BR112018074845A2 - complexo de ferro oxo-nitrogenado, sistema catalítico compreendendo o referido complexo de ferro oxo-nitrogenado e processo para a (co)polimerização de dienos conjugados - Google Patents
complexo de ferro oxo-nitrogenado, sistema catalítico compreendendo o referido complexo de ferro oxo-nitrogenado e processo para a (co)polimerização de dienos conjugadosInfo
- Publication number
- BR112018074845A2 BR112018074845A2 BR112018074845-5A BR112018074845A BR112018074845A2 BR 112018074845 A2 BR112018074845 A2 BR 112018074845A2 BR 112018074845 A BR112018074845 A BR 112018074845A BR 112018074845 A2 BR112018074845 A2 BR 112018074845A2
- Authority
- BR
- Brazil
- Prior art keywords
- oxo
- iron complex
- groups
- nitrogen iron
- polymerization
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/02—Iron compounds
- C07F15/025—Iron compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/04—Nickel compounds
- C07F15/045—Nickel compounds without a metal-carbon linkage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/20—Carbonyls
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F36/06—Butadiene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F36/08—Isoprene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/70—Iron group metals, platinum group metals or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/70—Iron group metals, platinum group metals or compounds thereof
- C08F4/7001—Iron group metals, platinum group metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
- C08F4/7003—Bidentate ligand
- C08F4/7004—Neutral ligand
- C08F4/7008—NO
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/70—Iron group metals, platinum group metals or compounds thereof
- C08F4/7001—Iron group metals, platinum group metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
- C08F4/708—Tetra- or multi-dentate ligand
- C08F4/7081—Neutral ligand
- C08F4/7083—ONNO
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
- B01J2531/31—Aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/842—Iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Catalysts (AREA)
Abstract
trata-se de um complexo de ferro oxo-nitrogenado de fórmula geral (i) ou (ii): onde: -r1 e r2, idênticos ou diferentes uns dos outros, representam um átomo de hidrogênio; ou são selecionados dentre grupos alquila c1-c20, de preferência c1-c15, lineares ou ramificados opcionalmente halogenados, opcionalmente grupos cicloalquila substituídos, opcionalmente grupos arila substituídos; -r3, idênticos ou diferentes um do outro, representam um átomo de hidrogênio; ou são selecionados dentre grupos alquila c1-c20, de preferência c1-c15, lineares ou ramificados opcionalmente halogenados, opcionalmente grupos cicloalquila substituídos, opcionalmente grupos arila substituídos; -x1 e x2, idênticos ou diferentes um do outro, representam um átomo de halogênio, tal como, por exemplo, cloro, bromo, iodo; ou são selecionados dentre grupos alquila c1-c20, de preferência c1-c15, lineares ou ramificados, grupos -ocor4 ou grupos -or4, onde r4 é selecionado dentre grupos alquila c1-c20, de preferência c1-c15, lineares ou ramificados. o referido complexo de ferro oxo-nitrogenado de fórmula geral (i) ou (ii) pode ser usado vantajosamente em um sistema catalítico para a (co)polimerização de dienos conjugados.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITUA2016A003932A ITUA20163932A1 (it) | 2016-05-30 | 2016-05-30 | Complesso osso-azotato di ferro, sistema catalitico comprendente detto complesso osso-azotato di ferro e procedimento per la (co)polimerizzazione di dieni coniugati |
IT102016000055704 | 2016-05-30 | ||
PCT/IB2017/053142 WO2017208128A1 (en) | 2016-05-30 | 2017-05-29 | Oxo-nitrogenated iron complex, catalytic system comprising said oxo-nitrogenated iron complex and process for the (co)polymerization of conjugated dienes |
Publications (2)
Publication Number | Publication Date |
---|---|
BR112018074845A2 true BR112018074845A2 (pt) | 2019-03-19 |
BR112018074845B1 BR112018074845B1 (pt) | 2022-08-30 |
Family
ID=57045300
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112018074845-5A BR112018074845B1 (pt) | 2016-05-30 | 2017-05-29 | Complexo de ferro oxo-nitrogenado, sistema catalítico compreendendo o referido complexo de ferro oxo-nitrogenado e processo para a (co)polimerização de dienos conjugados |
Country Status (10)
Country | Link |
---|---|
US (2) | US20190374932A1 (pt) |
KR (1) | KR102383025B1 (pt) |
CN (1) | CN109071719B (pt) |
BR (1) | BR112018074845B1 (pt) |
CA (1) | CA3016659A1 (pt) |
EA (1) | EA037267B1 (pt) |
IT (1) | ITUA20163932A1 (pt) |
SA (1) | SA518400113B1 (pt) |
WO (1) | WO2017208128A1 (pt) |
ZA (1) | ZA201805991B (pt) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10981846B1 (en) * | 2019-08-16 | 2021-04-20 | The United States Of America, As Represented By The Secretary Of The Navy | Producing cyclic fuels from conjugated diene |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
PL276385A1 (en) | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
IT1231774B (it) | 1989-08-03 | 1991-12-21 | Enichem Anic Spa | Catalizzatore e procedimento per la polimerizzazione e per la copolimerizzazione di alfa olefine. |
US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
CA2024830A1 (en) | 1989-09-29 | 1991-03-30 | Richard E. Campbell, Jr. | Process for preparation of syndiotactic vinyl aromatic polymers |
ES2087145T3 (es) | 1989-10-10 | 1996-07-16 | Fina Technology | Catalizadores metalocenos con acidos de lewis y alkilo-aluminios. |
KR0123370B1 (ko) | 1990-06-22 | 1997-11-12 | 벤 씨, 카덴헤드 | 올레핀 중합을 위한 알루미늄-비함유 모노사이클로 펜타디에닐 메탈로센 촉매 |
DE69117520T2 (de) | 1990-09-14 | 1996-08-01 | Exxon Chemical Patents Inc | Ionischer katalysator zur herstellung von polyalphaolefinen mit kontrollierter takticität |
US5189192A (en) | 1991-01-16 | 1993-02-23 | The Dow Chemical Company | Process for preparing addition polymerization catalysts via metal center oxidation |
US5721185A (en) | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
US5258475A (en) | 1991-07-12 | 1993-11-02 | Mobil Oil Corporation | Catalyst systems for polymerization and copolymerization of olefins |
US6180734B1 (en) | 1998-10-14 | 2001-01-30 | Bridgestone Corporation | Process for producing syndiotactic 1,2-polybutadiene and iron-based catalyst compositions for use therein |
US6277779B1 (en) | 1998-10-14 | 2001-08-21 | Bridgestone Corporation | Process and iron-based catalyst composition for the production of syndiotactic 1,2-polybutadiene |
US6211313B1 (en) * | 1999-11-12 | 2001-04-03 | Bridgestone Corporation | Iron-based catalyst composition and process for producing conjugated diene polymers |
US6284702B1 (en) | 1998-10-14 | 2001-09-04 | Bridgestone Corporation | Iron-based catalyst composition and process for producing syndiotactic 1,2-polybutadiene |
US6160063A (en) * | 1999-12-30 | 2000-12-12 | Bridgestone Corporation | Iron-based catalyst for producing binary cis-1,4-/1,2-polybutadiene |
GB0112023D0 (en) * | 2001-05-17 | 2001-07-11 | Bp Chem Int Ltd | Polymerisation catalyst |
GB0305927D0 (en) * | 2003-03-14 | 2003-04-23 | Ic Innovations Ltd | Compound |
BR112012000453A2 (pt) | 2009-07-10 | 2019-09-24 | Graphic Packaging Int Inc | embalagem para reter uma pluralidade de recipientes , molde para formar uma embalagem para manter um pluralidade de recipiente, e método para formar um embalagem para conter uma pluralidade de recipientes |
ITMI20122201A1 (it) * | 2012-12-20 | 2014-06-21 | Versalis Spa | Complesso osso-azotato di cobalto, sistema catalitico comprendente detto complesso osso-azotato e procedimento per la (co)polimerizzazione di dieni coniugati |
-
2016
- 2016-05-30 IT ITUA2016A003932A patent/ITUA20163932A1/it unknown
-
2017
- 2017-05-29 CA CA3016659A patent/CA3016659A1/en active Pending
- 2017-05-29 US US16/300,597 patent/US20190374932A1/en not_active Abandoned
- 2017-05-29 WO PCT/IB2017/053142 patent/WO2017208128A1/en active Application Filing
- 2017-05-29 CN CN201780026611.5A patent/CN109071719B/zh active Active
- 2017-05-29 BR BR112018074845-5A patent/BR112018074845B1/pt active IP Right Grant
- 2017-05-29 EA EA201891812A patent/EA037267B1/ru not_active IP Right Cessation
- 2017-05-29 KR KR1020187028725A patent/KR102383025B1/ko active IP Right Grant
-
2018
- 2018-09-06 ZA ZA2018/05991A patent/ZA201805991B/en unknown
- 2018-09-26 SA SA518400113A patent/SA518400113B1/ar unknown
-
2021
- 2021-03-17 US US17/204,570 patent/US11872548B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
ZA201805991B (en) | 2019-12-18 |
CA3016659A1 (en) | 2017-12-07 |
WO2017208128A1 (en) | 2017-12-07 |
ITUA20163932A1 (it) | 2017-11-30 |
SA518400113B1 (ar) | 2021-10-26 |
EA037267B1 (ru) | 2021-03-01 |
US20210245145A1 (en) | 2021-08-12 |
US20190374932A1 (en) | 2019-12-12 |
KR102383025B1 (ko) | 2022-04-04 |
BR112018074845B1 (pt) | 2022-08-30 |
KR20190015189A (ko) | 2019-02-13 |
CN109071719B (zh) | 2021-07-30 |
US11872548B2 (en) | 2024-01-16 |
WO2017208128A8 (en) | 2018-11-01 |
EA201891812A1 (ru) | 2019-06-28 |
CN109071719A (zh) | 2018-12-21 |
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B06W | Patent application suspended after preliminary examination (for patents with searches from other patent authorities) chapter 6.23 patent gazette] | ||
B350 | Update of information on the portal [chapter 15.35 patent gazette] | ||
B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 29/05/2017, OBSERVADAS AS CONDICOES LEGAIS |