BR112017014945A2 - processo contínuo para preparação de etileno glicol. - Google Patents

processo contínuo para preparação de etileno glicol.

Info

Publication number
BR112017014945A2
BR112017014945A2 BR112017014945-1A BR112017014945A BR112017014945A2 BR 112017014945 A2 BR112017014945 A2 BR 112017014945A2 BR 112017014945 A BR112017014945 A BR 112017014945A BR 112017014945 A2 BR112017014945 A2 BR 112017014945A2
Authority
BR
Brazil
Prior art keywords
ethylene glycol
hydrogen
continuous process
stirring reactor
continuously
Prior art date
Application number
BR112017014945-1A
Other languages
English (en)
Other versions
BR112017014945B1 (pt
Inventor
Cornelis Van Der Waal Jan
Johannes Maria Gruter Gerardus
Original Assignee
Avantium Knowledge Centre B.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=52781246&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=BR112017014945(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Avantium Knowledge Centre B.V. filed Critical Avantium Knowledge Centre B.V.
Publication of BR112017014945A2 publication Critical patent/BR112017014945A2/pt
Publication of BR112017014945B1 publication Critical patent/BR112017014945B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0053—Details of the reactor
    • B01J19/0066—Stirrers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B31/00—Reduction in general
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/20—Dihydroxylic alcohols
    • C07C31/202—Ethylene glycol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/00033—Continuous processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/30—Tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with noble metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

etileno glicol é preparado a partir de uma fonte de carboidrato por reação da fonte de carboidrato com hidrogênio em um processo contínuo, em que hidrogênio, a fonte de carboidrato e um diluente líquido são continuamente alimentados em um reator de agitação contínuo em que um sistema catalisador está presente, sistema catalisador o qual compreende um composto de tungstênio e pelo menos um metal de hidrogenólise selecionado dos grupos 8, 9 ou 10 da tabela periódica dos elementos, para obter a reação entre a fonte de carboidrato e hidrogênio para etileno glicol; em que continuamente uma mistura de produto que compreende etileno glicol e diluente é removida do reator de agitação contínuo; e em que continuamente ou periodicamente depois pelo menos um composto de tungstênio é adicionada ao reator de agitação contínuo (cstr).
BR112017014945-1A 2015-01-13 2016-01-13 processo contínuo para preparação de etileno glicol BR112017014945B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
NL2014121 2015-01-13
NL2014121 2015-01-13
PCT/NL2016/050029 WO2016114661A1 (en) 2015-01-13 2016-01-13 Continuous process for preparing ethylene glycol from a carbohydrate source

Publications (2)

Publication Number Publication Date
BR112017014945A2 true BR112017014945A2 (pt) 2018-03-13
BR112017014945B1 BR112017014945B1 (pt) 2021-06-08

Family

ID=52781246

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112017014945-1A BR112017014945B1 (pt) 2015-01-13 2016-01-13 processo contínuo para preparação de etileno glicol

Country Status (15)

Country Link
US (1) US10138184B2 (pt)
EP (1) EP3245181B1 (pt)
JP (1) JP6553743B2 (pt)
KR (1) KR20170105063A (pt)
CN (1) CN107406358B (pt)
AU (1) AU2016207242B2 (pt)
BR (1) BR112017014945B1 (pt)
CA (1) CA2973556C (pt)
LT (1) LT3245181T (pt)
MX (1) MX2017009161A (pt)
MY (1) MY185257A (pt)
PL (1) PL3245181T3 (pt)
SG (1) SG11201705686RA (pt)
UA (1) UA118147C2 (pt)
WO (1) WO2016114661A1 (pt)

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WO2015179302A1 (en) 2014-05-19 2015-11-26 Iowa Corn Promotion Board Process for the continuous production of ethylene glycol from carbohydrates
PL3245183T3 (pl) 2015-01-13 2020-07-27 Avantium Knowledge Centre B.V. Sposób wytwarzania glikolu etylenowego ze źródła węglowodanów
EP3365316B2 (en) 2015-10-20 2022-04-27 Shell Internationale Research Maatschappij B.V. Process for the production of glycols
CN108290809B (zh) * 2015-10-20 2022-04-15 国际壳牌研究有限公司 从碳水化合物馈料制造二醇的方法
US10472310B2 (en) 2016-06-03 2019-11-12 Iowa Corn Promotion Board Continuous processes for the highly selective conversion of sugars to propylene glycol or mixtures of propylene glycol and ethylene glycol
CN109641191B (zh) 2016-06-03 2023-04-04 爱荷华谷类推广协会 将产生己醛糖的碳水化合物高度选择性地转化为乙二醇的连续方法
WO2018024787A1 (en) 2016-08-04 2018-02-08 Shell Internationale Research Maatschappij B.V. Process for the production of glycols
BR112019004044B1 (pt) 2016-08-30 2022-11-29 Shell Internationale Research Maatschappij B.V. Processo para produzir etileno glicol de uma alimentação de carboidrato
CN108070079A (zh) 2016-11-09 2018-05-25 可口可乐公司 生物基meg和pet组合物以及制造它们的方法
CN108070075A (zh) 2016-11-09 2018-05-25 可口可乐公司 生物基meg和聚酯纤维组合物以及制造它们的方法
CA3044135A1 (en) 2016-12-07 2018-06-14 Shell Internationale Research Maatschappij B.V. Process for the preparation of glycols
WO2019175365A1 (en) 2018-03-14 2019-09-19 Avantium Knowledge Centre B.V. Process for the production of ethylene glycol and heterogeneous catalyst composition
EA202092099A1 (ru) * 2018-03-14 2020-11-26 Авантиум Нолидж Сентр Б.В. Способ производства этиленгликоля
BR112020017094B8 (pt) * 2018-03-14 2024-03-05 Avantium Knowledge Centre Bv Processo contínuo ou semicontínuo para a preparação de etilenoglicol
CN110882710B (zh) * 2018-09-07 2022-10-21 中国石油化工股份有限公司 碳化物基催化剂及其制备方法以及甘油氢解方法
BR112021004744A2 (pt) 2018-09-13 2021-06-01 Shell Internationale Research Maatschappij B.V. processo de partida para a produção de glicóis
DE102019113135A1 (de) * 2019-05-17 2020-11-19 Rheinisch-Westfälische Technische Hochschule (Rwth) Aachen Verfahren zur Herstellung von Glycolen aus Zuckern und Zuckeralkoholen
EP4003946A1 (en) 2019-07-31 2022-06-01 Avantium Knowledge Centre B.V. Process for preparing alkylene glycol from a carbohydrate source comprising hemicellulose, cellulose and lignin
CN112619660B (zh) * 2019-09-24 2022-10-11 中国石油化工股份有限公司 用于合成乙二醇的催化剂及其制备方法和应用
CA3155648A1 (en) 2019-09-24 2021-04-01 Iowa Corn Promotion Board Continuous, carbohydrate to ethylene glycol processes
WO2021165082A1 (en) 2020-02-17 2021-08-26 Avantium Knowledge Centre B.V. Process for preparing alkylene glycol mixture from a carbohydrate source with decreased selectivity for polyol side products
BR112022016195A2 (pt) 2020-02-17 2022-10-04 Avantium Knowledge Centre Bv Processos para produzir uma mistura e glicóis dissolvidos em água
US11680031B2 (en) 2020-09-24 2023-06-20 T. EN Process Technology, Inc. Continuous processes for the selective conversion of aldohexose-yielding carbohydrate to ethylene glycol using low concentrations of retro-aldol catalyst
US11319269B2 (en) 2020-09-24 2022-05-03 Iowa Corn Promotion Board Continuous processes for the selective conversion of aldohexose-yielding carbohydrate to ethylene glycol using low concentrations of retro-aldol catalyst
WO2022064039A1 (en) 2020-09-28 2022-03-31 Avantium Knowledge Centre B.V. Process for recovering and regenerating a catalyst from ash
BR112023004203A2 (pt) 2020-09-28 2023-04-11 Avantium Knowledge Centre Bv Processo para produzir etilenoglicol e/ou propilenoglicol e/ou glicerol
BR112023021092A2 (pt) 2021-04-21 2023-12-12 Avantium Knowledge Centre Bv Equipamento de processamento e processo para produzir etilenoglicol e/ou propilenoglicol e/ou glicerol de modo contínuo a partir de uma alimentação
WO2023186840A1 (en) 2022-03-29 2023-10-05 Avantium Knowledge Centre B.V. Process for preparing ethylene glycol from a carbohydrate source and hydrogen in a continuous way

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CN101768050B (zh) 2009-12-25 2012-12-05 北京大学 一种生产乙二醇和1，2-丙二醇的方法
CN102190562B (zh) 2010-03-17 2014-03-05 中国科学院大连化学物理研究所 一种多羟基化合物制乙二醇的方法
CN102643165B (zh) * 2011-06-28 2014-07-02 中国科学院大连化学物理研究所 连续加氢裂解糖转化生产乙二醇及1,2-丙二醇的方法
US8222464B2 (en) 2011-07-28 2012-07-17 Uop Llc Catalytic process for continuously generating polyols
EP2736869A4 (en) 2011-07-28 2015-01-07 Uop Llc OBTAINING POLYOLS FROM SACCHARIDES
US8222462B2 (en) 2011-07-28 2012-07-17 Uop Llc Process for generation of polyols from saccharides
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US8410319B2 (en) 2011-07-28 2013-04-02 Uop Llc Continuous catalytic generation of polyols from cellulose with recycle
CN102731254B (zh) * 2011-12-20 2015-02-04 中国科学院大连化学物理研究所 一种以玉米秸秆和/或高粱秸秆为原料制备乙二醇的方法
CN102731253B (zh) * 2011-12-20 2014-10-22 中国科学院大连化学物理研究所 一种抑制环醚醇生成的纤维素催化转化制乙二醇的方法
CN102731255B (zh) 2011-12-20 2014-10-22 中国科学院大连化学物理研究所 一种以玉米芯为原料制备乙二醇的方法
CN103420797B (zh) 2012-05-21 2015-04-08 中国科学院大连化学物理研究所 低金属负载量催化剂用于碳水化合物制备乙二醇的方法
CN102731258B (zh) * 2012-05-21 2014-07-23 中国科学院大连化学物理研究所 一种碳水化合物内循环催化转化制备低碳多元醇的方法
BR112015024224A2 (pt) 2013-04-05 2017-07-18 Shell Int Research processo para preparação de etileno glicol e 1,2-propileno glicol
BR112015019100A2 (pt) 2013-04-26 2017-07-18 Shell Int Research processo para a preparação de monoetileno glicol a partir de sacarose, e, processo para a conversão de sacarose em frutose e/ou derivados de frutose
RU2674144C2 (ru) * 2013-08-26 2018-12-05 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ получения гликолей
WO2015154258A1 (en) 2014-04-09 2015-10-15 Petroliam Nasional Berhad (Petronas) Selective conversion of saccharide containing feedstock to ethylene glycol
WO2015179302A1 (en) 2014-05-19 2015-11-26 Iowa Corn Promotion Board Process for the continuous production of ethylene glycol from carbohydrates
CN105523890B (zh) 2014-09-28 2021-04-16 长春美禾科技发展有限公司 一种制备二元醇的方法
PL3245182T3 (pl) 2015-01-13 2020-06-29 Avantium Knowledge Centre B.V. Sposób wytwarzania glikolu etylenowego z węglowodanu
PL3245183T3 (pl) 2015-01-13 2020-07-27 Avantium Knowledge Centre B.V. Sposób wytwarzania glikolu etylenowego ze źródła węglowodanów
WO2016114659A1 (en) 2015-01-13 2016-07-21 Avantium Knowledge Centre B.V. Process for preparing ethylene glycol from a carbohydrate source

Also Published As

Publication number Publication date
EP3245181A1 (en) 2017-11-22
BR112017014945B1 (pt) 2021-06-08
LT3245181T (lt) 2020-02-25
MX2017009161A (es) 2018-02-01
CA2973556A1 (en) 2016-07-21
EP3245181B1 (en) 2019-10-23
MY185257A (en) 2021-04-30
JP6553743B2 (ja) 2019-07-31
JP2018501321A (ja) 2018-01-18
CA2973556C (en) 2019-04-30
SG11201705686RA (en) 2017-08-30
AU2016207242B2 (en) 2018-09-13
AU2016207242A1 (en) 2017-08-03
UA118147C2 (uk) 2018-11-26
PL3245181T3 (pl) 2020-06-29
KR20170105063A (ko) 2017-09-18
CN107406358A (zh) 2017-11-28
US10138184B2 (en) 2018-11-27
US20180002259A1 (en) 2018-01-04
WO2016114661A1 (en) 2016-07-21
CN107406358B (zh) 2020-12-08

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Legal Events

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B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 13/01/2016, OBSERVADAS AS CONDICOES LEGAIS.