BR112017013726A2 - complexo de vanádio nitrogenado com oxo, sistema catalítico compreendendo o dito complexo de vanádio nitrogenado com oxo e processo para a (co)polimerização de dienos conjugados - Google Patents
complexo de vanádio nitrogenado com oxo, sistema catalítico compreendendo o dito complexo de vanádio nitrogenado com oxo e processo para a (co)polimerização de dienos conjugadosInfo
- Publication number
- BR112017013726A2 BR112017013726A2 BR112017013726-7A BR112017013726A BR112017013726A2 BR 112017013726 A2 BR112017013726 A2 BR 112017013726A2 BR 112017013726 A BR112017013726 A BR 112017013726A BR 112017013726 A2 BR112017013726 A2 BR 112017013726A2
- Authority
- BR
- Brazil
- Prior art keywords
- vanadium complex
- oxo
- polymerization
- groups
- nitrogen vanadium
- Prior art date
Links
- -1 oxo nitrogen vanadium Chemical compound 0.000 title abstract 4
- 230000003197 catalytic effect Effects 0.000 title abstract 3
- 150000001993 dienes Chemical class 0.000 title abstract 3
- 238000006116 polymerization reaction Methods 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 4
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 abstract 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 2
- 229910052801 chlorine Inorganic materials 0.000 abstract 2
- 239000000460 chlorine Substances 0.000 abstract 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 abstract 2
- 229910052720 vanadium Inorganic materials 0.000 abstract 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 150000002170 ethers Chemical group 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 abstract 1
- 125000003107 substituted aryl group Chemical group 0.000 abstract 1
- 125000005346 substituted cycloalkyl group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F136/06—Butadiene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F136/08—Isoprene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/60—Polymerisation by the diene synthesis
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/68—Vanadium, niobium, tantalum or compounds thereof
- C08F4/68008—Vanadium, niobium, tantalum or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
- C08F4/68017—Bidentate ligand
- C08F4/68025—Neutral ligand
- C08F4/68043—NO
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/68—Vanadium, niobium, tantalum or compounds thereof
- C08F4/68008—Vanadium, niobium, tantalum or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
- C08F4/68017—Bidentate ligand
- C08F4/68103—Monoanionic ligand
- C08F4/6812—NO
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
resumo ?complexo de vanádio nitrogenado com oxo, sistema catalítico compreendendo o dito complexo de vanádio nitrogenado com oxo e processo para a (co)polimerização de dienos conjugados? um complexo de vanádio nitrogenado com oxo que apresenta a fórmula geral (i): em que: - r1, r2, r3, r4, r5, r6 e r7, mutuamente idênticos ou diferentes, representam um átomo de hidrogênio; ou são selecionados a partir de grupos alquila c1-c20 lineares ou ramificados, preferivelmente, c1-c15, opcionalmente halogenados, grupos cicloalquila opcionalmente substituídos, grupos arila opcionalmente substituídos; - x1 e x2, mutuamente idênticos ou diferentes, representam um átomo de halogênio, tal como, por exemplo, cloro, bromo, iodo, preferivelmente, cloro; ou são selecionados a partir de grupos alquila c1-c20 lineares ou ramificados, preferivelmente, c1-c15, grupos -ocor8 ou grupos -or8, em que r8 é selecionado a partir de grupos alquila c1-c20 lineares ou ramificados, preferivelmente, c1-c15; - y é selecionado a partir de éteres, tais como, por exemplo, éter dietílico, tetra-hidrofurano (thf), dimetoxietano, preferivelmente, é tetra-hidrofurano (thf); - n é 0 ou 1. o dito complexo de vanádio nitrogenado com oxo que apresenta a fórmula geral (i) pode ser, vantajosamente, usado em um sistema catalítico para a (co)polimerização de dienos conjugados.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI20142219 | 2014-12-23 | ||
| ITMI2014A002219 | 2014-12-23 | ||
| PCT/EP2015/081106 WO2016102639A1 (en) | 2014-12-23 | 2015-12-23 | Oxo-nitrogenated vanadium complex, catalytic system comprising said oxo-nitrogenated vanadium complex and process for (co)polymerising conjugated dienes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR112017013726A2 true BR112017013726A2 (pt) | 2018-01-16 |
| BR112017013726B1 BR112017013726B1 (pt) | 2021-09-14 |
Family
ID=52574300
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112017013726-7A BR112017013726B1 (pt) | 2014-12-23 | 2015-12-23 | Complexo de vanádio nitrogenado com oxo, sistema catalítico compreendendo o dito complexo de vanádio nitrogenado com oxo e processo para a (co)polimerização de dienos conjugados |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US10301408B2 (pt) |
| EP (1) | EP3237463B1 (pt) |
| KR (1) | KR102586763B1 (pt) |
| CN (1) | CN107001501B (pt) |
| BR (1) | BR112017013726B1 (pt) |
| CA (1) | CA2961873A1 (pt) |
| EA (1) | EA031354B1 (pt) |
| ES (1) | ES2767308T3 (pt) |
| PL (1) | PL3237463T3 (pt) |
| SA (1) | SA517381292B1 (pt) |
| WO (1) | WO2016102639A1 (pt) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3428200B1 (en) * | 2016-03-11 | 2022-05-04 | JSR Corporation | Polymerization catalyst, copolymer, polymer composition, and crosslinked polymer |
| IT201700006307A1 (it) * | 2017-01-20 | 2018-07-20 | Versalis Spa | Complesso osso-azotato di ferro, sistema catalitico comprendente detto complesso osso-azotato di ferro e procedimento per la (co)polimerizzazione di dieni coniugati |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3076830A (en) * | 1959-04-29 | 1963-02-05 | Merck & Co Inc | Vanadium compounds |
| US3595842A (en) * | 1968-03-05 | 1971-07-27 | Dart Ind Inc | Novel catalysts for polymerization of ethylene-alpha-olefin diene terpolymer rubbers |
| JP3970433B2 (ja) | 1997-11-11 | 2007-09-05 | 三井化学株式会社 | 遷移金属化合物からなるオレフィン重合用触媒ならびに重合方法 |
| JP2001064316A (ja) | 1999-08-27 | 2001-03-13 | Ube Ind Ltd | 共役ジエン重合体の製造方法 |
| DE10107045A1 (de) * | 2001-02-13 | 2002-08-14 | Basf Ag | Verfahren zur Polymerisation von Olefinen |
| CN100424100C (zh) * | 2006-05-25 | 2008-10-08 | 中国科学院长春应用化学研究所 | 一种β-酮亚胺钒烯烃聚合催化剂及制备方法和应用 |
| CN101177463B (zh) * | 2007-12-06 | 2010-05-26 | 中国科学院长春应用化学研究所 | 一种负载β-二酮单亚胺钒烯烃聚合催化剂及制备方法和应用 |
| CN100586966C (zh) * | 2007-12-06 | 2010-02-03 | 中国科学院长春应用化学研究所 | 一种双水杨醛亚胺钒烯烃聚合催化剂及制备方法和应用 |
| CN101575393B (zh) * | 2009-06-12 | 2011-08-31 | 中国科学院长春应用化学研究所 | 一类双齿n,o配位的钒系催化剂的用途及用法 |
| WO2011061151A1 (en) | 2009-11-17 | 2011-05-26 | Basell Polyolefine Gmbh | Ethylene copolymers |
| ITMI20122201A1 (it) * | 2012-12-20 | 2014-06-21 | Versalis Spa | Complesso osso-azotato di cobalto, sistema catalitico comprendente detto complesso osso-azotato e procedimento per la (co)polimerizzazione di dieni coniugati |
| US9145492B1 (en) * | 2014-04-01 | 2015-09-29 | King Fahd University Of Petroleum And Minerals | Method to produce ultra-high molecular weight polyethylene |
-
2015
- 2015-12-23 CA CA2961873A patent/CA2961873A1/en active Pending
- 2015-12-23 PL PL15817857T patent/PL3237463T3/pl unknown
- 2015-12-23 BR BR112017013726-7A patent/BR112017013726B1/pt active IP Right Grant
- 2015-12-23 KR KR1020177010951A patent/KR102586763B1/ko active IP Right Grant
- 2015-12-23 US US15/538,338 patent/US10301408B2/en active Active
- 2015-12-23 CN CN201580064888.8A patent/CN107001501B/zh active Active
- 2015-12-23 EP EP15817857.4A patent/EP3237463B1/en active Active
- 2015-12-23 ES ES15817857T patent/ES2767308T3/es active Active
- 2015-12-23 EA EA201790485A patent/EA031354B1/ru not_active IP Right Cessation
- 2015-12-23 WO PCT/EP2015/081106 patent/WO2016102639A1/en active Application Filing
-
2017
- 2017-04-12 SA SA517381292A patent/SA517381292B1/ar unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ES2767308T3 (es) | 2020-06-17 |
| US20170349682A1 (en) | 2017-12-07 |
| SA517381292B1 (ar) | 2021-02-07 |
| EP3237463B1 (en) | 2019-10-23 |
| EA031354B1 (ru) | 2018-12-28 |
| CA2961873A1 (en) | 2016-06-30 |
| EA201790485A1 (ru) | 2017-11-30 |
| KR102586763B1 (ko) | 2023-10-10 |
| WO2016102639A1 (en) | 2016-06-30 |
| EP3237463A1 (en) | 2017-11-01 |
| CN107001501A (zh) | 2017-08-01 |
| BR112017013726B1 (pt) | 2021-09-14 |
| CN107001501B (zh) | 2020-06-23 |
| US10301408B2 (en) | 2019-05-28 |
| KR20170098211A (ko) | 2017-08-29 |
| PL3237463T3 (pl) | 2020-06-29 |
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| B06U | Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 23/12/2015, OBSERVADAS AS CONDICOES LEGAIS. |