CA1085541A - THERMOPLASTIC ELASTOMERS COMPRISING ETHYLENE-.alpha.- OLEFIN COPOLYMER, POLYPROPYLENE AND POLYBUTENE - Google Patents
THERMOPLASTIC ELASTOMERS COMPRISING ETHYLENE-.alpha.- OLEFIN COPOLYMER, POLYPROPYLENE AND POLYBUTENEInfo
- Publication number
- CA1085541A CA1085541A CA275,275A CA275275A CA1085541A CA 1085541 A CA1085541 A CA 1085541A CA 275275 A CA275275 A CA 275275A CA 1085541 A CA1085541 A CA 1085541A
- Authority
- CA
- Canada
- Prior art keywords
- ethylene
- composition
- polypropylene
- polybutene
- propylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 ETHYLENE- Chemical class 0.000 title claims abstract description 24
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 20
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 20
- 229920000089 Cyclic olefin copolymer Polymers 0.000 title claims abstract description 8
- 229920002725 thermoplastic elastomer Polymers 0.000 title claims abstract 5
- 229920001083 polybutene Polymers 0.000 title 1
- 239000000203 mixture Substances 0.000 claims abstract description 61
- 229920001748 polybutylene Polymers 0.000 claims abstract 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 13
- 239000005977 Ethylene Substances 0.000 claims description 13
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 13
- 229920001577 copolymer Polymers 0.000 claims description 12
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 8
- 150000001993 dienes Chemical class 0.000 claims description 5
- 239000000945 filler Substances 0.000 claims description 5
- 238000001746 injection moulding Methods 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical group C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 claims description 2
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 claims description 2
- 238000001125 extrusion Methods 0.000 claims description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims 4
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 claims 1
- 239000012963 UV stabilizer Substances 0.000 claims 1
- 239000003963 antioxidant agent Substances 0.000 claims 1
- 230000003078 antioxidant effect Effects 0.000 claims 1
- 229920001169 thermoplastic Polymers 0.000 abstract description 10
- 239000004416 thermosoftening plastic Substances 0.000 abstract description 10
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 239000012778 molding material Substances 0.000 abstract 1
- 229940093470 ethylene Drugs 0.000 description 10
- 229940095050 propylene Drugs 0.000 description 9
- 230000000704 physical effect Effects 0.000 description 5
- CBQYNPHHHJTCJS-UHFFFAOYSA-N Alline Chemical compound C1=CC=C2C3(O)CCN(C)C3NC2=C1 CBQYNPHHHJTCJS-UHFFFAOYSA-N 0.000 description 4
- 229920002943 EPDM rubber Polymers 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1 -dodecene Natural products CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 1
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 description 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- 241000518994 Conta Species 0.000 description 1
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 1
- 239000003508 Dilauryl thiodipropionate Substances 0.000 description 1
- 239000002656 Distearyl thiodipropionate Substances 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- YNPNZTXNASCQKK-UHFFFAOYSA-N Phenanthrene Natural products C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 1
- DGEZNRSVGBDHLK-UHFFFAOYSA-N [1,10]phenanthroline Chemical compound C1=CN=C2C3=NC=CC=C3C=CC2=C1 DGEZNRSVGBDHLK-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 229920003244 diene elastomer Polymers 0.000 description 1
- 235000019304 dilauryl thiodipropionate Nutrition 0.000 description 1
- PWWSSIYVTQUJQQ-UHFFFAOYSA-N distearyl thiodipropionate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCCCCCC PWWSSIYVTQUJQQ-UHFFFAOYSA-N 0.000 description 1
- 235000019305 distearyl thiodipropionate Nutrition 0.000 description 1
- 229940069096 dodecene Drugs 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- LDLDYFCCDKENPD-UHFFFAOYSA-N ethenylcyclohexane Chemical compound C=CC1CCCCC1 LDLDYFCCDKENPD-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 150000002848 norbornenes Chemical class 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229920005653 propylene-ethylene copolymer Polymers 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/673,234 US4078020A (en) | 1976-04-02 | 1976-04-02 | Thermoplastic elastomers comprising ethylene-α-olefin copolymer, polypropylene and polybutene |
| US673,34 | 1976-04-02 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1085541A true CA1085541A (en) | 1980-09-09 |
Family
ID=24701816
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA275,275A Expired CA1085541A (en) | 1976-04-02 | 1977-03-31 | THERMOPLASTIC ELASTOMERS COMPRISING ETHYLENE-.alpha.- OLEFIN COPOLYMER, POLYPROPYLENE AND POLYBUTENE |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4078020A (enExample) |
| JP (1) | JPS52121061A (enExample) |
| CA (1) | CA1085541A (enExample) |
| DE (1) | DE2714193A1 (enExample) |
| FR (1) | FR2346397A1 (enExample) |
| GB (1) | GB1532143A (enExample) |
| NL (1) | NL7703530A (enExample) |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2029420B (en) * | 1977-08-11 | 1982-09-15 | Kestrel Chemicals Ltd | Thermoplastic resin compositions containing a filler and artifacts formed therefrom |
| FR2405547A1 (fr) * | 1977-10-05 | 1979-05-04 | Charbonnages Ste Chimique | Condensateurs a film dielectrique plastique et leur procede de fabrication |
| GB2007685B (en) * | 1977-10-11 | 1982-05-12 | Asahi Dow Ltd | Composition for drawn film cold drawn film made of said composition and process for manufacture of said film |
| US4188350A (en) * | 1978-01-17 | 1980-02-12 | Union Carbide Corporation | Olefin polymer blends and films therefrom |
| US4196240A (en) * | 1978-01-18 | 1980-04-01 | Union Carbide Corporation | Heat shrinkable multilayer packaging film of blended copolymers and elastomers |
| US4207363A (en) * | 1978-03-29 | 1980-06-10 | Union Carbide Corporation | Flexible heat-shrinkable multilayer film for packaging primal meat |
| US4194039A (en) * | 1978-04-17 | 1980-03-18 | W. R. Grace & Co. | Multi-layer polyolefin shrink film |
| US4165302A (en) * | 1978-08-22 | 1979-08-21 | Cities Service Company | Filled resin compositions containing atactic polypropylene |
| US4311807A (en) * | 1980-07-22 | 1982-01-19 | Shell Oil Company | Polybutylene modified masterbatches for impact resistant polypropylene |
| US4666989A (en) * | 1980-07-22 | 1987-05-19 | Shell Oil Company | Polybutylene modified masterbatches for impact resistant polypropylene |
| DE3250051C2 (de) * | 1981-05-04 | 1994-02-17 | Schulman A Inc | Metallverzierung mit einer Beschichtung aus einem Ionomer-Gemisch und Verfahren zur Herstellung desselben |
| US4371583A (en) | 1981-05-04 | 1983-02-01 | A. Schulman, Inc. | Modified ionomer blend and laminated article |
| US4489034A (en) * | 1982-08-25 | 1984-12-18 | Shell Oil Company | Thermoforming process using modified polymer blend |
| US4650830A (en) * | 1983-05-31 | 1987-03-17 | Mitsui Petrochemical Industries, Ltd. | Thermoplastic elastomer composition and process for preparation thereof |
| US4649001A (en) * | 1984-04-17 | 1987-03-10 | Japan Styrene Paper Corporation | Process for producing polyethylene extruded foams |
| AU575992B2 (en) * | 1984-08-31 | 1988-08-11 | Shell Oil Company | Packaging film or sheet |
| US4666778A (en) * | 1984-08-31 | 1987-05-19 | Shell Oil Company | Packaging film and sheet capable of forming peelable seals with good optics |
| US4665130A (en) * | 1984-08-31 | 1987-05-12 | Shell Oil Company | Packaging film and sheet capable of forming peelable seals with good optics |
| US4966944A (en) * | 1986-12-10 | 1990-10-30 | Quantum Chemical Corporation | Impact propylene copolymers with improved bruise resistance |
| US5041491A (en) * | 1989-10-31 | 1991-08-20 | Amoco Corporation | Polypropylene with improved impact properties |
| US5143978A (en) * | 1990-08-28 | 1992-09-01 | Himont Incorporated | Dynamically partially crosslinked thermoplastic elastomer containing polybutene-1 |
| MY114719A (en) | 1995-06-29 | 2002-12-31 | Mitsui Chemicals Inc | Olefin thermoplastic elastomer compositions |
| US5780549A (en) * | 1996-07-29 | 1998-07-14 | General Electric Company | Polybutene polymers as modifiers for PVC |
| US5717021A (en) * | 1996-11-18 | 1998-02-10 | General Electric Company | Polycarbonate/ABS blends |
| IT1292027B1 (it) | 1997-05-29 | 1999-01-25 | Montell North America Inc | Miscela poliolefinica contenente poli(1-butene) |
| US6756443B2 (en) | 2002-01-25 | 2004-06-29 | E. I. Du Pont De Nemours And Company | Ionomer/polyamide blends with improved flow and impact properties |
| ITMI20031579A1 (it) * | 2003-08-01 | 2005-02-02 | Basell Poliolefine Spa | Concentrati di additivi, adatti all'impiego nella |
| CA2592026C (en) * | 2004-12-22 | 2010-11-30 | Advantage Polymers, Llc | Thermoplastic compositions and method of use thereof for molded articles |
| US7851556B2 (en) | 2007-01-12 | 2010-12-14 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates with low compression set |
| US7858689B2 (en) * | 2007-01-12 | 2010-12-28 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates with improved mechanical properties |
| DE602008004668D1 (de) * | 2007-08-22 | 2011-03-03 | Basell Poliolefine Srl | Weiche polyolefinzusammensetzungen mit verbesserter verarbeitbarkeit |
| EP2215166B1 (en) * | 2007-11-27 | 2014-06-04 | Basell Poliolefine Italia S.r.l. | Mixtures of bitumen and polymer compositions |
| BRPI0918979B1 (pt) * | 2008-09-24 | 2019-05-07 | Basell Poliolefine Italia S.R.L. | Composições de poliolefina com boa resistência ao branqueamento |
| JP7061034B2 (ja) * | 2018-06-29 | 2022-04-27 | 三井化学株式会社 | 重合体組成物及び重合体組成物からなる成形体 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1188280B (de) * | 1956-10-11 | 1965-03-04 | Montedison Spa | Herstellung von verstreckten, freitragenden Filmen |
| DE1228410C2 (de) * | 1962-03-23 | 1973-09-06 | Canadian Ind | Formmassen auf Basis von AEthylenpolymerisaten |
| GB1037819A (en) * | 1963-12-30 | 1966-08-03 | Canadian Ind | Ternary blends of polymers |
| US3733373A (en) * | 1971-04-01 | 1973-05-15 | Eastman Kodak Co | Poly-1-butene resins |
| DE2138685C3 (de) * | 1971-08-03 | 1974-05-30 | Chemische Werke Huels Ag, 4370 Marl | Thermoplastische Formmasse |
| US3806558A (en) * | 1971-08-12 | 1974-04-23 | Uniroyal Inc | Dynamically partially cured thermoplastic blend of monoolefin copolymer rubber and polyolefin plastic |
| JPS5425063B2 (enExample) * | 1972-01-19 | 1979-08-25 | ||
| US3835201A (en) * | 1972-08-29 | 1974-09-10 | Uniroyal Inc | Thermoplastic blend of copolymer rubber and polyolefin plastic |
| US3849520A (en) * | 1973-01-17 | 1974-11-19 | Mobil Oil Corp | Resinous blend and oriented shrink film comprising polypropylene,polybutene and ethylene/butene copolymer |
| US3946897A (en) * | 1974-03-25 | 1976-03-30 | Uniroyal, Inc. | Drum cover made from thermoplastic rubber |
-
1976
- 1976-04-02 US US05/673,234 patent/US4078020A/en not_active Expired - Lifetime
-
1977
- 1977-03-30 DE DE19772714193 patent/DE2714193A1/de not_active Withdrawn
- 1977-03-31 NL NL7703530A patent/NL7703530A/xx not_active Application Discontinuation
- 1977-03-31 FR FR7709704A patent/FR2346397A1/fr active Granted
- 1977-03-31 CA CA275,275A patent/CA1085541A/en not_active Expired
- 1977-04-01 GB GB13790/77A patent/GB1532143A/en not_active Expired
- 1977-04-01 JP JP3745877A patent/JPS52121061A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| DE2714193A1 (de) | 1977-10-13 |
| NL7703530A (nl) | 1977-10-04 |
| FR2346397B1 (enExample) | 1979-03-02 |
| JPS52121061A (en) | 1977-10-12 |
| GB1532143A (en) | 1978-11-15 |
| US4078020A (en) | 1978-03-07 |
| FR2346397A1 (fr) | 1977-10-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |