BRPI0706663A2 - método de produção de propileno, método de regeneração de catalisador, e catalisador sólido ácido - Google Patents
método de produção de propileno, método de regeneração de catalisador, e catalisador sólido ácido Download PDFInfo
- Publication number
- BRPI0706663A2 BRPI0706663A2 BRPI0706663-5A BRPI0706663A BRPI0706663A2 BR PI0706663 A2 BRPI0706663 A2 BR PI0706663A2 BR PI0706663 A BRPI0706663 A BR PI0706663A BR PI0706663 A2 BRPI0706663 A2 BR PI0706663A2
- Authority
- BR
- Brazil
- Prior art keywords
- catalyst
- propylene
- production method
- reaction
- solid
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 212
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title claims abstract description 136
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 title claims abstract description 131
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 70
- 239000011973 solid acid Substances 0.000 title claims abstract description 54
- 238000011069 regeneration method Methods 0.000 title claims abstract description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 125
- 238000006243 chemical reaction Methods 0.000 claims abstract description 119
- 239000011949 solid catalyst Substances 0.000 claims abstract description 32
- 239000002253 acid Substances 0.000 claims abstract description 26
- 239000011148 porous material Substances 0.000 claims abstract description 21
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000005336 cracking Methods 0.000 claims abstract description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000010438 heat treatment Methods 0.000 claims abstract description 8
- 239000001301 oxygen Substances 0.000 claims abstract description 8
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 8
- 239000001273 butane Substances 0.000 claims abstract description 6
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000006297 dehydration reaction Methods 0.000 claims description 61
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 59
- 239000005977 Ethylene Substances 0.000 claims description 59
- 230000018044 dehydration Effects 0.000 claims description 48
- 239000010457 zeolite Substances 0.000 claims description 21
- 230000015572 biosynthetic process Effects 0.000 claims description 20
- 229910052751 metal Inorganic materials 0.000 claims description 19
- 239000002184 metal Substances 0.000 claims description 19
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 18
- 229910021536 Zeolite Inorganic materials 0.000 claims description 17
- 150000002500 ions Chemical class 0.000 claims description 17
- 229910021645 metal ion Inorganic materials 0.000 claims description 17
- 150000002739 metals Chemical class 0.000 claims description 15
- 230000002378 acidificating effect Effects 0.000 claims description 12
- 229910019142 PO4 Inorganic materials 0.000 claims description 11
- 239000010452 phosphate Substances 0.000 claims description 10
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 9
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 7
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims description 6
- MPCVYAVDVXEPTK-UHFFFAOYSA-N butane Chemical compound CCC[CH2+] MPCVYAVDVXEPTK-UHFFFAOYSA-N 0.000 claims description 5
- YQHHCMVUMULAPZ-UHFFFAOYSA-N C[CH2+] Chemical compound C[CH2+] YQHHCMVUMULAPZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910001424 calcium ion Inorganic materials 0.000 claims description 4
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052783 alkali metal Inorganic materials 0.000 claims description 3
- 150000001340 alkali metals Chemical class 0.000 claims description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 3
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 3
- 238000003776 cleavage reaction Methods 0.000 claims description 3
- 238000005829 trimerization reaction Methods 0.000 claims description 3
- 238000011144 upstream manufacturing Methods 0.000 claims description 3
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims description 2
- 150000003013 phosphoric acid derivatives Chemical group 0.000 claims description 2
- 230000007017 scission Effects 0.000 claims description 2
- 235000021317 phosphate Nutrition 0.000 claims 2
- 239000000539 dimer Substances 0.000 claims 1
- 235000019441 ethanol Nutrition 0.000 description 55
- 208000005156 Dehydration Diseases 0.000 description 45
- 238000000034 method Methods 0.000 description 29
- 238000012360 testing method Methods 0.000 description 19
- 238000005755 formation reaction Methods 0.000 description 18
- 239000000571 coke Substances 0.000 description 15
- 239000012159 carrier gas Substances 0.000 description 11
- 239000007789 gas Substances 0.000 description 11
- 239000002994 raw material Substances 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 238000010586 diagram Methods 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- 239000002243 precursor Substances 0.000 description 9
- 239000011133 lead Substances 0.000 description 8
- 230000008929 regeneration Effects 0.000 description 8
- 239000007858 starting material Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 230000003197 catalytic effect Effects 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- -1 polypropylene Polymers 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
- 230000007246 mechanism Effects 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 230000036962 time dependent Effects 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 239000003377 acid catalyst Substances 0.000 description 4
- 125000004429 atom Chemical group 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- 238000000151 deposition Methods 0.000 description 4
- 238000013213 extrapolation Methods 0.000 description 4
- 230000037361 pathway Effects 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 230000001172 regenerating effect Effects 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 239000007806 chemical reaction intermediate Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000006471 dimerization reaction Methods 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000001307 helium Substances 0.000 description 2
- 229910052734 helium Inorganic materials 0.000 description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000000543 intermediate Substances 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 238000005649 metathesis reaction Methods 0.000 description 2
- 239000002808 molecular sieve Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
- 229910001415 sodium ion Inorganic materials 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 206010040007 Sense of oppression Diseases 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007850 degeneration Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- JYIMWRSJCRRYNK-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4] JYIMWRSJCRRYNK-UHFFFAOYSA-N 0.000 description 1
- XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- UPUANNBILBRCST-UHFFFAOYSA-N ethanol;ethene Chemical compound C=C.CCO UPUANNBILBRCST-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 229910001657 ferrierite group Inorganic materials 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 239000012213 gelatinous substance Substances 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- RVPVRDXYQKGNMQ-UHFFFAOYSA-N lead(2+) Chemical compound [Pb+2] RVPVRDXYQKGNMQ-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 125000004437 phosphorous atom Chemical class 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/40—Ethylene production
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006-012634 | 2006-01-20 | ||
| JP2006012634A JP5330635B2 (ja) | 2006-01-20 | 2006-01-20 | プロピレンの製造方法、触媒の再生方法、固体酸触媒 |
| PCT/IB2007/000191 WO2007083241A2 (en) | 2006-01-20 | 2007-01-18 | Production method for propylene, restoration method for catalyst, and solid acid catalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BRPI0706663A2 true BRPI0706663A2 (pt) | 2011-04-05 |
Family
ID=38120356
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0706663-5A BRPI0706663A2 (pt) | 2006-01-20 | 2007-01-18 | método de produção de propileno, método de regeneração de catalisador, e catalisador sólido ácido |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20100222203A1 (enExample) |
| EP (1) | EP1976813A2 (enExample) |
| JP (1) | JP5330635B2 (enExample) |
| BR (1) | BRPI0706663A2 (enExample) |
| WO (1) | WO2007083241A2 (enExample) |
Families Citing this family (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW200918487A (en) * | 2007-09-06 | 2009-05-01 | Asahi Kasei Chemicals Corp | Process for production of propylene |
| TW200918486A (en) | 2007-09-18 | 2009-05-01 | Asahi Kasei Chemicals Corp | Process for production of propylene |
| EP2108635A1 (en) | 2008-04-11 | 2009-10-14 | Total Petrochemicals Research Feluy | Process to make olefins from ethanol |
| CN101939276B (zh) * | 2008-02-07 | 2013-05-08 | 道达尔石油化学产品研究弗吕公司 | 由乙醇制造烯烃的方法 |
| US20110105815A1 (en) * | 2008-02-07 | 2011-05-05 | Total Petrochemicals Research Feluy | Process to Make Olefins from Ethanol |
| MX2010008723A (es) * | 2008-02-07 | 2010-11-30 | Total Petrochemicals Res Feluy | Deshidratacion de alcoholes en silicatos cristalinos. |
| EP2108637A1 (en) | 2008-04-11 | 2009-10-14 | Total Petrochemicals Research Feluy | Process to make olefins from ethanol. |
| JP5229882B2 (ja) * | 2008-07-04 | 2013-07-03 | 独立行政法人産業技術総合研究所 | エタノールからの炭素数３以上のオレフィン類の製造方法 |
| EP2196444A1 (en) | 2008-12-11 | 2010-06-16 | Total Petrochemicals Research Feluy | Process to make alpha olefins from ethanol |
| CN102361693A (zh) | 2009-01-23 | 2012-02-22 | 西格纳化学有限责任公司 | 使用纯相的、经煅烧的单位点及多位点多相催化剂对醇进行催化脱水 |
| JP5607024B2 (ja) * | 2009-03-02 | 2014-10-15 | 旭化成ケミカルズ株式会社 | プロピレンの製造方法 |
| JP5499918B2 (ja) * | 2009-06-05 | 2014-05-21 | 三菱化学株式会社 | 触媒の再生方法 |
| CN102470354A (zh) | 2009-08-11 | 2012-05-23 | 三菱化学株式会社 | 催化剂的制造方法 |
| JP5685870B2 (ja) * | 2009-09-14 | 2015-03-18 | 三菱化学株式会社 | プロピレンの製造方法 |
| WO2011135785A1 (en) | 2010-04-30 | 2011-11-03 | Toyota Jidosha Kabushiki Kaisha | Propylene production method |
| WO2011162717A1 (en) * | 2010-06-23 | 2011-12-29 | Agency For Science, Technology And Research | Method of producing alkenes by dehydration of a mixture of alcohols |
| JP2012045505A (ja) * | 2010-08-27 | 2012-03-08 | Idemitsu Kosan Co Ltd | 軽質オレフィン類製造用触媒、その製造方法及びそれを用いた軽質オレフィン類の製造方法 |
| JP5729150B2 (ja) * | 2011-06-08 | 2015-06-03 | トヨタ自動車株式会社 | Ｃ２−３オレフィンの製造方法及び製造装置 |
| WO2013004544A1 (en) | 2011-07-07 | 2013-01-10 | Ineos Europe Ag | Process and apparatus for producing olefins with heat transfer from steam cracking to alcohol dehydration process. |
| CA3092028C (en) | 2012-01-13 | 2022-08-30 | Lummus Technology Llc | Process for separating hydrocarbon compounds |
| US9670113B2 (en) | 2012-07-09 | 2017-06-06 | Siluria Technologies, Inc. | Natural gas processing and systems |
| US9598328B2 (en) | 2012-12-07 | 2017-03-21 | Siluria Technologies, Inc. | Integrated processes and systems for conversion of methane to multiple higher hydrocarbon products |
| WO2015081122A2 (en) | 2013-11-27 | 2015-06-04 | Siluria Technologies, Inc. | Reactors and systems for oxidative coupling of methane |
| CA3123783A1 (en) | 2014-01-08 | 2015-07-16 | Lummus Technology Llc | Ethylene-to-liquids systems and methods |
| US10377682B2 (en) | 2014-01-09 | 2019-08-13 | Siluria Technologies, Inc. | Reactors and systems for oxidative coupling of methane |
| EP3097068A4 (en) | 2014-01-09 | 2017-08-16 | Siluria Technologies, Inc. | Oxidative coupling of methane implementations for olefin production |
| JP2016098149A (ja) * | 2014-11-21 | 2016-05-30 | 三菱化学株式会社 | Ａｅｉ型ゼオライトの製造方法 |
| JP2016150931A (ja) * | 2015-02-19 | 2016-08-22 | 出光興産株式会社 | 軽質オレフィンの製造方法 |
| US9334204B1 (en) | 2015-03-17 | 2016-05-10 | Siluria Technologies, Inc. | Efficient oxidative coupling of methane processes and systems |
| US10793490B2 (en) | 2015-03-17 | 2020-10-06 | Lummus Technology Llc | Oxidative coupling of methane methods and systems |
| US20160289143A1 (en) | 2015-04-01 | 2016-10-06 | Siluria Technologies, Inc. | Advanced oxidative coupling of methane |
| US9328297B1 (en) | 2015-06-16 | 2016-05-03 | Siluria Technologies, Inc. | Ethylene-to-liquids systems and methods |
| WO2017065947A1 (en) | 2015-10-16 | 2017-04-20 | Siluria Technologies, Inc. | Separation methods and systems for oxidative coupling of methane |
| JP6600082B2 (ja) * | 2016-04-11 | 2019-10-30 | 旭化成株式会社 | 低級オレフィンの製造方法 |
| CA3250074A1 (en) | 2016-04-13 | 2025-02-24 | Lummus Technology Llc | Oxidative coupling of methane for olefin production |
| WO2018118105A1 (en) | 2016-12-19 | 2018-06-28 | Siluria Technologies, Inc. | Methods and systems for performing chemical separations |
| AU2018273238B2 (en) * | 2017-05-23 | 2022-02-10 | Lummus Technology Llc | Integration of oxidative coupling of methane processes |
| US10836689B2 (en) | 2017-07-07 | 2020-11-17 | Lummus Technology Llc | Systems and methods for the oxidative coupling of methane |
| CN118302400A (zh) | 2021-08-31 | 2024-07-05 | 鲁玛斯科技有限责任公司 | 用于进行甲烷氧化偶联的方法和系统 |
| JP2024051654A (ja) * | 2022-09-30 | 2024-04-11 | 旭化成株式会社 | エタノールの変換方法、炭化水素の製造方法、プロピレンの製造方法、芳香族化合物の製造方法、並びに、エタノールの変換装置 |
| CN119657213B (zh) * | 2023-09-21 | 2025-10-31 | 中国石油化工股份有限公司 | 一种合成生物质丙烯的催化剂及其制备方法和应用 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4499327A (en) * | 1982-10-04 | 1985-02-12 | Union Carbide Corporation | Production of light olefins |
| JPS6333342A (ja) * | 1986-07-29 | 1988-02-13 | Agency Of Ind Science & Technol | 合成ガスからのエチレンの製造法 |
| FR2740056B1 (fr) * | 1995-10-20 | 1997-12-05 | Inst Francais Du Petrole | Catalyseur supporte contenant du rhenium et de l'aluminium, procede de preparation et application a la metathese des olefines |
| US5962762A (en) * | 1995-12-13 | 1999-10-05 | Sun; Hsian-Ning | Use of transition metal containing small pore molecular sieve catalysts in oxygenate conversion |
| US6316683B1 (en) * | 1999-06-07 | 2001-11-13 | Exxonmobil Chemical Patents Inc. | Protecting catalytic activity of a SAPO molecular sieve |
| US6437208B1 (en) * | 1999-09-29 | 2002-08-20 | Exxonmobil Chemical Patents Inc. | Making an olefin product from an oxygenate |
| WO2005051872A1 (en) * | 2003-11-19 | 2005-06-09 | Exxonmobil Chemical Patents Inc. | Controlling the ratio of ethylene to propylene produced in an oxygenate to olefin conversion process |
| JP4826707B2 (ja) * | 2003-12-12 | 2011-11-30 | 三菱化学株式会社 | プロピレンの製造方法 |
| US7192987B2 (en) * | 2004-03-05 | 2007-03-20 | Exxonmobil Chemical Patents Inc. | Processes for making methanol streams and uses for the streams |
| US7405337B2 (en) * | 2004-09-21 | 2008-07-29 | Uop Llc | Conversion of oxygenate to propylene with selective hydrogen treatment of heavy olefin recycle stream |
-
2006
- 2006-01-20 JP JP2006012634A patent/JP5330635B2/ja not_active Expired - Fee Related
-
2007
- 2007-01-18 US US12/161,218 patent/US20100222203A1/en not_active Abandoned
- 2007-01-18 EP EP07700524A patent/EP1976813A2/en not_active Withdrawn
- 2007-01-18 WO PCT/IB2007/000191 patent/WO2007083241A2/en not_active Ceased
- 2007-01-18 BR BRPI0706663-5A patent/BRPI0706663A2/pt not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| WO2007083241A3 (en) | 2007-12-13 |
| US20100222203A1 (en) | 2010-09-02 |
| EP1976813A2 (en) | 2008-10-08 |
| JP2007191444A (ja) | 2007-08-02 |
| JP5330635B2 (ja) | 2013-10-30 |
| WO2007083241A2 (en) | 2007-07-26 |
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