BR9601346A - Composição de monômero estabilizado mistura estabilizadora e processo para inibição da polimeração prematura de um monômero - Google Patents

Composição de monômero estabilizado mistura estabilizadora e processo para inibição da polimeração prematura de um monômero

Info

Publication number
BR9601346A
BR9601346A BR9601346A BR9601346A BR9601346A BR 9601346 A BR9601346 A BR 9601346A BR 9601346 A BR9601346 A BR 9601346A BR 9601346 A BR9601346 A BR 9601346A BR 9601346 A BR9601346 A BR 9601346A
Authority
BR
Brazil
Prior art keywords
monomer
inhibiting
composition
premature polymerization
stabilizer mixture
Prior art date
Application number
BR9601346A
Other languages
English (en)
Portuguese (pt)
Inventor
Samuel Evans
Matthew Edward Gande
Peter Nesvadba
Volker Hartmut Von Ahn
Roland Arthur Edwin Winter
Original Assignee
Ciba Geigy Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy Ag filed Critical Ciba Geigy Ag
Publication of BR9601346A publication Critical patent/BR9601346A/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C46/00Preparation of quinones
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00Carboxylic acid nitriles
    • C07C255/49Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C255/56Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and doubly-bound oxygen atoms bound to the carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07BGENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B63/00Purification; Separation; Stabilisation; Use of additives
    • C07B63/04Use of additives
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/45Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by at least one doubly—bound oxygen atom, not being part of a —CHO group
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C225/00Compounds containing amino groups and doubly—bound oxygen atoms bound to the same carbon skeleton, at least one of the doubly—bound oxygen atoms not being part of a —CHO group, e.g. amino ketones
    • C07C225/22Compounds containing amino groups and doubly—bound oxygen atoms bound to the same carbon skeleton, at least one of the doubly—bound oxygen atoms not being part of a —CHO group, e.g. amino ketones having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/657Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings
    • C07C49/683Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings having unsaturation outside the aromatic rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/703Unsaturated compounds containing a keto groups being part of a ring containing hydroxy groups
    • C07C49/747Unsaturated compounds containing a keto groups being part of a ring containing hydroxy groups containing six-membered aromatic rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/753Unsaturated compounds containing a keto groups being part of a ring containing ether groups, groups, groups, or groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/48Separation; Purification; Stabilisation; Use of additives
    • C07C67/62Use of additives, e.g. for stabilisation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00Purification; Separation; Use of additives
    • C07C7/20Use of additives, e.g. for stabilisation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00Systems containing only non-condensed rings
    • C07C2601/12Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Polymerisation Methods In General (AREA)
  • Hydrogenated Pyridines (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Heterocyclic Compounds Containing Sulfur Atoms (AREA)
  • Furan Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pyrrole Compounds (AREA)
  • Polymerization Catalysts (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
BR9601346A 1995-04-14 1996-04-12 Composição de monômero estabilizado mistura estabilizadora e processo para inibição da polimeração prematura de um monômero BR9601346A (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/422,284 US5616774A (en) 1995-04-14 1995-04-14 Inhibition of unsaturated monomers with 7-aryl quinone methides

Publications (1)

Publication Number Publication Date
BR9601346A true BR9601346A (pt) 1998-01-13

Family

ID=23674187

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9601346A BR9601346A (pt) 1995-04-14 1996-04-12 Composição de monômero estabilizado mistura estabilizadora e processo para inibição da polimeração prematura de um monômero

Country Status (12)

Country Link
US (1) US5616774A (de)
EP (1) EP0737660B1 (de)
JP (1) JP3774854B2 (de)
KR (1) KR100441136B1 (de)
CN (1) CN1054594C (de)
AT (1) ATE222224T1 (de)
BR (1) BR9601346A (de)
CA (1) CA2174060C (de)
CZ (1) CZ296467B6 (de)
DE (1) DE69622910T2 (de)
ES (1) ES2181861T3 (de)
TW (1) TW394786B (de)

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DE19609312A1 (de) * 1996-03-09 1997-09-11 Basf Ag Stabilisierte Monomerenzusammensetzung
DE69710163T2 (de) * 1996-12-02 2002-10-02 Ondeo Nalco Energy Serv Lp Hemmung der Polymerisation von vinylaromatischen Monomeren
US6024894A (en) * 1998-03-25 2000-02-15 Betzdearborn Inc. Compositions and methods for inhibiting vinyl aromatic monomer polymerization
AU760809B2 (en) * 1998-09-09 2003-05-22 Baker Hughes Incorporated Styrene monomer polymerization inhibition using substituted dihydroxyarenes and nitroxides
DE60023542T2 (de) 1999-12-02 2006-07-20 Crompton Corp., Middlebury Polymerisationsinhibierung von ungesättigten monomeren
US6685823B2 (en) * 2000-10-16 2004-02-03 Uniroyal Chemical Company, Inc. C-nitrosoaniline compounds and their blends as polymerization inhibitors
CA2422655A1 (en) * 2000-10-16 2002-04-25 Uniroyal Chemical Company, Inc. Blends of quinone alkide and nitroxyl compounds as polymerization inhibitors
KR100822007B1 (ko) * 2001-03-20 2008-04-15 시바 스폐셜티 케미칼스 홀딩 인코포레이티드 방염성 조성물
US6960279B2 (en) * 2002-05-06 2005-11-01 Fina Technology, Inc. Method for stabilizing vinyl aromatic monomers using selected polymerization inhibitors and polymers prepared therewith
US6926820B2 (en) * 2002-09-20 2005-08-09 G.E. Betz, Inc. Inhibition of viscosity increase and fouling in hydrocarbon streams including unsaturation
JP4790414B2 (ja) * 2003-03-17 2011-10-12 伯東株式会社 芳香族ビニル化合物の重合抑制剤および重合抑制方法
US7128826B2 (en) * 2003-07-31 2006-10-31 General Electric Company Polymerization inhibitor for styrene dehydrogenation units
WO2006024621A1 (en) * 2004-09-03 2006-03-09 Ciba Specialty Chemicals Holding Inc. In-can stabilizers
CN101163736B (zh) * 2005-04-21 2011-06-08 西巴特殊化学品控股有限公司 罐内稳定剂混合物
US7553896B2 (en) * 2005-06-17 2009-06-30 Chemtura Corporation Ortho-nitrosophenols as polymerization inhibitors
DE102007052891A1 (de) 2007-11-02 2009-05-07 Evonik Degussa Gmbh Verfahren zur Stabilisierung von olefinisch ungesättigten Monomeren
US8247593B2 (en) * 2008-05-13 2012-08-21 Nalco Company Process for preparing substituted 7-cyano quinone methides
US8187346B2 (en) * 2008-12-29 2012-05-29 Fina Technology, Inc. Stabilization of pygas for storage
US8298440B2 (en) * 2010-06-03 2012-10-30 General Electric Company Methods and compositions for inhibiting vinyl aromatic monomer polymerization
US9090526B2 (en) * 2011-06-13 2015-07-28 Nalco Company Synergistic combination for inhibiting polymerization of vinyl monomers
US8884038B2 (en) 2011-06-13 2014-11-11 Nalco Company Synthesis of 7-acetyleno quinone methide derivatives and their application as vinylic polymerization retarders
US9206268B2 (en) 2011-09-16 2015-12-08 General Electric Company Methods and compositions for inhibiting polystyrene formation during styrene production
US8901362B2 (en) * 2012-02-02 2014-12-02 General Electric Company Methods and compositions for styrene inhibition via in situ generation of quinone methides
WO2013156360A1 (de) * 2012-04-20 2013-10-24 Hilti Aktiengesellschaft Kombination aus einem stabilen nitroxylradikal und einem quinonmethid als stabilisator für reaktionsharzmörtel auf basis radikalisch härtbarer verbindungen
US9611336B2 (en) 2012-10-25 2017-04-04 Baker Hughes Incorporated Quinone compounds for inhibiting monomer polymerization
US9944577B2 (en) 2012-10-25 2018-04-17 Baker Hughes, A Ge Company, Llc Hydroquinone compounds for inhibiting monomer polymerization
WO2014130008A1 (en) * 2013-02-19 2014-08-28 General Electric Company Use of aliphatic nitroso compounds as inhibitors of radical polymerization of activated vinyl monomers
DE102013204950A1 (de) 2013-03-20 2014-09-25 Evonik Industries Ag Verfahren und Zusammensetzung zur Inhibierung der Polymerisation von Cyclopentadienverbindungen
ES2624415T3 (es) 2014-09-08 2017-07-14 Evonik Degussa Gmbh (Tio)acetales fenólicos como agentes inhibidores de la polimerización de monómeros olefínicamente insaturados
TWI669317B (zh) 2014-09-22 2019-08-21 德商贏創德固賽有限責任公司 反應性單體的改良製造方法
EP3820836A1 (de) 2018-07-13 2021-05-19 Ecolab USA, Inc. Zusammensetzungen aus sauerstoffhaltigen aminen und chinonmethiden als antifouling-mittel für vinylische monomere
TW202005938A (zh) 2018-07-13 2020-02-01 美商藝康美國公司 具有胺穩定劑之聚合抑制劑及阻滯劑組合物
US11312793B2 (en) 2018-09-28 2022-04-26 Ecolab Usa Inc. Amino-quinone antipolymerants and methods of using
JP7247630B2 (ja) * 2019-02-13 2023-03-29 栗田工業株式会社 不飽和芳香族単量体の重合を抑制する方法
TW202114976A (zh) 2019-10-11 2021-04-16 美商藝康美國公司 醌甲基化物及銨鹽抗聚合劑組合物及方法
CN115490711A (zh) * 2021-06-18 2022-12-20 唐山师范学院 4-(3-苯硼酸)亚甲基-2,6-二叔丁基-2,5-环己二烯-1-酮化合物的合成和应用
CN115490666A (zh) * 2021-06-18 2022-12-20 唐山师范学院 4-噻吩亚甲基-2,6-二叔丁基-2,5-环己二烯-1-酮化合物的合成及应用
CN115490653A (zh) * 2021-06-18 2022-12-20 唐山师范学院 4-呋喃亚甲基-2,6-二叔丁基-2,5-环己二烯-1-酮化合物的合成及应用
CN114656353A (zh) * 2022-04-13 2022-06-24 卫星化学股份有限公司 一种绿色环保型化合物在丙烯酸生产过程中的应用
CN116553996A (zh) * 2023-07-07 2023-08-08 吉林金海化工新材料有限公司 一种阻聚剂及其应用

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US4040911A (en) * 1976-01-02 1977-08-09 Gulf Research & Development Company Process for inhibiting the polymerization of styrene
US4003800A (en) * 1976-01-02 1977-01-18 Gulf Research & Development Company Styrene purification process
US4032547A (en) * 1976-02-23 1977-06-28 Gulf Research & Development Company Quinone alkide synthesis system
CA2070551C (en) * 1991-07-12 2003-04-01 Anthony V. Grossi Polymerization inhibitors for acrylic acids and esters
US5221764A (en) * 1992-02-18 1993-06-22 Betz Laboratories, Inc. Methods and compositions for inhibiting acrylic acid polymerization
US5254760A (en) * 1992-07-29 1993-10-19 Ciba-Geigy Corporation Inhibiting polymerization of vinyl aromatic monomers

Also Published As

Publication number Publication date
DE69622910D1 (de) 2002-09-19
CN1139094A (zh) 1997-01-01
CZ106896A3 (en) 1996-11-13
CZ296467B6 (cs) 2006-03-15
KR960037632A (ko) 1996-11-19
CA2174060C (en) 2009-08-11
EP0737660B1 (de) 2002-08-14
JP3774854B2 (ja) 2006-05-17
ATE222224T1 (de) 2002-08-15
KR100441136B1 (ko) 2004-10-20
ES2181861T3 (es) 2003-03-01
US5616774A (en) 1997-04-01
JPH09165408A (ja) 1997-06-24
EP0737660A1 (de) 1996-10-16
DE69622910T2 (de) 2003-05-08
TW394786B (en) 2000-06-21
CN1054594C (zh) 2000-07-19
CA2174060A1 (en) 1996-10-15

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Legal Events

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PC Transfer

Free format text: CIBA SC HOLDING AG (CH)

TC Change of name
PC Transfer

Free format text: NALCO/EXXON ENERGY CHEMICALS L.P. (US)

FB34 Technical and formal requirements: requirement - article 34 of industrial property law
B25D Requested change of name of applicant approved
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 24/04/2007, OBSERVADAS AS CONDICOES LEGAIS.

B21A Patent or certificate of addition expired [chapter 21.1 patent gazette]