BR9913133A - Processo para fabricação de acroleìna a partir depropileno por reação redox - Google Patents

Processo para fabricação de acroleìna a partir depropileno por reação redox

Info

Publication number
BR9913133A
BR9913133A BR9913133-1A BR9913133A BR9913133A BR 9913133 A BR9913133 A BR 9913133A BR 9913133 A BR9913133 A BR 9913133A BR 9913133 A BR9913133 A BR 9913133A
Authority
BR
Brazil
Prior art keywords
propylene
acrolein
solid
redox reaction
manufacture
Prior art date
Application number
BR9913133-1A
Other languages
English (en)
Inventor
Gilles Descat
Jean Pierre Schirmann
Michel Simon
Eric Etienne
Harlotte Pham
Original Assignee
Atochem Elf Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atochem Elf Sa filed Critical Atochem Elf Sa
Publication of BR9913133A publication Critical patent/BR9913133A/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Silicon Compounds (AREA)

Abstract

"PROCESSO PARA FABRICAçãO DE ACROLEINA A PARTIRDE PROPILENO POR REAçãO REDOX". A invenção se refereao uso de uma composição sólida de óxidos mistos de fórmula (I):Mo~ 12~Bi~ a~Fe~ b~Co~ c~Ni~ d~Si~ e~K~ f~Cr~ g~O~ x~com 0,5 <243> a <243>5; 0,1 <243> b <243> 10; 0,5 <243> c<243> 10; O <243> d <243> 10; O <243> e <243> 15; 0 <243> f<243> 1; 0,1 <243> g <243> 2; x é a quantidade de oxigênio ligadaa outros elementos e depende de seus estados de oxidação, naprodução de acroleína por oxidação de propileno, a ditacomposição sólida reage com propileno pela reação redox (1):sólido~ oxidado~ + propileno - sólido~ reduzido~ + acroleína. Ométodo de fabricação de acroleína consiste em reagir propilenogasoso com uma composição sólida de fórmula (I), numatemperatura na faixa de 200 a 600<198> C, sob pressão na faixade 1,01 x 10^ 4^ a 1,01 x 10^ 6^ Pa (0,1 a 10 atmosferas), e comum tempo de retenção de 0,01 segundo a 90 segundos, naausência de oxigênio molecular, produzindo deste modo a ditareação redox (1).
BR9913133-1A 1998-08-21 1999-08-18 Processo para fabricação de acroleìna a partir depropileno por reação redox BR9913133A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9810598A FR2782512B1 (fr) 1998-08-21 1998-08-21 Procede de fabrication d'acroleine a partir du propylene par reaction redox et utilisation d'une composition solide d'oxydes mixtes comme systeme redox dans la dite reaction
PCT/FR1999/002005 WO2000010955A1 (fr) 1998-08-21 1999-08-18 Procede de fabrication d'acroleine a partir du propylene par reaction redox

Publications (1)

Publication Number Publication Date
BR9913133A true BR9913133A (pt) 2001-10-30

Family

ID=9529807

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9913133-1A BR9913133A (pt) 1998-08-21 1999-08-18 Processo para fabricação de acroleìna a partir depropileno por reação redox

Country Status (11)

Country Link
EP (1) EP1105364A1 (pt)
JP (1) JP2002523386A (pt)
KR (1) KR20010079661A (pt)
CN (1) CN1313844A (pt)
AU (1) AU5173799A (pt)
BR (1) BR9913133A (pt)
CA (1) CA2351632A1 (pt)
FR (1) FR2782512B1 (pt)
ID (1) ID29798A (pt)
MX (1) MXPA01001869A (pt)
WO (1) WO2000010955A1 (pt)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103157483A (zh) * 2011-12-13 2013-06-19 上海华谊丙烯酸有限公司 复合氧化物催化剂及其制造方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4341717A (en) * 1973-03-08 1982-07-27 The Standard Oil Company Reactor for contacting gases and a particulate solid
JPS6133234A (ja) * 1984-07-23 1986-02-17 Mitsubishi Petrochem Co Ltd 触媒の再生法
DE4436385A1 (de) * 1994-10-12 1996-04-18 Basf Ag Verfahren zur katalytischen oxidativen Dehydrierung von Alkylaromaten und Paraffinen
FR2760008A1 (fr) * 1997-02-27 1998-08-28 Atochem Elf Sa Procede de fabrication d'acroleine a partir du propylene par reaction redox et utilisation d'une composition solide d'oxydes mixtes comme systeme redox dans ladite reaction
KR20010021832A (ko) * 1997-07-15 2001-03-15 아토피나 프로필렌에서 아크롤린으로의 개선된 증기상 산화

Also Published As

Publication number Publication date
FR2782512A1 (fr) 2000-02-25
EP1105364A1 (fr) 2001-06-13
KR20010079661A (ko) 2001-08-22
FR2782512B1 (fr) 2000-09-15
ID29798A (id) 2001-10-11
JP2002523386A (ja) 2002-07-30
MXPA01001869A (es) 2002-04-08
CA2351632A1 (fr) 2000-03-02
CN1313844A (zh) 2001-09-19
WO2000010955A1 (fr) 2000-03-02
AU5173799A (en) 2000-03-14

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Legal Events

Date Code Title Description
FA10 Dismissal: dismissal - article 33 of industrial property law
B11Y Definitive dismissal acc. article 33 of ipl - extension of time limit for request of examination expired