BR112017007803A2 - sistema de catalisador duplo para polióis com elevado teor de hidroxilas primárias - Google Patents
sistema de catalisador duplo para polióis com elevado teor de hidroxilas primáriasInfo
- Publication number
- BR112017007803A2 BR112017007803A2 BR112017007803A BR112017007803A BR112017007803A2 BR 112017007803 A2 BR112017007803 A2 BR 112017007803A2 BR 112017007803 A BR112017007803 A BR 112017007803A BR 112017007803 A BR112017007803 A BR 112017007803A BR 112017007803 A2 BR112017007803 A2 BR 112017007803A2
- Authority
- BR
- Brazil
- Prior art keywords
- mixture
- temperature
- molecular weight
- primary hydroxyl
- oxide
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/269—Mixed catalyst systems, i.e. containing more than one reactive component or catalysts formed in-situ
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/266—Metallic elements not covered by group C08G65/2648 - C08G65/2645, or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/75—Cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/24—Nitrogen compounds
- B01J27/26—Cyanides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/2654—Aluminium or boron; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/2663—Metal cyanide catalysts, i.e. DMC's
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2696—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the process or apparatus used
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Toxicology (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Health & Medical Sciences (AREA)
- Polyethers (AREA)
Abstract
um método para produzir um poliol com elevado teor de grupos hidroxila primária e um elevado peso molecular médio numérico, inclui a preparação de uma mistura que inclui um catalisador de cianeto metálico duplo e um poliol de poliéter com baixo peso molecular tendo um peso molecular médio numérico menor que 1.000 g/mol. o poliol de poliéter é derivado de óxido de propileno, óxido de etileno ou de óxido de butileno, ajustando-se a mistura para ter uma primeira temperatura, adicionando-se pelo menos uma substância selecionada dentre óxido de propileno, óxido de etileno e óxido de butileno à mistura na primeira temperatura, permitindo-se que a mistura reaja para formar uma mistura reagida, adicionando-se um catalisador de ácido de lewis à mistura reagida, ajustando-se a mistura de reação incluindo o segundo catalisador para ter uma segunda temperatura que é menor que a primeira temperatura, e adicionando-se pelo menos uma substância adicional selecionada dentre óxido de propileno, óxido de etileno e óxido de butileno à mistura reagida na segunda temperatura, de tal modo que um poliol resultante tendo um teor de grupos hidroxila primária de pelo menos 60% e um peso molecular médio numérico maior que 2.500 g/mol seja formado.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201462067072P | 2014-10-22 | 2014-10-22 | |
US62/067,072 | 2014-10-22 | ||
PCT/US2015/056143 WO2016064698A1 (en) | 2014-10-22 | 2015-10-19 | Dual catalyst system for high primary hydroxyl polyols |
Publications (2)
Publication Number | Publication Date |
---|---|
BR112017007803A2 true BR112017007803A2 (pt) | 2017-12-19 |
BR112017007803B1 BR112017007803B1 (pt) | 2021-10-13 |
Family
ID=54478959
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112017007803-1A BR112017007803B1 (pt) | 2014-10-22 | 2015-10-19 | Método para produzir um elevado teor de grupo hidroxilas primária e um poliol com elevado peso molecular médio numérico |
Country Status (10)
Country | Link |
---|---|
US (1) | US9896542B2 (pt) |
EP (1) | EP3209706B1 (pt) |
JP (1) | JP6598855B2 (pt) |
KR (1) | KR102480802B1 (pt) |
CN (1) | CN107075108B (pt) |
AU (1) | AU2015336243B2 (pt) |
BR (1) | BR112017007803B1 (pt) |
ES (1) | ES2698433T3 (pt) |
SG (1) | SG11201703116TA (pt) |
WO (1) | WO2016064698A1 (pt) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SG11202002055UA (en) | 2017-09-14 | 2020-04-29 | Dow Global Technologies Llc | Process of manufacturing polyols |
CN111212866B (zh) | 2017-09-14 | 2023-02-21 | 西北大学 | 制造多元醇的方法 |
EP3681932B1 (en) * | 2017-09-14 | 2021-06-09 | Dow Global Technologies LLC | Lewis acid polymerization catalyst |
US11634539B2 (en) | 2018-09-24 | 2023-04-25 | Saudi Aramco Technologies Company | Polycarbonate block copolymers and methods thereof |
CN109280142B (zh) * | 2018-09-27 | 2021-02-12 | 山东一诺威新材料有限公司 | 慢回弹聚醚多元醇及其制备方法和应用 |
BR112021004617A2 (pt) * | 2018-09-28 | 2021-05-25 | Dow Global Technologies Llc | copolímero de óxido de butileno e óxido de etileno contendo hidroxila, poliuretano, e, método one-shot para produzir um poliuretano. |
CN111087597B (zh) * | 2018-10-23 | 2023-01-24 | 中国石油化工股份有限公司 | 高活性聚醚多元醇的制备方法 |
CN111087600B (zh) * | 2018-10-23 | 2023-03-03 | 中国石油化工股份有限公司 | 聚氨酯弹性体树脂及其制备方法 |
JP2022515209A (ja) | 2018-12-20 | 2022-02-17 | ビーエーエスエフ ソシエタス・ヨーロピア | コンパクトなポリウレタン |
EP3931236B1 (en) * | 2019-02-25 | 2023-03-08 | Northwestern University | Lewis acid polymerization catalyst |
WO2021021845A1 (en) | 2019-08-01 | 2021-02-04 | Dow Global Technologies Llc | Process for purifying polyether polyols |
CN111057228A (zh) * | 2019-12-13 | 2020-04-24 | 张家港美景荣化学工业有限公司 | 一种低分子量聚醚多元醇的制备方法 |
PL4097168T3 (pl) * | 2020-01-31 | 2024-04-08 | Dow Global Technologies Llc | Polimeryzacja tlenku alkilenu z wykorzystaniem związków glinu i amidyn cyklicznych |
CN113072695B (zh) * | 2021-03-30 | 2022-07-08 | 浙江皇马科技股份有限公司 | 一种低温流动性好的稳泡表面活性剂的制备方法 |
PL442356A1 (pl) * | 2022-09-26 | 2024-04-02 | Pcc Rokita Spółka Akcyjna | Poliol polieterowy, sposób jego wytwarzania i jego zastosowanie oraz elastyczna pianka poliuretanowa |
CN115785435B (zh) * | 2022-12-29 | 2023-08-11 | 杭州普力材料科技有限公司 | 一种一步法制备聚醚多元醇的方法 |
Family Cites Families (23)
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GB8517188D0 (en) | 1985-07-06 | 1985-08-14 | Bp Chem Int Ltd | Metal perfluorosulphonic acid polymer catalyst |
JP2743454B2 (ja) * | 1989-04-07 | 1998-04-22 | 旭硝子株式会社 | ポリエーテル類の製造方法 |
US5391722A (en) | 1990-03-30 | 1995-02-21 | Olin Corporation | Acid-catalyzed fabrication of precursors for use in making polyols using double metal cyanide catalysts |
WO1993019113A1 (en) | 1992-03-24 | 1993-09-30 | The Dow Chemical Company | Novel finishing process for hydroxy-functional polyethers |
US5296433A (en) | 1992-04-14 | 1994-03-22 | Minnesota Mining And Manufacturing Company | Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom |
US5763642A (en) | 1997-06-19 | 1998-06-09 | Arco Chemical Technology, L.P. | Low monol polyoxy (higher) alkylene polyols with primary hydroxyl content |
DE19817676A1 (de) | 1998-04-21 | 1999-10-28 | Bayer Ag | Verfahren zur aufarbeitungsfreien Herstellung langkettiger Polyetherpolyole |
US6028230A (en) * | 1998-06-05 | 2000-02-22 | Arco Chemical Technology, L.P. | Epoxide polymerization process |
DE59911016D1 (de) * | 1998-07-10 | 2004-12-09 | Sanyo Chemical Ind Ltd | Neue polyoxyalkylenpolyole und verfahren zur herstellung eines polymers mit ringöffnung |
DE10001779A1 (de) * | 2000-01-18 | 2001-07-19 | Basf Ag | Verfahren zur Herstellung von Polyetheralkoholen |
US7005552B2 (en) | 2003-11-03 | 2006-02-28 | Bayer Materialscience Llc | Single reactor synthesis of KOH-capped polyols based on DMC-synthesized intermediates |
US7186867B2 (en) * | 2004-04-21 | 2007-03-06 | Basf Aktiengesellschaft | Process for preparing reactive polyether polyols having an ethylene oxide end block |
EP2026906A2 (en) | 2006-05-23 | 2009-02-25 | Dow Corning Corporation | Borane catalyst complexes with amide functional polymers and curable compositions made therefrom |
WO2008123323A1 (ja) * | 2007-03-28 | 2008-10-16 | Asahi Glass Company, Limited | ポリオールの製造方法および該ポリオール |
JP5201141B2 (ja) | 2007-06-22 | 2013-06-05 | 旭硝子株式会社 | ポリマー分散ポリオールおよび軟質ポリウレタンフォームの製造方法 |
AR073933A1 (es) | 2008-05-19 | 2010-12-15 | Dow Global Technologies Inc | Procedimiento de flujo de recirculacion continuo para la produccion de poliol de polieter |
KR101384038B1 (ko) | 2009-03-30 | 2014-04-09 | 산요가세이고교 가부시키가이샤 | 폴리옥시알킬렌폴리올 또는 모노올 및 폴리우레탄 수지 |
DE102009031584A1 (de) | 2009-07-03 | 2011-01-05 | Bayer Materialscience Ag | Verfahren zur Herstellung von Polyetherpolyolen mit primären Hydroxyl-Endgruppen |
EP2563834B1 (en) | 2010-04-29 | 2019-02-27 | Dow Global Technologies LLC | Hybrid polyester-polyether polyols |
US8470415B2 (en) | 2010-07-12 | 2013-06-25 | Carestream Health, Inc. | Transparent ink-jet recording film |
BR112013016657B1 (pt) | 2010-12-27 | 2021-11-03 | Dow Global Technologies Llc | Método para produzir um produto de poliéter monol ou poliéter poliol |
BR112013025054B1 (pt) | 2011-03-31 | 2020-03-17 | Dow Global Technologies Llc | Método para produzir um poliéter poliol de cadeia curta |
ES2599073T3 (es) | 2011-07-04 | 2017-01-31 | Repsol, S.A. | Método continuo para la síntesis de polioles |
-
2015
- 2015-10-19 US US15/504,368 patent/US9896542B2/en active Active
- 2015-10-19 ES ES15791819T patent/ES2698433T3/es active Active
- 2015-10-19 AU AU2015336243A patent/AU2015336243B2/en active Active
- 2015-10-19 WO PCT/US2015/056143 patent/WO2016064698A1/en active Application Filing
- 2015-10-19 KR KR1020177011540A patent/KR102480802B1/ko active IP Right Grant
- 2015-10-19 BR BR112017007803-1A patent/BR112017007803B1/pt active IP Right Grant
- 2015-10-19 EP EP15791819.4A patent/EP3209706B1/en active Active
- 2015-10-19 JP JP2017519670A patent/JP6598855B2/ja active Active
- 2015-10-19 CN CN201580056460.9A patent/CN107075108B/zh active Active
- 2015-10-19 SG SG11201703116TA patent/SG11201703116TA/en unknown
Also Published As
Publication number | Publication date |
---|---|
CN107075108A (zh) | 2017-08-18 |
ES2698433T3 (es) | 2019-02-04 |
CN107075108B (zh) | 2019-09-03 |
JP6598855B2 (ja) | 2019-10-30 |
US9896542B2 (en) | 2018-02-20 |
US20170240702A1 (en) | 2017-08-24 |
SG11201703116TA (en) | 2017-05-30 |
KR102480802B1 (ko) | 2022-12-23 |
AU2015336243B2 (en) | 2019-04-18 |
EP3209706A1 (en) | 2017-08-30 |
JP2017531719A (ja) | 2017-10-26 |
AU2015336243A1 (en) | 2017-05-18 |
BR112017007803B1 (pt) | 2021-10-13 |
KR20170074893A (ko) | 2017-06-30 |
EP3209706B1 (en) | 2018-09-05 |
WO2016064698A1 (en) | 2016-04-28 |
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Legal Events
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B06U | Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette] | ||
B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 19/10/2015, OBSERVADAS AS CONDICOES LEGAIS. |