EA039462B9 - Оксо-азотсодержащий комплекс железа, каталитическая система, включающая указанный оксо-азотсодержащий комплекс железа, и способ (со)полимеризации сопряженных диенов - Google Patents

Оксо-азотсодержащий комплекс железа, каталитическая система, включающая указанный оксо-азотсодержащий комплекс железа, и способ (со)полимеризации сопряженных диенов

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Publication number
EA039462B9
EA039462B9 EA201990858A EA201990858A EA039462B9 EA 039462 B9 EA039462 B9 EA 039462B9 EA 201990858 A EA201990858 A EA 201990858A EA 201990858 A EA201990858 A EA 201990858A EA 039462 B9 EA039462 B9 EA 039462B9
Authority
EA
Eurasian Patent Office
Prior art keywords
oxo
iron complex
nitrogenated iron
polymerization
nitrogenated
Prior art date
Application number
EA201990858A
Other languages
English (en)
Other versions
EA201990858A1 (ru
EA039462B1 (ru
Inventor
Анна Соммацци
Гвидо Пампалони
Джованни Риччи
Франческо Маси
Филиппо Ренили
Original Assignee
ВЕРСАЛИС С.п.А.
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Publication date
Application filed by ВЕРСАЛИС С.п.А. filed Critical ВЕРСАЛИС С.п.А.
Publication of EA201990858A1 publication Critical patent/EA201990858A1/ru
Publication of EA039462B1 publication Critical patent/EA039462B1/ru
Publication of EA039462B9 publication Critical patent/EA039462B9/ru

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/02—Iron compounds
    • C07F15/025—Iron compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C249/00—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C249/02—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton of compounds containing imino groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/02—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups
    • C07C251/04—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C251/06—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of a saturated carbon skeleton
    • C07C251/08—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of a saturated carbon skeleton being acyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/08—Isoprene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F36/08—Isoprene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/70—Iron group metals, platinum group metals or compounds thereof
    • C08F4/7001—Iron group metals, platinum group metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/7003—Bidentate ligand
    • C08F4/7004—Neutral ligand
    • C08F4/7008—NO
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F36/06—Butadiene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)

Abstract

Оксо-азотсодержащий комплекс железа, имеющий общую формулу (I)где R1 и R2, одинаковые или разные, выбраны из линейных или разветвленных C1-C20 алкильных групп; R3 представляет собой фенильные группы, необязательно замещенные одной или более линейных или разветвленных C1-C20 алкильных групп; X, будучи одинаковым, представляет собой атом галогена, выбранный из хлора, брома, йода; n равно 2 или 3. Указанный оксо-азотсодержащий комплекс железа, имеющий общую формулу (I), можно преимущественно использовать в каталитической системе для (со)полимеризации сопряженных диенов.
EA201990858A 2017-01-20 2018-01-18 Оксо-азотсодержащий комплекс железа, каталитическая система, включающая указанный оксо-азотсодержащий комплекс железа, и способ (со)полимеризации сопряженных диенов EA039462B9 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT102017000006307A IT201700006307A1 (it) 2017-01-20 2017-01-20 Complesso osso-azotato di ferro, sistema catalitico comprendente detto complesso osso-azotato di ferro e procedimento per la (co)polimerizzazione di dieni coniugati
PCT/IB2018/050308 WO2018134757A1 (en) 2017-01-20 2018-01-18 Oxo-nitrogenated iron complex, catalytic system comprising said oxo-nitrogenated iron complex and process for the (co)polymerization of conjugated dienes

Publications (3)

Publication Number Publication Date
EA201990858A1 EA201990858A1 (ru) 2019-12-30
EA039462B1 EA039462B1 (ru) 2022-01-28
EA039462B9 true EA039462B9 (ru) 2022-02-21

Family

ID=58737747

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EA201990858A EA039462B9 (ru) 2017-01-20 2018-01-18 Оксо-азотсодержащий комплекс железа, каталитическая система, включающая указанный оксо-азотсодержащий комплекс железа, и способ (со)полимеризации сопряженных диенов

Country Status (19)

Country Link
US (1) US11518776B2 (ru)
EP (1) EP3571210B1 (ru)
KR (1) KR102575575B1 (ru)
CN (1) CN110167949B (ru)
BR (1) BR112019014988B1 (ru)
CA (1) CA3041883A1 (ru)
DK (1) DK3571210T3 (ru)
EA (1) EA039462B9 (ru)
ES (1) ES2917890T3 (ru)
HR (1) HRP20220778T1 (ru)
HU (1) HUE058821T2 (ru)
IT (1) IT201700006307A1 (ru)
PL (1) PL3571210T3 (ru)
PT (1) PT3571210T (ru)
RS (1) RS63308B1 (ru)
SA (1) SA519401767B1 (ru)
SI (1) SI3571210T1 (ru)
WO (1) WO2018134757A1 (ru)
ZA (1) ZA201902695B (ru)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110483586B (zh) * 2019-08-27 2021-07-09 中国科学技术大学 大位阻酮亚胺镍催化剂及其配体化合物、制备方法和应用

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US3151047A (en) * 1960-09-12 1964-09-29 Phillips Petroleum Co Separation of organic compounds by fractional distillation and phase separation
US3373177A (en) * 1963-05-20 1968-03-12 Union Oil Co Preparation of metal chelates of beta-iminocarbonyls
US6545108B1 (en) * 1999-02-22 2003-04-08 Eastman Chemical Company Catalysts containing N-pyrrolyl substituted nitrogen donors
KR20030007830A (ko) * 2000-05-31 2003-01-23 이 아이 듀폰 디 네모아 앤드 캄파니 올레핀 중합용 촉매
JP2003535107A (ja) * 2000-05-31 2003-11-25 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー オレフィンの重合
CN101186660A (zh) * 2000-05-31 2008-05-28 纳幕尔杜邦公司 烯烃聚合催化剂
WO2002059165A2 (en) * 2001-01-26 2002-08-01 E.I. Dupont De Nemours And Company Polymerization of olefinic compounds
US6710007B2 (en) * 2001-01-26 2004-03-23 E. I. Du Pont De Nemours And Company Polymerization of olefinic compounds
US7199255B2 (en) * 2001-12-18 2007-04-03 Univation Technologies, Llc Imino-amide catalysts for olefin polymerization
JP2005200305A (ja) * 2004-01-13 2005-07-28 Nippon Synthetic Chem Ind Co Ltd:The イミダゾール類の製造方法
ITMI20111652A1 (it) * 2011-09-14 2013-03-15 Polimeri Europa Spa Complesso oss-azotato di lantanidi, sistema catalitico comprendente detto complesso osso-azotato e procedimento per la (co)polimerizzazione di dieni coniugati
ITMI20122203A1 (it) * 2012-12-20 2014-06-21 Versalis Spa Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso osso-azotato di cobalto
ITMI20122199A1 (it) * 2012-12-20 2014-06-21 Versalis Spa Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso bis-imminico di cobalto
ITMI20122201A1 (it) 2012-12-20 2014-06-21 Versalis Spa Complesso osso-azotato di cobalto, sistema catalitico comprendente detto complesso osso-azotato e procedimento per la (co)polimerizzazione di dieni coniugati
ITMI20131830A1 (it) * 2013-11-05 2015-05-06 Versalis Spa Polibutadieni di-blocco stereoregolari a struttura 1,4-cis/1,2 sindiotattica da polimerizzazione stereospecifica
WO2016102639A1 (en) * 2014-12-23 2016-06-30 Versalis S.P.A. Oxo-nitrogenated vanadium complex, catalytic system comprising said oxo-nitrogenated vanadium complex and process for (co)polymerising conjugated dienes

Also Published As

Publication number Publication date
CA3041883A1 (en) 2018-07-26
ZA201902695B (en) 2022-09-28
EA201990858A1 (ru) 2019-12-30
DK3571210T3 (da) 2022-06-07
BR112019014988A2 (pt) 2020-04-28
IT201700006307A1 (it) 2018-07-20
KR102575575B1 (ko) 2023-09-05
PT3571210T (pt) 2022-05-27
SI3571210T1 (sl) 2022-07-29
EP3571210A1 (en) 2019-11-27
ES2917890T3 (es) 2022-07-12
BR112019014988B1 (pt) 2022-12-20
US20210292354A1 (en) 2021-09-23
WO2018134757A1 (en) 2018-07-26
EA039462B1 (ru) 2022-01-28
HRP20220778T1 (hr) 2022-09-16
HUE058821T2 (hu) 2022-09-28
CN110167949B (zh) 2022-08-23
US11518776B2 (en) 2022-12-06
RS63308B1 (sr) 2022-07-29
SA519401767B1 (ar) 2023-02-19
CN110167949A (zh) 2019-08-23
EP3571210B1 (en) 2022-04-13
KR20190101962A (ko) 2019-09-02
PL3571210T3 (pl) 2022-08-08

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