BR9801050B1 - óxidos metálicos coloidais apresentando grupos de isocianato bloqueados. - Google Patents

óxidos metálicos coloidais apresentando grupos de isocianato bloqueados.

Info

Publication number
BR9801050B1
BR9801050B1 BRPI9801050-6A BR9801050A BR9801050B1 BR 9801050 B1 BR9801050 B1 BR 9801050B1 BR 9801050 A BR9801050 A BR 9801050A BR 9801050 B1 BR9801050 B1 BR 9801050B1
Authority
BR
Brazil
Prior art keywords
isocyanate groups
metal oxides
blocked isocyanate
colloidal metal
colloidal
Prior art date
Application number
BRPI9801050-6A
Other languages
English (en)
Other versions
BR9801050A (pt
Inventor
Stefan Dr Groth
Claus Dr Kobusch
Lutz Dr Schmalstieg
Lothar Dr Puppe
Theodor Dr Engbert
Manfred Dr Bock
Gerhard Jonschker
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Publication of BR9801050A publication Critical patent/BR9801050A/pt
Publication of BR9801050B1 publication Critical patent/BR9801050B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3893—Low-molecular-weight compounds having heteroatoms other than oxygen containing silicon
    • C08G18/3895—Inorganic compounds, e.g. aqueous alkalimetalsilicate solutions; Organic derivatives thereof containing no direct silicon-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3897—Low-molecular-weight compounds having heteroatoms other than oxygen containing heteroatoms other than oxygen, halogens, nitrogen, sulfur, phosphorus or silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8003—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
    • C08G18/8054—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/38
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
    • C08G18/8083—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with compounds containing at least one heteroatom other than oxygen or nitrogen
    • C08G18/809—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with compounds containing at least one heteroatom other than oxygen or nitrogen containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
    • C08G18/8096—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with two or more compounds having only one group containing active hydrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Paints Or Removers (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Surface Treatment Of Glass (AREA)
BRPI9801050-6A 1997-04-14 1998-04-14 óxidos metálicos coloidais apresentando grupos de isocianato bloqueados. BR9801050B1 (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19715426A DE19715426A1 (de) 1997-04-14 1997-04-14 Blockierte Isocyanatgruppen aufweisende kolloidale Metalloxide

Publications (2)

Publication Number Publication Date
BR9801050A BR9801050A (pt) 1999-10-05
BR9801050B1 true BR9801050B1 (pt) 2009-01-13

Family

ID=7826395

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI9801050-6A BR9801050B1 (pt) 1997-04-14 1998-04-14 óxidos metálicos coloidais apresentando grupos de isocianato bloqueados.

Country Status (9)

Country Link
US (1) US5998504A (pt)
EP (1) EP0872500B1 (pt)
AT (1) ATE256156T1 (pt)
BR (1) BR9801050B1 (pt)
CA (1) CA2234280C (pt)
CZ (1) CZ293477B6 (pt)
DE (2) DE19715426A1 (pt)
ES (1) ES2212162T3 (pt)
PT (1) PT872500E (pt)

Families Citing this family (53)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6248225B1 (en) 1998-05-26 2001-06-19 Ppg Industries Ohio, Inc. Process for forming a two-coat electrodeposited composite coating the composite coating and chip resistant electrodeposited coating composition
US6423425B1 (en) 1998-05-26 2002-07-23 Ppg Industries Ohio, Inc. Article having a chip-resistant electrodeposited coating and a process for forming an electrodeposited coating
US6596401B1 (en) 1998-11-10 2003-07-22 C. R. Bard Inc. Silane copolymer compositions containing active agents
WO2000050523A1 (de) 1999-02-25 2000-08-31 Basf Coatings Ag Die verwendung von tricyclodecandimethanol zur herstellung von mehrschichtlackierungen
DE19909894A1 (de) 1999-03-06 2000-09-07 Basf Coatings Ag Sol-Gel-Überzug für einschichtige oder mehrschichtige Lackierungen
DE19910876C2 (de) * 1999-03-11 2003-07-17 Fraunhofer Ges Forschung Verfahren zur Herstellung einer bewitterungsbeständigen Beschichtung
DE19914896A1 (de) 1999-04-01 2000-10-05 Basf Coatings Ag Thermisch und/oder mit aktinischer Strahlung härtbarer wäßriger Beschichtungsstoff und seine Verwendung
WO2000075244A1 (de) 1999-06-02 2000-12-14 E.I. Du Pont De Nemours And Company Mit nanopartikeln modifizierte bindemittel für überzugsmittel und deren verwendung
DE19933098A1 (de) * 1999-07-15 2001-01-18 Herberts Gmbh & Co Kg Mit Nanopartikeln modifizierte Bindemittel für Überzugsmittel und deren Verwendung
JP2003506519A (ja) 1999-07-30 2003-02-18 ピーピージー インダストリーズ オハイオ，インコーポレイティド 改良ひっかき抵抗性を有するコーティング組成物、コート基材及びそれに関連する方法
CA2380408C (en) 1999-07-30 2008-04-22 Ppg Industries Ohio, Inc. Coating compositions having improved scratch resistance, coated substrates and methods related thereto
US6610777B1 (en) 1999-07-30 2003-08-26 Ppg Industries Ohio, Inc. Flexible coating compositions having improved scratch resistance, coated substrates and methods related thereto
JP4284020B2 (ja) 1999-07-30 2009-06-24 ピーピージー インダストリーズ オハイオ， インコーポレイテッド 改良ひっかき抵抗性を有する硬化コーティング、コート基材及びそれに関連する方法
US6623791B2 (en) 1999-07-30 2003-09-23 Ppg Industries Ohio, Inc. Coating compositions having improved adhesion, coated substrates and methods related thereto
DE19940858A1 (de) 1999-08-27 2001-03-01 Basf Coatings Ag Sol-Gel-Überzug für einschichtige oder mehrschichtige Lackierungen
JP2003508604A (ja) 1999-09-09 2003-03-04 クレアヴィス ゲゼルシャフト フュア テヒノロギー ウント イノヴェイション ミット ベシュレンクテル ハフツング 抗菌性添加剤
GB9923747D0 (en) * 1999-10-07 1999-12-08 Welding Inst Composite materials,their production and uses
US6716895B1 (en) 1999-12-15 2004-04-06 C.R. Bard, Inc. Polymer compositions containing colloids of silver salts
US7179849B2 (en) 1999-12-15 2007-02-20 C. R. Bard, Inc. Antimicrobial compositions containing colloids of oligodynamic metals
US6579539B2 (en) 1999-12-22 2003-06-17 C. R. Bard, Inc. Dual mode antimicrobial compositions
US6635341B1 (en) 2000-07-31 2003-10-21 Ppg Industries Ohio, Inc. Coating compositions comprising silyl blocked components, coating, coated substrates and methods related thereto
DE10053347A1 (de) * 2000-10-27 2002-05-08 Bayer Ag Formkörper und Beschichtungen auf Basis von silanfunktionellen Bindern
DE10060327A1 (de) 2000-12-04 2002-06-06 Degussa Vernetzer und wärmehärtende Lacke
EP1236765A1 (de) 2001-02-28 2002-09-04 hanse chemie GmbH Siliciumdioxiddispersion
ES2235076T3 (es) * 2001-09-11 2005-07-01 3M Innovative Properties Company Recubrimientos duros de nanocomposiciones resistentes a las manchas y metodos para fabricacion de los mismos.
AU2002357050A1 (en) 2001-12-03 2003-06-17 C.R. Bard, Inc. Microbe-resistant medical device, microbe-resistant polymeric coating and methods for producing same
DE10200929A1 (de) * 2002-01-12 2003-07-31 Basf Coatings Ag Polysiloxan-Sole, Verfahren zu ihrer Herstellung und ihre Verwendung
DE10200928A1 (de) * 2002-01-12 2003-09-25 Basf Coatings Ag Organische Dispersionen von oberflächenmodifizierten Nanopartikeln, Verfahren zu ihrer Herstellung und ihre Verwendung
DE10247359A1 (de) 2002-10-10 2004-04-29 Basf Coatings Ag Nanopartikel, Verfahren zur Modifizierung ihrer Oberfläche, Dispersion der Nanopartikel, Verfahren zu ihrer Herstellung und ihre Verwendung
DE10326538A1 (de) * 2003-06-12 2005-01-05 Institut für Neue Materialien Gemeinnützige GmbH Abriebfeste optische Schichten und Formkörper
DE102004008202A1 (de) * 2004-02-18 2005-09-01 Basf Ag Komposites aus Thermoplasten mit monodispers verteilten Füllstoffen
DE102004023071A1 (de) * 2004-05-11 2005-12-08 Basf Ag Pumpbare Tricyclodecandimethylol enthaltende Zusammensetzung
DE102004040264A1 (de) * 2004-08-19 2006-02-23 Consortium für elektrochemische Industrie GmbH Partikel mit geschützten Isocyanatgruppen
US20080145547A1 (en) 2004-10-12 2008-06-19 Sdc Technologies, Inc. Coating Compositions, Articles, And Methods Of Coating Articles
KR100926813B1 (ko) * 2005-02-10 2009-11-12 와커 헤미 아게 보호된 이소시아네이트기를 지닌 입자를 함유하는 바니시
DE502006002325D1 (de) * 2005-02-10 2009-01-22 Wacker Chemie Ag Lacke enthaltend partikel mit geschützten isocyanatgruppen
BRPI0609208B1 (pt) * 2005-03-11 2017-02-07 The Sherwin-Williams Company composição de revestimento curável resistente a arranhão e substrato revestido com um revestimento de múltiplas camadas decorativo e/ou protetor
DE102005034347A1 (de) * 2005-07-22 2007-01-25 Consortium für elektrochemische Industrie GmbH Lacke enthaltend Partikel
DE102005034350A1 (de) 2005-07-22 2007-01-25 Consortium für elektrochemische Industrie GmbH Lacke enthaltend Partikel
DE102005043073A1 (de) * 2005-09-10 2007-03-15 Basf Coatings Ag Thermoplastische Nanopartikel, Verfahren zu ihrer Herstellung und ihre Verwendung
TWI357436B (en) * 2007-08-31 2012-02-01 Ind Tech Res Inst Multilayer fire-resistant material
AU2006341424A1 (en) * 2006-03-31 2007-10-11 Sdc Technologies, Inc. Coating compositions, articles, and methods of coating articles
DE102006053156A1 (de) * 2006-11-10 2008-05-15 Wacker Chemie Ag Zusammensetzungen enthaltend Phosphonat-funktionelle Partikel
DE102006054289A1 (de) * 2006-11-17 2008-05-21 Bayer Materialscience Ag Nanopartikelmodifizierte Polyisocyanate
US8088940B2 (en) * 2007-03-30 2012-01-03 Momentive Performance Materials Inc. Hydrolyzable silanes of low VOC-generating potential and resinous compositions containing same
EP2058349A1 (de) * 2007-11-08 2009-05-13 Bayer MaterialScience AG Nanopartikelmodifizierte Polyisocyanate
DE102008020440A1 (de) 2008-04-23 2009-10-29 Merck Patent Gmbh Reaktiv oberflächenmodifizierte Partikel
EP2119736A1 (de) 2008-05-16 2009-11-18 Bayer MaterialScience AG Stabile nanopartikelhaltige Polyisocyanate
US8512464B2 (en) * 2009-12-02 2013-08-20 3M Innovative Properties Company Functionalized zirconia nanoparticles and high index films made therefrom
DE102011006674A1 (de) 2011-04-01 2012-10-04 Bayer Materialscience Aktiengesellschaft Polymere Nanopartikel und Beschichtungsmittel mit polymeren Nanopartikel
DE102015200277B4 (de) * 2015-01-12 2019-10-10 Semperit Ag Holding Verwendung eines Haftvermittler zur stoffschlüssigen Verbindung eines polymeren organischen Werkstoffes mit einem anorganischen Substrat und Verfahren zur stoffschlüssigen Verbindung eines polymeren organischen Werkstoffes mit einem anorganischen Substrat unter Verwendung eines Haftvermittlers
EP3715396A1 (de) * 2019-03-26 2020-09-30 PolyU GmbH Zusammensetzung und verfahren zur herstellung silylierter polymere und deren verwendung
CN114699799B (zh) * 2022-03-03 2023-06-23 江苏汉德科技有限公司 一种具有离子交换特征的氨基甲酸酯色谱填料的制备方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3790527A (en) 1972-07-21 1974-02-05 Gen Electric Flexible tack free silicone resins
US3887514A (en) 1974-01-02 1975-06-03 Gen Electric Bodied organopolysiloxanes and process therefor
US4006271A (en) 1976-01-28 1977-02-01 Itek Corporation Abrasion resistant coating for polycarbonate substrates
US4153768A (en) * 1976-03-04 1979-05-08 Blount David H Organic hydroxy silicates utilized as curing agents for polyurethane prepolymers
US4243720A (en) 1978-11-01 1981-01-06 General Electric Company Silicone coated abrasion resistant polycarbonate article
US4476281A (en) * 1978-11-30 1984-10-09 General Electric Company Silicone resin coating composition
US4278804A (en) 1980-05-30 1981-07-14 General Electric Company Ultraviolet light absorbing agents and compositions and articles containing same
US4419405A (en) 1981-01-15 1983-12-06 General Electric Company Ultraviolet light absorbing agents and compositions and articles containing same
US4624870A (en) 1984-11-14 1986-11-25 General Electric Company Sodium free silicone resin coating compositions
US4680232A (en) 1986-01-02 1987-07-14 General Electric Company Abrasion and UV resistant coating compositions
JPS6411154A (en) * 1987-07-06 1989-01-13 Mitsui Toatsu Chemicals Thixotropic polyurethane polymer composition
US5270352A (en) * 1989-07-05 1993-12-14 Basf Corporation Surface-modified micaceous particulates having improved dispersibility in aqueous media
US5013770A (en) * 1989-07-27 1991-05-07 Basf Corporation Cross-linkable surface-modified micaceous particulates and coating compositions containing the same
JP2657257B2 (ja) * 1989-10-13 1997-09-24 信越化学工業 株式会社 低着色性のプライマー組成物

Also Published As

Publication number Publication date
PT872500E (pt) 2004-04-30
EP0872500B1 (de) 2003-12-10
CZ111098A3 (cs) 1998-11-11
CA2234280C (en) 2007-07-03
CA2234280A1 (en) 1998-10-14
BR9801050A (pt) 1999-10-05
CZ293477B6 (cs) 2004-05-12
EP0872500A1 (de) 1998-10-21
ATE256156T1 (de) 2003-12-15
DE59810373D1 (de) 2004-01-22
US5998504A (en) 1999-12-07
ES2212162T3 (es) 2004-07-16
MX9802860A (es) 1998-12-31
DE19715426A1 (de) 1998-10-15

Similar Documents

Publication Publication Date Title
BR9801050B1 (pt) óxidos metálicos coloidais apresentando grupos de isocianato bloqueados.
DE69321845D1 (en) Hydroxyethylaminosulfonamide verwendbar als inhibitoren retroviraler proteasen
EP1666466A3 (en) Mutilin derivatives and their use as Antimicrobials
TW269678B (pt)
DE68929111D1 (de) Verwendung von Halogenkohlenwasserstofflösungsmitteln
ATE215530T1 (de) 7-substituierte-8-substituierte-9-substituierte amino-7-demethyl-6-deoxy-tetracycline als antibiotische mittel
WO1999047507A3 (en) 1,3,4-thiadiazoles useful for the treatment of cmv infections
WO2003041664A1 (fr) Cosmetiques contenant un mineral argileux
EP1522535A3 (en) Environmental barrier coating
DE69813170D1 (de) Silberkatalysator, Verfahren zu dessen Herstellung und Verfahren zur Herstellung von Ethylenoxid
EP0864575A3 (en) Compounds containing urea and alkoxysilane groups
DK612488D0 (da) Siliciumoxid af en med zink forligelig type, fremgangsmaade til fremstilling heraf og tandpasta indeholdende siliciumoxidet
HUP9904198A2 (hu) Új 2-imidazolin-5-ont tartalmazó fungicid készítmények
ATE285423T1 (de) Wässrige verbindungen die alkoxysilan- und/oder silanolgruppen enthalten
EP0430872A3 (en) Tool or instrument with a wear-resistant hard layer for working or processing of organic material
JPS5675493A (en) Novel azepinoindoles* their manufacture and pharmaceutic composition containing them
EP0972808A4 (en) COMPOSITION CONTAINING A DITHIOCARBONATE COMPOUND
ATE163434T1 (de) Katalysator für die herstellung von elastomeren ethylenpropylen copolymeren
NO904031L (no) Fremgangsmaate ved fremstilling av beta-karbonyl-karboksyamider av 1,3-tiazolidiner.
CA2144344A1 (en) Cyclic benzylamino, benzylamido and benzylimido derivatives as antipsychotic agents
ZA947888B (en) Herbicidal compounds
MD970135A (en) Arylthiocompound as an antibacterial and antiviral remedy
IL107001A0 (en) Tetrahydroacridine amino compounds and pharmaceutical compositions containing them
EP0742222A3 (en) Novel silacyclohexane compounds, preparation thereof, liquid crystal compositions comprising the same, and liquid crystal devices comprising the composition
ATE185568T1 (de) Silizium-enthaltende sonnenschutzfilter, diese enthaltende sonnenschutzzusammensetzungen und deren verwendung

Legal Events

Date Code Title Description
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 07/04/2009, OBSERVADAS AS CONDICOES LEGAIS.

B24H Lapse because of non-payment of annual fees (definitively: art 78 iv lpi)
B24F Patent annual fee: publication cancelled

Free format text: ANULADA A PUBLICACAO CODIGO 24.8 NA RPI NO 2259 DE 22/04/2014 POR TER SIDO INDEVIDA.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE AS 15A, 16A, 17A, 18A, 19A, 20A E 21A ANUIDADES.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2607 DE 22-12-2020 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.