CA1058788A - Non-aqueous dispersions of water-soluble polymers and aqueous solutions therefrom - Google Patents
Non-aqueous dispersions of water-soluble polymers and aqueous solutions therefromInfo
- Publication number
- CA1058788A CA1058788A CA225,159A CA225159A CA1058788A CA 1058788 A CA1058788 A CA 1058788A CA 225159 A CA225159 A CA 225159A CA 1058788 A CA1058788 A CA 1058788A
- Authority
- CA
- Canada
- Prior art keywords
- water
- polymer
- soluble
- aqueous
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000006185 dispersion Substances 0.000 title claims abstract description 35
- 239000007864 aqueous solution Substances 0.000 title claims abstract description 22
- 229920003169 water-soluble polymer Polymers 0.000 title claims abstract description 15
- 229920000642 polymer Polymers 0.000 claims abstract description 99
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 68
- 239000000178 monomer Substances 0.000 claims abstract description 26
- 239000000080 wetting agent Substances 0.000 claims abstract description 15
- 238000004519 manufacturing process Methods 0.000 claims abstract description 7
- 239000007762 w/o emulsion Substances 0.000 claims abstract description 6
- 239000003999 initiator Substances 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 15
- 230000008569 process Effects 0.000 claims description 15
- 239000002245 particle Substances 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 11
- 238000003860 storage Methods 0.000 claims description 5
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 4
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 3
- 239000003125 aqueous solvent Substances 0.000 claims 2
- 229920006395 saturated elastomer Polymers 0.000 claims 1
- 239000000243 solution Substances 0.000 abstract description 22
- 239000003795 chemical substances by application Substances 0.000 abstract description 12
- 230000014759 maintenance of location Effects 0.000 abstract description 11
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 abstract description 6
- 238000002360 preparation method Methods 0.000 abstract description 5
- 238000004821 distillation Methods 0.000 abstract description 4
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000945 filler Substances 0.000 abstract description 2
- 238000006116 polymerization reaction Methods 0.000 abstract description 2
- 239000000839 emulsion Substances 0.000 description 37
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 21
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- 239000012071 phase Substances 0.000 description 14
- -1 aliphatic alcohols Chemical class 0.000 description 13
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 10
- 125000004432 carbon atom Chemical group C* 0.000 description 9
- 239000007787 solid Substances 0.000 description 9
- 239000008346 aqueous phase Substances 0.000 description 8
- 239000004815 dispersion polymer Substances 0.000 description 8
- 239000002253 acid Substances 0.000 description 7
- 229940117913 acrylamide Drugs 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 5
- 239000012965 benzophenone Substances 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 238000010533 azeotropic distillation Methods 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000010419 fine particle Substances 0.000 description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
- 239000011976 maleic acid Substances 0.000 description 3
- 239000012074 organic phase Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000001593 sorbitan monooleate Substances 0.000 description 3
- 235000011069 sorbitan monooleate Nutrition 0.000 description 3
- 229940035049 sorbitan monooleate Drugs 0.000 description 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- MSAHTMIQULFMRG-UHFFFAOYSA-N 1,2-diphenyl-2-propan-2-yloxyethanone Chemical compound C=1C=CC=CC=1C(OC(C)C)C(=O)C1=CC=CC=C1 MSAHTMIQULFMRG-UHFFFAOYSA-N 0.000 description 2
- KMNCBSZOIQAUFX-UHFFFAOYSA-N 2-ethoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OCC)C(=O)C1=CC=CC=C1 KMNCBSZOIQAUFX-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 244000028419 Styrax benzoin Species 0.000 description 2
- 235000000126 Styrax benzoin Nutrition 0.000 description 2
- 235000008411 Sumatra benzointree Nutrition 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 2
- 150000003926 acrylamides Chemical class 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 2
- 150000004056 anthraquinones Chemical class 0.000 description 2
- 229960002130 benzoin Drugs 0.000 description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
- 150000008366 benzophenones Chemical class 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 235000019382 gum benzoic Nutrition 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 229940070721 polyacrylate Drugs 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 239000001124 (E)-prop-1-ene-1,2,3-tricarboxylic acid Substances 0.000 description 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 1
- POPBYCBXVLHSKO-UHFFFAOYSA-N 9,10-dioxoanthracene-1-carboxylic acid Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2C(=O)O POPBYCBXVLHSKO-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Substances CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 229940091181 aconitic acid Drugs 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 239000001164 aluminium sulphate Substances 0.000 description 1
- 235000011128 aluminium sulphate Nutrition 0.000 description 1
- 125000004103 aminoalkyl group Chemical group 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- RJGDLRCDCYRQOQ-UHFFFAOYSA-N anthrone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3CC2=C1 RJGDLRCDCYRQOQ-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 125000000051 benzyloxy group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])O* 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- YXVFYQXJAXKLAK-UHFFFAOYSA-N biphenyl-4-ol Chemical group C1=CC(O)=CC=C1C1=CC=CC=C1 YXVFYQXJAXKLAK-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
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- ITCAUAYQCALGGV-XTICBAGASA-M sodium;(1r,4ar,4br,10ar)-1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylate Chemical compound [Na+].C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C([O-])=O ITCAUAYQCALGGV-XTICBAGASA-M 0.000 description 1
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- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
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- 238000010998 test method Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
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- GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
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- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- KJIOQYGWTQBHNH-UHFFFAOYSA-N undecanol Chemical compound CCCCCCCCCCCO KJIOQYGWTQBHNH-UHFFFAOYSA-N 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/09—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/14—Water soluble or water swellable polymers, e.g. aqueous gels
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Polymerisation Methods In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2419764A DE2419764B2 (de) | 1974-04-24 | 1974-04-24 | Verfahren zur Herstellung von Dispersionen wasserlöslicher Polymerisate und deren Verwendung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1058788A true CA1058788A (en) | 1979-07-17 |
Family
ID=5913791
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA225,159A Expired CA1058788A (en) | 1974-04-24 | 1975-04-22 | Non-aqueous dispersions of water-soluble polymers and aqueous solutions therefrom |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US4029622A (en, 2012) |
| JP (1) | JPS5117927A (en, 2012) |
| AT (1) | AT341215B (en, 2012) |
| BE (1) | BE828164A (en, 2012) |
| CA (1) | CA1058788A (en, 2012) |
| CH (1) | CH597260A5 (en, 2012) |
| DE (1) | DE2419764B2 (en, 2012) |
| ES (1) | ES436906A1 (en, 2012) |
| FI (1) | FI751208A7 (en, 2012) |
| FR (1) | FR2268821B1 (en, 2012) |
| GB (1) | GB1499731A (en, 2012) |
| IT (1) | IT1035412B (en, 2012) |
| NL (1) | NL7504820A (en, 2012) |
| NO (1) | NO751288L (en, 2012) |
| SE (1) | SE7504706L (en, 2012) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1131098A (en) * | 1977-12-02 | 1982-09-07 | David B. Braun | Rapidly dissolved water-soluble polymer composition |
| DE2906215C2 (de) * | 1979-02-17 | 1982-04-01 | Bunawerke Hüls GmbH, 4370 Marl | Verfahren zur Herstellung einer ggf. Strecköle enthaltenden Kautschuk-Füllstoff-Mischung |
| US4212784A (en) * | 1979-05-04 | 1980-07-15 | Nalco Chemical Co. | Polymerization of water soluble polymers in water-in-oil latex form to produce emulsions containing high polymer solids levels and low oil levels |
| DE2925962A1 (de) * | 1979-06-27 | 1981-01-22 | Bayer Ag | Flutmittelzusatz fuer die tertiaere erdoelfoerderung |
| DE2926103A1 (de) * | 1979-06-28 | 1981-01-08 | Bayer Ag | Nichtwaessrige dispersionen wasserloeslicher polymerer |
| FR2507606B1 (fr) * | 1981-06-12 | 1985-11-15 | Hoechst France | Nouvelles dispersions stables, eau dans huile de polymeres cationiques hydrosolubles a base d'acrylate de dimethylaminoethyle salifie ou quaternise, leur procede de fabrication et leur application comme floculants |
| US4374216A (en) * | 1981-12-09 | 1983-02-15 | Celanese Corporation | Stable high solids water-in-oil slurry dispersion composition |
| DE3206730C1 (de) * | 1982-02-25 | 1983-05-19 | Chemische Fabrik Stockhausen GmbH, 4150 Krefeld | Verfahren zur Herstellung zustands- und wirkungsstabiler nicht-waessriger Dispersionen wasserloeslicher Polymerisate |
| GB8309275D0 (en) * | 1983-04-06 | 1983-05-11 | Allied Colloids Ltd | Dissolution of water soluble polymers in water |
| DE3484407D1 (de) * | 1983-05-17 | 1991-05-16 | Allied Colloids Ltd | Polymersuspensionen. |
| DE3426080C2 (de) * | 1984-07-14 | 1996-09-19 | Basf Ag | Verfahren zur Herstellung konzentrierter, stabiler Wasser-in-Öl-Polymeremulsionen von wasserlöslichen oder wasserquellbaren Polymerisaten |
| US4659771A (en) * | 1985-08-22 | 1987-04-21 | Hercules Incorporated | Polyacrylate dispersions |
| US4997582A (en) * | 1986-12-09 | 1991-03-05 | Phillips Petroleum Company | Compositions for acid treating subterranean formations |
| US5155156A (en) * | 1988-06-15 | 1992-10-13 | Scanley Clyde S | Finely divided water soluble polymers and method for the production thereof |
| DE4103969A1 (de) * | 1991-02-09 | 1992-08-13 | Basf Ag | Verfahren zur herstellung von feinteiligen, wasserloeslichen oder wasserquellbaren polymerisaten |
| CA2111297A1 (en) * | 1992-12-21 | 1994-06-22 | Calgon Corporation | Process for preparing novel high solids non-aqueous polymer compositions |
| CA2111293A1 (en) * | 1992-12-21 | 1994-06-22 | Wood E. Hunter | Process for preparing novel high solids non-aqueous polymer compositions |
| US5358611A (en) * | 1993-05-17 | 1994-10-25 | Rohm And Haas Company | Method of reducing impurities in aqueous monomer solutions |
| BR9509581A (pt) * | 1994-11-03 | 1997-12-23 | Hercules Inc | Eteres de celulose em dispersões de polimerização em emulsão |
| WO2005103091A1 (en) * | 2004-04-21 | 2005-11-03 | Ciba Specialty Chemicals Water Treatments Limited | Composition and method of preparing high solid emulsions |
| JP4866066B2 (ja) * | 2005-11-18 | 2012-02-01 | 花王株式会社 | 化粧料 |
| US8629192B2 (en) * | 2009-12-30 | 2014-01-14 | The Procter And Gamble Company | Method for the production of high internal phase emulsion foams using ultraviolet light |
| FR2992323B1 (fr) | 2012-06-25 | 2015-07-03 | Soc Dexploitation De Produits Pour Les Industries Chimiques Seppic | Nouveau latex inverse auto-inversible exempt de tensioactif, son utilisation comme agent epaississant dans une composition cosmetique |
| MX364227B (es) | 2012-11-14 | 2019-04-17 | Basf Se | Proceso para la produccion de petroleo terciario. |
| US9701890B2 (en) | 2012-11-14 | 2017-07-11 | Basf Se | Process for tertiary mineral oil production |
| US10619087B2 (en) | 2015-12-08 | 2020-04-14 | Chevron U.S.A. Inc. | Methods for hydrocarbon recovery |
| WO2017100344A1 (en) | 2015-12-08 | 2017-06-15 | Chevron U.S.A. Inc. | Methods for hydrocarbon recovery |
| WO2017100327A1 (en) | 2015-12-08 | 2017-06-15 | Kemira Oyj | Liquid polymer compositions |
| US11299409B2 (en) | 2015-12-08 | 2022-04-12 | Kemira Oyj | Polymer compositions and methods of use |
| JP2019507198A (ja) | 2015-12-08 | 2019-03-14 | ケミラ・オー・ウー・イィー | 逆エマルション組成物 |
| CA3046084A1 (en) | 2016-12-07 | 2018-06-14 | Chevron U.S.A. Inc. | Methods and systems for generating aqueous polymer solutions |
| AU2018294335A1 (en) | 2017-06-30 | 2020-01-30 | Kemira Oyj | High stability polymer compositions with poly(alkyl) acrylate compounds for enhanced oil recovery applications |
| BR112019028277B1 (pt) | 2017-06-30 | 2024-02-06 | Kemira Oyj | Composição de polímero líquida ou emulsão inversa |
| WO2019006369A1 (en) | 2017-06-30 | 2019-01-03 | Chevron U.S.A. | HIGH STABILITY POLYMER COMPOSITIONS FOR ASSISTED OIL RECOVERY APPLICATIONS |
| FR3096985B1 (fr) * | 2019-06-05 | 2021-05-14 | S N F Sa | Procede de preparation de polymeres structures sous forme de poudre par voie gel |
| WO2021175760A1 (en) | 2020-03-06 | 2021-09-10 | Basf Se | Method of fracturing subterranean formations |
| WO2021175757A1 (en) | 2020-03-06 | 2021-09-10 | Basf Se | Method of manufacturing an aqueous polyacrylamide premix |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2982749A (en) * | 1957-07-15 | 1961-05-02 | Dow Chemical Co | Inverse suspension polymerization of water soluble unsaturated monomers |
| US3284393A (en) * | 1959-11-04 | 1966-11-08 | Dow Chemical Co | Water-in-oil emulsion polymerization process for polymerizing watersoluble monomers |
| US3278506A (en) * | 1961-08-21 | 1966-10-11 | Nalco Chemical Co | Water-soluble polymers and copolymers |
| GB1084050A (en, 2012) * | 1963-11-18 | |||
| US3507840A (en) * | 1967-04-27 | 1970-04-21 | Nalco Chemical Co | Method of removing water from water-soluble polymers |
| US3826771A (en) * | 1973-01-11 | 1974-07-30 | Nalco Chemical Co | Stable high solids water-in-oil emulsions of water soluble polymers |
-
1974
- 1974-04-24 DE DE2419764A patent/DE2419764B2/de not_active Ceased
-
1975
- 1975-04-11 NO NO751288A patent/NO751288L/no unknown
- 1975-04-21 US US05/570,185 patent/US4029622A/en not_active Expired - Lifetime
- 1975-04-21 BE BE155593A patent/BE828164A/xx unknown
- 1975-04-21 GB GB16341/75A patent/GB1499731A/en not_active Expired
- 1975-04-22 CA CA225,159A patent/CA1058788A/en not_active Expired
- 1975-04-22 IT IT49233/75A patent/IT1035412B/it active
- 1975-04-22 FI FI751208A patent/FI751208A7/fi not_active Application Discontinuation
- 1975-04-22 AT AT306775A patent/AT341215B/de not_active IP Right Cessation
- 1975-04-23 JP JP50048731A patent/JPS5117927A/ja active Granted
- 1975-04-23 SE SE7504706A patent/SE7504706L/xx unknown
- 1975-04-23 CH CH516775A patent/CH597260A5/xx not_active IP Right Cessation
- 1975-04-23 NL NL7504820A patent/NL7504820A/xx not_active Application Discontinuation
- 1975-04-24 FR FR7512885A patent/FR2268821B1/fr not_active Expired
- 1975-04-24 ES ES436906A patent/ES436906A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL7504820A (nl) | 1975-10-28 |
| CH597260A5 (en, 2012) | 1978-03-31 |
| FR2268821A1 (en, 2012) | 1975-11-21 |
| AT341215B (de) | 1978-01-25 |
| DE2419764B2 (de) | 1979-12-06 |
| ES436906A1 (es) | 1977-04-01 |
| ATA306775A (de) | 1977-05-15 |
| JPS5117927A (en) | 1976-02-13 |
| BE828164A (fr) | 1975-10-21 |
| IT1035412B (it) | 1979-10-20 |
| SE7504706L (sv) | 1975-10-27 |
| GB1499731A (en) | 1978-02-01 |
| DE2419764A1 (de) | 1975-12-18 |
| FR2268821B1 (en, 2012) | 1979-10-05 |
| NO751288L (en, 2012) | 1975-10-27 |
| US4029622A (en) | 1977-06-14 |
| JPS5758370B2 (en, 2012) | 1982-12-09 |
| FI751208A7 (en, 2012) | 1975-10-25 |
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