CA1060949A - Rechargeable nickel-zinc battery - Google Patents
Rechargeable nickel-zinc batteryInfo
- Publication number
- CA1060949A CA1060949A CA243,763A CA243763A CA1060949A CA 1060949 A CA1060949 A CA 1060949A CA 243763 A CA243763 A CA 243763A CA 1060949 A CA1060949 A CA 1060949A
- Authority
- CA
- Canada
- Prior art keywords
- oxide
- zinc
- negative electrode
- group
- hydroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- QELJHCBNGDEXLD-UHFFFAOYSA-N nickel zinc Chemical compound [Ni].[Zn] QELJHCBNGDEXLD-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 239000003792 electrolyte Substances 0.000 claims abstract description 41
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000011701 zinc Substances 0.000 claims abstract description 22
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 21
- 239000006096 absorbing agent Substances 0.000 claims abstract description 16
- 229910000480 nickel oxide Inorganic materials 0.000 claims abstract description 8
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims description 27
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 16
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 12
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 12
- -1 polyethylene Polymers 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 11
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 10
- 239000000920 calcium hydroxide Substances 0.000 claims description 10
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 10
- 239000011149 active material Substances 0.000 claims description 9
- 239000004745 nonwoven fabric Substances 0.000 claims description 9
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 8
- 239000000292 calcium oxide Substances 0.000 claims description 8
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 8
- 229920005989 resin Polymers 0.000 claims description 8
- 239000011347 resin Substances 0.000 claims description 8
- 239000011787 zinc oxide Substances 0.000 claims description 8
- 229910000416 bismuth oxide Inorganic materials 0.000 claims description 7
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 claims description 7
- 239000004800 polyvinyl chloride Substances 0.000 claims description 7
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 5
- 229940049676 bismuth hydroxide Drugs 0.000 claims description 5
- TZSXPYWRDWEXHG-UHFFFAOYSA-K bismuth;trihydroxide Chemical compound [OH-].[OH-].[OH-].[Bi+3] TZSXPYWRDWEXHG-UHFFFAOYSA-K 0.000 claims description 5
- PLLZRTNVEXYBNA-UHFFFAOYSA-L cadmium hydroxide Chemical compound [OH-].[OH-].[Cd+2] PLLZRTNVEXYBNA-UHFFFAOYSA-L 0.000 claims description 5
- CXKCTMHTOKXKQT-UHFFFAOYSA-N cadmium oxide Inorganic materials [Cd]=O CXKCTMHTOKXKQT-UHFFFAOYSA-N 0.000 claims description 5
- CFEAAQFZALKQPA-UHFFFAOYSA-N cadmium(2+);oxygen(2-) Chemical compound [O-2].[Cd+2] CFEAAQFZALKQPA-UHFFFAOYSA-N 0.000 claims description 5
- 239000000395 magnesium oxide Substances 0.000 claims description 5
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 5
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 5
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 claims description 5
- 229910021511 zinc hydroxide Inorganic materials 0.000 claims description 5
- 229940007718 zinc hydroxide Drugs 0.000 claims description 5
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 229910052731 fluorine Inorganic materials 0.000 claims description 4
- 239000011737 fluorine Substances 0.000 claims description 4
- 229910052709 silver Inorganic materials 0.000 claims description 4
- 239000004332 silver Substances 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 239000004793 Polystyrene Substances 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 3
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 3
- 229920002223 polystyrene Polymers 0.000 claims description 3
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 3
- 229910001369 Brass Inorganic materials 0.000 claims description 2
- 239000004677 Nylon Substances 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 239000010951 brass Substances 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 229920001778 nylon Polymers 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 229920003002 synthetic resin Polymers 0.000 claims description 2
- 239000000057 synthetic resin Substances 0.000 claims description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 229910044991 metal oxide Inorganic materials 0.000 claims 1
- 150000004706 metal oxides Chemical class 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 229920002994 synthetic fiber Polymers 0.000 claims 1
- 239000012209 synthetic fiber Substances 0.000 claims 1
- 238000010276 construction Methods 0.000 abstract description 2
- 239000012670 alkaline solution Substances 0.000 description 8
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 6
- 239000004810 polytetrafluoroethylene Substances 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- UKWHYYKOEPRTIC-UHFFFAOYSA-N mercury(ii) oxide Chemical compound [Hg]=O UKWHYYKOEPRTIC-UHFFFAOYSA-N 0.000 description 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 3
- 229960002645 boric acid Drugs 0.000 description 3
- 235000010338 boric acid Nutrition 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 229910000474 mercury oxide Inorganic materials 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229940101209 mercuric oxide Drugs 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 238000002161 passivation Methods 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- 150000003752 zinc compounds Chemical class 0.000 description 2
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical group FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- VDTZYABQBPMANF-UHFFFAOYSA-N SSSSSSSSSSSSSSSSSSS Chemical compound SSSSSSSSSSSSSSSSSSS VDTZYABQBPMANF-UHFFFAOYSA-N 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 238000006388 chemical passivation reaction Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 210000001787 dendrite Anatomy 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- MSKQYWJTFPOQAV-UHFFFAOYSA-N fluoroethene;prop-1-ene Chemical group CC=C.FC=C MSKQYWJTFPOQAV-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 239000011812 mixed powder Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000007773 negative electrode material Substances 0.000 description 1
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 239000011369 resultant mixture Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229940087291 tridecyl alcohol Drugs 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical compound [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/24—Electrodes for alkaline accumulators
- H01M4/244—Zinc electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/34—Gastight accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/449—Separators, membranes or diaphragms characterised by the material having a layered structure
- H01M50/451—Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/449—Separators, membranes or diaphragms characterised by the material having a layered structure
- H01M50/454—Separators, membranes or diaphragms characterised by the material having a layered structure comprising a non-fibrous layer and a fibrous layer superimposed on one another
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
- Cell Separators (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP844075A JPS5626108B2 (enrdf_load_stackoverflow) | 1975-01-20 | 1975-01-20 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1060949A true CA1060949A (en) | 1979-08-21 |
Family
ID=11693175
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA243,763A Expired CA1060949A (en) | 1975-01-20 | 1976-01-19 | Rechargeable nickel-zinc battery |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4037033A (enrdf_load_stackoverflow) |
| JP (1) | JPS5626108B2 (enrdf_load_stackoverflow) |
| CA (1) | CA1060949A (enrdf_load_stackoverflow) |
| DE (1) | DE2601571C2 (enrdf_load_stackoverflow) |
| FR (1) | FR2298193A1 (enrdf_load_stackoverflow) |
| GB (1) | GB1530961A (enrdf_load_stackoverflow) |
Families Citing this family (48)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4415636A (en) * | 1975-08-22 | 1983-11-15 | Energy Research Corporation | Secondary batteries having a zinc negative electrode |
| GB1558725A (en) * | 1977-01-13 | 1980-01-09 | Energy Res Corp | Secondary batteris having a zinc negative electrode |
| US4332871A (en) * | 1980-09-15 | 1982-06-01 | Energy Research Corporation | Zinc electrode with cement additive |
| JPS57134863A (en) | 1981-02-13 | 1982-08-20 | Sanyo Electric Co Ltd | Alkaline lead storage battery |
| DE3272109D1 (en) * | 1981-04-28 | 1986-08-28 | Wiggins Teape Group Ltd | Alkaline battery having a paper separator |
| US4361632A (en) * | 1981-05-22 | 1982-11-30 | Kimberly-Clark Corporation | Alkaline battery, composite separator therefor |
| MA19807A1 (fr) * | 1982-06-11 | 1983-12-31 | Compositons Electrolytiques So | Anodes en materiaux composites et accumulateurs utilisant lesdites anodes . |
| EP0114884A4 (en) * | 1982-07-27 | 1985-02-28 | Gould Inc | SEALED NICKEL-ZINC BATTERY. |
| JPH0624147B2 (ja) * | 1982-08-09 | 1994-03-30 | ヒューズ・エアクラフト・カンパニー | 電解液溜を有するニッケル―カドミウム電池 |
| WO1984002232A1 (en) * | 1982-11-19 | 1984-06-07 | Gould Inc | Sealed nickel-zinc cell |
| US4552821A (en) * | 1983-06-30 | 1985-11-12 | Duracell Inc. | Sealed nickel-zinc battery |
| US4892794A (en) * | 1988-07-18 | 1990-01-09 | Minnesota Mining And Manufacturing Company | Battery |
| CA2110097C (en) * | 1992-11-30 | 2002-07-09 | Soichiro Kawakami | Secondary battery |
| KR100287119B1 (ko) * | 1994-07-26 | 2001-05-02 | 윤종용 | 알카리 2차전지용 니켈전극의 화성방법 |
| RU2105396C1 (ru) * | 1996-02-01 | 1998-02-20 | Общество с ограниченной ответственностью "Интергрин" | Никель-цинковый аккумулятор |
| JP3653410B2 (ja) * | 1998-03-24 | 2005-05-25 | 三洋電機株式会社 | 密閉型アルカリ亜鉛蓄電池 |
| US6500584B1 (en) * | 1998-03-27 | 2002-12-31 | Matsushita Electric Industrial Co., Ltd. | Manganese dry batteries |
| KR100307453B1 (ko) * | 1999-02-19 | 2001-09-26 | 김순택 | 리튬이온 2차 전지의 음극 |
| US6344295B1 (en) | 1999-04-30 | 2002-02-05 | Noranda, Inc. | Zinc alloy powder for use in rechargeable cells |
| CA2325308A1 (en) * | 2000-11-10 | 2002-05-10 | Jeffrey Phillips | Negative electrode formulation for a low toxicity zinc electrode having additives with redox potentials negative to zinc potential |
| CA2325791A1 (en) * | 2000-11-10 | 2002-05-10 | Jeffrey Phillips | Negative electrode formulation for a low toxicity zinc electrode having additives with redox potentials positive to zinc potential |
| CA2377065A1 (en) | 2001-03-15 | 2002-09-15 | Powergenix Systems Inc. | Alkaline cells having low toxicity rechargeable zinc electrodes |
| US7550230B2 (en) * | 2001-03-15 | 2009-06-23 | Powergenix Systems, Inc. | Electrolyte composition for nickel-zinc batteries |
| WO2002095850A1 (en) * | 2001-05-24 | 2002-11-28 | Rayovac Corporation | Ionically conductive additive for zinc-based anode in alkaline electrochemical cells |
| US20040229116A1 (en) * | 2002-05-24 | 2004-11-18 | Malinski James Andrew | Perforated separator for an electrochemical cell |
| TW200520292A (en) | 2003-08-08 | 2005-06-16 | Rovcal Inc | High capacity alkaline cell |
| WO2005020353A2 (en) * | 2003-08-18 | 2005-03-03 | Powergenix Systems, Inc. | Method of manufacturing nickel zinc batteries |
| US20080163478A1 (en) * | 2003-08-18 | 2008-07-10 | Powergenix Systems, Inc. | Method for manufacturing nickel zinc batteries |
| US7914920B2 (en) * | 2003-10-09 | 2011-03-29 | The Gillette Company | Battery separator |
| AR047875A1 (es) | 2004-06-04 | 2006-03-01 | Rovcal Inc | Celdas alcalinas que presentan alta capacidad |
| US7291186B2 (en) * | 2004-11-01 | 2007-11-06 | Teck Cominco Metals Ltd. | Solid porous zinc electrodes and methods of making same |
| US20060216584A1 (en) * | 2005-03-24 | 2006-09-28 | Michael Cheiky | Oxidation resistant electrolyte absorber |
| US8703330B2 (en) * | 2005-04-26 | 2014-04-22 | Powergenix Systems, Inc. | Nickel zinc battery design |
| US7799455B2 (en) * | 2006-11-29 | 2010-09-21 | The Gillette Company | Battery separator and method of making same |
| US20110262803A1 (en) * | 2008-03-27 | 2011-10-27 | Zpower, Inc. | Electrodes and Electrochemical Cells Employing the Same |
| US20110123859A1 (en) * | 2008-03-27 | 2011-05-26 | Zpower, Inc. | Polymer Electrolytes |
| EP2272119B1 (en) | 2008-03-27 | 2014-04-23 | ZPower, LLC | Electrode separator |
| CA2720078A1 (en) * | 2008-04-02 | 2009-10-08 | Powergenix Systems, Inc. | Cylindrical nickel-zinc cell with negative can |
| US20110117413A1 (en) * | 2009-11-19 | 2011-05-19 | Yichun Wang | Alkaline Battery Separators with Ion-Trapping Molecules |
| US9401509B2 (en) | 2010-09-24 | 2016-07-26 | Zpower, Llc | Cathode |
| CN102263269B (zh) * | 2011-06-22 | 2015-04-01 | 广东博特动力能源有限公司 | 锌镍电池负极活性材料、斜拉网负极基体、负极及其制备方法 |
| TWI452755B (zh) * | 2011-12-29 | 2014-09-11 | Ind Tech Res Inst | 隔離膜及其製造方法 |
| EP2901516B1 (en) | 2012-09-27 | 2017-06-14 | ZPower, LLC | Cathode |
| GB2511494B (en) * | 2013-03-04 | 2015-01-21 | Cumulus Energy Storage Ltd | Rechargeable copper-zinc cell |
| US11611115B2 (en) | 2017-12-29 | 2023-03-21 | Form Energy, Inc. | Long life sealed alkaline secondary batteries |
| JP7566737B2 (ja) | 2018-07-27 | 2024-10-15 | フォーム エナジー インク | 電気化学セル用の負極 |
| US12294086B2 (en) | 2019-07-26 | 2025-05-06 | Form Energy, Inc. | Low cost metal electrodes |
| CN116979135B (zh) * | 2023-06-21 | 2024-08-27 | 湖北隆中实验室 | 一种异质纳米线复合固态电解质及其制备方法与应用 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3042732A (en) * | 1959-10-14 | 1962-07-03 | Union Carbide Corp | Anodes for alkaline cells |
| FR1398713A (fr) * | 1961-12-07 | 1965-05-14 | Accumulateurs Fixes | Procédé de construction d'accumulateurs électriques et de cellules électrolytiques étanches et articles obtenus |
| FR1485539A (fr) * | 1965-12-30 | 1967-06-23 | Accumulateurs Fixes | Perfectionnement aux cellules électrochimiques comportant des électriodes négatives à base de zinc |
| US3516862A (en) * | 1968-04-01 | 1970-06-23 | Gen Electric | Rechargeable alkaline-zinc cell with porous matrix containing trapping material to eliminate zinc dendrites |
| JPS4813775B1 (enrdf_load_stackoverflow) * | 1970-04-17 | 1973-04-28 | ||
| US3669746A (en) * | 1970-08-03 | 1972-06-13 | Gates Rubber Co | Separators for secondary alkaline batteries having a zinc-containing electrode |
| US3873367A (en) * | 1970-08-17 | 1975-03-25 | Rhein Westfael Elect Werk Ag | Zinc-container electrode |
| US3736185A (en) * | 1970-11-27 | 1973-05-29 | Mc Donnell Douglas Corp | Non-gassing battery separator and method of production |
| DE2156554C3 (de) * | 1971-11-15 | 1975-05-28 | Varta Batterie Ag, 3000 Hannover | Verfahren zur Herstellung eines gasdicht verschlossenen alkalischen Akkumulators |
| JPS5713102B2 (enrdf_load_stackoverflow) * | 1972-11-27 | 1982-03-15 | ||
| JPS5461B2 (enrdf_load_stackoverflow) * | 1973-11-21 | 1979-01-05 |
-
1975
- 1975-01-20 JP JP844075A patent/JPS5626108B2/ja not_active Expired
-
1976
- 1976-01-12 GB GB1009/76A patent/GB1530961A/en not_active Expired
- 1976-01-16 DE DE2601571A patent/DE2601571C2/de not_active Expired
- 1976-01-19 CA CA243,763A patent/CA1060949A/en not_active Expired
- 1976-01-20 US US05/650,782 patent/US4037033A/en not_active Expired - Lifetime
- 1976-01-20 FR FR7601354A patent/FR2298193A1/fr active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| DE2601571A1 (de) | 1976-07-22 |
| FR2298193B1 (enrdf_load_stackoverflow) | 1981-11-20 |
| JPS5626108B2 (enrdf_load_stackoverflow) | 1981-06-16 |
| GB1530961A (en) | 1978-11-01 |
| DE2601571C2 (de) | 1982-09-30 |
| JPS5183134A (enrdf_load_stackoverflow) | 1976-07-21 |
| US4037033A (en) | 1977-07-19 |
| FR2298193A1 (fr) | 1976-08-13 |
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