CA1191852A - Organic thiosulphates and thiosulphonates useful as stabilising agents for rubber vulcanisates - Google Patents

Organic thiosulphates and thiosulphonates useful as stabilising agents for rubber vulcanisates

Info

Publication number
CA1191852A
CA1191852A CA000406838A CA406838A CA1191852A CA 1191852 A CA1191852 A CA 1191852A CA 000406838 A CA000406838 A CA 000406838A CA 406838 A CA406838 A CA 406838A CA 1191852 A CA1191852 A CA 1191852A
Authority
CA
Canada
Prior art keywords
group
formula
ion
phenyl
radical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA000406838A
Other languages
English (en)
French (fr)
Inventor
Philippe G. Moniotte
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer Agriculture BVBA
Original Assignee
Monsanto Europe NV SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Europe NV SA filed Critical Monsanto Europe NV SA
Application granted granted Critical
Publication of CA1191852A publication Critical patent/CA1191852A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41—Compounds containing sulfur bound to oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C381/00—Compounds containing carbon and sulfur and having functional groups not covered by groups C07C301/00 - C07C337/00
    • C07C381/02—Thiosulfates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41—Compounds containing sulfur bound to oxygen
    • C08K5/42—Sulfonic acids; Derivatives thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Fats And Perfumes (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
CA000406838A 1981-07-08 1982-07-07 Organic thiosulphates and thiosulphonates useful as stabilising agents for rubber vulcanisates Expired CA1191852A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB81/21098 1981-07-08
GB8121098 1981-07-08
GB81/24716 1981-08-13
GB8124716 1981-08-13

Publications (1)

Publication Number Publication Date
CA1191852A true CA1191852A (en) 1985-08-13

Family

ID=26280059

Family Applications (1)

Application Number Title Priority Date Filing Date
CA000406838A Expired CA1191852A (en) 1981-07-08 1982-07-07 Organic thiosulphates and thiosulphonates useful as stabilising agents for rubber vulcanisates

Country Status (16)

Country Link
US (3) US4417012A (no)
EP (1) EP0070143B1 (no)
JP (1) JPH03115259A (no)
AU (1) AU548746B2 (no)
BR (1) BR8203948A (no)
CA (1) CA1191852A (no)
CS (1) CS239927B2 (no)
DD (1) DD202296A5 (no)
DE (1) DE3262422D1 (no)
IE (1) IE53303B1 (no)
MX (1) MX163019B (no)
NO (1) NO160847C (no)
PL (1) PL131210B1 (no)
RO (1) RO85393B (no)
SU (1) SU1159491A3 (no)
UA (1) UA5970A1 (no)

Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4532080A (en) * 1982-10-21 1985-07-30 Monsanto Europe, S.A. Adhesion promoters
GB8401508D0 (en) * 1984-01-20 1984-02-22 Monsanto Europe Sa Compounds useful as rubber/metal bonding promoters
US4654271A (en) * 1984-04-10 1987-03-31 Monsanto Europe, S. A. Metal complexes useful as rubber/metal bonding promoters
GB8608052D0 (en) * 1986-04-02 1986-05-08 Shell Int Research Organic thiosulphates
US6207764B1 (en) * 1995-04-26 2001-03-27 Monsanto Company Halogenated elastomer compositions
US6809137B2 (en) * 1998-06-08 2004-10-26 Bridgestone Corporation Rubber composition and pneumatic tire using said rubber composition
JP4521074B2 (ja) * 1998-06-08 2010-08-11 株式会社ブリヂストン ゴム組成物及びそれを用いた空気入りタイヤ
US7328733B2 (en) * 1999-12-28 2008-02-12 Exxonmobil Chemical Patents Inc. Inner tube compositions having improved heat resistance characteristics
CA2395434C (en) 1999-12-28 2010-04-27 Donald S. Tracey Inner tube compositions having improved heat resistance characteristics
CN1268673C (zh) * 2001-06-13 2006-08-09 埃克森美孚化学专利公司 低渗透性纳米复合材料
US6420505B1 (en) 2001-06-20 2002-07-16 Eastman Kodak Company Process for preparing thiosulfate salt polymers
US7060757B2 (en) * 2003-02-06 2006-06-13 Bridgestone Corporation Rubber composition and pneumatic tire using the same
DE102004018193A1 (de) * 2004-04-15 2005-11-03 Bayer Ag Herstellung von Thioschwefelsäurederivaten
EP1600439B1 (de) * 2004-05-26 2016-02-03 LANXESS Deutschland GmbH Herstellung von derivatisierten Dithiolen
MY138552A (en) * 2005-02-18 2009-06-30 Teijin Aramid Bv Method for enhancing rubber properties by using bunte salt-treated fiber
JP4747660B2 (ja) * 2005-04-28 2011-08-17 宇部興産株式会社 ジチオスルフェート化合物の製造方法
US7674861B1 (en) 2008-10-30 2010-03-09 Momentive Performance Materials Inc. Thiocarbamoyldisufanyl-functional cycloaliphatic compound, process for its preparation, filled sulfur-vulcanizable elastomer composition containing same and articles fabricated therefrom
US8124206B2 (en) 2008-10-30 2012-02-28 Momentive Performance Materials, Inc. Sulfur-containing cycloaliphatic compound, filled sulfur-vulcanizable elastomer composition containing sulfur-containing cycloaliphatic compound and articles fabricated therefrom
US8470197B2 (en) 2008-10-30 2013-06-25 Momentive Performance Materials Inc. Crosslinked polysulfide-containing cycloaliphatic compound, process for its preparation, filled sulfur-vulcanizable elastomer composition containing same and articles fabricated therefrom
US8334340B2 (en) * 2008-10-30 2012-12-18 Momentive Performance Materials, Inc. Sulfur-containing cycloaliphatic compound, process for its preparation, filled sulfur-vulcanizable elastomer composition containing same and articles fabricated therefrom
JP5051274B2 (ja) * 2009-06-04 2012-10-17 住友化学株式会社 加硫ゴムが有する粘弾性特性を改善させるためのｓ−（３−アミノプロピル）チオ硫酸および／またはその金属塩の使用
JP5589564B2 (ja) * 2009-06-30 2014-09-17 住友化学株式会社 加硫ゴム及びその製造方法
WO2011078859A1 (en) * 2009-12-23 2011-06-30 Michelin Recherche Et Technique S.A. Rubber composition for aircraft tire treads
KR101831473B1 (ko) * 2010-07-28 2018-02-26 수미토모 케미칼 컴퍼니 리미티드 아미노알킬 티오황산 화합물의 제조 방법
JP5905112B2 (ja) 2011-10-24 2016-04-20 ブリヂストン アメリカズ タイヤ オペレイションズ エルエルシー シリカ充填ゴム組成物およびその製造方法
CN102816095B (zh) * 2012-08-14 2014-07-30 北京彤程创展科技有限公司 一种有机硫代硫酸盐的制备方法
CN103265465B (zh) * 2013-05-27 2014-09-10 哈尔滨工业大学 一种耦合结晶回收废液中二水合六亚甲基-1,6-二硫代硫酸二钠盐的方法
CN103819377B (zh) * 2013-12-16 2016-01-06 菏泽佳成化工有限公司 二水合六亚甲基1,6-二硫代硫酸二钠盐的制备方法
CN103626685B (zh) * 2013-12-20 2016-07-13 北京彤程创展科技有限公司 一种双功能有机硫代硫酸盐及其制备方法
JP5598622B1 (ja) 2014-03-10 2014-10-01 日東紡績株式会社 ガラスチョップドストランドマット、ガラスチョップドストランドマットロール、ガラスチョップドストランドマットの製造方法及び自動車成形天井材
JP5900526B2 (ja) * 2014-03-27 2016-04-06 横浜ゴム株式会社 ゴム組成物及びこれを用いる空気入りタイヤ
CN105017144B (zh) * 2014-04-25 2019-05-28 圣奥化学科技有限公司 一种橡胶防老剂rd及其制备方法
WO2020081283A1 (en) 2018-10-15 2020-04-23 Flexsys America, L.P. Stabilized thiosulfates and their use in rubber compositions
US11905256B2 (en) 2018-11-01 2024-02-20 Flexsys America L.P. Triazinanes and methods of making them
CN110294700A (zh) * 2019-07-05 2019-10-01 山东阳谷华泰化工股份有限公司 一种二水合六亚甲基-1,6-二硫代硫酸二钠盐的合成方法
US20220298123A1 (en) 2019-08-29 2022-09-22 Flexsys America L.P. Triazinane derivatives and methods of making them
CN110885444B (zh) * 2019-12-02 2021-12-10 锦西化工研究院有限公司 一种低密度聚硫橡胶聚合物及其制备方法
JP2021095445A (ja) * 2019-12-13 2021-06-24 Ｔｏｙｏ Ｔｉｒｅ株式会社 インナーライナー用ゴム組成物、及びそれを用いた空気入りタイヤ
EP4139285A1 (en) 2020-04-21 2023-03-01 Flexsys America L.P. Triazinanes possessing thiosulfonate end-groups and methods of making them
CN114384199B (zh) * 2022-01-17 2022-11-01 杭州沐源生物医药科技有限公司 一种利用电位滴定法测定氯化钾颗粒含量的方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU177881A (no) *
DE1750070U (de) * 1953-05-07 1957-08-08 Bernhardt & Schulte Fabrik Ele Rastgesperre fuer elektrische drehschalter.
US2936295A (en) * 1956-06-22 1960-05-10 Exxon Research Engineering Co Thermal and mechanical stable latices of isoolefin-multiolefin rubbery polymers and process for preparing same
US3054781A (en) * 1959-03-24 1962-09-18 Borden Co Thiosulfate process of making organic polysulfides
BE588030A (no) * 1959-04-29
US3153077A (en) * 1960-03-08 1964-10-13 Stevens & Co Inc J P Process for preparing organic bis-thiosulfates
NL267024A (no) * 1960-08-25 1900-01-01
NL276618A (no) * 1961-03-31 1900-01-01
US3535249A (en) * 1966-10-24 1970-10-20 Goodyear Tire & Rubber Antioxidant compositions,their use in polymers and products made therefrom
US3732192A (en) * 1971-05-24 1973-05-08 Universal Oil Prod Co Rubber formulations containing thiosulfonate esters
US3869435A (en) * 1971-11-19 1975-03-04 Monsanto Co Method for cross-linking rubber
FR2432508A1 (fr) * 1977-10-14 1980-02-29 Elf Union Procede pour l'obtention d'alkylthiosulfates et d'alkylidenethiosulfates

Also Published As

Publication number Publication date
CS520382A2 (en) 1985-05-15
DD202296A5 (de) 1983-09-07
RO85393B (ro) 1984-11-30
IE53303B1 (en) 1988-10-12
AU8563982A (en) 1983-01-13
PL131210B1 (en) 1984-10-31
JPH03115259A (ja) 1991-05-16
DE3262422D1 (en) 1985-03-28
EP0070143A1 (en) 1983-01-19
BR8203948A (pt) 1983-06-28
NO160847C (no) 1989-06-07
IE821638L (en) 1983-01-08
SU1159491A3 (ru) 1985-05-30
NO822362L (no) 1983-01-10
UA5970A1 (uk) 1994-12-29
EP0070143B1 (en) 1985-02-20
US4587296A (en) 1986-05-06
AU548746B2 (en) 1986-01-02
CS239927B2 (en) 1986-01-16
RO85393A (ro) 1984-10-31
MX163019B (es) 1991-08-05
US4417012A (en) 1983-11-22
PL237334A1 (en) 1983-02-14
US4520154A (en) 1985-05-28
NO160847B (no) 1989-02-27

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Legal Events

Date Code Title Description
MKEX Expiry
MKEX Expiry

Effective date: 20020813