BRPI1004306B1 - Processo catalítico oxidativo para síntese de ácido lático - Google Patents

Processo catalítico oxidativo para síntese de ácido lático Download PDF

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Publication number
BRPI1004306B1
BRPI1004306B1 BRPI1004306-3A BRPI1004306A BRPI1004306B1 BR PI1004306 B1 BRPI1004306 B1 BR PI1004306B1 BR PI1004306 A BRPI1004306 A BR PI1004306A BR PI1004306 B1 BRPI1004306 B1 BR PI1004306B1
Authority
BR
Brazil
Prior art keywords
lactic acid
catalyst
range
reactor
reaction
Prior art date
Application number
BRPI1004306-3A
Other languages
English (en)
Portuguese (pt)
Inventor
André Fraga Marco
Mota De Albuquerque Elise
Amaral Candido Robert
Cunha Olivier Beta
Carvalho Chiapetta Simone
Barros Gaspar Alexandre
Gomes Junior Marlito
Galvão Siqueira Bernardo
Bezerra De Menezes Raphael
Maria Duarte De Farias Andrea
René Klotz Rabello Carlos
Original Assignee
Int - Instituto Nacional De Tecnologia
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Int - Instituto Nacional De Tecnologia filed Critical Int - Instituto Nacional De Tecnologia
Priority to BRPI1004306-3A priority Critical patent/BRPI1004306B1/pt
Priority to PCT/BR2011/000290 priority patent/WO2013023257A1/pt
Priority to EP11870840.3A priority patent/EP2610238A4/en
Priority to JP2013535209A priority patent/JP2014518540A/ja
Priority to US13/817,302 priority patent/US20140148616A1/en
Publication of BRPI1004306A2 publication Critical patent/BRPI1004306A2/pt
Priority to US14/148,963 priority patent/US20140121408A1/en
Publication of BRPI1004306B1 publication Critical patent/BRPI1004306B1/pt

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/617—500-1000 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/48—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/58—Platinum group metals with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/63—Platinum group metals with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/648—Vanadium, niobium or tantalum or polonium
    • B01J23/6484—Niobium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/068—Noble metals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
BRPI1004306-3A 2010-08-18 2010-08-18 Processo catalítico oxidativo para síntese de ácido lático BRPI1004306B1 (pt)

Priority Applications (6)

Application Number Priority Date Filing Date Title
BRPI1004306-3A BRPI1004306B1 (pt) 2010-08-18 2010-08-18 Processo catalítico oxidativo para síntese de ácido lático
PCT/BR2011/000290 WO2013023257A1 (pt) 2010-08-18 2011-08-18 Processo catalítico oxidativo para síntese de ácido lático
EP11870840.3A EP2610238A4 (en) 2010-08-18 2011-08-18 CATALYTIC OXIDATIVE PROCESS FOR THE SYNTHESIS OF LACTIC ACID
JP2013535209A JP2014518540A (ja) 2010-08-18 2011-08-18 乳酸を合成するための触媒による酸化方法
US13/817,302 US20140148616A1 (en) 2010-08-18 2011-08-18 Processo catalitico oxidativo para sintese de acido latico
US14/148,963 US20140121408A1 (en) 2010-08-18 2014-01-07 Oxidative catalytic process for the synthesis of lactic acid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
BRPI1004306-3A BRPI1004306B1 (pt) 2010-08-18 2010-08-18 Processo catalítico oxidativo para síntese de ácido lático

Publications (2)

Publication Number Publication Date
BRPI1004306A2 BRPI1004306A2 (pt) 2012-05-08
BRPI1004306B1 true BRPI1004306B1 (pt) 2018-04-17

Family

ID=46001907

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI1004306-3A BRPI1004306B1 (pt) 2010-08-18 2010-08-18 Processo catalítico oxidativo para síntese de ácido lático

Country Status (5)

Country Link
US (1) US20140148616A1 (enExample)
EP (1) EP2610238A4 (enExample)
JP (1) JP2014518540A (enExample)
BR (1) BRPI1004306B1 (enExample)
WO (1) WO2013023257A1 (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR102012027339B1 (pt) * 2012-10-25 2019-08-27 Instituto Nac De Tecnologia Int processo para síntese direta de ácido lático
KR102069833B1 (ko) 2016-04-12 2020-01-23 주식회사 엘지화학 아크릴산의 제조방법
CN107029799B (zh) * 2017-04-18 2020-01-24 江苏大学 一种包覆型磁性纳米Fe3O4负载钯催化剂在甘油制备乳酸中的应用
EP3453786A1 (en) 2017-09-08 2019-03-13 Nederlandse Organisatie voor toegepast- natuurwetenschappelijk onderzoek TNO Method for producing lactic acid
CN108404860B (zh) * 2018-05-18 2021-02-23 王顺方 一种无机重金属离子吸附材料的制备方法
CN111482184B (zh) * 2020-04-22 2023-03-21 江苏大学 一种Cu/Pd/Au三元复合金属催化剂及其制备方法和应用
CN115055201B (zh) * 2022-05-18 2024-08-23 汕尾职业技术学院 一种乙炔芳构化反应制备苯的催化剂及其制备和应用

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5128614B2 (enExample) * 1972-07-15 1976-08-20
GB8512230D0 (en) * 1985-05-14 1985-06-19 Shell Internationale Researche Preparation of carboxylic acid salt
GB9012813D0 (en) * 1990-06-08 1990-08-01 Bp Chem Int Ltd Production of hydroxy carboxylic compounds
DE4228487A1 (de) * 1991-08-30 1993-03-04 Kao Corp Verfahren zur herstellung einer eine carbonyl- und/oder carboxylgruppe aufweisenden verbindung
JP3276413B2 (ja) * 1991-08-30 2002-04-22 花王株式会社 カルボニル基及び／又はカルボキシル基を有する化合物の製造方法
CN100588641C (zh) 2008-02-02 2010-02-10 北京大学 一种利用甘油合成乳酸的方法
DE102008013474B4 (de) 2008-03-10 2013-08-08 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Katalytisches Verfahren zur Gewinnung von chemischen Grundstoffen aus nachwachsenden Rohstoffen

Also Published As

Publication number Publication date
EP2610238A1 (en) 2013-07-03
BRPI1004306A2 (pt) 2012-05-08
WO2013023257A1 (pt) 2013-02-21
JP2014518540A (ja) 2014-07-31
US20140148616A1 (en) 2014-05-29
WO2013023257A8 (pt) 2013-04-04
EP2610238A4 (en) 2014-08-27

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Legal Events

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B03A Publication of a patent application or of a certificate of addition of invention [chapter 3.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]