BRPI0515603B1 - Método para estabilizar hidróxido de cobre (ii), hidróxido de cobre (ii) estabilizado e composição - Google Patents
Método para estabilizar hidróxido de cobre (ii), hidróxido de cobre (ii) estabilizado e composição Download PDFInfo
- Publication number
- BRPI0515603B1 BRPI0515603B1 BRPI0515603-3A BRPI0515603A BRPI0515603B1 BR PI0515603 B1 BRPI0515603 B1 BR PI0515603B1 BR PI0515603 A BRPI0515603 A BR PI0515603A BR PI0515603 B1 BRPI0515603 B1 BR PI0515603B1
- Authority
- BR
- Brazil
- Prior art keywords
- copper
- hydroxide
- water
- phosphate
- stabilized
- Prior art date
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- JJLJMEJHUUYSSY-UHFFFAOYSA-L copper(II) hydroxide Inorganic materials [OH-].[OH-].[Cu+2] JJLJMEJHUUYSSY-UHFFFAOYSA-L 0.000 title claims abstract description 252
- 238000000034 method Methods 0.000 title claims abstract description 119
- AEJIMXVJZFYIHN-UHFFFAOYSA-N copper;dihydrate Chemical compound O.O.[Cu] AEJIMXVJZFYIHN-UHFFFAOYSA-N 0.000 title claims abstract description 96
- 239000000203 mixture Substances 0.000 title claims abstract description 53
- 230000000087 stabilizing effect Effects 0.000 title claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 62
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 56
- 239000007787 solid Substances 0.000 claims abstract description 22
- 239000003085 diluting agent Substances 0.000 claims abstract description 21
- 239000007788 liquid Substances 0.000 claims abstract description 14
- 239000004094 surface-active agent Substances 0.000 claims abstract description 12
- 238000001035 drying Methods 0.000 claims abstract description 11
- 239000000843 powder Substances 0.000 claims description 29
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 26
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 16
- 239000010949 copper Substances 0.000 claims description 14
- 229910021529 ammonia Inorganic materials 0.000 claims description 13
- 229910052802 copper Inorganic materials 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 238000001704 evaporation Methods 0.000 claims description 3
- 230000001590 oxidative effect Effects 0.000 claims description 2
- 229910001956 copper hydroxide Inorganic materials 0.000 abstract description 57
- 239000005750 Copper hydroxide Substances 0.000 abstract description 56
- 229910019142 PO4 Inorganic materials 0.000 abstract description 50
- 239000010452 phosphate Substances 0.000 abstract description 47
- 235000021317 phosphate Nutrition 0.000 description 49
- 230000008569 process Effects 0.000 description 39
- 239000006188 syrup Substances 0.000 description 23
- 235000020357 syrup Nutrition 0.000 description 23
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 22
- -1 dusts Substances 0.000 description 22
- 238000009472 formulation Methods 0.000 description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- 239000000126 substance Substances 0.000 description 12
- 238000012360 testing method Methods 0.000 description 11
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 10
- 238000000354 decomposition reaction Methods 0.000 description 10
- 239000011734 sodium Substances 0.000 description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 9
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 9
- 235000019800 disodium phosphate Nutrition 0.000 description 9
- 229910000397 disodium phosphate Inorganic materials 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 230000000844 anti-bacterial effect Effects 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 230000006641 stabilisation Effects 0.000 description 8
- 238000011105 stabilization Methods 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 7
- 239000000417 fungicide Substances 0.000 description 7
- 239000008187 granular material Substances 0.000 description 7
- 229910052708 sodium Inorganic materials 0.000 description 7
- 239000007921 spray Substances 0.000 description 7
- 241000196324 Embryophyta Species 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 230000000855 fungicidal effect Effects 0.000 description 6
- 239000011521 glass Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- 229910000162 sodium phosphate Inorganic materials 0.000 description 6
- 239000001488 sodium phosphate Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 238000010998 test method Methods 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-L Phosphate ion(2-) Chemical compound OP([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-L 0.000 description 5
- 239000007900 aqueous suspension Substances 0.000 description 5
- 239000003899 bactericide agent Substances 0.000 description 5
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 5
- 229960004643 cupric oxide Drugs 0.000 description 5
- 238000001914 filtration Methods 0.000 description 5
- 238000000227 grinding Methods 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 235000011007 phosphoric acid Nutrition 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 239000004033 plastic Substances 0.000 description 5
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 4
- 239000004480 active ingredient Substances 0.000 description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 4
- 150000001879 copper Chemical class 0.000 description 4
- PTVDYARBVCBHSL-UHFFFAOYSA-N copper;hydrate Chemical compound O.[Cu] PTVDYARBVCBHSL-UHFFFAOYSA-N 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 239000000499 gel Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 235000019799 monosodium phosphate Nutrition 0.000 description 4
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- 235000011008 sodium phosphates Nutrition 0.000 description 4
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 4
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 4
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- 239000005751 Copper oxide Substances 0.000 description 3
- 239000005752 Copper oxychloride Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 230000002411 adverse Effects 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- HKMOPYJWSFRURD-UHFFFAOYSA-N chloro hypochlorite;copper Chemical compound [Cu].ClOCl HKMOPYJWSFRURD-UHFFFAOYSA-N 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 229910000431 copper oxide Inorganic materials 0.000 description 3
- 229910000365 copper sulfate Inorganic materials 0.000 description 3
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 description 3
- 235000019797 dipotassium phosphate Nutrition 0.000 description 3
- 229910000396 dipotassium phosphate Inorganic materials 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 239000010408 film Substances 0.000 description 3
- 239000002917 insecticide Substances 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 239000000575 pesticide Substances 0.000 description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 238000001694 spray drying Methods 0.000 description 3
- ZMYFCFLJBGAQRS-IAGOWNOFSA-N (2S,3R)-epoxiconazole Chemical compound C1=CC(F)=CC=C1[C@]1(CN2N=CN=C2)[C@@H](C=2C(=CC=CC=2)Cl)O1 ZMYFCFLJBGAQRS-IAGOWNOFSA-N 0.000 description 2
- PCCSBWNGDMYFCW-UHFFFAOYSA-N 5-methyl-5-(4-phenoxyphenyl)-3-(phenylamino)-1,3-oxazolidine-2,4-dione Chemical compound O=C1C(C)(C=2C=CC(OC=3C=CC=CC=3)=CC=2)OC(=O)N1NC1=CC=CC=C1 PCCSBWNGDMYFCW-UHFFFAOYSA-N 0.000 description 2
- 239000004254 Ammonium phosphate Substances 0.000 description 2
- 241000193830 Bacillus <bacterium> Species 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- 239000005772 Famoxadone Substances 0.000 description 2
- 229920000388 Polyphosphate Polymers 0.000 description 2
- 244000000231 Sesamum indicum Species 0.000 description 2
- 235000003434 Sesamum indicum Nutrition 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 239000005857 Trifloxystrobin Substances 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- RAOSIAYCXKBGFE-UHFFFAOYSA-K [Cu+3].[O-]P([O-])([O-])=O Chemical compound [Cu+3].[O-]P([O-])([O-])=O RAOSIAYCXKBGFE-UHFFFAOYSA-K 0.000 description 2
- 230000000895 acaricidal effect Effects 0.000 description 2
- 239000000642 acaricide Substances 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 229910000318 alkali metal phosphate Inorganic materials 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 2
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 2
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 2
- 235000019289 ammonium phosphates Nutrition 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 2
- 235000005822 corn Nutrition 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- AZSFNUJOCKMOGB-UHFFFAOYSA-K cyclotriphosphate(3-) Chemical compound [O-]P1(=O)OP([O-])(=O)OP([O-])(=O)O1 AZSFNUJOCKMOGB-UHFFFAOYSA-K 0.000 description 2
- HAORKNGNJCEJBX-UHFFFAOYSA-N cyprodinil Chemical compound N=1C(C)=CC(C2CC2)=NC=1NC1=CC=CC=C1 HAORKNGNJCEJBX-UHFFFAOYSA-N 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 2
- SKQUUKNCBWILCD-UHFFFAOYSA-J dicopper;chloride;trihydroxide Chemical compound [OH-].[OH-].[OH-].[Cl-].[Cu+2].[Cu+2] SKQUUKNCBWILCD-UHFFFAOYSA-J 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-M dihydrogenphosphate Chemical compound OP(O)([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-M 0.000 description 2
- FBOUIAKEJMZPQG-BLXFFLACSA-N diniconazole-M Chemical compound C1=NC=NN1/C([C@H](O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1Cl FBOUIAKEJMZPQG-BLXFFLACSA-N 0.000 description 2
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 2
- 235000011180 diphosphates Nutrition 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 2
- 208000015181 infectious disease Diseases 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000000543 intermediate Substances 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- 235000019837 monoammonium phosphate Nutrition 0.000 description 2
- 235000019796 monopotassium phosphate Nutrition 0.000 description 2
- 229910000402 monopotassium phosphate Inorganic materials 0.000 description 2
- 229910052901 montmorillonite Inorganic materials 0.000 description 2
- 230000001069 nematicidal effect Effects 0.000 description 2
- 239000005645 nematicide Substances 0.000 description 2
- YLYBTZIQSIBWLI-UHFFFAOYSA-N octyl acetate Chemical compound CCCCCCCCOC(C)=O YLYBTZIQSIBWLI-UHFFFAOYSA-N 0.000 description 2
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000001205 polyphosphate Substances 0.000 description 2
- 235000011176 polyphosphates Nutrition 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
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- 229910000160 potassium phosphate Inorganic materials 0.000 description 2
- 235000011009 potassium phosphates Nutrition 0.000 description 2
- TVLSRXXIMLFWEO-UHFFFAOYSA-N prochloraz Chemical compound C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl TVLSRXXIMLFWEO-UHFFFAOYSA-N 0.000 description 2
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Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G3/00—Compounds of copper
- C01G3/02—Oxides; Hydroxides
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
- A01N59/20—Copper
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
- C01P2006/64—Optical properties, e.g. expressed in CIELAB-values b* (yellow-blue axis)
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US60662204P | 2004-09-02 | 2004-09-02 | |
| US60/606,622 | 2004-09-02 | ||
| PCT/US2005/030986 WO2006028853A1 (en) | 2004-09-02 | 2005-08-30 | Method for stabilizing copper hydroxide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0515603A BRPI0515603A (pt) | 2008-07-29 |
| BRPI0515603B1 true BRPI0515603B1 (pt) | 2018-02-27 |
Family
ID=35455905
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0515603-3A BRPI0515603B1 (pt) | 2004-09-02 | 2005-08-30 | Método para estabilizar hidróxido de cobre (ii), hidróxido de cobre (ii) estabilizado e composição |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US7402296B2 (enExample) |
| EP (1) | EP1811847B1 (enExample) |
| JP (1) | JP5014134B2 (enExample) |
| KR (1) | KR101176681B1 (enExample) |
| CN (1) | CN101010008B (enExample) |
| AU (1) | AU2005282807B2 (enExample) |
| BR (1) | BRPI0515603B1 (enExample) |
| CA (1) | CA2577813C (enExample) |
| ES (1) | ES2573687T3 (enExample) |
| HU (1) | HUE028843T2 (enExample) |
| MX (1) | MX2007002183A (enExample) |
| PE (1) | PE20060940A1 (enExample) |
| PL (1) | PL1811847T3 (enExample) |
| RU (1) | RU2388696C2 (enExample) |
| SI (1) | SI1811847T1 (enExample) |
| UA (1) | UA96407C2 (enExample) |
| WO (1) | WO2006028853A1 (enExample) |
| ZA (1) | ZA200701572B (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| UA120848C2 (uk) * | 2013-11-26 | 2020-02-25 | Юпл Лімітед | Спосіб контролю іржі |
| US9271502B2 (en) | 2014-05-23 | 2016-03-01 | Robert Sabin | Potentiation of fixed coppers and other pesticides containing copper and supplementing plant nutrition |
| US9586871B2 (en) | 2014-05-23 | 2017-03-07 | Robert Sabin | Potentiation of fixed coppers and other pesticides containing copper and supplementing plant nutrition |
| US9247734B2 (en) | 2014-05-23 | 2016-02-02 | Robert Sabin | Potentiation of fixed coppers and other pesticides containing copper and supplementing plant nutrition |
| US9718739B2 (en) | 2014-05-23 | 2017-08-01 | Robert Sabin | Potentiation of fixed coppers and other pesticides containing copper and supplementing plant nutrition |
| US9487453B2 (en) | 2014-05-23 | 2016-11-08 | Robert Sabin | Potentiation of fixed coppers and other pesticides containing copper and supplementing plant nutrition |
| DE102016004627A1 (de) * | 2016-04-15 | 2017-10-19 | Spiess-Urania Chemicals Gmbh | Fungizides-Bakterizides Pflanzenschutzmittel |
| US20190152796A1 (en) * | 2016-04-20 | 2019-05-23 | Nanotheranostics Inc. | Preparation of Stable Copper(II) Hydroxide |
| CR20210476A (es) | 2017-03-07 | 2021-12-10 | Upl Ltd | COMBINACIONES FUNGICIDAS (Divisional 2019-0405) |
| CN114684847B (zh) * | 2020-12-25 | 2023-11-10 | 广州科城环保科技有限公司 | 氢氧化铜及其制备方法、应用和杀菌剂 |
| CN114516654B (zh) * | 2022-02-09 | 2024-02-27 | 广州科城环保科技有限公司 | 一种改性氢氧化铜的制备方法及其制备的改性氢氧化铜 |
| CN116161693A (zh) * | 2023-03-21 | 2023-05-26 | 珠海汇华环保技术有限公司 | 一种利用废线路板蚀刻液生产稳定氢氧化铜的方法 |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1800828A (en) | 1925-09-15 | 1931-04-14 | Cellocilk Company | Method of making copper hydroxide |
| US1867357A (en) | 1927-02-23 | 1932-07-12 | Furness Corp | Method of making coper hydroxide |
| US2525242A (en) | 1946-07-10 | 1950-10-10 | Lake Chemical Co | Manufacture of cupric hydrate |
| US2536096A (en) | 1947-09-02 | 1951-01-02 | Mountain Copper Company Ltd | Process for manufacture of copper compounds |
| USRE24324E (en) | 1951-05-05 | 1957-05-28 | Method of making stable cupric | |
| US2924505A (en) | 1956-01-03 | 1960-02-09 | Henry Bower Chemical Mfg Compa | Copper hydrate-phosphorus complex and process for making same |
| US3428731A (en) * | 1965-10-19 | 1969-02-18 | Mary A Furness | Stable dispersions of finely divided phosphate-process cupric hydroxide |
| US3628920A (en) | 1969-02-25 | 1971-12-21 | Cities Service Co | Preparation of a cupric hydroxide-phosphorous complex |
| US3635668A (en) | 1969-03-21 | 1972-01-18 | Cities Service Co | Copper hydrate production |
| US4490337A (en) | 1981-03-26 | 1984-12-25 | Kocide Chemical Corporation | Preparation of cupric hydroxide |
| DE3145997A1 (de) * | 1981-11-20 | 1983-06-01 | Norddeutsche Affinerie AG, 2000 Hamburg | Fungizides mittel |
| DE3145995A1 (de) * | 1981-11-20 | 1983-06-01 | Norddeutsche Affinerie AG, 2000 Hamburg | Verfahren zur herstellung von kupfer-ii-hydroxid |
| US4447336A (en) * | 1981-12-18 | 1984-05-08 | Monsanto Company | Stabilized galactomannan gum compositions |
| US4418056A (en) * | 1982-12-27 | 1983-11-29 | Cuproquim S.A. | Process for making cupric hydroxide |
| DE3342292A1 (de) * | 1983-11-23 | 1985-05-30 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur herstellung von basischem kupferphosphat mit heller eigenfarbe und einer mittleren korngroesse < 10 (my) |
| DE3419089A1 (de) * | 1984-05-23 | 1985-11-28 | Norddeutsche Affinerie AG, 2000 Hamburg | Verfahren zur herstellung von kupfer-ii-hydroxid |
| US4808406A (en) | 1984-12-05 | 1989-02-28 | Kocide Chemical Corporation | Preparation of cupric hydroxide compositions |
| DE3606920A1 (de) | 1986-03-04 | 1987-09-10 | Norddeutsche Affinerie | Verfahren zur herstellung von kupferhydroxid |
| CA2051716C (en) * | 1990-10-01 | 2002-05-14 | James H. Lefiles | Copper hydroxide dry flowable bactericide/fungicide and method of making and using same |
| ZA931681B (en) * | 1992-04-03 | 1993-12-07 | Griffin Corp | Copper complex bactericide/fungicide and method of making same |
| JP3612592B2 (ja) * | 1994-09-29 | 2005-01-19 | 大陽日酸株式会社 | 水酸化銅の安定化方法及び安定化された水酸化銅組成物 |
| DE19543803B4 (de) | 1995-11-24 | 2006-05-18 | Chemische Fabrik Budenheim Kg | Verfahren zur Herstellung von Kupfer(II)-hydroxid-phosphat |
| US6596246B2 (en) * | 2001-03-20 | 2003-07-22 | Dermet Sa De Cv | Process for producing stable cupric hydroxide and basic cupric salts |
| ITMI20010607A1 (it) | 2001-03-22 | 2002-09-22 | Caffaro Spa Ind Chim | Procedimento per la preparazione di idrossiso di rame e dispositivo utilizzato nel procedimento |
-
2005
- 2005-08-30 EP EP05794059.5A patent/EP1811847B1/en not_active Expired - Lifetime
- 2005-08-30 US US11/661,516 patent/US7402296B2/en not_active Expired - Lifetime
- 2005-08-30 UA UAA200702435A patent/UA96407C2/ru unknown
- 2005-08-30 CN CN2005800296527A patent/CN101010008B/zh not_active Expired - Lifetime
- 2005-08-30 BR BRPI0515603-3A patent/BRPI0515603B1/pt active IP Right Grant
- 2005-08-30 AU AU2005282807A patent/AU2005282807B2/en not_active Ceased
- 2005-08-30 WO PCT/US2005/030986 patent/WO2006028853A1/en not_active Ceased
- 2005-08-30 KR KR1020077007405A patent/KR101176681B1/ko not_active Expired - Fee Related
- 2005-08-30 ES ES05794059.5T patent/ES2573687T3/es not_active Expired - Lifetime
- 2005-08-30 PL PL05794059T patent/PL1811847T3/pl unknown
- 2005-08-30 JP JP2007530316A patent/JP5014134B2/ja not_active Expired - Lifetime
- 2005-08-30 MX MX2007002183A patent/MX2007002183A/es active IP Right Grant
- 2005-08-30 SI SI200532070A patent/SI1811847T1/sl unknown
- 2005-08-30 ZA ZA200701572A patent/ZA200701572B/xx unknown
- 2005-08-30 RU RU2007111936/15A patent/RU2388696C2/ru not_active IP Right Cessation
- 2005-08-30 HU HUE05794059A patent/HUE028843T2/en unknown
- 2005-08-30 CA CA2577813A patent/CA2577813C/en not_active Expired - Fee Related
- 2005-08-31 PE PE2005000997A patent/PE20060940A1/es not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| AU2005282807A1 (en) | 2006-03-16 |
| KR20070056136A (ko) | 2007-05-31 |
| CA2577813C (en) | 2014-01-21 |
| US20070270601A1 (en) | 2007-11-22 |
| CN101010008B (zh) | 2012-08-22 |
| KR101176681B1 (ko) | 2012-08-23 |
| RU2007111936A (ru) | 2008-10-10 |
| JP2008511536A (ja) | 2008-04-17 |
| MX2007002183A (es) | 2007-04-02 |
| EP1811847A1 (en) | 2007-08-01 |
| SI1811847T1 (sl) | 2016-07-29 |
| UA96407C2 (ru) | 2011-11-10 |
| RU2388696C2 (ru) | 2010-05-10 |
| BRPI0515603A (pt) | 2008-07-29 |
| JP5014134B2 (ja) | 2012-08-29 |
| HUE028843T2 (en) | 2017-01-30 |
| AU2005282807B2 (en) | 2011-01-27 |
| PE20060940A1 (es) | 2006-09-15 |
| EP1811847B1 (en) | 2016-03-02 |
| CN101010008A (zh) | 2007-08-01 |
| ZA200701572B (en) | 2008-08-27 |
| CA2577813A1 (en) | 2006-03-16 |
| ES2573687T3 (es) | 2016-06-09 |
| PL1811847T3 (pl) | 2016-08-31 |
| US7402296B2 (en) | 2008-07-22 |
| WO2006028853A1 (en) | 2006-03-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B06F | Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette] | ||
| B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
| B09B | Patent application refused [chapter 9.2 patent gazette] |
Free format text: INDEFIRO O PEDIDO DE ACORDO COM O(S) ARTIGO(S) 8 E 13 DA LPI |
|
| B12B | Appeal against refusal [chapter 12.2 patent gazette] | ||
| B25A | Requested transfer of rights approved |
Owner name: KOCIDE LLC (US) |
|
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |