CA1069239A - Polymeric and/or monomeric dental composition comprising submicron inorganic filler - Google Patents
Polymeric and/or monomeric dental composition comprising submicron inorganic fillerInfo
- Publication number
- CA1069239A CA1069239A CA218,407A CA218407A CA1069239A CA 1069239 A CA1069239 A CA 1069239A CA 218407 A CA218407 A CA 218407A CA 1069239 A CA1069239 A CA 1069239A
- Authority
- CA
- Canada
- Prior art keywords
- material according
- microfine
- inorganic filler
- filler
- dental
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011256 inorganic filler Substances 0.000 title claims abstract description 30
- 229910003475 inorganic filler Inorganic materials 0.000 title claims abstract description 30
- 239000000203 mixture Substances 0.000 title claims description 17
- 239000000463 material Substances 0.000 claims abstract description 58
- 239000000178 monomer Substances 0.000 claims abstract description 29
- 239000002245 particle Substances 0.000 claims abstract description 28
- 239000005548 dental material Substances 0.000 claims abstract description 20
- 229920000642 polymer Polymers 0.000 claims abstract description 16
- 239000000945 filler Substances 0.000 claims description 35
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 26
- 235000012239 silicon dioxide Nutrition 0.000 claims description 13
- 239000000377 silicon dioxide Substances 0.000 claims description 13
- 239000011230 binding agent Substances 0.000 claims description 9
- 239000011521 glass Substances 0.000 claims description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 7
- -1 methacrylate ester Chemical class 0.000 claims description 7
- AMFGWXWBFGVCKG-UHFFFAOYSA-N Panavia opaque Chemical compound C1=CC(OCC(O)COC(=O)C(=C)C)=CC=C1C(C)(C)C1=CC=C(OCC(O)COC(=O)C(C)=C)C=C1 AMFGWXWBFGVCKG-UHFFFAOYSA-N 0.000 claims description 6
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims description 4
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims description 4
- 150000002734 metacrylic acid derivatives Chemical class 0.000 claims description 4
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 3
- 239000007795 chemical reaction product Substances 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 239000005388 borosilicate glass Substances 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 239000003605 opacifier Substances 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- XFBCATPOLVMYCV-UHFFFAOYSA-N 2-[4-[2-[4-(2-hydroxyethoxy)phenyl]propan-2-yl]phenoxy]ethanol;2-methylprop-2-enoic acid Chemical compound CC(=C)C(O)=O.CC(=C)C(O)=O.C=1C=C(OCCO)C=CC=1C(C)(C)C1=CC=C(OCCO)C=C1 XFBCATPOLVMYCV-UHFFFAOYSA-N 0.000 claims 1
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims 1
- JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 claims 1
- 229960005363 aluminium oxide Drugs 0.000 claims 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate Chemical compound [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims 1
- 239000012948 isocyanate Substances 0.000 claims 1
- 150000002894 organic compounds Chemical class 0.000 claims 1
- 239000000049 pigment Substances 0.000 claims 1
- 238000005498 polishing Methods 0.000 abstract description 6
- 238000011049 filling Methods 0.000 description 21
- 238000004519 manufacturing process Methods 0.000 description 7
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 6
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 6
- 235000019400 benzoyl peroxide Nutrition 0.000 description 6
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 6
- 239000011159 matrix material Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 238000002156 mixing Methods 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 239000004342 Benzoyl peroxide Substances 0.000 description 4
- 239000011324 bead Substances 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
- 206010041662 Splinter Diseases 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 239000004568 cement Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Chemical compound CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 3
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 229940106691 bisphenol a Drugs 0.000 description 2
- 239000012612 commercial material Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000008602 contraction Effects 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 208000002925 dental caries Diseases 0.000 description 2
- 210000003298 dental enamel Anatomy 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229940063559 methacrylic acid Drugs 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000011253 protective coating Substances 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- HWSSEYVMGDIFMH-UHFFFAOYSA-N 2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOC(=O)C(C)=C HWSSEYVMGDIFMH-UHFFFAOYSA-N 0.000 description 1
- YFICSDVNKFLZRQ-UHFFFAOYSA-N 3-trimethylsilylpropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCC[Si](C)(C)C YFICSDVNKFLZRQ-UHFFFAOYSA-N 0.000 description 1
- 229910000497 Amalgam Inorganic materials 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- 241000905957 Channa melasoma Species 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- OWIKHYCFFJSOEH-UHFFFAOYSA-N Isocyanic acid Chemical class N=C=O OWIKHYCFFJSOEH-UHFFFAOYSA-N 0.000 description 1
- 229910000502 Li-aluminosilicate Inorganic materials 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 238000006887 Ullmann reaction Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- HNYOPLTXPVRDBG-UHFFFAOYSA-N barbituric acid Chemical compound O=C1CC(=O)NC(=O)N1 HNYOPLTXPVRDBG-UHFFFAOYSA-N 0.000 description 1
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229960003563 calcium carbonate Drugs 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229940063557 methacrylate Drugs 0.000 description 1
- 230000010494 opalescence Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 238000002444 silanisation Methods 0.000 description 1
- 239000005368 silicate glass Substances 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61C—DENTISTRY; APPARATUS OR METHODS FOR ORAL OR DENTAL HYGIENE
- A61C13/00—Dental prostheses; Making same
- A61C13/08—Artificial teeth; Making same
- A61C13/09—Composite teeth, e.g. front and back section; Multilayer teeth
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61C—DENTISTRY; APPARATUS OR METHODS FOR ORAL OR DENTAL HYGIENE
- A61C5/00—Filling or capping teeth
- A61C5/20—Repairing attrition damage, e.g. facets
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
- A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
Landscapes
- Health & Medical Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Chemical & Material Sciences (AREA)
- Dentistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Plastic & Reconstructive Surgery (AREA)
- Dental Preparations (AREA)
- Adhesives Or Adhesive Processes (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2403211A DE2403211C3 (de) | 1974-01-23 | 1974-01-23 | Werkstoff für Dentalzwecke |
| DE2405578A DE2405578C3 (de) | 1974-02-06 | 1974-02-06 | Polymerisierbares Bindemittel enthaltender Dentalwerkstoff und seine Verwendung für Zähne und Zahnersatzteile |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1069239A true CA1069239A (en) | 1980-01-01 |
Family
ID=25766502
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA218,407A Expired CA1069239A (en) | 1974-01-23 | 1975-01-22 | Polymeric and/or monomeric dental composition comprising submicron inorganic filler |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPS5936602B2 (en, 2012) |
| AT (1) | AT338437B (en, 2012) |
| CA (1) | CA1069239A (en, 2012) |
| FR (1) | FR2272638B1 (en, 2012) |
| GB (1) | GB1488403A (en, 2012) |
| SE (2) | SE429609B (en, 2012) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5367002A (en) * | 1992-02-06 | 1994-11-22 | Dentsply Research & Development Corp. | Dental composition and method |
| US6139322A (en) * | 1991-07-12 | 2000-10-31 | Dentsply Research & Development Corp | Denture |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4010545A (en) * | 1976-01-09 | 1977-03-08 | Johnson & Johnson | Adhesive bonding to teeth of orthodontic brackets and the like |
| SE458906B (sv) * | 1976-02-09 | 1989-05-22 | Minnesota Mining & Mfg | Dentalrekonstruktionsmaterial framstaellt genom blandning och polymerisation av ett flytande organiskt polymeriserbart bindemedel och ett finfoerdelat partikulaert fyllmedel |
| DE2728764A1 (de) * | 1977-06-25 | 1979-01-18 | Bayer Ag | Formulierte zahnfuellmaterialien |
| EP0040232B2 (de) | 1979-11-22 | 1993-09-29 | ESPE Stiftung & Co Produktions- und Vertriebs KG | Verwendung von kieselsäuregranulaten als füllstoffe für dentalmassen |
| US4297266A (en) * | 1980-02-08 | 1981-10-27 | Den-Mat, Inc. | Microfilled dental composite and method using the same |
| JPS5774369A (en) * | 1980-10-28 | 1982-05-10 | Mitsui Petrochem Ind Ltd | Coating composition |
| EP0053442B2 (en) | 1980-12-03 | 1993-05-19 | Imperial Chemical Industries Plc | Dental compositions |
| US4514342A (en) * | 1982-02-16 | 1985-04-30 | Dentsply Limited | Polyethylenically unsaturated monophosphates |
| JPS58152804A (ja) * | 1982-03-08 | 1983-09-10 | Tokuyama Soda Co Ltd | 複合組成物 |
| US4544359A (en) * | 1984-01-13 | 1985-10-01 | Pentron Corporation | Dental restorative material |
| GB2169906A (en) * | 1985-01-17 | 1986-07-23 | Suzanne Gillian Carus | Radio opaque materials |
| DE3708618A1 (de) * | 1987-03-17 | 1988-09-29 | Kulzer & Co Gmbh | Kunststoff-zahnersatzteil |
| JP2829414B2 (ja) * | 1988-06-29 | 1998-11-25 | 日東電工株式会社 | 粘着部材及びその製造方法 |
| JPH0725648B2 (ja) * | 1988-08-02 | 1995-03-22 | クルツァ ゲーエムベーハー | プラスチック義歯部材 |
| JP2517753B2 (ja) * | 1988-12-28 | 1996-07-24 | 株式会社ジーシーデンタルプロダクツ | 人工歯とその製造方法 |
| JPH0585120U (ja) * | 1992-04-14 | 1993-11-16 | デイエツクスアンテナ株式会社 | 高周波バンドパスフィルタ |
| JP3489899B2 (ja) * | 1995-03-09 | 2004-01-26 | 株式会社クラレ | 歯科用組成物 |
| DE102005019600A1 (de) | 2005-04-27 | 2006-11-09 | Ivoclar Vivadent Ag | Oberflächenmodifizierte Füllstoffe |
| ATE524154T1 (de) | 2008-01-18 | 2011-09-15 | Ivoclar Vivadent Ag | Dentalmaterialien mit oberflächenfunktionalisierten füllstoffen |
| CN119528453A (zh) * | 2024-12-06 | 2025-02-28 | 中山市新感觉玻璃有限公司 | 一种单向透视防爆玻璃及其制备方法 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3751391A (en) * | 1971-10-28 | 1973-08-07 | Nat Res Dev | Zinc oxide-poly(acrylic acid)surgical cements |
-
1975
- 1975-01-17 FR FR7502032A patent/FR2272638B1/fr not_active Expired
- 1975-01-20 AT AT39175A patent/AT338437B/de not_active IP Right Cessation
- 1975-01-21 GB GB2593/75A patent/GB1488403A/en not_active Expired
- 1975-01-22 CA CA218,407A patent/CA1069239A/en not_active Expired
- 1975-01-23 JP JP50010095A patent/JPS5936602B2/ja not_active Expired
- 1975-01-23 SE SE7500725A patent/SE429609B/xx not_active IP Right Cessation
-
1978
- 1978-03-10 SE SE7802777A patent/SE437120B/sv not_active IP Right Cessation
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6139322A (en) * | 1991-07-12 | 2000-10-31 | Dentsply Research & Development Corp | Denture |
| US6843654B1 (en) | 1991-07-12 | 2005-01-18 | Dentsply Research & Development Corp. | Dental prosthesis |
| US5367002A (en) * | 1992-02-06 | 1994-11-22 | Dentsply Research & Development Corp. | Dental composition and method |
Also Published As
| Publication number | Publication date |
|---|---|
| SE7500725L (en, 2012) | 1975-07-24 |
| JPS50124491A (en, 2012) | 1975-09-30 |
| AT338437B (de) | 1977-08-25 |
| GB1488403A (en) | 1977-10-12 |
| FR2272638B1 (en, 2012) | 1982-06-25 |
| SE437120B (sv) | 1985-02-11 |
| AU7741275A (en) | 1976-07-22 |
| FR2272638A1 (en, 2012) | 1975-12-26 |
| SE429609B (sv) | 1983-09-19 |
| SE7802777L (sv) | 1978-03-10 |
| ATA39175A (de) | 1976-12-15 |
| JPS5936602B2 (ja) | 1984-09-05 |
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