CA1288536C - Adhesive blends and composite structures - Google Patents
Adhesive blends and composite structuresInfo
- Publication number
- CA1288536C CA1288536C CA000541031A CA541031A CA1288536C CA 1288536 C CA1288536 C CA 1288536C CA 000541031 A CA000541031 A CA 000541031A CA 541031 A CA541031 A CA 541031A CA 1288536 C CA1288536 C CA 1288536C
- Authority
- CA
- Canada
- Prior art keywords
- blend
- copolymer
- anhydride
- propylene
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 108
- 239000000853 adhesive Substances 0.000 title claims abstract description 33
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 33
- 239000002131 composite material Substances 0.000 title claims abstract description 33
- 229920001577 copolymer Polymers 0.000 claims abstract description 62
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 43
- 229920001155 polypropylene Polymers 0.000 claims abstract description 42
- -1 polypropylene Polymers 0.000 claims abstract description 37
- 239000005977 Ethylene Substances 0.000 claims abstract description 34
- 239000000463 material Substances 0.000 claims abstract description 31
- 238000000034 method Methods 0.000 claims abstract description 30
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 26
- 230000004888 barrier function Effects 0.000 claims abstract description 20
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 19
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims abstract description 11
- 229920001198 elastomeric copolymer Polymers 0.000 claims abstract description 10
- 238000009826 distribution Methods 0.000 claims abstract description 7
- 229920001519 homopolymer Polymers 0.000 claims description 26
- 239000000758 substrate Substances 0.000 claims description 14
- 229920001384 propylene homopolymer Polymers 0.000 claims description 11
- 239000000178 monomer Substances 0.000 claims description 10
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical group O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 9
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 8
- 230000005484 gravity Effects 0.000 claims description 8
- 239000000155 melt Substances 0.000 claims description 8
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 8
- KNDQHSIWLOJIGP-UMRXKNAASA-N (3ar,4s,7r,7as)-rel-3a,4,7,7a-tetrahydro-4,7-methanoisobenzofuran-1,3-dione Chemical compound O=C1OC(=O)[C@@H]2[C@H]1[C@]1([H])C=C[C@@]2([H])C1 KNDQHSIWLOJIGP-UMRXKNAASA-N 0.000 claims description 7
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 claims description 7
- 239000004715 ethylene vinyl alcohol Substances 0.000 claims description 7
- 229920000642 polymer Polymers 0.000 claims description 7
- 150000008064 anhydrides Chemical class 0.000 claims description 6
- RZXDTJIXPSCHCI-UHFFFAOYSA-N hexa-1,5-diene-2,5-diol Chemical compound OC(=C)CCC(O)=C RZXDTJIXPSCHCI-UHFFFAOYSA-N 0.000 claims description 6
- 229920000578 graft copolymer Polymers 0.000 claims description 5
- 229920001897 terpolymer Polymers 0.000 claims description 5
- LTVUCOSIZFEASK-MPXCPUAZSA-N (3ar,4s,7r,7as)-3a-methyl-3a,4,7,7a-tetrahydro-4,7-methano-2-benzofuran-1,3-dione Chemical compound C([C@H]1C=C2)[C@H]2[C@H]2[C@]1(C)C(=O)OC2=O LTVUCOSIZFEASK-MPXCPUAZSA-N 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 4
- 150000008065 acid anhydrides Chemical class 0.000 claims description 4
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 claims description 4
- 229940018557 citraconic acid Drugs 0.000 claims description 4
- 239000013536 elastomeric material Substances 0.000 claims description 4
- 239000001530 fumaric acid Substances 0.000 claims description 4
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 4
- 239000011976 maleic acid Substances 0.000 claims description 4
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 claims description 4
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 4
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 claims description 4
- SDQGRJKYBWFIDP-UHFFFAOYSA-N 3-but-2-enyl-4-methyloxolane-2,5-dione Chemical compound CC=CCC1C(C)C(=O)OC1=O SDQGRJKYBWFIDP-UHFFFAOYSA-N 0.000 claims description 3
- 239000004677 Nylon Substances 0.000 claims description 3
- 229920001778 nylon Polymers 0.000 claims description 3
- 238000000071 blow moulding Methods 0.000 claims description 2
- 238000003475 lamination Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- DKWZAJKBAUFZCH-UHFFFAOYSA-N 2-oxaspiro[4.4]non-7-ene-1,3-dione Chemical compound O=C1OC(=O)CC11CC=CC1 DKWZAJKBAUFZCH-UHFFFAOYSA-N 0.000 claims 3
- OEMSKMUAMXLNKL-UHFFFAOYSA-N 5-methyl-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C(C)=CCC2C(=O)OC(=O)C12 OEMSKMUAMXLNKL-UHFFFAOYSA-N 0.000 claims 3
- KNDQHSIWLOJIGP-UHFFFAOYSA-N 826-62-0 Chemical compound C1C2C3C(=O)OC(=O)C3C1C=C2 KNDQHSIWLOJIGP-UHFFFAOYSA-N 0.000 claims 3
- FEPCMSPFPMPWJK-OLPJDRRASA-N maleopimaric acid Chemical compound C([C@]12C=C([C@H](C[C@@H]11)[C@H]3C(OC(=O)[C@@H]23)=O)C(C)C)C[C@@H]2[C@]1(C)CCC[C@@]2(C)C(O)=O FEPCMSPFPMPWJK-OLPJDRRASA-N 0.000 claims 3
- 229920005606 polypropylene copolymer Polymers 0.000 claims 2
- 238000001125 extrusion Methods 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- 239000004743 Polypropylene Substances 0.000 abstract description 29
- 229940095050 propylene Drugs 0.000 abstract description 17
- 229920001684 low density polyethylene Polymers 0.000 abstract description 9
- 239000004702 low-density polyethylene Substances 0.000 abstract description 9
- 229920001971 elastomer Polymers 0.000 abstract description 6
- 239000000806 elastomer Substances 0.000 abstract description 5
- 238000002474 experimental method Methods 0.000 description 23
- 229940093470 ethylene Drugs 0.000 description 15
- 239000007789 gas Substances 0.000 description 9
- 239000004698 Polyethylene Substances 0.000 description 8
- 229920000573 polyethylene Polymers 0.000 description 8
- 229920001038 ethylene copolymer Polymers 0.000 description 5
- 230000008030 elimination Effects 0.000 description 4
- 238000003379 elimination reaction Methods 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- 229910018663 Mn O Inorganic materials 0.000 description 2
- 108091036732 NRON Proteins 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 229920000092 linear low density polyethylene Polymers 0.000 description 2
- 239000004707 linear low-density polyethylene Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 229920000136 polysorbate Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229920005604 random copolymer Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- KMOUUZVZFBCRAM-UHFFFAOYSA-N 1,2,3,6-tetrahydrophthalic anhydride Chemical compound C1C=CCC2C(=O)OC(=O)C21 KMOUUZVZFBCRAM-UHFFFAOYSA-N 0.000 description 1
- KAVDAMFOTJIBCK-XSHPSBQMSA-N 5-[(e)-2-bromoethenyl]-1-[(1s,3r,4s)-3-hydroxy-4-(hydroxymethyl)cyclopentyl]pyrimidine-2,4-dione Chemical compound C1[C@@H](O)[C@H](CO)C[C@@H]1N1C(=O)NC(=O)C(\C=C\Br)=C1 KAVDAMFOTJIBCK-XSHPSBQMSA-N 0.000 description 1
- 206010059837 Adhesion Diseases 0.000 description 1
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
- 101100130497 Drosophila melanogaster Mical gene Proteins 0.000 description 1
- 101100345589 Mus musculus Mical1 gene Proteins 0.000 description 1
- 241001296096 Probles Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 101150050541 denD gene Proteins 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000005003 food packaging material Substances 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- IICQZTQZQSBHBY-UHFFFAOYSA-N non-2-ene Chemical compound CCCCCCC=CC IICQZTQZQSBHBY-UHFFFAOYSA-N 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/10—Homopolymers or copolymers of propene
- C09J123/14—Copolymers of propene
- C09J123/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/24—Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US89093686A | 1986-07-28 | 1986-07-28 | |
| US890,936 | 1986-07-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1288536C true CA1288536C (en) | 1991-09-03 |
Family
ID=25397361
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000541031A Expired - Lifetime CA1288536C (en) | 1986-07-28 | 1987-06-30 | Adhesive blends and composite structures |
Country Status (4)
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4842947A (en) * | 1986-07-28 | 1989-06-27 | Quantum Chemical Corporation | Adhesive blends and composite structures |
| GB8618587D0 (en) * | 1986-07-30 | 1986-09-10 | Bp Chem Int Ltd | Adhesive blends |
| JPH03115483A (ja) * | 1989-09-29 | 1991-05-16 | Ube Ind Ltd | ホットメルト接着剤組成物 |
| JP5316300B2 (ja) | 2009-08-07 | 2013-10-16 | 信越化学工業株式会社 | 耐摩耗性シリコーンコーティング組成物並びに被覆物品及びその製造方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3483276A (en) * | 1964-12-04 | 1969-12-09 | Hercules Inc | Blends of modified and unmodified polypropylene |
| JPS5936586B2 (ja) * | 1976-04-09 | 1984-09-04 | 三井化学株式会社 | 多層積層構造物 |
| US4076670A (en) * | 1977-01-27 | 1978-02-28 | Eastman Kodak Company | Hot-melt adhesives having improved properties at elevated temperatures |
| JPS5814459B2 (ja) * | 1977-12-28 | 1983-03-19 | 住友化学工業株式会社 | 接着性樹脂組成物 |
| CA1150882A (en) * | 1980-08-15 | 1983-07-26 | Seymour Schmukler | Adhesive blends and composite structures |
| JPS59206446A (ja) * | 1983-04-04 | 1984-11-22 | Idemitsu Petrochem Co Ltd | プロピレン樹脂組成物 |
| JPS608347A (ja) * | 1983-06-28 | 1985-01-17 | Chisso Corp | 接着性ポリプロピレン組成物 |
-
1987
- 1987-06-30 CA CA000541031A patent/CA1288536C/en not_active Expired - Lifetime
- 1987-07-27 JP JP62185651A patent/JPH0660300B2/ja not_active Expired - Lifetime
- 1987-07-28 EP EP87110928A patent/EP0257323B1/en not_active Expired - Lifetime
- 1987-07-28 DE DE8787110928T patent/DE3782885T2/de not_active Expired - Fee Related
- 1987-09-21 JP JP62235053A patent/JPS63212544A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| EP0257323A1 (en) | 1988-03-02 |
| JPS6335675A (ja) | 1988-02-16 |
| DE3782885T2 (de) | 1993-06-17 |
| JPH0438227B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1992-06-23 |
| EP0257323B1 (en) | 1992-12-02 |
| JPS63212544A (ja) | 1988-09-05 |
| DE3782885D1 (de) | 1993-01-14 |
| JPH0660300B2 (ja) | 1994-08-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKLA | Lapsed |