BR112018011007A2 - método para produzir 2-alquil-4-trifluorometil-3-ácidos alquil sulfonil benzoicos por oxidação de tioéter quimiosseletiva. - Google Patents
método para produzir 2-alquil-4-trifluorometil-3-ácidos alquil sulfonil benzoicos por oxidação de tioéter quimiosseletiva.Info
- Publication number
- BR112018011007A2 BR112018011007A2 BR112018011007-8A BR112018011007A BR112018011007A2 BR 112018011007 A2 BR112018011007 A2 BR 112018011007A2 BR 112018011007 A BR112018011007 A BR 112018011007A BR 112018011007 A2 BR112018011007 A2 BR 112018011007A2
- Authority
- BR
- Brazil
- Prior art keywords
- alkyl
- trifluoromethyl
- chemoselective
- producing
- benzoic acids
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C315/00—Preparation of sulfones; Preparation of sulfoxides
- C07C315/02—Preparation of sulfones; Preparation of sulfoxides by formation of sulfone or sulfoxide groups by oxidation of sulfides, or by formation of sulfone groups by oxidation of sulfoxides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
- C07C309/78—Halides of sulfonic acids
- C07C309/86—Halides of sulfonic acids having halosulfonyl groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
- C07C309/89—Halides of sulfonic acids having halosulfonyl groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing carboxyl groups bound to the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/14—Sulfones; Sulfoxides having sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/44—Sulfones; Sulfoxides having sulfone or sulfoxide groups and carboxyl groups bound to the same carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
- C07C319/20—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides by reactions not involving the formation of sulfide groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
- C07C323/01—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and halogen atoms, or nitro or nitroso groups bound to the same carbon skeleton
- C07C323/09—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and halogen atoms, or nitro or nitroso groups bound to the same carbon skeleton having sulfur atoms of thio groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
- C07C323/50—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
- C07C323/62—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
- C07C323/64—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and sulfur atoms, not being part of thio groups, bound to the same carbon skeleton
- C07C323/65—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and sulfur atoms, not being part of thio groups, bound to the same carbon skeleton containing sulfur atoms of sulfone or sulfoxide groups bound to the carbon skeleton
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
método para produzir 2-alquil-4-trifluorometil-3-ácidos alquil sulfonil benzoicos por oxidação de tioéter quimiosseletiva. é descrito um processo para a preparação de 2-alquil-4-trifluorometil-3-ácidos alquilsulfonilbenzoicos da fórmula (i). aqui, os substituintes são radicais, como alquil e fenil substituído.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP15196992 | 2015-11-30 | ||
EP15196992.0 | 2015-11-30 | ||
PCT/EP2016/078971 WO2017093172A1 (de) | 2015-11-30 | 2016-11-28 | Verfahren zur herstellung von 2-alkyl-4-trifluormethyl-3-alkylsulfonylbenzoesäuren durch chemoselektive thioetheroxidation |
Publications (2)
Publication Number | Publication Date |
---|---|
BR112018011007A2 true BR112018011007A2 (pt) | 2018-12-04 |
BR112018011007B1 BR112018011007B1 (pt) | 2021-05-11 |
Family
ID=54770880
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112018011007-8A BR112018011007B1 (pt) | 2015-11-30 | 2016-11-28 | método para produzir 2-alquil-4-trifluorometil-3-ácidos alquil sulfonil benzoicos por oxidação de tioéter quimiosseletiva |
Country Status (12)
Country | Link |
---|---|
US (1) | US10252990B2 (pt) |
EP (1) | EP3383843B1 (pt) |
JP (1) | JP6831380B2 (pt) |
KR (1) | KR20180088397A (pt) |
CN (1) | CN108349885B (pt) |
BR (1) | BR112018011007B1 (pt) |
DK (1) | DK3383843T3 (pt) |
ES (1) | ES2757248T3 (pt) |
IL (1) | IL259592A (pt) |
MX (1) | MX2018006638A (pt) |
TW (1) | TWI721034B (pt) |
WO (1) | WO2017093172A1 (pt) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112194603B (zh) * | 2019-07-08 | 2022-11-18 | 长沙嘉桥生物科技有限公司 | 一种2-氯-3-甲基-4-甲磺酰基苯甲酸的制备方法 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19548428C1 (de) * | 1995-12-22 | 1997-08-28 | Hoechst Ag | 2-Alkylmerkapto-4-(trifluormethyl)-benzoesäureester sowie ein Verfahren zu ihrer Herstellung |
GB9714302D0 (en) * | 1997-07-07 | 1997-09-10 | Rhone Poulenc Agrochimie | Process |
EP1980556A1 (de) * | 2007-04-12 | 2008-10-15 | Bayer CropScience AG | 4-(4-Trifluormethyl-3-thiobenzoyl)pyrazole und ihre Verwendung als Herbizide |
BR112013001406B1 (pt) * | 2010-07-21 | 2018-10-09 | Bayer Ip Gmbh | (4-trifluor-metil-3-tiobenzoil)ciclohe-hexa-nodionas, seu uso, agentes herbicidas, e processo para combater plantas indesejadas |
CN103596946B (zh) | 2011-03-22 | 2016-05-11 | 拜耳知识产权有限责任公司 | N-(1,3,4-噁二唑-2-基)芳基甲酰胺及其作为除草剂的用途 |
WO2014086746A1 (de) * | 2012-12-07 | 2014-06-12 | Bayer Cropscience Ag | N-(isoxazol-3-yl)-arylcarbonsäureamide und ihre verwendung als herbizide |
UY35421A (es) * | 2013-03-15 | 2014-10-31 | Nihon Nohyaku Co Ltd | Compuesto heterocíclico condensado o su sal, insecticida agrícola u hortícola que comprende el comp uesto y método de uso del insecticida |
-
2016
- 2016-11-11 TW TW105136841A patent/TWI721034B/zh active
- 2016-11-28 EP EP16810270.5A patent/EP3383843B1/de active Active
- 2016-11-28 MX MX2018006638A patent/MX2018006638A/es unknown
- 2016-11-28 DK DK16810270T patent/DK3383843T3/da active
- 2016-11-28 WO PCT/EP2016/078971 patent/WO2017093172A1/de active Application Filing
- 2016-11-28 US US15/778,699 patent/US10252990B2/en active Active
- 2016-11-28 BR BR112018011007-8A patent/BR112018011007B1/pt active IP Right Grant
- 2016-11-28 JP JP2018527767A patent/JP6831380B2/ja active Active
- 2016-11-28 ES ES16810270T patent/ES2757248T3/es active Active
- 2016-11-28 KR KR1020187014763A patent/KR20180088397A/ko not_active Application Discontinuation
- 2016-11-28 CN CN201680065707.8A patent/CN108349885B/zh active Active
-
2018
- 2018-05-24 IL IL259592A patent/IL259592A/en active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
WO2017093172A1 (de) | 2017-06-08 |
BR112018011007B1 (pt) | 2021-05-11 |
IL259592A (en) | 2018-07-31 |
ES2757248T3 (es) | 2020-04-28 |
TW201720794A (zh) | 2017-06-16 |
CN108349885B (zh) | 2020-05-15 |
TWI721034B (zh) | 2021-03-11 |
US20180354898A1 (en) | 2018-12-13 |
CN108349885A (zh) | 2018-07-31 |
EP3383843B1 (de) | 2019-09-25 |
JP6831380B2 (ja) | 2021-02-17 |
JP2018535239A (ja) | 2018-11-29 |
KR20180088397A (ko) | 2018-08-03 |
MX2018006638A (es) | 2018-08-15 |
EP3383843A1 (de) | 2018-10-10 |
US10252990B2 (en) | 2019-04-09 |
DK3383843T3 (da) | 2019-11-18 |
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B06U | Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette] | ||
B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 28/11/2016, OBSERVADAS AS CONDICOES LEGAIS. |