EA201990858A1 - Оксоазотсодержащий комплекс железа, каталитическая система, включающая указанный оксоазотсодержащий комплекс железа, и способ (со)полимеризации сопряженных диенов - Google Patents

Оксоазотсодержащий комплекс железа, каталитическая система, включающая указанный оксоазотсодержащий комплекс железа, и способ (со)полимеризации сопряженных диенов

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Publication number
EA201990858A1
EA201990858A1 EA201990858A EA201990858A EA201990858A1 EA 201990858 A1 EA201990858 A1 EA 201990858A1 EA 201990858 A EA201990858 A EA 201990858A EA 201990858 A EA201990858 A EA 201990858A EA 201990858 A1 EA201990858 A1 EA 201990858A1
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EA
Eurasian Patent Office
Prior art keywords
oxo
nitrogen
containing iron
iron complex
groups
Prior art date
Application number
EA201990858A
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English (en)
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EA039462B9 (ru
EA039462B1 (ru
Inventor
Анна Соммацци
Пампалони Гвидо
Джованни Риччи
Франческо Маси
Филиппо Ренили
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ВЕРСАЛИС С.п.А.
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Application filed by ВЕРСАЛИС С.п.А. filed Critical ВЕРСАЛИС С.п.А.
Publication of EA201990858A1 publication Critical patent/EA201990858A1/ru
Publication of EA039462B1 publication Critical patent/EA039462B1/ru
Publication of EA039462B9 publication Critical patent/EA039462B9/ru

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/02—Iron compounds
    • C07F15/025—Iron compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C249/00—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C249/02—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton of compounds containing imino groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/02—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups
    • C07C251/04—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C251/06—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of a saturated carbon skeleton
    • C07C251/08—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of a saturated carbon skeleton being acyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/08—Isoprene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F36/08—Isoprene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/70—Iron group metals, platinum group metals or compounds thereof
    • C08F4/7001—Iron group metals, platinum group metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/7003—Bidentate ligand
    • C08F4/7004—Neutral ligand
    • C08F4/7008—NO
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F36/06—Butadiene

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)

Abstract

Оксоазотсодержащий комплекс железа, имеющий общую формулу (I)где Rи R, одинаковые или разные, представляют собой атом водорода, или они выбраны из линейных или разветвленных, необязательно галогенированных C-C, предпочтительно C-Cалкильных групп, необязательно замещенных циклоалкильных групп, необязательно замещенных арильных групп; Rпредставляет собой атом водорода, или он выбран из линейных или разветвленных, необязательно галогенированных C-C, предпочтительно C-Cалкильных групп, необязательно замещенных циклоалкильных групп, необязательно замещенных арильных групп; X, одинаковые или разные, представляют собой атом галогена, такой как, например, хлор, бром, йод, предпочтительно хлор, или они выбраны из линейных или разветвленных C-C, предпочтительно C-Cалкильных групп, -OCORгрупп или -ORгрупп, в которых Rвыбран из линейных или разветвленных C-C, предпочтительно C-Cалкильных групп; n равно 2 или 3. Указанный оксоазотсодержащий комплекс железа, имеющий общую формулу (I), можно преимущественно использовать в каталитической системе для (со)полимеризации сопряженных диенов.
EA201990858A 2017-01-20 2018-01-18 Оксо-азотсодержащий комплекс железа, каталитическая система, включающая указанный оксо-азотсодержащий комплекс железа, и способ (со)полимеризации сопряженных диенов EA039462B9 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT102017000006307A IT201700006307A1 (it) 2017-01-20 2017-01-20 Complesso osso-azotato di ferro, sistema catalitico comprendente detto complesso osso-azotato di ferro e procedimento per la (co)polimerizzazione di dieni coniugati
PCT/IB2018/050308 WO2018134757A1 (en) 2017-01-20 2018-01-18 Oxo-nitrogenated iron complex, catalytic system comprising said oxo-nitrogenated iron complex and process for the (co)polymerization of conjugated dienes

Publications (3)

Publication Number Publication Date
EA201990858A1 true EA201990858A1 (ru) 2019-12-30
EA039462B1 EA039462B1 (ru) 2022-01-28
EA039462B9 EA039462B9 (ru) 2022-02-21

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EA201990858A EA039462B9 (ru) 2017-01-20 2018-01-18 Оксо-азотсодержащий комплекс железа, каталитическая система, включающая указанный оксо-азотсодержащий комплекс железа, и способ (со)полимеризации сопряженных диенов

Country Status (19)

Country Link
US (1) US11518776B2 (ru)
EP (1) EP3571210B1 (ru)
KR (1) KR102575575B1 (ru)
CN (1) CN110167949B (ru)
BR (1) BR112019014988B1 (ru)
CA (1) CA3041883A1 (ru)
DK (1) DK3571210T3 (ru)
EA (1) EA039462B9 (ru)
ES (1) ES2917890T3 (ru)
HR (1) HRP20220778T1 (ru)
HU (1) HUE058821T2 (ru)
IT (1) IT201700006307A1 (ru)
PL (1) PL3571210T3 (ru)
PT (1) PT3571210T (ru)
RS (1) RS63308B1 (ru)
SA (1) SA519401767B1 (ru)
SI (1) SI3571210T1 (ru)
WO (1) WO2018134757A1 (ru)
ZA (1) ZA201902695B (ru)

Families Citing this family (1)

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CN110483586B (zh) * 2019-08-27 2021-07-09 中国科学技术大学 大位阻酮亚胺镍催化剂及其配体化合物、制备方法和应用

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US3373177A (en) * 1963-05-20 1968-03-12 Union Oil Co Preparation of metal chelates of beta-iminocarbonyls
US6545108B1 (en) * 1999-02-22 2003-04-08 Eastman Chemical Company Catalysts containing N-pyrrolyl substituted nitrogen donors
KR20030007830A (ko) * 2000-05-31 2003-01-23 이 아이 듀폰 디 네모아 앤드 캄파니 올레핀 중합용 촉매
JP2003535107A (ja) * 2000-05-31 2003-11-25 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー オレフィンの重合
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WO2002059165A2 (en) * 2001-01-26 2002-08-01 E.I. Dupont De Nemours And Company Polymerization of olefinic compounds
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ITMI20122203A1 (it) * 2012-12-20 2014-06-21 Versalis Spa Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso osso-azotato di cobalto
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CA3041883A1 (en) 2018-07-26
ZA201902695B (en) 2022-09-28
DK3571210T3 (da) 2022-06-07
BR112019014988A2 (pt) 2020-04-28
IT201700006307A1 (it) 2018-07-20
KR102575575B1 (ko) 2023-09-05
EA039462B9 (ru) 2022-02-21
PT3571210T (pt) 2022-05-27
SI3571210T1 (sl) 2022-07-29
EP3571210A1 (en) 2019-11-27
ES2917890T3 (es) 2022-07-12
BR112019014988B1 (pt) 2022-12-20
US20210292354A1 (en) 2021-09-23
WO2018134757A1 (en) 2018-07-26
EA039462B1 (ru) 2022-01-28
HRP20220778T1 (hr) 2022-09-16
HUE058821T2 (hu) 2022-09-28
CN110167949B (zh) 2022-08-23
US11518776B2 (en) 2022-12-06
RS63308B1 (sr) 2022-07-29
SA519401767B1 (ar) 2023-02-19
CN110167949A (zh) 2019-08-23
EP3571210B1 (en) 2022-04-13
KR20190101962A (ko) 2019-09-02
PL3571210T3 (pl) 2022-08-08

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