BR9915221A - Conjunto de reformador de vapor de gás combustìvel hidrocarboneto, e, processo para formar um componente resistente à deposição de carbono - Google Patents

Conjunto de reformador de vapor de gás combustìvel hidrocarboneto, e, processo para formar um componente resistente à deposição de carbono

Info

Publication number
BR9915221A
BR9915221A BR9915221-5A BR9915221A BR9915221A BR 9915221 A BR9915221 A BR 9915221A BR 9915221 A BR9915221 A BR 9915221A BR 9915221 A BR9915221 A BR 9915221A
Authority
BR
Brazil
Prior art keywords
carbon
passages
reformer
walls
compaction
Prior art date
Application number
BR9915221-5A
Other languages
English (en)
Inventor
Roger R Leisieur
Herbert J Setzer
Original Assignee
Int Fuel Cells Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Int Fuel Cells Llc filed Critical Int Fuel Cells Llc
Publication of BR9915221A publication Critical patent/BR9915221A/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006—Controlling or regulating processes
    • B01J19/002—Avoiding undesirable reactions or side-effects, e.g. avoiding explosions, or improving the yield by suppressing side-reactions
    • B01J19/0026—Avoiding carbon deposits
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/02—Apparatus characterised by being constructed of material selected for its chemically-resistant properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
    • B01J8/0085—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction promoting uninterrupted fluid flow, e.g. by filtering out particles in front of the catalyst layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/062—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes being installed in a furnace
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Multi-step processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386—Catalytic partial combustion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00477—Controlling the temperature by thermal insulation means
    • B01J2208/00495—Controlling the temperature by thermal insulation means using insulating materials or refractories
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00504—Controlling the temperature by means of a burner
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00245—Avoiding undesirable reactions or side-effects
    • B01J2219/00247—Fouling of the reactor or the process equipment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/02—Apparatus characterised by their chemically-resistant properties
    • B01J2219/0204—Apparatus characterised by their chemically-resistant properties comprising coatings on the surfaces in direct contact with the reactive components
    • B01J2219/0218—Apparatus characterised by their chemically-resistant properties comprising coatings on the surfaces in direct contact with the reactive components of ceramic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/02—Apparatus characterised by their chemically-resistant properties
    • B01J2219/0204—Apparatus characterised by their chemically-resistant properties comprising coatings on the surfaces in direct contact with the reactive components
    • B01J2219/0236—Metal based
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/066—Integration with other chemical processes with fuel cells
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C01B2203/0816—Heating by flames
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0866—Methods of heating the process for making hydrogen or synthesis gas by combination of different heating methods
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1011—Packed bed of catalytic structures, e.g. particles, packing elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1023—Catalysts in the form of a monolith or honeycomb
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1035—Catalyst coated on equipment surfaces, e.g. reactor walls
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16—Controlling the process
    • C01B2203/1604—Starting up the process
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

''CONJUNTO DE REFORMADOR DE VAPOR DE GáS COMBUSTìVEL HIDROCARBONETO, E, PROCESSO PARA FORMAR UM COMPONENTE RESISTENTE à DEPOSIçãO DE CARBONO'' Um conjunto de reformador de gás combustivel para uso em usina de energia de célula de combustível inclui passagens de gás combustível (2), que contém uma compactação de alumina em partículas (12) em que uma mistura de corrente de vapor - combustível hidrocarboneto vaporizada é aquecida. As paredes (4) das passagens (2) tem um revestimento de alumina que protege as paredes (4) da corrosão. O revestimento (4) e compactação (12) são sobrepostos por uma camada de óxido de metal alcalino-terroso que limita o acúmulo de carbono sobre as superfícies das paredes (4) e evita o entupimento prematuro das passagens (2). A camada limitadora do acúmulo de carbono é formada em componentes das passagens do reformador por aplicação de uma suspensão à base d'água de compostos de metal alcalino-terroso para as superfícies da passagem do reformador, e então secagem da suspensão para solidificar a mesma. O material de compactação revestido (14) é operativo para converter qualquer carbono livre restante na corrente de gás para dióxido de carbono, ou monóxido de cabono, assim ainda limitando a deposição de carbono no conjunto.
BR9915221-5A 1998-11-10 1999-11-10 Conjunto de reformador de vapor de gás combustìvel hidrocarboneto, e, processo para formar um componente resistente à deposição de carbono BR9915221A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/190,855 US6258330B1 (en) 1998-11-10 1998-11-10 Inhibition of carbon deposition on fuel gas steam reformer walls
PCT/US1999/026558 WO2000029092A1 (en) 1998-11-10 1999-11-10 Inhibition of carbon deposition on fuel gas steam reformer walls

Publications (1)

Publication Number Publication Date
BR9915221A true BR9915221A (pt) 2001-07-24

Family

ID=22703076

Family Applications (2)

Application Number Title Priority Date Filing Date
BR9915221-5A BR9915221A (pt) 1998-11-10 1999-11-10 Conjunto de reformador de vapor de gás combustìvel hidrocarboneto, e, processo para formar um componente resistente à deposição de carbono
BR9915190-1A BR9915190A (pt) 1998-11-10 1999-11-10 Conjunto de reformador de gás combustìvel de hidrocarboneto

Family Applications After (1)

Application Number Title Priority Date Filing Date
BR9915190-1A BR9915190A (pt) 1998-11-10 1999-11-10 Conjunto de reformador de gás combustìvel de hidrocarboneto

Country Status (10)

Country Link
US (1) US6258330B1 (pt)
EP (2) EP1148939B1 (pt)
JP (2) JP2002529359A (pt)
KR (2) KR100599893B1 (pt)
CN (2) CN1170623C (pt)
AU (2) AU2148600A (pt)
BR (2) BR9915221A (pt)
DE (1) DE69941093D1 (pt)
ID (1) ID29948A (pt)
WO (2) WO2000029092A1 (pt)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020182132A1 (en) * 2000-10-04 2002-12-05 Lesieur Roger R. Fuel gas reformer assemblage
US6767376B1 (en) 2000-11-10 2004-07-27 Sofco-Efs Holdings, L.L.C. Selectively controllable modular auto-thermal reformer and method for same
US6759016B2 (en) * 2000-11-30 2004-07-06 Ballard Power Systems Inc. Compact multiple tube steam reformer
US20020108308A1 (en) * 2001-02-13 2002-08-15 Grieve Malcolm James Temperature/reaction management system for fuel reformer systems
US7025903B2 (en) 2001-02-15 2006-04-11 Delphi Technologies, Inc. Reformer system process
KR100918672B1 (ko) * 2001-10-03 2009-09-22 소니 가부시끼 가이샤 수지폐재로부터의 수소회수방법, 수지폐재로부터의 수소의제조방법 및 수지폐재로부터의 수소의 제조장치
AUPS087502A0 (en) * 2002-03-04 2002-03-28 Ceramic Fuel Cells Limited Solid oxide fuel cell
AU2003208176B2 (en) * 2002-03-04 2008-12-11 Chaozhou Three-Circle (Group) Co., Ltd. Solid oxide fuel cell
US20030188475A1 (en) * 2002-03-29 2003-10-09 Shabbir Ahmed Dynamic fuel processor with controlled declining temperatures
US20030223926A1 (en) * 2002-04-14 2003-12-04 Edlund David J. Steam reforming fuel processor, burner assembly, and methods of operating the same
EP1516663A3 (en) * 2002-04-14 2006-03-22 IdaTech, LLC. Steam reformer with burner
DE10313529A1 (de) * 2003-03-26 2004-10-14 Basf Ag Reaktor für Hochtemperaturreaktionen und Verwendung
DE10313527A1 (de) * 2003-03-26 2004-10-14 Basf Ag Verfahren zur Durchführung einer Hochtemperaturreaktion, Reaktor zur Durchführung des Verfahrens, Verfahren zum Scale-Up eines Reaktors sowie Verwendung
JP4998932B2 (ja) * 2004-12-21 2012-08-15 三菱化工機株式会社 メタノール改質装置
JP4799995B2 (ja) * 2005-10-20 2011-10-26 東京瓦斯株式会社 水蒸気改質器
KR100993468B1 (ko) 2009-02-05 2010-11-09 삼성에스디아이 주식회사 자동 점화형 자열 개질기 및 이를 구비하는 연료전지 시스템
JP5423180B2 (ja) * 2009-06-26 2014-02-19 パナソニック株式会社 水素生成装置
AT513931B1 (de) * 2013-02-04 2017-03-15 Avl List Gmbh Reformereinheit für Brennstoffzellensystem
ITMI20131564A1 (it) * 2013-09-23 2015-03-24 Rivoira S P A Sistema per la generazione di endogas
KR101518204B1 (ko) * 2015-01-30 2015-05-11 주식회사 한중엔시에스 예열기가 병합된 연료전지용 다채널 직립형 개질기
US11111143B2 (en) 2016-04-12 2021-09-07 Ohio State Innovation Foundation Chemical looping syngas production from carbonaceous fuels
NL2017215B1 (nl) * 2016-07-22 2018-01-30 Green Vision Holding Bv Apparaat voor het omzetten van een voedingsgas in productgas
EP3296255A1 (de) * 2016-09-14 2018-03-21 L'air Liquide, Société Anonyme Pour L'Étude Et L'exploitation Des Procédés Georges Claude Reformerrohr mit strukturiertem katalysator und verbessertem wärmehaushalt
CN109996760B (zh) 2016-10-25 2022-09-02 法国德西尼布 用于重整的催化剂管
AU2018312361B2 (en) 2017-07-31 2021-11-18 Ohio State Innovation Foundation Reactor system with unequal reactor assembly operating pressures
US11413574B2 (en) 2018-08-09 2022-08-16 Ohio State Innovation Foundation Systems, methods and materials for hydrogen sulfide conversion
AU2020271068A1 (en) 2019-04-09 2021-09-30 Ohio State Innovation Foundation Alkene generation using metal sulfide particles
EP3772372A1 (en) * 2019-08-05 2021-02-10 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Method for preventing fluidizazion in an upward-flow catalytic fixed bed reactor
CN112054227B (zh) * 2020-09-15 2021-11-26 上海捷氢科技有限公司 氢燃料电池车的氢气利用装置和方法

Family Cites Families (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB472629A (en) * 1936-01-24 1937-09-24 Distillers Co Yeast Ltd Improvements in process and apparatus for carrying out exothermic reactions
JPS496824Y1 (pt) * 1968-02-01 1974-02-18
US3760933A (en) * 1969-04-03 1973-09-25 Martin Marietta Corp Apparatus for rapidly coating surfaces with wet, particulate materials
DE2046324A1 (de) * 1970-09-19 1972-03-23 Berger, Heinz, 3470 Höxter Vorrichtung zur Vernichtung der schädlichen Anteile der Abgase von Verbrennungsmotoren
US3791143A (en) * 1971-11-10 1974-02-12 Engelhard Min & Chem Process and apparatus
CA1095696A (en) * 1976-12-22 1981-02-17 Richard F. Buswell Catalytic reaction apparatus
FR2374946A1 (fr) * 1976-12-22 1978-07-21 United Technologies Corp Appareil pour la mise en oeuvre de reactions catalytiques endothermiques
JPS5469105A (en) * 1977-11-10 1979-06-02 Genhiru Rubuobuichi Sutoriaru Thermal decomposition of hydrocarbons
JPS55158170A (en) * 1979-05-25 1980-12-09 Ngk Spark Plug Co High speed cutting ceramic tool
JPS5684789A (en) * 1979-12-13 1981-07-10 Toyo Eng Corp High-temperature treatment of hydrocarbon-containing material
JPS5736784A (en) * 1980-08-16 1982-02-27 Mitsui Toatsu Chem Inc Method of effectively utilizing exhaust gas in fuel-cell power generation device, and system for that
JPS5827787A (ja) * 1981-08-10 1983-02-18 Matsushita Electric Ind Co Ltd カ−ボン抑制方法
JPS58156350A (ja) * 1982-03-12 1983-09-17 Matsushita Electric Ind Co Ltd 排ガス浄化装置
US4451578A (en) * 1982-04-26 1984-05-29 United Technologies Corporation Iron oxide catalyst for steam reforming
JPS6183602A (ja) * 1984-09-29 1986-04-28 Toshiba Corp 改質装置
JPS62132995A (ja) * 1985-12-06 1987-06-16 Toyo Eng Corp 炭化水素高温処理用複層耐熱材料
GB8629497D0 (en) * 1986-12-10 1987-01-21 British Petroleum Co Plc Apparatus
US4820314A (en) * 1987-02-11 1989-04-11 International Fuel Cells Corporation Fuel cell power plant reformer
US5070072A (en) * 1987-05-04 1991-12-03 Eastman Kodak Company Conductive articles and processes for their preparation
JPH01315332A (ja) * 1988-06-14 1989-12-20 Mitsubishi Electric Corp 反応装置
JP2567055B2 (ja) * 1988-08-31 1996-12-25 株式会社東芝 燃料改質装置
JP2818171B2 (ja) * 1988-09-09 1998-10-30 東洋シーシーアイ株式会社 炭化水素の水蒸気改質反応用触媒及びその製造方法
US4900712A (en) 1988-09-30 1990-02-13 Prototech Company Catalytic washcoat and method of preparation of the same
JPH02132764A (ja) * 1988-11-14 1990-05-22 Hitachi Ltd 溶融炭酸塩型燃料電池
JPH0431243Y2 (pt) * 1989-03-02 1992-07-28
US5266281A (en) * 1989-09-16 1993-11-30 Xytel Technologies Partnership Catalytic reactor
ES2201223T3 (es) * 1991-03-08 2004-03-16 Chevron Phillips Chemical Company Lp Procedimiento de reformado en condiciones de bajo nivel de azufre.
US5805973A (en) * 1991-03-25 1998-09-08 General Electric Company Coated articles and method for the prevention of fuel thermal degradation deposits
JPH0593239A (ja) * 1991-09-30 1993-04-16 Kubota Corp 炭化水素類の熱分解・改質反応用管
JPH05245379A (ja) * 1992-03-03 1993-09-24 Tokyo Gas Co Ltd サイクリック式ガス化触媒及びその製造方法
US5888292A (en) * 1992-04-27 1999-03-30 Stellar Materials Bonded aggregate composition and binders for the same
US5254318A (en) * 1992-07-20 1993-10-19 Stone & Webster Engineering Corporation Lined reformer tubes for high pressure reformer reactors
JPH06111838A (ja) * 1992-09-30 1994-04-22 Toshiba Corp 改質器、改質システム、及び燃料電池システム
JP3322933B2 (ja) * 1993-03-05 2002-09-09 株式会社東芝 燃料改質器
JP3409894B2 (ja) * 1993-11-17 2003-05-26 トヨタ自動車株式会社 排ガス浄化用触媒及び排ガス浄化方法
GB9403198D0 (en) * 1994-02-19 1994-04-13 Rolls Royce Plc A solid oxide fuel cell stack
US5470360A (en) * 1994-03-10 1995-11-28 International Fuel Cells Corporation Fuel cell power plant reformer burner gas flow control system
JP3579155B2 (ja) * 1995-01-18 2004-10-20 東芝セラミックス株式会社 焼成用道具材
EP0728831B1 (de) * 1995-02-17 2000-07-12 Linde Aktiengesellschaft Verfahren zum Spalten von Kohlenwasserstoffen und Vorrichtung
US5846915A (en) * 1995-10-26 1998-12-08 Clearwater, Inc. Delayed breaking of gelled hydrocarbon fracturing fluid
US5733347A (en) * 1995-12-27 1998-03-31 International Fuel Cells Corp. Compact fuel gas reformer assemblage
JPH10306362A (ja) * 1997-04-28 1998-11-17 Nippon Steel Hardfacing Co Ltd 溶融金属に対する耐食性および耐剥離性が優れた複合溶射皮膜を形成した溶融金属浴用部材

Also Published As

Publication number Publication date
EP1148939B1 (en) 2009-07-08
WO2000029092A1 (en) 2000-05-25
EP1140322B1 (en) 2011-07-13
KR20010089430A (ko) 2001-10-06
KR100599893B1 (ko) 2006-07-13
AU2843000A (en) 2000-06-05
BR9915190A (pt) 2001-08-14
CN1120214C (zh) 2003-09-03
ID29948A (id) 2001-10-25
EP1148939A1 (en) 2001-10-31
JP2002529359A (ja) 2002-09-10
AU2148600A (en) 2000-05-29
US6258330B1 (en) 2001-07-10
KR20010110296A (ko) 2001-12-12
DE69941093D1 (de) 2009-08-20
CN1330570A (zh) 2002-01-09
EP1140322A4 (en) 2005-01-19
JP2002529895A (ja) 2002-09-10
EP1140322A1 (en) 2001-10-10
CN1170623C (zh) 2004-10-13
EP1148939A4 (en) 2005-01-19
WO2000027518A1 (en) 2000-05-18
CN1325319A (zh) 2001-12-05
KR100563182B1 (ko) 2006-03-27

Similar Documents

Publication Publication Date Title
BR9915221A (pt) Conjunto de reformador de vapor de gás combustìvel hidrocarboneto, e, processo para formar um componente resistente à deposição de carbono
BR9908509A (pt) Processo de obtenção de um substrato, substrato, e, dispersão em fase lìquida
DE602004002721T2 (de) Umweltsperrschicht für Substrate auf der Basis von Silizium
Stein et al. Erosion of thermal spray MCr–Cr3C2 cermet coatings
JP5383967B2 (ja) 環境腐食から保護する被覆ケイ素含有材料
US2978360A (en) Combustion catalysis
US6352790B1 (en) Substrate containing silicon and a barrier layer which functions as a protective/thermal barrier coating
BR9915231A (pt) Conjunto de reformador de vapor de gás combustìvel hidrocarboneto ou um aparelho de reação de oxidação parcial, e, processo para formar um componente resistente à deposição de carbono
PT1507020E (pt) Camada aplicada por projecção por plasma para superfícies de deslizamento de cilindros de blocos de motor e processo para a sua produção
PE12497A1 (es) Catalizador y proceso para la preparacion de hidrocarburos
EA200100066A1 (ru) Огнестойкая вспучивающаяся композиция для покрытия лигноцеллюлозных материалов
BR0103931A (pt) Processo para aplicação de um revestimento contendo alumìnio usando uma mistura de pasta fluida inorgânica
ES2191773T3 (es) Materiales a base de oxido, su procedimiento de preparacion y composiciones de catalizador que contienen estos materiales.
JP2007051364A5 (pt)
DE112008003502T5 (de) Verfahren zum Verbessern der Beständigkeit gegen CMAS-Infiltration
US20090293786A1 (en) Biomass Combustion Chamber and Refractory Components
BR9807714A (pt) Processo para a fabricação de corpos compostos de cerâmica-metal, corpos compostos de cerâmica-metal e seu emprego
Formanek et al. New generation of protective coatings intended for the power industry
KR20040018321A (ko) 복합체 열 보호 시스템 및 방법
Cardoso et al. Intumescent coatings using epoxy, alkyd, acrylic, silicone, and silicone–epoxy hybrid resins for steel fire protection
US4612240A (en) Thermally matched coatings for ceramic fiber insulation
CA2250555A1 (en) Spray coating powder material and high-temperature components coated therewith
Joseph et al. Hot corrosion behavior of Al2O3+ Sm2SrAl2O7 composite thermal barrier coatings
BR0102822A (pt) Revestimento anti-corrosão aplicado durante processo de jato percussão
EP0960308B1 (de) Gasturbinenanlage mit einem mit keramiksteinen ausgekleideten brennkammergehäuse

Legal Events

Date Code Title Description
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B25D Requested change of name of applicant approved

Owner name: UTC FUEL CELLS, LLC (US)

Free format text: ALTERADO DE: INTERNATIONAL FUEL CELLS, LLC

B25D Requested change of name of applicant approved

Owner name: UTC POWER CORPORATION (US)

Free format text: ALTERADO DE: UTC FUEL CELLS, LLC

B11D Dismissal acc. art. 38, par 2 of ipl - failure to pay fee after grant in time