CA1075669A - Oxidation catalysts - Google Patents

Oxidation catalysts

Info

Publication number
CA1075669A
CA1075669A CA242,831A CA242831A CA1075669A CA 1075669 A CA1075669 A CA 1075669A CA 242831 A CA242831 A CA 242831A CA 1075669 A CA1075669 A CA 1075669A
Authority
CA
Canada
Prior art keywords
mixture
catalyst
manganese
oxidation
propylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA242,831A
Other languages
English (en)
French (fr)
Inventor
Robert K. Grasselli
Dev D. Suresh
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Co
Original Assignee
Standard Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Co filed Critical Standard Oil Co
Application granted granted Critical
Publication of CA1075669A publication Critical patent/CA1075669A/en
Expired legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/88Molybdenum
    • B01J23/887Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8878Chromium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24Chromium, molybdenum or tungsten
    • B01J23/30Tungsten
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32Manganese, technetium or rhenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66Silver or gold
    • B01J23/68Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/683Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
    • B01J23/686Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten with molybdenum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/888Tungsten
    • B01J23/8885Tungsten containing also molybdenum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14Phosphorus; Compounds thereof
    • B01J27/186Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19Molybdenum
    • B01J27/192Molybdenum with bismuth
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00Preparation of carboxylic acid nitriles
    • C07C253/24Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C07C253/26Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CA242,831A 1975-01-13 1975-12-30 Oxidation catalysts Expired CA1075669A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US53540375A 1975-01-13 1975-01-13

Publications (1)

Publication Number Publication Date
CA1075669A true CA1075669A (en) 1980-04-15

Family

ID=24134033

Family Applications (1)

Application Number Title Priority Date Filing Date
CA242,831A Expired CA1075669A (en) 1975-01-13 1975-12-30 Oxidation catalysts

Country Status (13)

Country Link
JP (1) JPS5195991A (es)
AT (1) AT348978B (es)
BR (1) BR7600141A (es)
CA (1) CA1075669A (es)
DD (1) DD123739A5 (es)
DE (1) DE2600128A1 (es)
ES (1) ES444223A1 (es)
FR (1) FR2297082A1 (es)
GB (1) GB1497589A (es)
IN (1) IN145044B (es)
IT (1) IT1054781B (es)
NL (1) NL7600312A (es)
SU (1) SU718000A3 (es)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL7909142A (nl) * 1978-12-26 1980-06-30 Halcon Res & Dev Katalysator en werkwijze voor de bereiding van methacrylzuur.
NZ197767A (en) * 1980-08-04 1983-04-12 Merck & Co Inc Ammoxidation catalyst containing manganese chromium and molybdenum oxides
JPS57130548A (en) * 1981-02-05 1982-08-13 Mitsubishi Chem Ind Ltd Catalyst composition
WO2013113743A1 (de) 2012-01-30 2013-08-08 Basf Se Verfahren zur herstellung von butadien und/oder butenen aus n-butan
JP2015530394A (ja) 2012-09-20 2015-10-15 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se C4炭化水素流からの酸素の除去によるブタジエンの製造方法
US9399606B2 (en) 2012-12-06 2016-07-26 Basf Se Catalyst and process for the oxidative dehydrogenation of N-butenes to butadiene
KR20150094620A (ko) 2012-12-06 2015-08-19 바스프 에스이 n-부텐의 부타디엔으로의 산화성 탈수소화 방법
JP2016503073A (ja) 2013-01-15 2016-02-01 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se 酸化的脱水素化によるn−ブテン類からの1,3−ブタジエンの製造方法
US10144681B2 (en) 2013-01-15 2018-12-04 Basf Se Process for the oxidative dehydrogenation of N-butenes to butadiene
CN104936930B (zh) 2013-01-16 2017-03-29 巴斯夫欧洲公司 通过在产物加工期间监控过氧化物含量进行正丁烯的氧化脱氢制备丁二烯的方法
JP2016526565A (ja) 2013-07-10 2016-09-05 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se n−ブテンをブタジエンへと酸化脱水素化する方法
KR20160078357A (ko) 2013-10-30 2016-07-04 바스프 에스이 산화성 탈수소화에 의해 n-부텐으로부터 1,3-부타디엔을 제조하는 방법
CN106103390A (zh) 2014-01-13 2016-11-09 巴斯夫欧洲公司 启动用于正丁烯的氧化脱氢的反应器的方法
DE102014203725A1 (de) 2014-02-28 2015-09-03 Basf Se Oxidationskatalysator mit sattelförmigem Trägerformkörper
WO2016023892A1 (de) 2014-08-12 2016-02-18 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung
KR20170063608A (ko) 2014-09-26 2017-06-08 바스프 에스이 산화성 탈수소화에 의해 n-부텐으로부터 1,3-부타디엔을 제조하는 방법
JP6625634B2 (ja) 2014-11-03 2019-12-25 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se 酸化的脱水素化によりn−ブテン類から1,3−ブタジエンを製造するための方法
WO2016075065A1 (de) 2014-11-14 2016-05-19 Basf Se Verfahren zur herstellung von 1,3-butadien durch dehydrierung von n-butenen unter bereitstellung eines butane und 2-butene enthaltenden stoffstromes
KR20170133404A (ko) 2015-03-26 2017-12-05 바스프 에스이 산화성 탈수소화에 의한 n-부텐으로부터의 1,3-부타디엔의 제조
WO2016151074A1 (de) 2015-03-26 2016-09-29 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung
KR20170134522A (ko) 2015-03-26 2017-12-06 바스프 에스이 산화성 탈수소화에 의한 n-부텐으로부터의 1,3-부타디엔의 제조
WO2016150940A1 (de) 2015-03-26 2016-09-29 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung
US20180354872A1 (en) 2015-12-03 2018-12-13 Basf Se Method for producing butadiene by oxidatively dehydrogenating n-butenes
JP2019501938A (ja) 2016-01-13 2019-01-24 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se 酸化的脱水素化によるn−ブテンからの1,3−ブタジエンの製造方法
EP3411348A1 (de) 2016-02-04 2018-12-12 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung
CN109843836A (zh) 2016-08-09 2019-06-04 巴斯夫欧洲公司 启动用于正丁烯的氧化脱氢的反应器的方法
WO2018095856A1 (de) 2016-11-22 2018-05-31 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine methacrolein-abtrennung bei der aufarbeitung
WO2018095776A1 (de) 2016-11-22 2018-05-31 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine wässrige wäsche des c4-produktgasstroms
EP3323797A1 (de) 2016-11-22 2018-05-23 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine saure wäsche des c4-produktgasstroms
WO2018095840A1 (de) 2016-11-22 2018-05-31 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine furan-abtrennung bei der aufarbeitung
WO2018219996A1 (de) 2017-06-02 2018-12-06 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung in kreisgasfahrweise mit co2-angereichertem kreisgas
WO2018234158A1 (de) 2017-06-19 2018-12-27 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine wäsche des c4-produktgasstroms

Also Published As

Publication number Publication date
DE2600128A1 (de) 1976-07-15
ATA10676A (de) 1978-08-15
DD123739A5 (es) 1977-01-12
FR2297082A1 (fr) 1976-08-06
AT348978B (de) 1979-03-12
IN145044B (es) 1978-08-19
FR2297082B1 (es) 1982-02-26
IT1054781B (it) 1981-11-30
ES444223A1 (es) 1977-05-01
JPS5195991A (es) 1976-08-23
GB1497589A (en) 1978-01-12
SU718000A3 (ru) 1980-02-25
BR7600141A (pt) 1976-08-31
NL7600312A (nl) 1976-07-15

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