BRPI0910629A2 - processo para a fabricação de acroleína ou do ácido acrílico a partir da glicerina - Google Patents

processo para a fabricação de acroleína ou do ácido acrílico a partir da glicerina

Info

Publication number
BRPI0910629A2
BRPI0910629A2 BRPI0910629A BRPI0910629A BRPI0910629A2 BR PI0910629 A2 BRPI0910629 A2 BR PI0910629A2 BR PI0910629 A BRPI0910629 A BR PI0910629A BR PI0910629 A BRPI0910629 A BR PI0910629A BR PI0910629 A2 BRPI0910629 A2 BR PI0910629A2
Authority
BR
Brazil
Prior art keywords
acrolein
glycerine
manufacture
acrylic acid
acrylic
Prior art date
Application number
BRPI0910629A
Other languages
English (en)
Inventor
Jean-Luc Dubois
Kimito Okumura
Yasuhiro Magatani
Original Assignee
Arkema France
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema France filed Critical Arkema France
Publication of BRPI0910629A2 publication Critical patent/BRPI0910629A2/pt
Publication of BRPI0910629B1 publication Critical patent/BRPI0910629B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
BRPI0910629-4A 2008-04-16 2009-04-14 Process for preparing acrolein, process for preparing acrylic acid from glycerol, and using catalyst BRPI0910629B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
IBPCT/IB2008/000919 2008-04-16
PCT/IB2008/000919 WO2009127889A1 (en) 2008-04-16 2008-04-16 Process for manufacturing acrolein from glycerol
PCT/JP2009/057818 WO2009128555A2 (en) 2008-04-16 2009-04-14 Process for manufacturing acrolein or acrylic acid from glycerin

Publications (2)

Publication Number Publication Date
BRPI0910629A2 true BRPI0910629A2 (pt) 2015-09-22
BRPI0910629B1 BRPI0910629B1 (pt) 2018-01-16

Family

ID=39811522

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0910629-4A BRPI0910629B1 (pt) 2008-04-16 2009-04-14 Process for preparing acrolein, process for preparing acrylic acid from glycerol, and using catalyst

Country Status (12)

Country Link
US (1) US8252960B2 (pt)
EP (1) EP2265565B1 (pt)
JP (1) JP5512543B2 (pt)
KR (1) KR101818242B1 (pt)
CN (1) CN102066301B (pt)
BR (1) BRPI0910629B1 (pt)
ES (1) ES2393304T3 (pt)
MY (1) MY149709A (pt)
PL (1) PL2265565T3 (pt)
PT (1) PT2265565E (pt)
TW (1) TWI444361B (pt)
WO (2) WO2009127889A1 (pt)

Families Citing this family (43)

* Cited by examiner, † Cited by third party
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FR2939791B1 (fr) 2008-12-16 2011-01-14 Adisseo France Sas Procede de preparation d'acroleine a partir de glycerol ou de glycerine brute
EP2477736A1 (en) 2009-09-18 2012-07-25 Nippon Kayaku Kabushiki Kaisha Catalyst and process for preparing acrolein and/or acrylic acid by dehydration reaction of glycerin
US20130066100A1 (en) * 2009-10-15 2013-03-14 Nippon Kayaku Kabushiki Kaisha Process for preparing catalyst used in production of unsaturated aldehyde and/or unsaturated carboxylic acid by dehydration reaction of glycerin, and catalyst obtained
FR2954312B1 (fr) 2009-12-21 2012-02-10 Adisseo France Sas Procede de preparation d'acroleine par deshydratation catalytique de glycerol ou glycerine
FR2961507B1 (fr) 2010-06-17 2016-03-04 Adisseo France Sas Procede de preparation d'acroleine a partir de glycerol ou de glycerine
WO2012035540A1 (en) 2010-09-16 2012-03-22 Ganapati Dadasaheb Yadav Process for the production of acrolein and reusable catalyst thereof
CN102008970A (zh) * 2010-09-28 2011-04-13 上海华谊丙烯酸有限公司 一种磷钼杂多酸失活催化剂再生方法
FR2966456B1 (fr) 2010-10-26 2013-03-15 Adisseo France Sas Procede d'obtention d'acroleine par deshydratation catalytique de glycerol ou de glycerine
WO2012102411A2 (ja) 2011-01-28 2012-08-02 日本化薬株式会社 飽和アルデヒドを選択的に低減させる触媒と、その製造方法
WO2012101471A1 (en) 2011-01-28 2012-08-02 Arkema France Improved process for manufacturing acrolein/acrylic acid
WO2013008279A1 (en) 2011-07-14 2013-01-17 Nippon Kayaku Kabushiki Kaisha Process for preparing catalyst used in production of acrolein and/or acrylic acid and process for preparing acrolein and/or acrylic acid by dehydration reaction of glycerin
WO2013017904A1 (en) 2011-07-29 2013-02-07 Arkema France Improved process of dehydration reactions
BR112014001873A2 (pt) * 2011-07-29 2017-02-21 Nippon Kayaku Kk catalisador para preparação de acroleína e ácido acrílico por desidratação de glicerina, e seu processo de produção
US8981172B2 (en) 2011-09-16 2015-03-17 Eastman Chemical Company Catalytic dehydration of alcohols and ethers over a ternary mixed oxide
FR2989684B1 (fr) 2012-04-18 2014-10-31 Arkema France Procede de fabrication d'acroleine et/ou d'acide acrylique a partir de glycerol
CN102659540A (zh) * 2012-04-28 2012-09-12 江苏大学 一种杂多酸碱金属盐催化甘油液相脱水制备丙烯醛的方法
KR101436146B1 (ko) * 2012-06-19 2014-09-01 한국화학연구원 글리세롤로부터 아크롤레인을 제조하는데 사용되는 촉매계 및 이를 이용하여 아크롤레인을 제조하는 방법
FR2997398B1 (fr) * 2012-10-30 2014-11-21 Adisseo France Sas Procede de preparation de l’acroleine a partir de glycerol
CN103301879B (zh) * 2013-06-13 2015-06-10 江苏大学 负载型分子筛催化剂的制备方法及其应用
KR101616528B1 (ko) * 2013-07-16 2016-04-28 주식회사 엘지화학 글리세린 탈수반응용 촉매, 이의 제조 방법 및 아크롤레인의 제조 방법
WO2015034948A1 (en) 2013-09-03 2015-03-12 Myriant Corporation A process for manufacturing acrylic acid, acrylonitrile and 1,4-butanediol from 1,3-propanediol
WO2015046716A1 (ko) * 2013-09-30 2015-04-02 주식회사 엘지화학 글리세린 탈수반응용 촉매, 이의 제조 방법 및 아크롤레인의 제조 방법
KR101606191B1 (ko) * 2013-09-30 2016-03-24 주식회사 엘지화학 글리세린 탈수반응용 촉매, 이의 제조 방법 및 아크롤레인의 제조 방법
FR3017617B1 (fr) 2014-02-19 2016-02-12 Arkema France Procede de production d'acide acrylique bio-source
FR3019545B1 (fr) 2014-04-04 2016-03-11 Arkema France Procede de synthese directe de (meth)acroleine a partir d'ethers et/ou acetals
US9796648B2 (en) 2014-05-02 2017-10-24 University Of Tennessee Research Foundation Glycerol dehydration methods and products thereof
CN104387249B (zh) * 2014-10-30 2017-03-01 清华大学 丙烯醛制备方法
CN104745645A (zh) * 2015-02-11 2015-07-01 江南大学 一种生物转化丙烯醛合成丙烯酸的方法
US20160368861A1 (en) 2015-06-19 2016-12-22 Southern Research Institute Compositions and methods related to the production of acrylonitrile
CA2994446C (en) 2015-08-28 2021-01-12 The Procter & Gamble Company Catalysts for the dehydration of hydroxypropionic acid and its derivatives
JP6190023B1 (ja) * 2015-10-07 2017-08-30 日本化学工業株式会社 リン酸タングステン酸ジルコニウムの製造方法
WO2017061402A1 (ja) * 2015-10-07 2017-04-13 日本化学工業株式会社 リン酸タングステン酸ジルコニウムの製造方法
KR102052708B1 (ko) * 2015-12-22 2019-12-09 주식회사 엘지화학 글리세린 탈수 반응용 촉매, 이의 제조 방법 및 상기 촉매를 이용한 아크롤레인의 제조 방법
KR102044428B1 (ko) 2015-12-23 2019-12-02 주식회사 엘지화학 글리세린으로부터 아크릴산의 제조방법
CN107345948B (zh) * 2016-05-04 2019-07-05 中国石油天然气股份有限公司 一种液相混合物中不饱和醛含量的测定方法
US9708249B1 (en) * 2016-08-24 2017-07-18 Southern Research Institute Compositions and methods related to the production of acrylonitrile
WO2018152520A1 (en) * 2017-02-17 2018-08-23 Trahan David O System for sulfide treatment in oilfield systems
CN109305908B (zh) * 2017-07-28 2021-08-03 中国石油化工股份有限公司 甘油合成丙烯酸的方法
CN109304165B (zh) * 2017-07-28 2021-10-01 中国石油化工股份有限公司 甘油合成丙烯酸催化剂
CN109304164B (zh) * 2017-07-28 2021-08-03 中国石油化工股份有限公司 甘油一步法合成丙烯酸催化剂
CN109305909B (zh) * 2017-07-28 2021-08-03 中国石油化工股份有限公司 甘油一步法合成丙烯酸的方法
US11938465B2 (en) 2019-03-18 2024-03-26 Jiangnan University Coordination zirconium phosphotungstate catalyst and its application in catalytic hydrogenation of furfural
CN116196950B (zh) * 2023-02-16 2024-05-24 北华大学 一种双金属掺杂杂多酸催化剂的合成方法及在木质素转化中的应用

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US4366088A (en) * 1981-01-26 1982-12-28 Ashland Oil, Inc. Support for a phosphate-containing catalyst
FR2657792B1 (fr) 1990-02-07 1992-05-15 Norsolor Sa Systeme catalytique et son application a l'oxydeshydrogenation d'acides carboxyliques satures.
DE4238493C1 (de) * 1992-11-14 1994-04-21 Degussa Verfahren zur Herstellung von Acrolein und dessen Verwendung
DE19848208A1 (de) 1998-10-20 2000-04-27 Deg Engineering Gmbh Reaktor für die katalytische Umsetzung von Reaktionsmedien, insbesondere von gasförmigen Reaktionsmedien
DE10019381B4 (de) 2000-04-19 2006-05-18 Daun, Klaus-Dieter, Dipl.-Ing. Reaktor für die katalytische Umsetzung von Reaktionsmedien, insbesondere von gasförmigen Reaktionsmedien
US7268254B2 (en) * 2003-07-24 2007-09-11 Basf Aktiengesellschaft Preparation of (meth)acrolein and/or (meth)acrylic acid by heterogeneously catalyzed partial oxidation of C3 and/or C4 precursor compounds in a reactor having thermoplate modules
FR2882052B1 (fr) * 2005-02-15 2007-03-23 Arkema Sa Procede de deshydratation du glycerol en acroleine
FR2882053B1 (fr) * 2005-02-15 2007-03-23 Arkema Sa Procede de deshydratation du glycerol en acrolene
TWI438187B (zh) * 2005-02-28 2014-05-21 Evonik Degussa Gmbh 丙烯酸和基於可再生原料之吸水聚合物結構及二者之製備方法
EP1902006B1 (en) * 2005-07-06 2014-08-13 BP Chemicals Limited The dehydration of mixed alcohols
WO2007058221A1 (ja) * 2005-11-15 2007-05-24 Nippon Shokubai Co., Ltd. 多価アルコールの脱水方法
JP2008088149A (ja) * 2006-01-04 2008-04-17 Nippon Shokubai Co Ltd アクロレイン製造用触媒及びそれを用いたアクロレイン製造方法
JP4041513B2 (ja) * 2006-03-30 2008-01-30 株式会社日本触媒 グリセリン脱水用触媒、グリセリン脱水用触媒の製造方法、アクロレインの製造方法、およびアクロレイン誘導体の製造方法
MY176982A (en) * 2008-04-16 2020-08-31 Arkema France Catalyst for preparing acrolein or acrylic acid by dehydration reaction of glycerin and method for producing the same

Also Published As

Publication number Publication date
PT2265565E (pt) 2012-11-06
TWI444361B (zh) 2014-07-11
PL2265565T3 (pl) 2013-01-31
TW201006793A (en) 2010-02-16
JP2011518111A (ja) 2011-06-23
EP2265565A2 (en) 2010-12-29
KR20110004872A (ko) 2011-01-14
US20110160491A1 (en) 2011-06-30
US8252960B2 (en) 2012-08-28
WO2009127889A1 (en) 2009-10-22
KR101818242B1 (ko) 2018-02-21
WO2009128555A2 (en) 2009-10-22
CN102066301B (zh) 2014-12-17
EP2265565B1 (en) 2012-08-01
BRPI0910629B1 (pt) 2018-01-16
JP5512543B2 (ja) 2014-06-04
MY149709A (en) 2013-09-30
ES2393304T3 (es) 2012-12-20
CN102066301A (zh) 2011-05-18
WO2009128555A3 (en) 2010-03-11

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Legal Events

Date Code Title Description
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]
B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 10A ANUIDADE.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2510 DE 12-02-2019 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.