BRPI0516282B1 - “artigo selecionado de embalagem, recipiente, laminado, invólucro de linguiça ou combinação dos mesmos e processo para formar a película” - Google Patents
“artigo selecionado de embalagem, recipiente, laminado, invólucro de linguiça ou combinação dos mesmos e processo para formar a película” Download PDFInfo
- Publication number
- BRPI0516282B1 BRPI0516282B1 BRPI0516282A BRPI0516282A BRPI0516282B1 BR PI0516282 B1 BRPI0516282 B1 BR PI0516282B1 BR PI0516282 A BRPI0516282 A BR PI0516282A BR PI0516282 A BRPI0516282 A BR PI0516282A BR PI0516282 B1 BRPI0516282 B1 BR PI0516282B1
- Authority
- BR
- Brazil
- Prior art keywords
- vinylidene chloride
- film
- acrylate
- polymer
- plasticizer
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 72
- 230000008569 process Effects 0.000 title claims abstract description 38
- 235000013580 sausages Nutrition 0.000 title claims abstract description 37
- 238000004806 packaging method and process Methods 0.000 title claims description 24
- 239000000203 mixture Substances 0.000 claims abstract description 114
- 229920000642 polymer Polymers 0.000 claims abstract description 109
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims abstract description 104
- 239000004014 plasticizer Substances 0.000 claims abstract description 92
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims abstract description 67
- 125000005250 alkyl acrylate group Chemical group 0.000 claims abstract description 51
- 239000002356 single layer Substances 0.000 claims abstract description 38
- 239000000178 monomer Substances 0.000 claims abstract description 34
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 23
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims abstract description 11
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920001577 copolymer Polymers 0.000 claims description 48
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 39
- 238000002425 crystallisation Methods 0.000 claims description 34
- 230000008025 crystallization Effects 0.000 claims description 34
- 238000006116 polymerization reaction Methods 0.000 claims description 29
- 230000035699 permeability Effects 0.000 claims description 23
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 22
- 239000001301 oxygen Substances 0.000 claims description 22
- 229910052760 oxygen Inorganic materials 0.000 claims description 22
- 238000010992 reflux Methods 0.000 claims description 21
- 230000009477 glass transition Effects 0.000 claims description 20
- 238000001816 cooling Methods 0.000 claims description 14
- 150000002148 esters Chemical class 0.000 claims description 14
- 239000004593 Epoxy Substances 0.000 claims description 13
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 12
- 125000005907 alkyl ester group Chemical group 0.000 claims description 10
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 9
- 239000005977 Ethylene Substances 0.000 claims description 9
- 239000012530 fluid Substances 0.000 claims description 9
- 239000004711 α-olefin Substances 0.000 claims description 7
- 239000004433 Thermoplastic polyurethane Substances 0.000 claims description 6
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 5
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims description 5
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 claims description 4
- 238000003303 reheating Methods 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- 238000000113 differential scanning calorimetry Methods 0.000 claims 3
- IYABWNGZIDDRAK-UHFFFAOYSA-N allene Chemical group C=C=C IYABWNGZIDDRAK-UHFFFAOYSA-N 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 12
- 239000010408 film Substances 0.000 description 159
- 238000001125 extrusion Methods 0.000 description 41
- 238000010438 heat treatment Methods 0.000 description 32
- 238000007789 sealing Methods 0.000 description 32
- 239000011347 resin Substances 0.000 description 31
- 229920005989 resin Polymers 0.000 description 31
- 239000000654 additive Substances 0.000 description 28
- 239000010410 layer Substances 0.000 description 27
- 230000004888 barrier function Effects 0.000 description 22
- 238000002156 mixing Methods 0.000 description 22
- 239000003549 soybean oil Substances 0.000 description 21
- 235000012424 soybean oil Nutrition 0.000 description 21
- 239000000463 material Substances 0.000 description 20
- 235000013305 food Nutrition 0.000 description 16
- -1 packaging Substances 0.000 description 16
- 238000010411 cooking Methods 0.000 description 11
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 10
- PYGXAGIECVVIOZ-UHFFFAOYSA-N Dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 description 10
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 9
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 8
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- 239000011521 glass Substances 0.000 description 8
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 8
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 8
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 8
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- 239000005033 polyvinylidene chloride Substances 0.000 description 8
- 230000000996 additive effect Effects 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 239000000725 suspension Substances 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 6
- 230000015556 catabolic process Effects 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 238000006731 degradation reaction Methods 0.000 description 6
- 238000011049 filling Methods 0.000 description 6
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 238000012549 training Methods 0.000 description 6
- LZFZQYNTEZSWCP-UHFFFAOYSA-N 2,6-dibutyl-4-methylphenol Chemical compound CCCCC1=CC(C)=CC(CCCC)=C1O LZFZQYNTEZSWCP-UHFFFAOYSA-N 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 229920001519 homopolymer Polymers 0.000 description 5
- 239000012188 paraffin wax Substances 0.000 description 5
- 235000019809 paraffin wax Nutrition 0.000 description 5
- 235000019271 petrolatum Nutrition 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000001993 wax Substances 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 229920000800 acrylic rubber Polymers 0.000 description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000011888 foil Substances 0.000 description 4
- 235000021388 linseed oil Nutrition 0.000 description 4
- 239000000944 linseed oil Substances 0.000 description 4
- 235000013372 meat Nutrition 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 4
- 229920000058 polyacrylate Polymers 0.000 description 4
- 238000012667 polymer degradation Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 230000002902 bimodal effect Effects 0.000 description 3
- 238000009529 body temperature measurement Methods 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 229920001903 high density polyethylene Polymers 0.000 description 3
- 239000004700 high-density polyethylene Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 238000003475 lamination Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 229940037312 stearamide Drugs 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 229920001897 terpolymer Polymers 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 230000008602 contraction Effects 0.000 description 2
- 230000001627 detrimental effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000010696 ester oil Substances 0.000 description 2
- 239000005043 ethylene-methyl acrylate Substances 0.000 description 2
- 238000007765 extrusion coating Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 235000021268 hot food Nutrition 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 235000019645 odor Nutrition 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000375 suspending agent Substances 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- QWQNFXDYOCUEER-UHFFFAOYSA-N 2,3-ditert-butyl-4-methylphenol Chemical compound CC1=CC=C(O)C(C(C)(C)C)=C1C(C)(C)C QWQNFXDYOCUEER-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- RPRPDTXKGSIXMD-UHFFFAOYSA-N Caproic acid n-butyl ester Natural products CCCCCC(=O)OCCCC RPRPDTXKGSIXMD-UHFFFAOYSA-N 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- 240000002129 Malva sylvestris Species 0.000 description 1
- 235000006770 Malva sylvestris Nutrition 0.000 description 1
- 239000004614 Process Aid Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 235000019486 Sunflower oil Nutrition 0.000 description 1
- 239000004164 Wax ester Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 235000013351 cheese Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001860 citric acid derivatives Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
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- 125000003700 epoxy group Chemical group 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
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- 239000004611 light stabiliser Substances 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 229940127554 medical product Drugs 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- MYSWGNHLJGOCPT-UHFFFAOYSA-N methyl prop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C=C MYSWGNHLJGOCPT-UHFFFAOYSA-N 0.000 description 1
- 230000001617 migratory effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 235000021485 packed food Nutrition 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
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- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 235000015277 pork Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical group CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
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- 150000003839 salts Chemical class 0.000 description 1
- 229940116351 sebacate Drugs 0.000 description 1
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000001542 size-exclusion chromatography Methods 0.000 description 1
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- 239000010409 thin film Substances 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
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- 235000019386 wax ester Nutrition 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
- B29C55/28—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of blown tubular films, e.g. by inflation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0016—Plasticisers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2027/00—Use of polyvinylhalogenides or derivatives thereof as moulding material
- B29K2027/08—PVDC, i.e. polyvinylidene chloride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2033/00—Use of polymers of unsaturated acids or derivatives thereof as moulding material
- B29K2033/04—Polymers of esters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/0005—Condition, form or state of moulded material or of the material to be shaped containing compounding ingredients
- B29K2105/0038—Plasticisers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/0085—Copolymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2023/00—Tubular articles
- B29L2023/001—Tubular films, sleeves
- B29L2023/002—Sausage casings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/08—Homopolymers or copolymers of vinylidene chloride
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1324—Flexible food casing [e.g., sausage type, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1334—Nonself-supporting tubular film or bag [e.g., pouch, envelope, packet, etc.]
- Y10T428/1345—Single layer [continuous layer]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/1379—Contains vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/1397—Single layer [continuous layer]
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
- Closures For Containers (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Bag Frames (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US61800304P | 2004-10-12 | 2004-10-12 | |
| US62005704P | 2004-10-19 | 2004-10-19 | |
| PCT/US2005/034284 WO2006044113A1 (en) | 2004-10-12 | 2005-09-26 | Plasticizer in alkyl acrylate vinylidene chloride polymer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0516282A BRPI0516282A (pt) | 2008-09-02 |
| BRPI0516282B1 true BRPI0516282B1 (pt) | 2016-11-29 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| BRPI0516282A BRPI0516282B1 (pt) | 2004-10-12 | 2005-09-26 | “artigo selecionado de embalagem, recipiente, laminado, invólucro de linguiça ou combinação dos mesmos e processo para formar a película” |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US7754300B2 (https=) |
| EP (1) | EP1802684B1 (https=) |
| JP (1) | JP2008516067A (https=) |
| CN (1) | CN101039989B (https=) |
| AU (1) | AU2005296152A1 (https=) |
| BR (1) | BRPI0516282B1 (https=) |
| CA (1) | CA2581147A1 (https=) |
| PL (1) | PL1802684T3 (https=) |
| RU (1) | RU2397183C2 (https=) |
| SG (1) | SG156694A1 (https=) |
| WO (1) | WO2006044113A1 (https=) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2476464C2 (ru) * | 2007-11-22 | 2013-02-27 | Солвей (Сосьете Аноним) | Композиция, по меньшей мере, одного винилиденхлоридного сополимера |
| EP2329065B1 (en) * | 2008-08-27 | 2012-05-16 | Dow Global Technologies LLC | Polyvinylidene chloride compositions and their use in monofilament structures |
| CN101664991B (zh) * | 2008-09-02 | 2015-03-25 | 富士胶片株式会社 | 用于制备膜的方法和光学膜 |
| EP2163570A1 (en) * | 2008-09-10 | 2010-03-17 | Rohm and Haas France SA | Urethane Arcrylic Blends |
| CN101580563B (zh) * | 2009-05-21 | 2011-01-05 | 浙江巨化股份有限公司电化厂 | 一种vdc/ma共聚pvdc组合物的制备方法 |
| US9828475B2 (en) * | 2009-11-20 | 2017-11-28 | Dow Global Technologies Llc | Printable monolayer polyvinylidene chloride structures |
| FR2957351B1 (fr) | 2010-03-10 | 2013-06-28 | Solvay | Composition a base de copolymere du chlorure de vinylidene |
| TWI523607B (zh) | 2010-04-15 | 2016-03-01 | 陶氏農業科學公司 | 使用含有聚二氯乙烯（ｐｖｄｃ）蒸氣障壁之多層薄膜的農用薰蒸技術 |
| CA2833603C (en) | 2011-05-04 | 2019-08-27 | Michael Ray Leaman | Improved polymeric composition for cement based substructures |
| EP2791218B1 (en) | 2011-12-12 | 2020-12-02 | SK Saran Americas LLC | Process of incorporating solid inorganic additives into solid polymers using a liquid dispersion |
| BR112015007257B1 (pt) * | 2012-10-05 | 2021-09-28 | Sk Saran Americas Llc | Composição e artigo |
| CN103059199B (zh) * | 2012-12-26 | 2015-12-23 | 海南聚能功能薄膜技术开发有限公司 | 水煮型专用pvdc胶乳及其制备方法和用途 |
| ES2688532T3 (es) | 2013-01-18 | 2018-11-05 | Basf Se | Composiciones de recubrimiento a base de dispersión acrílica |
| BR112016010111B1 (pt) * | 2013-11-11 | 2021-07-13 | Sk Saran Americas Llc | Processo para produzir um copolímero baseado em cloreto de vinilideno |
| CN106574094A (zh) * | 2014-08-15 | 2017-04-19 | 陶氏环球技术有限责任公司 | 包含偏二氯乙烯互聚物的组合物、由其制成的膜和包括所述膜的制品 |
| JP6913506B2 (ja) * | 2017-05-16 | 2021-08-04 | 株式会社クレハ | 塩化ビニリデン系樹脂フィルム及び塩化ビニリデン系樹脂組成物 |
| ES2962943T3 (es) * | 2018-01-16 | 2024-03-21 | Viscofan Sa | Tripa alimentaria con propiedades antifúngicas y procedimiento para su producción |
| CN114644798A (zh) * | 2020-12-18 | 2022-06-21 | Sk 新技术株式会社 | 用于制备具有改善的收缩率的聚偏二氯乙烯单层薄膜的组合物及包含该组合物的食品包装 |
| CN114044995A (zh) * | 2021-12-01 | 2022-02-15 | 郑州新生印务有限公司 | 一种pvdc高阻隔基材膜及其制备方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3007903A (en) | 1956-04-16 | 1961-11-07 | Dow Chemical Co | Continuous polymerization process |
| US2968651A (en) | 1957-02-08 | 1961-01-17 | Dow Chemical Co | Process for preparing normally crystalline vinylidene chloride polymers |
| US3879359A (en) | 1972-04-11 | 1975-04-22 | Dow Chemical Co | High vinylidene chloride polymer content coating resins and method of preparation |
| JPS6024812B2 (ja) | 1979-11-09 | 1985-06-14 | 呉羽化学工業株式会社 | 塩化ビニリデン系樹脂ケ−シング |
| JPS62267331A (ja) * | 1986-05-16 | 1987-11-20 | Asahi Chem Ind Co Ltd | 塩化ビニリデン系樹脂でできたストレツチ包装用フイルム |
| JPS62267332A (ja) * | 1986-05-16 | 1987-11-20 | Asahi Chem Ind Co Ltd | ラミネ−ト用塩化ビニリデン系樹脂延伸フイルム |
| JPS62275675A (ja) * | 1986-05-24 | 1987-11-30 | Asahi Chem Ind Co Ltd | 筒状包装体 |
| US5147594A (en) * | 1989-06-09 | 1992-09-15 | W. R. Grace & Co.-Conn. | Extruding vinylidene chloride copolymer flexible packaging film |
| US5002989A (en) * | 1989-09-01 | 1991-03-26 | The Dow Chemical Company | Formulation for extrudable vinylidene chloride copolymers having high barrier properties |
| EP0435788A3 (en) * | 1989-12-28 | 1992-05-27 | American National Can Company | Ma-pvdc formulations, films and structures which maintain high barrier properties after retorting |
| NZ244002A (en) | 1991-08-23 | 1996-03-26 | Grace W R & Co | Extrudable composition containing plasticiser, acrylate/styrene polymer and vinylidene chloride copolymer; multilayer polymeric films |
| JPH06312452A (ja) | 1993-04-30 | 1994-11-08 | Asahi Chem Ind Co Ltd | 常温流通食品用包装フィルム及びこれを用いた包装容器 |
| DK0627465T3 (da) * | 1993-06-03 | 1999-08-09 | Cryovac Inc | Barriereblanding og fødevareemballeringsfolie indeholdende blandingen. |
| US6291565B1 (en) * | 1994-05-19 | 2001-09-18 | The Dow Chemical Company | Food packaging film |
| US5679465A (en) * | 1995-10-03 | 1997-10-21 | W. R. Grace & Co.-Conn. | Vinylidene chloride composition and film with high thermal stability |
| US6045924A (en) | 1996-06-19 | 2000-04-04 | Cryovac, Inc. | Film from a vinylidene chloride copolymer containing blend |
| JP2002502901A (ja) | 1998-02-09 | 2002-01-29 | ハンツマン・インターナショナル・エルエルシー | 硬質熱可塑性ポリウレタンを含む組成物からのエラストマー |
| CN1305510A (zh) * | 1998-05-13 | 2001-07-25 | 陶氏化学公司 | 可挤出的偏二氯乙烯聚合物组合物 |
| DE19822387C1 (de) | 1998-05-19 | 1999-10-07 | Basf Ag | Mischungen, enthaltend thermoplastisches Polyurethan |
| CN1202142C (zh) | 1998-08-18 | 2005-05-18 | 陶氏环球技术公司 | 可挤出的阻透聚合物组合物、制备该组合物以及含有该组合物的单层或多层结构的方法 |
| US6323299B1 (en) | 1998-12-02 | 2001-11-27 | Kraton Polymers U.S. Llc | Method for producing mixed polyol thermoplastic polyurethane compositions |
| US20020014717A1 (en) * | 1999-03-31 | 2002-02-07 | Susan Marie Kling | Process for producing thermoplastic films by blown film extrusion and films produced thereby |
| US6294638B1 (en) | 1999-10-08 | 2001-09-25 | Bayer Corporation | Soft, transparent and processable thermoplastic polyurethane |
| US6713105B1 (en) | 2000-10-12 | 2004-03-30 | Cryovac, Inc. | Vinylidene chloride film having reduced protein adhesion |
-
2005
- 2005-09-26 CN CN2005800347726A patent/CN101039989B/zh not_active Expired - Lifetime
- 2005-09-26 SG SG200907321-4A patent/SG156694A1/en unknown
- 2005-09-26 JP JP2007536708A patent/JP2008516067A/ja active Pending
- 2005-09-26 AU AU2005296152A patent/AU2005296152A1/en not_active Abandoned
- 2005-09-26 CA CA002581147A patent/CA2581147A1/en not_active Abandoned
- 2005-09-26 WO PCT/US2005/034284 patent/WO2006044113A1/en not_active Ceased
- 2005-09-26 BR BRPI0516282A patent/BRPI0516282B1/pt not_active IP Right Cessation
- 2005-09-26 US US11/663,374 patent/US7754300B2/en active Active
- 2005-09-26 PL PL05800766T patent/PL1802684T3/pl unknown
- 2005-09-26 RU RU2007117700/02A patent/RU2397183C2/ru not_active IP Right Cessation
- 2005-09-26 EP EP05800766A patent/EP1802684B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CN101039989A (zh) | 2007-09-19 |
| RU2007117700A (ru) | 2008-11-20 |
| CN101039989B (zh) | 2010-06-09 |
| JP2008516067A (ja) | 2008-05-15 |
| PL1802684T3 (pl) | 2013-06-28 |
| AU2005296152A1 (en) | 2006-04-27 |
| CA2581147A1 (en) | 2006-04-27 |
| RU2397183C2 (ru) | 2010-08-20 |
| US20090123678A1 (en) | 2009-05-14 |
| EP1802684A1 (en) | 2007-07-04 |
| EP1802684B1 (en) | 2013-01-16 |
| SG156694A1 (en) | 2009-11-26 |
| US7754300B2 (en) | 2010-07-13 |
| BRPI0516282A (pt) | 2008-09-02 |
| WO2006044113A1 (en) | 2006-04-27 |
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| B08G | Application fees: restoration [chapter 8.7 patent gazette] | ||
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| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
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| B25D | Requested change of name of applicant approved | ||
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