BR112017005347A2 - estabilidade de catalisador e prevenção de corrosão aperfeiçoadas no processo de produção de ácido acético - Google Patents

estabilidade de catalisador e prevenção de corrosão aperfeiçoadas no processo de produção de ácido acético

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Publication number
BR112017005347A2
BR112017005347A2 BR112017005347A BR112017005347A BR112017005347A2 BR 112017005347 A2 BR112017005347 A2 BR 112017005347A2 BR 112017005347 A BR112017005347 A BR 112017005347A BR 112017005347 A BR112017005347 A BR 112017005347A BR 112017005347 A2 BR112017005347 A2 BR 112017005347A2
Authority
BR
Brazil
Prior art keywords
acetic acid
metal salts
combinations
additives
production process
Prior art date
Application number
BR112017005347A
Other languages
English (en)
Other versions
BR112017005347B1 (pt
Inventor
A Salisbury Brian
f white Daniel
L Ramage David
T Fern Jared
C Hallinan Noel
Original Assignee
Lyondellbasell Acetyls Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lyondellbasell Acetyls Llc filed Critical Lyondellbasell Acetyls Llc
Publication of BR112017005347A2 publication Critical patent/BR112017005347A2/pt
Publication of BR112017005347B1 publication Critical patent/BR112017005347B1/pt

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/464—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20—Carbon compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/50—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/08—Acetic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

trata-se de processos para produzir ácido acético que incluem, em geral, colocar em contato metanol e monóxido de carbono na presença de um meio de reação sob condições de carbonilação suficientes para formar ácido acético, em que o meio de reação inclui um catalisador de carbonilação selecionado dentre catalisadores de ródio, catalisadores de irídio e catalisadores de paládio; de 1% em peso a 14% em peso de água; e uma pluralidade de aditivos, derivados gerados in situ da pluralidade de aditivos ou combinações dos mesmos; e a pluralidade de aditivos inclui um primeiro aditivo que inclui um ou mais óxidos de fosfina e um segundo aditivo selecionado dentre heteropoliácidos, sais metálicos e combinações dos mesmos, em que os heteropoliácidos são representados pela fórmula hnm12xo40, em que h é hidrogênio, m é selecionado dentre tungstênio e molibdênio, x é selecionado dentre fósforo e silício e o é oxigênio, e n é 3 ou 4, e os sais metálicos são selecionados dentre sais metálicos de transição, sais metálicos de lantanídio e combinações dos mesmos; e recuperar ácido acético a partir do processo.
BR112017005347-0A 2014-09-22 2015-09-21 estabilidade de catalisador e prevenção de corrosão aperfeiçoadas no processo de produção de ácido acético BR112017005347B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US14/492,529 US9475746B2 (en) 2014-09-22 2014-09-22 Catalyst stability and corrosion prevention in acetic acid production process
US14/492,529 2014-09-22
PCT/US2015/051211 WO2016048889A1 (en) 2014-09-22 2015-09-21 Improved catalyst stability and corrosion prevention in acetic acid production process

Publications (2)

Publication Number Publication Date
BR112017005347A2 true BR112017005347A2 (pt) 2017-12-12
BR112017005347B1 BR112017005347B1 (pt) 2020-10-20

Family

ID=54207834

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112017005347-0A BR112017005347B1 (pt) 2014-09-22 2015-09-21 estabilidade de catalisador e prevenção de corrosão aperfeiçoadas no processo de produção de ácido acético

Country Status (7)

Country Link
US (2) US9475746B2 (pt)
EP (1) EP3197855B1 (pt)
KR (1) KR101823845B1 (pt)
CN (1) CN106715378B (pt)
BR (1) BR112017005347B1 (pt)
SG (1) SG11201702183RA (pt)
WO (1) WO2016048889A1 (pt)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9475746B2 (en) * 2014-09-22 2016-10-25 Lyondellbasell Acetyls, Llc Catalyst stability and corrosion prevention in acetic acid production process
CN117120408B (zh) * 2021-04-02 2024-05-07 利安德巴塞尔乙酰有限责任公司 用于生产乙酸的方法和系统
WO2023137005A1 (en) 2022-01-11 2023-07-20 Lyondellbasell Acetyls, Llc Removal of aldehydes in acetic acid production
WO2023154545A1 (en) 2022-02-14 2023-08-17 Lyondellbasell Acetyls, Llc Removal of aldehydes in acetic acid production
WO2023158791A1 (en) 2022-02-18 2023-08-24 Lyondellbasell Acetyls, Llc Removal of aldehydes in acetic acid production

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4909939A (en) 1984-06-16 1990-03-20 American Cyanamid Company Process for solvent extraction using phosphine oxide mixtures
US5817869A (en) 1995-10-03 1998-10-06 Quantum Chemical Corporation Use of pentavalent Group VA oxides in acetic acid processing
GB9625335D0 (en) 1996-12-05 1997-01-22 Bp Chem Int Ltd Process
CN1113845C (zh) * 1998-05-27 2003-07-09 千年石油化工公司 五价va族氧化物在乙酸制备方法中的应用
US6552221B1 (en) 1998-12-18 2003-04-22 Millenium Petrochemicals, Inc. Process control for acetic acid manufacture
DE19923118A1 (de) * 1999-05-19 2000-11-23 Henkel Kgaa Chromfreies Korrosionsschutzmittel und Korrosionsschutzverfahren
WO2011159268A1 (en) * 2010-06-14 2011-12-22 Celanese Internaltional Corporation Carbonylation process
US8785684B2 (en) 2010-06-14 2014-07-22 Celanese International Corporation Methanol carbonylation process with rhodium catalyst, an iodide salt and a metallic co-catalyst selected from transition metals, indium, strontium, barium, zinc, tin and heteropoly acids
US8835681B2 (en) 2010-06-14 2014-09-16 Celanese International Corporation Methanol carbonylation process with rhodium catalyst and a lanthanide metal co-catalyst
US8519182B2 (en) * 2010-10-18 2013-08-27 Lyondell Chemical Technology, L.P. Acetic acid production process
US9475746B2 (en) * 2014-09-22 2016-10-25 Lyondellbasell Acetyls, Llc Catalyst stability and corrosion prevention in acetic acid production process

Also Published As

Publication number Publication date
US20170008827A1 (en) 2017-01-12
US9790159B2 (en) 2017-10-17
US20160083324A1 (en) 2016-03-24
EP3197855A1 (en) 2017-08-02
SG11201702183RA (en) 2017-04-27
KR101823845B1 (ko) 2018-01-30
EP3197855B1 (en) 2019-10-23
WO2016048889A1 (en) 2016-03-31
CN106715378B (zh) 2018-02-09
BR112017005347B1 (pt) 2020-10-20
KR20170072875A (ko) 2017-06-27
US9475746B2 (en) 2016-10-25
CN106715378A (zh) 2017-05-24

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Legal Events

Date Code Title Description
B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 21/09/2015, OBSERVADAS AS CONDICOES LEGAIS.