EP2736869A4 - Generation of polyols from saccharides - Google Patents

Generation of polyols from saccharides

Info

Publication number
EP2736869A4
EP2736869A4 EP12817777.1A EP12817777A EP2736869A4 EP 2736869 A4 EP2736869 A4 EP 2736869A4 EP 12817777 A EP12817777 A EP 12817777A EP 2736869 A4 EP2736869 A4 EP 2736869A4
Authority
EP
European Patent Office
Prior art keywords
saccharides
polyols
generation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP12817777.1A
Other languages
German (de)
French (fr)
Other versions
EP2736869A2 (en
Inventor
John Q Chen
Tom N Kalnes
Joseph A Kocal
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honeywell UOP LLC
Original Assignee
UOP LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/192,907 external-priority patent/US20110312487A1/en
Priority claimed from US13/192,970 external-priority patent/US8222462B2/en
Application filed by UOP LLC filed Critical UOP LLC
Publication of EP2736869A2 publication Critical patent/EP2736869A2/en
Publication of EP2736869A4 publication Critical patent/EP2736869A4/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6525—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6527—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8871—Rare earth metals or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
EP12817777.1A 2011-07-28 2012-07-03 Generation of polyols from saccharides Withdrawn EP2736869A4 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US13/192,907 US20110312487A1 (en) 2011-07-28 2011-07-28 Catalyst system for generation of polyols from saccharides
US13/192,970 US8222462B2 (en) 2011-07-28 2011-07-28 Process for generation of polyols from saccharides
PCT/US2012/045343 WO2013015955A2 (en) 2011-07-28 2012-07-03 Generation of polyols from saccharides

Publications (2)

Publication Number Publication Date
EP2736869A2 EP2736869A2 (en) 2014-06-04
EP2736869A4 true EP2736869A4 (en) 2015-01-07

Family

ID=47601711

Family Applications (1)

Application Number Title Priority Date Filing Date
EP12817777.1A Withdrawn EP2736869A4 (en) 2011-07-28 2012-07-03 Generation of polyols from saccharides

Country Status (6)

Country Link
EP (1) EP2736869A4 (en)
CN (1) CN103608320A (en)
BR (1) BR112013026705A2 (en)
CA (1) CA2832741A1 (en)
TW (1) TWI539994B (en)
WO (1) WO2013015955A2 (en)

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Publication number Priority date Publication date Assignee Title
BR112015020388B1 (en) 2013-04-05 2020-12-08 Shell Internationale Research Maatschappij B.V process for the catalytic conversion of a feed load containing saccharide
EP2981515B1 (en) 2013-04-05 2017-02-01 Shell Internationale Research Maatschappij B.V. Process for the preparation of glycols
WO2014173973A1 (en) 2013-04-26 2014-10-30 Shell Internationale Research Maatschappij B.V. Process for the preparation of monoethylene glycol
WO2015028398A1 (en) * 2013-08-26 2015-03-05 Shell Internationale Research Maatschappij B.V. Process for the preparation of glycols
EP3039002B1 (en) * 2013-08-30 2018-07-25 Shell International Research Maatschappij B.V. Process for the conversion of saccharide-containing feedstock
WO2015154258A1 (en) * 2014-04-09 2015-10-15 Petroliam Nasional Berhad (Petronas) Selective conversion of saccharide containing feedstock to ethylene glycol
CN111606781B (en) 2014-09-28 2023-11-28 长春美禾科技发展有限公司 Method for preparing dihydric alcohol
JP6494795B2 (en) 2015-01-13 2019-04-03 アバンティウム・ナレッジ・センター・ベー・フェー Process for producing ethylene glycol from carbohydrate sources
CN107428642B (en) * 2015-01-13 2020-11-27 阿凡田知识中心有限公司 Process for the preparation of ethylene glycol from a carbohydrate source
EP3245183B1 (en) * 2015-01-13 2019-10-23 Avantium Knowledge Centre B.v. Process for preparing ethylene glycol from a carbohydrate source
CA2973556C (en) 2015-01-13 2019-04-30 Avantium Knowledge Centre B.V. Continuous process for preparing ethylene glycol from a carbohydrate source
CA2989506C (en) * 2015-06-30 2023-10-10 Evert Van Der Heide Process for the preparation of glycols
CA2997373C (en) * 2015-09-07 2023-07-18 Shell Internationale Research Maatschappij B.V. Process for recovering a metallic component
BR112018010230A2 (en) * 2015-11-19 2018-11-27 Shell Int Research catalyst system and process for glycol production
BR112018010227B1 (en) * 2015-11-19 2021-03-23 Shell Internationale Research Maatschappij B.V. PROCESS FOR THE PREPARATION OF MONOETHYLENE GLYCOL FROM STARTING MATERIAL THAT UNDERSTANDS ONE OR MORE SACARIDES
WO2017085222A1 (en) * 2015-11-19 2017-05-26 Shell Internationale Research Maatschappij B.V. Catalyst system and process for the production of glycols
EP3377216A1 (en) * 2015-11-19 2018-09-26 Shell Internationale Research Maatschappij B.V. Catalyst system and process for the production of glycols
CN108367266B (en) 2015-12-09 2021-07-06 国际壳牌研究有限公司 Process for the preparation of diols
CN108602738A (en) 2016-02-09 2018-09-28 国际壳牌研究有限公司 The method for manufacturing aklylene glycol
CN108778446A (en) * 2016-03-07 2018-11-09 国际壳牌研究有限公司 Method for recycling metal component
CN116730800A (en) 2016-06-03 2023-09-12 泰恩工艺技术有限公司 Continuous process for highly selective conversion of aldohexose-producing carbohydrates to ethylene glycol
BR112019001733B1 (en) 2016-08-04 2023-01-17 Shell Internationale Research Maatschappij B.V. PROCESS FOR THE PREPARATION OF GLYCOLS FROM A FEED STOCK CONTAINING SACCHARIDE IN A REACTOR SYSTEM
CA3037049A1 (en) * 2016-09-29 2018-04-05 Shell Internationale Research Maatschappij B.V. Method for acid treatment conditioning of a catalyst in the production of glycols
BR112019008618B1 (en) * 2016-10-28 2022-06-28 Shell Internationale Research Maatschappij B.V. PROCESS FOR THE PRODUCTION OF GLYCOLS
BR112021004744A2 (en) 2018-09-13 2021-06-01 Shell Internationale Research Maatschappij B.V. starting process for the production of glycols
BR112021004750A2 (en) 2018-09-13 2021-06-01 Shell Internationale Research Maatschappij B.V. shutdown process for the production of glycols
WO2020212542A1 (en) 2019-04-17 2020-10-22 Shell Internationale Research Maatschappij B.V. Stirred injection mixing process
WO2023083948A1 (en) 2021-11-12 2023-05-19 Shell Internationale Research Maatschappij B.V. Process for separating glycol from diols
WO2023150656A1 (en) 2022-02-04 2023-08-10 Shell Usa, Inc. Process for producing glycol from renewable feedstock

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JP2007326849A (en) * 2006-05-09 2007-12-20 Kao Corp Method for producing polyhydric alcohol hydrogenolysis product
EP2017250A1 (en) * 2006-05-09 2009-01-21 Kao Corporation Process for producing product of hydrogenolysis of polyhydric alcohol
CN101768050A (en) * 2009-12-25 2010-07-07 北京大学 Method for preparing ethylene glycol and 1,2-propylene glycol
US20100256424A1 (en) * 2008-10-24 2010-10-07 Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences Method of preparing ethylene glycol cellulose
WO2011050691A1 (en) * 2009-10-27 2011-05-05 中国科学院大连化学物理研究所 Tungsten carbide catalyst supported on mesoporous carbon, preparation and application thereof
EP2548858A1 (en) * 2010-03-17 2013-01-23 Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences Process for preparing ethylene glycol from polyhydric compounds
WO2013015990A2 (en) * 2011-07-28 2013-01-31 Uop Llc Catalytic process for continuously generating polyols

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MY159308A (en) * 2009-12-30 2016-12-30 Virent Inc Catalysts for hydrodeoxygenation of polyols

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JP2007326849A (en) * 2006-05-09 2007-12-20 Kao Corp Method for producing polyhydric alcohol hydrogenolysis product
EP2017250A1 (en) * 2006-05-09 2009-01-21 Kao Corporation Process for producing product of hydrogenolysis of polyhydric alcohol
US20100256424A1 (en) * 2008-10-24 2010-10-07 Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences Method of preparing ethylene glycol cellulose
WO2011050691A1 (en) * 2009-10-27 2011-05-05 中国科学院大连化学物理研究所 Tungsten carbide catalyst supported on mesoporous carbon, preparation and application thereof
CN101768050A (en) * 2009-12-25 2010-07-07 北京大学 Method for preparing ethylene glycol and 1,2-propylene glycol
EP2548858A1 (en) * 2010-03-17 2013-01-23 Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences Process for preparing ethylene glycol from polyhydric compounds
WO2013015990A2 (en) * 2011-07-28 2013-01-31 Uop Llc Catalytic process for continuously generating polyols

Non-Patent Citations (2)

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Title
CHAMINAND J ET AL: "Glycerol hydrogenolysis on heterogeneous catalysts", GREEN CHEMISTRY, ROYAL SOCIETY OF CHEMISTRY, CAMBRIDGE, GB, vol. 6, 1 January 2004 (2004-01-01), pages 359 - 361, XP003016972, ISSN: 1463-9262, DOI: 10.1039/B407378A *
MING-YUAN ZHENG ET AL: "Transition Metal-Tungsten Bimetallic Catalysts for the Conversion of Cellulose into Ethylene Glycol", CHEMSUSCHEM, vol. 3, no. 1, 25 January 2010 (2010-01-25), pages 63 - 66, XP055003506, ISSN: 1864-5631, DOI: 10.1002/cssc.200900197 *

Also Published As

Publication number Publication date
CA2832741A1 (en) 2013-01-31
WO2013015955A2 (en) 2013-01-31
TWI539994B (en) 2016-07-01
EP2736869A2 (en) 2014-06-04
TW201315540A (en) 2013-04-16
CN103608320A (en) 2014-02-26
BR112013026705A2 (en) 2016-12-27
WO2013015955A3 (en) 2013-03-21

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