000 claims abstract 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract 2
- 238000004821 distillation Methods 0.000 claims abstract 2
- 239000003456 ion exchange resin Substances 0.000 claims abstract 2
- 229920003303 ion-exchange polymer Polymers 0.000 claims abstract 2
- 239000011148 porous material Substances 0.000 claims description 4
- 239000007858 starting material Substances 0.000 claims 3
- 239000007864 aqueous solution Substances 0.000 claims 2
- 229910010293 ceramic material Inorganic materials 0.000 claims 1
- 239000003925 fat Substances 0.000 claims 1
- 238000001914 filtration Methods 0.000 claims 1
- 230000007062 hydrolysis Effects 0.000 claims 1
- 238000006460 hydrolysis reaction Methods 0.000 claims 1
- 238000006140 methanolysis reaction Methods 0.000 claims 1
- 239000003921 oil Substances 0.000 claims 1
- 238000000746 purification Methods 0.000 claims 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract description 4
- -1 splitters crude Chemical compound 0.000 abstract 1
- 150000002500 ions Chemical class 0.000 description 18
- HSRJKNPTNIJEKV-UHFFFAOYSA-N Guaifenesin Chemical compound COC1=CC=CC=C1OCC(O)CO HSRJKNPTNIJEKV-UHFFFAOYSA-N 0.000 description 8
- 101100536354 Drosophila melanogaster tant gene Proteins 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- DNXHEGUUPJUMQT-UHFFFAOYSA-N (+)-estrone Natural products OC1=CC=C2C3CCC(C)(C(CC4)=O)C4C3CCC2=C1 DNXHEGUUPJUMQT-UHFFFAOYSA-N 0.000 description 1
- BHMLFPOTZYRDKA-IRXDYDNUSA-N (2s)-2-[(s)-(2-iodophenoxy)-phenylmethyl]morpholine Chemical compound IC1=CC=CC=C1O[C@@H](C=1C=CC=CC=1)[C@H]1OCCNC1 BHMLFPOTZYRDKA-IRXDYDNUSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 240000006409 Acacia auriculiformis Species 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- 101100349268 Caenorhabditis elegans ntr-2 gene Proteins 0.000 description 1
- 101100087530 Caenorhabditis elegans rom-1 gene Proteins 0.000 description 1
- 101100501444 Escherichia phage P1 17 gene Proteins 0.000 description 1
- 241001633628 Lycoris Species 0.000 description 1
- 101100305983 Mus musculus Rom1 gene Proteins 0.000 description 1
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 1
- 241001387976 Pera Species 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 241000534944 Thia Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 210000004379 membrane Anatomy 0.000 description 1
- GLVAUDGFNGKCSF-UHFFFAOYSA-N mercaptopurine Chemical compound S=C1NC=NC2=C1NC=N2 GLVAUDGFNGKCSF-UHFFFAOYSA-N 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/18—Polyhydroxylic acyclic alcohols
- C07C31/22—Trihydroxylic alcohols, e.g. glycerol
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/18—Polyhydroxylic acyclic alcohols
- C07C31/22—Trihydroxylic alcohols, e.g. glycerol
- C07C31/225—Glycerol
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Cosmetics (AREA)
- Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP88201702 | 1988-08-09 | ||
| EP88201702.3 | 1988-08-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1329782C true CA1329782C (en) | 1994-05-24 |
Family
ID=8199834
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA 607783 Expired - Fee Related CA1329782C (en) | 1988-08-09 | 1989-08-08 | Process for purifying crude glycerol |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US4990695A (OSRAM) |
| EP (1) | EP0358255B1 (OSRAM) |
| JP (1) | JPH068259B2 (OSRAM) |
| KR (1) | KR920003099B1 (OSRAM) |
| AU (1) | AU617506B2 (OSRAM) |
| BR (1) | BR8904007A (OSRAM) |
| CA (1) | CA1329782C (OSRAM) |
| DE (1) | DE68911239T2 (OSRAM) |
| ES (1) | ES2047106T3 (OSRAM) |
| IN (1) | IN170612B (OSRAM) |
| MY (1) | MY105093A (OSRAM) |
| ZA (1) | ZA896078B (OSRAM) |
Families Citing this family (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04132796A (ja) * | 1990-09-26 | 1992-05-07 | Mitsubishi Kakoki Kaisha Ltd | 植物油の製造方法 |
| DE4203157A1 (de) * | 1992-02-05 | 1993-08-12 | Henkel Kgaa | Verfahren zum reinigen von glycerinwasser |
| DE4220639A1 (de) * | 1992-06-24 | 1994-01-05 | Henkel Kgaa | Verfahren zur chemischen Reinigung natürlicher Öle und Fette |
| US5501741A (en) * | 1994-01-11 | 1996-03-26 | Uss-Posco | Process for purifying aqueous rinse solutions used in metal forming operations |
| RU2133730C1 (ru) * | 1996-07-22 | 1999-07-27 | Товарищество с ограниченной ответственностью "Биокосметическая фабрика" | Способ обработки глицерина |
| DE19938874B4 (de) * | 1999-08-17 | 2005-11-17 | Peter Greven Fettchemie Gmbh & Co. Kg | Verfahren zum Entfernen von kurzkettigen Fettsäuren aus einer wäßrigen Glycerinlösung |
| ATE511498T1 (de) * | 2003-11-20 | 2011-06-15 | Solvay | Verfahren zur herstellung von dichlorpropanol aus glycerin und einem chlorinierungsmittel in anwesenheit von einem katalysator ausgewählt aus adipin- und glutarsaeure |
| KR20080036555A (ko) | 2005-05-20 | 2008-04-28 | 솔베이(소시에떼아노님) | 클로로히드린으로부터 출발하여 에폭시드를 제조하는 방법 |
| TWI323249B (en) * | 2005-05-20 | 2010-04-11 | Solvay | Continuous process for preparing chlorohydrins |
| KR101434680B1 (ko) | 2005-11-08 | 2014-08-26 | 솔베이(소시에떼아노님) | 글리세롤의 염소화에 의한 디클로로프로판올의 제조 방법 |
| GB2437516A (en) * | 2006-04-26 | 2007-10-31 | Bai Leng | Method and apparatus for purifying glycerine using filter membranes and a deionisation means |
| KR100979372B1 (ko) | 2006-06-14 | 2010-08-31 | 솔베이(소시에떼아노님) | 조 글리세롤계 생성물, 그 정제방법 및 디클로로프로판올의제조에의 그 용도 |
| US20100032617A1 (en) * | 2007-02-20 | 2010-02-11 | Solvay (Societe Anonyme) | Process for manufacturing epichlorohydrin |
| FR2913421B1 (fr) * | 2007-03-07 | 2009-05-15 | Solvay | Procede de fabrication de dichloropropanol. |
| AU2008223787B2 (en) * | 2007-03-08 | 2013-09-26 | Adcuram Nutrition Holding Gmbh | Process for the preparation of citric acid employing filamentous fungi in a culture medium comprising glycerol |
| FR2913684B1 (fr) | 2007-03-14 | 2012-09-14 | Solvay | Procede de fabrication de dichloropropanol |
| JP4805201B2 (ja) * | 2007-03-22 | 2011-11-02 | 月島環境エンジニアリング株式会社 | 膜分離を用いた目的物質の分離方法と装置 |
| BRPI0704952A2 (pt) * | 2007-04-04 | 2008-11-18 | Rohm & Haas | mÉtodo para a purificaÇço de glicerol |
| TW200911740A (en) | 2007-06-01 | 2009-03-16 | Solvay | Process for manufacturing a chlorohydrin |
| TWI500609B (zh) | 2007-06-12 | 2015-09-21 | Solvay | 含有環氧氯丙烷的產品，其製備及其不同應用中的用途 |
| TW200911693A (en) * | 2007-06-12 | 2009-03-16 | Solvay | Aqueous composition containing a salt, manufacturing process and use |
| WO2008156612A1 (en) * | 2007-06-15 | 2008-12-24 | Cargill, Incorporated | Process for the purification of crude glycerol compositions |
| EP2207617A1 (en) | 2007-10-02 | 2010-07-21 | SOLVAY (Société Anonyme) | Use of compositions containing silicon for improving the corrosion resistance of vessels |
| FR2925045B1 (fr) | 2007-12-17 | 2012-02-24 | Solvay | Produit a base de glycerol, procede pour son obtention et son utilisation dans la fabrication de dichloropropanol |
| DE102007062409A1 (de) | 2007-12-20 | 2009-06-25 | New Environmental Technology Gmbh | Verfahren zur Reinigung von Rohglyzerin |
| TWI478875B (zh) | 2008-01-31 | 2015-04-01 | Solvay | 使水性組成物中之有機物質降解之方法 |
| JP5619721B2 (ja) | 2008-04-03 | 2014-11-05 | ソルヴェイ（ソシエテ アノニム） | グリセロールを含む組成物、それを得る方法およびジクロロプロパノールの製造でのその使用 |
| GB2459738B (en) * | 2008-05-07 | 2013-03-06 | Bai Leng | Method of purification |
| KR100877384B1 (ko) * | 2008-06-30 | 2009-01-07 | 바이오원 (주) | 필터링 기술을 이용한 조 글리세린의 정제방법 |
| FR2935968B1 (fr) * | 2008-09-12 | 2010-09-10 | Solvay | Procede pour la purification de chlorure d'hydrogene |
| FR2939434B1 (fr) * | 2008-12-08 | 2012-05-18 | Solvay | Procede de traitement de glycerol. |
| DE102008060888A1 (de) * | 2008-12-09 | 2010-06-10 | Evonik Stockhausen Gmbh | Verfahren zur Herstellung von Acrolein umfassend die Aufarbeitung einer Rohglycerin-Phase |
| CN101445425B (zh) * | 2008-12-22 | 2012-01-04 | 湖南尔康制药股份有限公司 | 一种注射用甘油的制备方法 |
| US20110004031A1 (en) * | 2009-05-06 | 2011-01-06 | S.I.I., Llc | Glycerin purification |
| EP2295394A1 (en) | 2009-09-11 | 2011-03-16 | Rhodia Poliamida E Especialidades Ltda | Process for the purification of crude glycerol |
| FR2964657B1 (fr) | 2010-09-15 | 2013-01-18 | Rhodia Operations | Procede de purification du glycerol brut |
| US9309209B2 (en) | 2010-09-30 | 2016-04-12 | Solvay Sa | Derivative of epichlorohydrin of natural origin |
| CN102229521B (zh) * | 2011-05-14 | 2013-11-06 | 江门市鸿捷精细化工有限公司 | 一种粗甘油精制及副产物回收工艺 |
| CN102408309B (zh) * | 2011-09-19 | 2013-09-11 | 鲁东大学 | 一种甘油废液的纯化方法 |
| JP6385199B2 (ja) * | 2014-08-22 | 2018-09-05 | 花王株式会社 | 軽油添加剤 |
| WO2017119007A1 (en) | 2016-01-07 | 2017-07-13 | Institute Of Chemical Technology | Process for purification and refining of glycerol |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB190424100A (en) * | 1904-11-08 | 1904-12-22 | William Emil Garrigues | Improvements in or relating to Process for the Recovery of Glycerine from Spent Soap Lye, and Apparatus therefor. |
| EP0080684B1 (en) * | 1981-11-30 | 1985-08-28 | Asahi Kasei Kogyo Kabushiki Kaisha | Membrane filtration using ultrafiltration membrane |
| JPS58126827A (ja) * | 1982-01-25 | 1983-07-28 | Nippon Oil & Fats Co Ltd | 高純度グリセリンの製造法 |
-
1989
- 1989-08-08 CA CA 607783 patent/CA1329782C/en not_active Expired - Fee Related
- 1989-08-09 DE DE89202064T patent/DE68911239T2/de not_active Expired - Fee Related
- 1989-08-09 BR BR8904007A patent/BR8904007A/pt not_active IP Right Cessation
- 1989-08-09 KR KR1019890011329A patent/KR920003099B1/ko not_active Expired
- 1989-08-09 ES ES89202064T patent/ES2047106T3/es not_active Expired - Lifetime
- 1989-08-09 ZA ZA896078A patent/ZA896078B/xx unknown
- 1989-08-09 JP JP20660089A patent/JPH068259B2/ja not_active Expired - Lifetime
- 1989-08-09 AU AU39436/89A patent/AU617506B2/en not_active Ceased
- 1989-08-09 US US07/391,280 patent/US4990695A/en not_active Expired - Fee Related
- 1989-08-09 IN IN222/BOM/89A patent/IN170612B/en unknown
- 1989-08-09 MY MYPI89001084A patent/MY105093A/en unknown
- 1989-08-09 EP EP89202064A patent/EP0358255B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0358255B1 (en) | 1993-12-08 |
| BR8904007A (pt) | 1990-03-20 |
| DE68911239T2 (de) | 1994-04-14 |
| KR900003092A (ko) | 1990-03-23 |
| JPH02101031A (ja) | 1990-04-12 |
| MY105093A (en) | 1994-08-30 |
| ES2047106T3 (es) | 1994-02-16 |
| EP0358255A1 (en) | 1990-03-14 |
| JPH068259B2 (ja) | 1994-02-02 |
| KR920003099B1 (ko) | 1992-04-18 |
| IN170612B (OSRAM) | 1992-04-18 |
| US4990695A (en) | 1991-02-05 |
| AU3943689A (en) | 1990-03-15 |
| DE68911239D1 (de) | 1994-01-20 |
| ZA896078B (en) | 1991-04-24 |
| AU617506B2 (en) | 1991-11-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKLA | Lapsed |