BR112017007586B1 - composição para perfume encapsulado, seu método de formação e produto para higiene pessoal sem enxague - Google Patents
composição para perfume encapsulado, seu método de formação e produto para higiene pessoal sem enxague Download PDFInfo
- Publication number
- BR112017007586B1 BR112017007586B1 BR112017007586-5A BR112017007586A BR112017007586B1 BR 112017007586 B1 BR112017007586 B1 BR 112017007586B1 BR 112017007586 A BR112017007586 A BR 112017007586A BR 112017007586 B1 BR112017007586 B1 BR 112017007586B1
- Authority
- BR
- Brazil
- Prior art keywords
- perfume
- capsules
- composition
- weight
- encapsulated perfume
- Prior art date
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- 239000002304 perfume Substances 0.000 title claims abstract description 186
- 239000000203 mixture Substances 0.000 title claims abstract description 98
- 238000000034 method Methods 0.000 title claims description 41
- 230000015572 biosynthetic process Effects 0.000 title description 10
- 239000002775 capsule Substances 0.000 claims abstract description 129
- 229920002396 Polyurea Polymers 0.000 claims abstract description 32
- 239000004615 ingredient Substances 0.000 claims description 57
- 239000000839 emulsion Substances 0.000 claims description 49
- 230000001166 anti-perspirative effect Effects 0.000 claims description 22
- 239000003213 antiperspirant Substances 0.000 claims description 22
- 239000002781 deodorant agent Substances 0.000 claims description 22
- 239000000843 powder Substances 0.000 claims description 16
- 239000002904 solvent Substances 0.000 claims description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 238000001694 spray drying Methods 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 5
- 241001465754 Metazoa Species 0.000 abstract description 4
- 239000000047 product Substances 0.000 description 46
- 150000001299 aldehydes Chemical group 0.000 description 36
- -1 terpene hydrocarbons Chemical class 0.000 description 30
- 239000000463 material Substances 0.000 description 25
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical class O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 22
- 230000008569 process Effects 0.000 description 19
- 239000011162 core material Substances 0.000 description 18
- 230000007062 hydrolysis Effects 0.000 description 18
- 238000006460 hydrolysis reaction Methods 0.000 description 18
- 239000003921 oil Substances 0.000 description 18
- 229920002451 polyvinyl alcohol Polymers 0.000 description 18
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 15
- 229910052782 aluminium Inorganic materials 0.000 description 14
- 239000004372 Polyvinyl alcohol Substances 0.000 description 13
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 13
- 150000001412 amines Chemical group 0.000 description 13
- 239000006185 dispersion Substances 0.000 description 13
- 239000008346 aqueous phase Substances 0.000 description 12
- 239000012071 phase Substances 0.000 description 12
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 10
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 10
- 239000000084 colloidal system Substances 0.000 description 10
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 10
- 239000012948 isocyanate Substances 0.000 description 10
- 150000002513 isocyanates Chemical class 0.000 description 10
- 239000000523 sample Substances 0.000 description 9
- 229920002472 Starch Polymers 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 8
- 229920001577 copolymer Polymers 0.000 description 8
- 230000001681 protective effect Effects 0.000 description 8
- 235000019698 starch Nutrition 0.000 description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 7
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 7
- 238000005538 encapsulation Methods 0.000 description 7
- 239000000178 monomer Substances 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- 210000004243 sweat Anatomy 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 125000004122 cyclic group Chemical group 0.000 description 6
- 238000009826 distribution Methods 0.000 description 6
- 230000002209 hydrophobic effect Effects 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000003094 microcapsule Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- 239000004471 Glycine Substances 0.000 description 5
- 229920002873 Polyethylenimine Polymers 0.000 description 5
- 239000004480 active ingredient Substances 0.000 description 5
- 230000002776 aggregation Effects 0.000 description 5
- 125000000129 anionic group Chemical group 0.000 description 5
- 238000000149 argon plasma sintering Methods 0.000 description 5
- UREZNYTWGJKWBI-UHFFFAOYSA-M benzethonium chloride Chemical compound [Cl-].C1=CC(C(C)(C)CC(C)(C)C)=CC=C1OCCOCC[N+](C)(C)CC1=CC=CC=C1 UREZNYTWGJKWBI-UHFFFAOYSA-M 0.000 description 5
- 125000002091 cationic group Chemical group 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 125000000524 functional group Chemical group 0.000 description 5
- JARKCYVAAOWBJS-UHFFFAOYSA-N hexanal Chemical compound CCCCCC=O JARKCYVAAOWBJS-UHFFFAOYSA-N 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 239000003755 preservative agent Substances 0.000 description 5
- CZCBTSFUTPZVKJ-UHFFFAOYSA-N rose oxide Chemical compound CC1CCOC(C=C(C)C)C1 CZCBTSFUTPZVKJ-UHFFFAOYSA-N 0.000 description 5
- 229960001860 salicylate Drugs 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000008107 starch Substances 0.000 description 5
- KMPQYAYAQWNLME-UHFFFAOYSA-N undecanal Chemical compound CCCCCCCCCCC=O KMPQYAYAQWNLME-UHFFFAOYSA-N 0.000 description 5
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 150000001241 acetals Chemical class 0.000 description 4
- 150000001413 amino acids Chemical class 0.000 description 4
- 150000001805 chlorine compounds Chemical class 0.000 description 4
- 239000002612 dispersion medium Substances 0.000 description 4
- WFEISWUNAJPLRX-ONNFQVAWSA-N dupical Chemical compound C12CCCC2C2C\C(=C/CCC=O)C1C2 WFEISWUNAJPLRX-ONNFQVAWSA-N 0.000 description 4
- 229920000159 gelatin Polymers 0.000 description 4
- 235000019322 gelatine Nutrition 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 150000002576 ketones Chemical class 0.000 description 4
- 238000005191 phase separation Methods 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 4
- 208000035985 Body Odor Diseases 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 3
- 108010010803 Gelatin Proteins 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 238000004220 aggregation Methods 0.000 description 3
- YPZUZOLGGMJZJO-UHFFFAOYSA-N ambrofix Natural products C1CC2C(C)(C)CCCC2(C)C2C1(C)OCC2 YPZUZOLGGMJZJO-UHFFFAOYSA-N 0.000 description 3
- 239000012736 aqueous medium Substances 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000006071 cream Substances 0.000 description 3
- KSMVZQYAVGTKIV-UHFFFAOYSA-N decanal Chemical compound CCCCCCCCCC=O KSMVZQYAVGTKIV-UHFFFAOYSA-N 0.000 description 3
- HFJRKMMYBMWEAD-UHFFFAOYSA-N dodecanal Chemical compound CCCCCCCCCCCC=O HFJRKMMYBMWEAD-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 239000008273 gelatin Substances 0.000 description 3
- 235000011852 gelatine desserts Nutrition 0.000 description 3
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 3
- FXHGMKSSBGDXIY-UHFFFAOYSA-N heptanal Chemical compound CCCCCCC=O FXHGMKSSBGDXIY-UHFFFAOYSA-N 0.000 description 3
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- ZYTMANIQRDEHIO-KXUCPTDWSA-N isopulegol Chemical compound C[C@@H]1CC[C@@H](C(C)=C)[C@H](O)C1 ZYTMANIQRDEHIO-KXUCPTDWSA-N 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical class [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 description 3
- GYHFUZHODSMOHU-UHFFFAOYSA-N nonanal Chemical compound CCCCCCCCC=O GYHFUZHODSMOHU-UHFFFAOYSA-N 0.000 description 3
- NUJGJRNETVAIRJ-UHFFFAOYSA-N octanal Chemical compound CCCCCCCC=O NUJGJRNETVAIRJ-UHFFFAOYSA-N 0.000 description 3
- ZRSNZINYAWTAHE-UHFFFAOYSA-N p-methoxybenzaldehyde Chemical compound COC1=CC=C(C=O)C=C1 ZRSNZINYAWTAHE-UHFFFAOYSA-N 0.000 description 3
- 230000037081 physical activity Effects 0.000 description 3
- 229920000058 polyacrylate Polymers 0.000 description 3
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- 239000001267 polyvinylpyrrolidone Substances 0.000 description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 3
- 230000002335 preservative effect Effects 0.000 description 3
- GHBFNMLVSPCDGN-UHFFFAOYSA-N rac-1-monooctanoylglycerol Chemical compound CCCCCCCC(=O)OCC(O)CO GHBFNMLVSPCDGN-UHFFFAOYSA-N 0.000 description 3
- 230000004044 response Effects 0.000 description 3
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- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 3
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- 239000010457 zeolite Substances 0.000 description 3
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical compound C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 2
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- ULDHMXUKGWMISQ-SECBINFHSA-N (-)-carvone Chemical compound CC(=C)[C@@H]1CC=C(C)C(=O)C1 ULDHMXUKGWMISQ-SECBINFHSA-N 0.000 description 2
- FINOAUDUYKVGDS-UHFFFAOYSA-N (2-tert-butylcyclohexyl) acetate Chemical compound CC(=O)OC1CCCCC1C(C)(C)C FINOAUDUYKVGDS-UHFFFAOYSA-N 0.000 description 2
- HZYHMHHBBBSGHB-ODYTWBPASA-N (2E,6Z)-nona-2,6-dienal Chemical compound CC\C=C/CC\C=C\C=O HZYHMHHBBBSGHB-ODYTWBPASA-N 0.000 description 2
- MXIGGIZQUGDKAP-UHFFFAOYSA-N (4-methyl-4-phenylpentan-2-yl) acetate Chemical compound CC(=O)OC(C)CC(C)(C)C1=CC=CC=C1 MXIGGIZQUGDKAP-UHFFFAOYSA-N 0.000 description 2
- CWRKZMLUDFBPAO-VOTSOKGWSA-N (e)-dec-4-enal Chemical compound CCCCC\C=C\CCC=O CWRKZMLUDFBPAO-VOTSOKGWSA-N 0.000 description 2
- BVDMQAQCEBGIJR-UHFFFAOYSA-N 1-(2,2,6-trimethylcyclohexyl)hexan-3-ol Chemical compound CCCC(O)CCC1C(C)CCCC1(C)C BVDMQAQCEBGIJR-UHFFFAOYSA-N 0.000 description 2
- YBUIAJZFOGJGLJ-SWRJLBSHSA-N 1-cedr-8-en-9-ylethanone Chemical compound C1[C@]23[C@H](C)CC[C@H]3C(C)(C)[C@@H]1C(C)=C(C(C)=O)C2 YBUIAJZFOGJGLJ-SWRJLBSHSA-N 0.000 description 2
- ZYVYEJXMYBUCMN-UHFFFAOYSA-N 1-methoxy-2-methylpropane Chemical class COCC(C)C ZYVYEJXMYBUCMN-UHFFFAOYSA-N 0.000 description 2
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- JEPWTUCYPWOCQV-UHFFFAOYSA-N 2,4-dimethyl-2-(5,5,8,8-tetramethyl-6,7-dihydronaphthalen-2-yl)-1,3-dioxolane Chemical compound O1C(C)COC1(C)C1=CC=C2C(C)(C)CCC(C)(C)C2=C1 JEPWTUCYPWOCQV-UHFFFAOYSA-N 0.000 description 2
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- UEGBWDUVDAKUGA-UHFFFAOYSA-N 2,6,10-trimethylundec-9-enal Chemical compound CC(C)=CCCC(C)CCCC(C)C=O UEGBWDUVDAKUGA-UHFFFAOYSA-N 0.000 description 2
- RQXTZKGDMNIWJF-UHFFFAOYSA-N 2-butan-2-ylcyclohexan-1-one Chemical compound CCC(C)C1CCCCC1=O RQXTZKGDMNIWJF-UHFFFAOYSA-N 0.000 description 2
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- VKPRTBDRPNWOGL-UHFFFAOYSA-N 3,4,4a,5,8,8a-hexahydro-3',7-dimethyl-spiro(1,4-methanonaphthalene-2(1h),2'-oxirane) Chemical compound CC1OC11C(C2C3CC=C(C)C2)CC3C1 VKPRTBDRPNWOGL-UHFFFAOYSA-N 0.000 description 2
- JFTSYAALCNQOKO-UHFFFAOYSA-N 3-(4-ethylphenyl)-2,2-dimethylpropanal Chemical compound CCC1=CC=C(CC(C)(C)C=O)C=C1 JFTSYAALCNQOKO-UHFFFAOYSA-N 0.000 description 2
- DFJMIMVMOIFPQG-UHFFFAOYSA-N 3-methyl-5-phenylpentanal Chemical compound O=CCC(C)CCC1=CC=CC=C1 DFJMIMVMOIFPQG-UHFFFAOYSA-N 0.000 description 2
- MYHGOWDLVRDUFA-UHFFFAOYSA-N 3-phenylbutanal Chemical compound O=CCC(C)C1=CC=CC=C1 MYHGOWDLVRDUFA-UHFFFAOYSA-N 0.000 description 2
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- YVSNOTITPICPTB-UHFFFAOYSA-N 4-methyl-2-(2-methylpropyl)oxan-4-ol Chemical compound CC(C)CC1CC(C)(O)CCO1 YVSNOTITPICPTB-UHFFFAOYSA-N 0.000 description 2
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- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
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- A—HUMAN NECESSITIES
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- C—CHEMISTRY; METALLURGY
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- A61K2800/60—Particulates further characterized by their structure or composition
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- A61K2800/62—Coated
- A61K2800/624—Coated by macromolecular compounds
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- A—HUMAN NECESSITIES
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- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/60—Particulates further characterized by their structure or composition
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- A61K2800/652—The particulate/core comprising organic material
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| PCT/EP2015/074813 WO2016071151A1 (en) | 2014-11-07 | 2015-10-27 | Capsule composition |
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| BR112017007586A2 BR112017007586A2 (pt) | 2017-12-19 |
| BR112017007586B1 true BR112017007586B1 (pt) | 2020-12-01 |
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| EP3471874B1 (en) | 2016-06-17 | 2020-03-18 | TRuCapSol, LLC. | Controlled release particles and methods for preparation thereof |
| GB201615905D0 (en) | 2016-09-19 | 2016-11-02 | Givaudan Sa | Improvements in or relating to organic compounds |
| WO2019039385A1 (ja) * | 2017-08-21 | 2019-02-28 | 富士フイルム株式会社 | マイクロカプセル、組成物及び化粧用シート |
| WO2019173062A1 (en) | 2018-03-07 | 2019-09-12 | Trucapsol, Llc | Reduced permeability microcapsules |
| GB201804038D0 (en) * | 2018-03-14 | 2018-04-25 | Givaudan Sa | Improvements in or realating to organic compounds |
| US11344502B1 (en) | 2018-03-29 | 2022-05-31 | Trucapsol Llc | Vitamin delivery particle |
| MX2020008896A (es) * | 2018-03-30 | 2020-10-12 | Firmenich & Cie | Proceso para preparar microcapsulas con deposicion mejorada. |
| JP7177855B2 (ja) * | 2018-04-24 | 2022-11-24 | シムライズ アーゲー | 直鎖および環式脂肪族ポリイソシアネートで調製されたコア-シェルカプセル |
| CN108714117B (zh) * | 2018-07-06 | 2021-04-27 | 浙江丽芙秀化妆品有限公司 | 一种长效香水及其制备方法 |
| US11794161B1 (en) | 2018-11-21 | 2023-10-24 | Trucapsol, Llc | Reduced permeability microcapsules |
| JP7267439B2 (ja) * | 2019-02-13 | 2023-05-01 | シムライズ アーゲー | マイクロカプセルの調製のためのプロセス |
| US11571674B1 (en) | 2019-03-28 | 2023-02-07 | Trucapsol Llc | Environmentally biodegradable microcapsules |
| US11542392B1 (en) | 2019-04-18 | 2023-01-03 | Trucapsol Llc | Multifunctional particle additive for enhancement of toughness and degradation in biodegradable polymers |
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| US12302933B2 (en) | 2021-06-25 | 2025-05-20 | Trucapsol Llc | Flavor delivery system |
| US12187829B2 (en) | 2021-08-12 | 2025-01-07 | Trucapsol Llc | Environmentally biodegradable microcapsules |
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| US11878280B2 (en) | 2022-04-19 | 2024-01-23 | Trucapsol Llc | Microcapsules comprising natural materials |
| US11904288B1 (en) | 2023-02-13 | 2024-02-20 | Trucapsol Llc | Environmentally biodegradable microcapsules |
| US11969491B1 (en) | 2023-02-22 | 2024-04-30 | Trucapsol Llc | pH triggered release particle |
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| GB201010701D0 (en) | 2010-06-25 | 2010-08-11 | Givaudan Sa | Process for producing microcapsules |
| EP2399667B1 (en) | 2010-06-25 | 2017-03-08 | Cognis IP Management GmbH | Process for producing microcapsules |
| WO2011161265A2 (en) | 2010-06-25 | 2011-12-29 | Givaudan Sa | Compositions |
| US20130249059A1 (en) | 2010-11-29 | 2013-09-26 | The Nippon Synthetic Chemical Industry Co., Ltd. | Coating liquid for impurity diffusion |
| WO2012107323A1 (en) | 2011-02-07 | 2012-08-16 | Firmenich Sa | Polyurea microcapsules |
| PL2822682T3 (pl) | 2011-11-29 | 2017-09-29 | Firmenich Sa | Mikrokapsułki i ich zastosowanie |
| MX380407B (es) | 2011-12-07 | 2025-03-12 | Givaudan Sa | Microcapsulas, proceso para elaborar las microcapsulas, y composiciones que utilizan las microcapsulas. |
| JP2015502969A (ja) * | 2011-12-22 | 2015-01-29 | ジボダン エス エー | 香料のカプセル化におけるまたは香料のカプセル化に関わる改善 |
| WO2013092375A1 (en) | 2011-12-22 | 2013-06-27 | Firmenich Sa | Process for preparing polyurea microcapsules |
| TWI646978B (zh) | 2012-10-25 | 2019-01-11 | Givaudan Sa | 膠囊 |
| CN105246456A (zh) | 2013-05-22 | 2016-01-13 | 弗门尼舍有限公司 | 含有释放气体的对光不稳定的化合物的微胶囊及其用途 |
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2015
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- 2015-10-27 JP JP2017524346A patent/JP6883514B2/ja active Active
- 2015-10-27 BR BR112017007586-5A patent/BR112017007586B1/pt active IP Right Grant
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| US10398632B2 (en) | 2019-09-03 |
| CN107072925A (zh) | 2017-08-18 |
| EP3215231B1 (en) | 2020-12-16 |
| JP2017533240A (ja) | 2017-11-09 |
| CN107072925B (zh) | 2021-03-12 |
| EP3215231A1 (en) | 2017-09-13 |
| US20180228702A1 (en) | 2018-08-16 |
| JP6883514B2 (ja) | 2021-06-09 |
| BR112017007586A2 (pt) | 2017-12-19 |
| EP3215231B2 (en) | 2024-07-31 |
| KR102547707B1 (ko) | 2023-06-23 |
| KR20170072344A (ko) | 2017-06-26 |
| WO2016071151A1 (en) | 2016-05-12 |
| ZA201702202B (en) | 2019-06-26 |
| MX2017004536A (es) | 2017-06-27 |
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