DE2419764B2 - Verfahren zur Herstellung von Dispersionen wasserlöslicher Polymerisate und deren Verwendung - Google Patents
Verfahren zur Herstellung von Dispersionen wasserlöslicher Polymerisate und deren VerwendungInfo
- Publication number
- DE2419764B2 DE2419764B2 DE2419764A DE2419764A DE2419764B2 DE 2419764 B2 DE2419764 B2 DE 2419764B2 DE 2419764 A DE2419764 A DE 2419764A DE 2419764 A DE2419764 A DE 2419764A DE 2419764 B2 DE2419764 B2 DE 2419764B2
- Authority
- DE
- Germany
- Prior art keywords
- polymer
- water
- soluble
- emulsion
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
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- 238000000034 method Methods 0.000 title claims description 14
- 238000002360 preparation method Methods 0.000 title claims description 9
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- 229920000642 polymer Polymers 0.000 claims description 98
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- 239000000178 monomer Substances 0.000 claims description 20
- 239000007864 aqueous solution Substances 0.000 claims description 17
- 239000000080 wetting agent Substances 0.000 claims description 15
- 239000002245 particle Substances 0.000 claims description 13
- 238000006116 polymerization reaction Methods 0.000 claims description 12
- 239000007762 w/o emulsion Substances 0.000 claims description 7
- 238000003860 storage Methods 0.000 claims description 5
- 239000000839 emulsion Substances 0.000 description 29
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- 239000000243 solution Substances 0.000 description 18
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- 239000000203 mixture Substances 0.000 description 16
- 239000012071 phase Substances 0.000 description 15
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- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 5
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- 150000001447 alkali salts Chemical class 0.000 description 4
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
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- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 3
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- 239000011347 resin Substances 0.000 description 3
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- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
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- MSAHTMIQULFMRG-UHFFFAOYSA-N 1,2-diphenyl-2-propan-2-yloxyethanone Chemical compound C=1C=CC=CC=1C(OC(C)C)C(=O)C1=CC=CC=C1 MSAHTMIQULFMRG-UHFFFAOYSA-N 0.000 description 2
- KMNCBSZOIQAUFX-UHFFFAOYSA-N 2-ethoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OCC)C(=O)C1=CC=CC=C1 KMNCBSZOIQAUFX-UHFFFAOYSA-N 0.000 description 2
- VVBLNCFGVYUYGU-UHFFFAOYSA-N 4,4'-Bis(dimethylamino)benzophenone Chemical compound C1=CC(N(C)C)=CC=C1C(=O)C1=CC=C(N(C)C)C=C1 VVBLNCFGVYUYGU-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Substances CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 244000028419 Styrax benzoin Species 0.000 description 2
- 235000000126 Styrax benzoin Nutrition 0.000 description 2
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- 235000008411 Sumatra benzointree Nutrition 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 238000010533 azeotropic distillation Methods 0.000 description 2
- 229960002130 benzoin Drugs 0.000 description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
- 150000008366 benzophenones Chemical class 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 239000012024 dehydrating agents Substances 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 239000002421 finishing Substances 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 235000019382 gum benzoic Nutrition 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 150000007522 mineralic acids Chemical class 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 2
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- 235000005985 organic acids Nutrition 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
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- 239000000047 product Substances 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 239000001593 sorbitan monooleate Substances 0.000 description 2
- 229940035049 sorbitan monooleate Drugs 0.000 description 2
- 235000011069 sorbitan monooleate Nutrition 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- 239000001124 (E)-prop-1-ene-1,2,3-tricarboxylic acid Substances 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- POPBYCBXVLHSKO-UHFFFAOYSA-N 9,10-dioxoanthracene-1-carboxylic acid Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2C(=O)O POPBYCBXVLHSKO-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
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- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- MZVQCMJNVPIDEA-UHFFFAOYSA-N [CH2]CN(CC)CC Chemical group [CH2]CN(CC)CC MZVQCMJNVPIDEA-UHFFFAOYSA-N 0.000 description 1
- 229940091181 aconitic acid Drugs 0.000 description 1
- 150000003926 acrylamides Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000004103 aminoalkyl group Chemical group 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- RJGDLRCDCYRQOQ-UHFFFAOYSA-N anthrone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3CC2=C1 RJGDLRCDCYRQOQ-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- YXVFYQXJAXKLAK-UHFFFAOYSA-N biphenyl-4-ol Chemical group C1=CC(O)=CC=C1C1=CC=CC=C1 YXVFYQXJAXKLAK-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
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- 239000003054 catalyst Substances 0.000 description 1
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- GTZCVFVGUGFEME-IWQZZHSRSA-N cis-aconitic acid Chemical compound OC(=O)C\C(C(O)=O)=C\C(O)=O GTZCVFVGUGFEME-IWQZZHSRSA-N 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
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- 238000005345 coagulation Methods 0.000 description 1
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- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
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- LIXVMPBOGDCSRM-UHFFFAOYSA-N nonylbenzene Chemical class CCCCCCCCCC1=CC=CC=C1 LIXVMPBOGDCSRM-UHFFFAOYSA-N 0.000 description 1
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- 239000011734 sodium Substances 0.000 description 1
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- 238000012360 testing method Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
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- 238000012546 transfer Methods 0.000 description 1
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- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
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- 229910052724 xenon Inorganic materials 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/09—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/14—Water soluble or water swellable polymers, e.g. aqueous gels
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Polymerisation Methods In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (15)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2419764A DE2419764B2 (de) | 1974-04-24 | 1974-04-24 | Verfahren zur Herstellung von Dispersionen wasserlöslicher Polymerisate und deren Verwendung |
| NO751288A NO751288L (en, 2012) | 1974-04-24 | 1975-04-11 | |
| GB16341/75A GB1499731A (en) | 1974-04-24 | 1975-04-21 | Non-aqueous dispersions of water-soluble polymers derived from alpha,beta-mono-olefinically unsaturated water-soluble monomers |
| BE155593A BE828164A (fr) | 1974-04-24 | 1975-04-21 | Dispersions non aqueuses de polymeres derivant de monomeres solubles dans l'eau |
| US05/570,185 US4029622A (en) | 1974-04-24 | 1975-04-21 | Non-aqueous polymer dispersions of water-soluble monomers |
| FI751208A FI751208A7 (en, 2012) | 1974-04-24 | 1975-04-22 | |
| AT306775A AT341215B (de) | 1974-04-24 | 1975-04-22 | Verfahren zur herstellung stabiler, lagerfahiger, nichtwasseriger polymerdispersionen |
| IT49233/75A IT1035412B (it) | 1974-04-24 | 1975-04-22 | Dispensioni non acquose di poli meri e procedimento per produrre soluzioni di polimeri da esse |
| CA225,159A CA1058788A (en) | 1974-04-24 | 1975-04-22 | Non-aqueous dispersions of water-soluble polymers and aqueous solutions therefrom |
| CH516775A CH597260A5 (en, 2012) | 1974-04-24 | 1975-04-23 | |
| SE7504706A SE7504706L (sv) | 1974-04-24 | 1975-04-23 | Icke-vattenhaltiga polymerdispersioner, framstellda genom polymerisation av vattenlosliga monomerer. |
| JP50048731A JPS5117927A (en) | 1974-04-24 | 1975-04-23 | Jugotaino hisuiseibunsanbutsu |
| NL7504820A NL7504820A (nl) | 1974-04-24 | 1975-04-23 | Werkwijze voor het bereiden van geen water bevattende polymeerdispersies van in water oplosbare monomeren. |
| FR7512885A FR2268821B1 (en, 2012) | 1974-04-24 | 1975-04-24 | |
| ES436906A ES436906A1 (es) | 1974-04-24 | 1975-04-24 | Procedimiento para la obtencion de dispersiones no acuosas de polimeros hidrosolubles. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2419764A DE2419764B2 (de) | 1974-04-24 | 1974-04-24 | Verfahren zur Herstellung von Dispersionen wasserlöslicher Polymerisate und deren Verwendung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2419764A1 DE2419764A1 (de) | 1975-12-18 |
| DE2419764B2 true DE2419764B2 (de) | 1979-12-06 |
Family
ID=5913791
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2419764A Ceased DE2419764B2 (de) | 1974-04-24 | 1974-04-24 | Verfahren zur Herstellung von Dispersionen wasserlöslicher Polymerisate und deren Verwendung |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US4029622A (en, 2012) |
| JP (1) | JPS5117927A (en, 2012) |
| AT (1) | AT341215B (en, 2012) |
| BE (1) | BE828164A (en, 2012) |
| CA (1) | CA1058788A (en, 2012) |
| CH (1) | CH597260A5 (en, 2012) |
| DE (1) | DE2419764B2 (en, 2012) |
| ES (1) | ES436906A1 (en, 2012) |
| FI (1) | FI751208A7 (en, 2012) |
| FR (1) | FR2268821B1 (en, 2012) |
| GB (1) | GB1499731A (en, 2012) |
| IT (1) | IT1035412B (en, 2012) |
| NL (1) | NL7504820A (en, 2012) |
| NO (1) | NO751288L (en, 2012) |
| SE (1) | SE7504706L (en, 2012) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2926103A1 (de) * | 1979-06-28 | 1981-01-08 | Bayer Ag | Nichtwaessrige dispersionen wasserloeslicher polymerer |
| DE3426080A1 (de) * | 1984-07-14 | 1986-01-16 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung konzentrierter, stabiler wasser-in-oel-polymeremulsionen von wasserloeslichen oder wasserquellbaren polymerisaten |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1131098A (en) * | 1977-12-02 | 1982-09-07 | David B. Braun | Rapidly dissolved water-soluble polymer composition |
| DE2906215C2 (de) * | 1979-02-17 | 1982-04-01 | Bunawerke Hüls GmbH, 4370 Marl | Verfahren zur Herstellung einer ggf. Strecköle enthaltenden Kautschuk-Füllstoff-Mischung |
| US4212784A (en) * | 1979-05-04 | 1980-07-15 | Nalco Chemical Co. | Polymerization of water soluble polymers in water-in-oil latex form to produce emulsions containing high polymer solids levels and low oil levels |
| DE2925962A1 (de) * | 1979-06-27 | 1981-01-22 | Bayer Ag | Flutmittelzusatz fuer die tertiaere erdoelfoerderung |
| FR2507606B1 (fr) * | 1981-06-12 | 1985-11-15 | Hoechst France | Nouvelles dispersions stables, eau dans huile de polymeres cationiques hydrosolubles a base d'acrylate de dimethylaminoethyle salifie ou quaternise, leur procede de fabrication et leur application comme floculants |
| US4374216A (en) * | 1981-12-09 | 1983-02-15 | Celanese Corporation | Stable high solids water-in-oil slurry dispersion composition |
| DE3206730C1 (de) * | 1982-02-25 | 1983-05-19 | Chemische Fabrik Stockhausen GmbH, 4150 Krefeld | Verfahren zur Herstellung zustands- und wirkungsstabiler nicht-waessriger Dispersionen wasserloeslicher Polymerisate |
| GB8309275D0 (en) * | 1983-04-06 | 1983-05-11 | Allied Colloids Ltd | Dissolution of water soluble polymers in water |
| DE3484407D1 (de) * | 1983-05-17 | 1991-05-16 | Allied Colloids Ltd | Polymersuspensionen. |
| US4659771A (en) * | 1985-08-22 | 1987-04-21 | Hercules Incorporated | Polyacrylate dispersions |
| US4997582A (en) * | 1986-12-09 | 1991-03-05 | Phillips Petroleum Company | Compositions for acid treating subterranean formations |
| US5155156A (en) * | 1988-06-15 | 1992-10-13 | Scanley Clyde S | Finely divided water soluble polymers and method for the production thereof |
| DE4103969A1 (de) * | 1991-02-09 | 1992-08-13 | Basf Ag | Verfahren zur herstellung von feinteiligen, wasserloeslichen oder wasserquellbaren polymerisaten |
| CA2111293A1 (en) * | 1992-12-21 | 1994-06-22 | Wood E. Hunter | Process for preparing novel high solids non-aqueous polymer compositions |
| CA2111297A1 (en) * | 1992-12-21 | 1994-06-22 | Calgon Corporation | Process for preparing novel high solids non-aqueous polymer compositions |
| US5358611A (en) * | 1993-05-17 | 1994-10-25 | Rohm And Haas Company | Method of reducing impurities in aqueous monomer solutions |
| PL319938A1 (en) * | 1994-11-03 | 1997-09-01 | Hercules Inc | Cellulose ethers in emulsive polymerisation suspensions |
| WO2005103091A1 (en) * | 2004-04-21 | 2005-11-03 | Ciba Specialty Chemicals Water Treatments Limited | Composition and method of preparing high solid emulsions |
| JP4866066B2 (ja) * | 2005-11-18 | 2012-02-01 | 花王株式会社 | 化粧料 |
| US8629192B2 (en) * | 2009-12-30 | 2014-01-14 | The Procter And Gamble Company | Method for the production of high internal phase emulsion foams using ultraviolet light |
| FR2992323B1 (fr) | 2012-06-25 | 2015-07-03 | Soc Dexploitation De Produits Pour Les Industries Chimiques Seppic | Nouveau latex inverse auto-inversible exempt de tensioactif, son utilisation comme agent epaississant dans une composition cosmetique |
| US9701890B2 (en) | 2012-11-14 | 2017-07-11 | Basf Se | Process for tertiary mineral oil production |
| BR112015010706B1 (pt) | 2012-11-14 | 2022-05-17 | Basf Se | Processo para a produção de óleo mineral |
| MX2018007008A (es) | 2015-12-08 | 2018-08-15 | Chevron Usa Inc | Metodos para recuperacion de hidrocarburos. |
| CA2950810A1 (en) | 2015-12-08 | 2017-06-08 | Chevron U.S.A. Inc. | Methods for hydrocarbon recovery |
| JP2019507198A (ja) | 2015-12-08 | 2019-03-14 | ケミラ・オー・ウー・イィー | 逆エマルション組成物 |
| KR20180093964A (ko) | 2015-12-08 | 2018-08-22 | 케미라 오와이제이 | 액체 중합체 조성물 |
| EP3386927A4 (en) | 2015-12-08 | 2019-08-21 | Kemira Oyj | POLYMERIC COMPOSITIONS AND METHODS OF USE |
| BR112019011745B1 (pt) | 2016-12-07 | 2023-05-09 | Chevron U.S.A. Inc | Métodos para preparar uma solução polimérica aquosa e método para recuperar hidrocarboneto |
| MX2020000048A (es) | 2017-06-30 | 2020-09-21 | Chevron Usa Inc | Composiciones de polimeros de alta estabilidad para aplicaciones mejoradas de recuperacion de petroleo. |
| MX2020000171A (es) | 2017-06-30 | 2020-07-22 | Kemira Oyj | Composiciones polimericas de estabilidad alta con compuestos de poli (alquil) acrilato para aplicaciones potenciadas de recuperacion de petroleo. |
| US11879061B2 (en) | 2017-06-30 | 2024-01-23 | Kemira Oyj | High stability polymer compositions with siloxane polyether compounds for enhanced oil recovery applications |
| FR3096985B1 (fr) * | 2019-06-05 | 2021-05-14 | S N F Sa | Procede de preparation de polymeres structures sous forme de poudre par voie gel |
| WO2021175760A1 (en) | 2020-03-06 | 2021-09-10 | Basf Se | Method of fracturing subterranean formations |
| WO2021175757A1 (en) | 2020-03-06 | 2021-09-10 | Basf Se | Method of manufacturing an aqueous polyacrylamide premix |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2982749A (en) * | 1957-07-15 | 1961-05-02 | Dow Chemical Co | Inverse suspension polymerization of water soluble unsaturated monomers |
| US3284393A (en) * | 1959-11-04 | 1966-11-08 | Dow Chemical Co | Water-in-oil emulsion polymerization process for polymerizing watersoluble monomers |
| US3278506A (en) * | 1961-08-21 | 1966-10-11 | Nalco Chemical Co | Water-soluble polymers and copolymers |
| GB1084050A (en, 2012) * | 1963-11-18 | |||
| US3507840A (en) * | 1967-04-27 | 1970-04-21 | Nalco Chemical Co | Method of removing water from water-soluble polymers |
| US3826771A (en) * | 1973-01-11 | 1974-07-30 | Nalco Chemical Co | Stable high solids water-in-oil emulsions of water soluble polymers |
-
1974
- 1974-04-24 DE DE2419764A patent/DE2419764B2/de not_active Ceased
-
1975
- 1975-04-11 NO NO751288A patent/NO751288L/no unknown
- 1975-04-21 BE BE155593A patent/BE828164A/xx unknown
- 1975-04-21 US US05/570,185 patent/US4029622A/en not_active Expired - Lifetime
- 1975-04-21 GB GB16341/75A patent/GB1499731A/en not_active Expired
- 1975-04-22 AT AT306775A patent/AT341215B/de not_active IP Right Cessation
- 1975-04-22 IT IT49233/75A patent/IT1035412B/it active
- 1975-04-22 CA CA225,159A patent/CA1058788A/en not_active Expired
- 1975-04-22 FI FI751208A patent/FI751208A7/fi not_active Application Discontinuation
- 1975-04-23 CH CH516775A patent/CH597260A5/xx not_active IP Right Cessation
- 1975-04-23 NL NL7504820A patent/NL7504820A/xx not_active Application Discontinuation
- 1975-04-23 SE SE7504706A patent/SE7504706L/xx unknown
- 1975-04-23 JP JP50048731A patent/JPS5117927A/ja active Granted
- 1975-04-24 FR FR7512885A patent/FR2268821B1/fr not_active Expired
- 1975-04-24 ES ES436906A patent/ES436906A1/es not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2926103A1 (de) * | 1979-06-28 | 1981-01-08 | Bayer Ag | Nichtwaessrige dispersionen wasserloeslicher polymerer |
| DE3426080A1 (de) * | 1984-07-14 | 1986-01-16 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung konzentrierter, stabiler wasser-in-oel-polymeremulsionen von wasserloeslichen oder wasserquellbaren polymerisaten |
Also Published As
| Publication number | Publication date |
|---|---|
| US4029622A (en) | 1977-06-14 |
| DE2419764A1 (de) | 1975-12-18 |
| GB1499731A (en) | 1978-02-01 |
| SE7504706L (sv) | 1975-10-27 |
| JPS5758370B2 (en, 2012) | 1982-12-09 |
| AT341215B (de) | 1978-01-25 |
| ATA306775A (de) | 1977-05-15 |
| JPS5117927A (en) | 1976-02-13 |
| NO751288L (en, 2012) | 1975-10-27 |
| NL7504820A (nl) | 1975-10-28 |
| ES436906A1 (es) | 1977-04-01 |
| BE828164A (fr) | 1975-10-21 |
| FR2268821A1 (en, 2012) | 1975-11-21 |
| FI751208A7 (en, 2012) | 1975-10-25 |
| CH597260A5 (en, 2012) | 1978-03-31 |
| CA1058788A (en) | 1979-07-17 |
| IT1035412B (it) | 1979-10-20 |
| FR2268821B1 (en, 2012) | 1979-10-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8235 | Patent refused |