SG11201702183RA - Improved catalyst stability and corrosion prevention in acetic acid production process - Google Patents

Improved catalyst stability and corrosion prevention in acetic acid production process

Info

Publication number
SG11201702183RA
SG11201702183RA SG11201702183RA SG11201702183RA SG11201702183RA SG 11201702183R A SG11201702183R A SG 11201702183RA SG 11201702183R A SG11201702183R A SG 11201702183RA SG 11201702183R A SG11201702183R A SG 11201702183RA SG 11201702183R A SG11201702183R A SG 11201702183RA
Authority
SG
Singapore
Prior art keywords
acetic acid
production process
acid production
corrosion prevention
improved catalyst
Prior art date
Application number
SG11201702183RA
Inventor
Noel C Hallinan
Brian A Salisbury
Daniel F White
David L Ramage
Jared T Fern
Original Assignee
Lyondellbasell Acetyls Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lyondellbasell Acetyls Llc filed Critical Lyondellbasell Acetyls Llc
Publication of SG11201702183RA publication Critical patent/SG11201702183RA/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/464—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20—Carbon compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/50—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/08—Acetic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
SG11201702183RA 2014-09-22 2015-09-21 Improved catalyst stability and corrosion prevention in acetic acid production process SG11201702183RA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US14/492,529 US9475746B2 (en) 2014-09-22 2014-09-22 Catalyst stability and corrosion prevention in acetic acid production process
PCT/US2015/051211 WO2016048889A1 (en) 2014-09-22 2015-09-21 Improved catalyst stability and corrosion prevention in acetic acid production process

Publications (1)

Publication Number Publication Date
SG11201702183RA true SG11201702183RA (en) 2017-04-27

Family

ID=54207834

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201702183RA SG11201702183RA (en) 2014-09-22 2015-09-21 Improved catalyst stability and corrosion prevention in acetic acid production process

Country Status (7)

Country Link
US (2) US9475746B2 (en)
EP (1) EP3197855B1 (en)
KR (1) KR101823845B1 (en)
CN (1) CN106715378B (en)
BR (1) BR112017005347B1 (en)
SG (1) SG11201702183RA (en)
WO (1) WO2016048889A1 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9475746B2 (en) * 2014-09-22 2016-10-25 Lyondellbasell Acetyls, Llc Catalyst stability and corrosion prevention in acetic acid production process
CN117120408B (en) * 2021-04-02 2024-05-07 利安德巴塞尔乙酰有限责任公司 Method and system for producing acetic acid
KR20240120741A (en) 2022-01-11 2024-08-07 라이온델바젤 아세틸, 엘엘씨 Removal of aldehydes in acetic acid production
US20230257335A1 (en) 2022-02-14 2023-08-17 Lyondellbasell Acetyls, Llc Removal of aldehydes in acetic acid production
WO2023158791A1 (en) 2022-02-18 2023-08-24 Lyondellbasell Acetyls, Llc Removal of aldehydes in acetic acid production
WO2024168128A1 (en) 2023-02-10 2024-08-15 Lyondellbasell Acetyls, Llc Control of iodides in acetic acid production

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4909939A (en) 1984-06-16 1990-03-20 American Cyanamid Company Process for solvent extraction using phosphine oxide mixtures
US5817869A (en) 1995-10-03 1998-10-06 Quantum Chemical Corporation Use of pentavalent Group VA oxides in acetic acid processing
GB9625335D0 (en) 1996-12-05 1997-01-22 Bp Chem Int Ltd Process
CN1113845C (en) * 1998-05-27 2003-07-09 千年石油化工公司 Use of pentavalent group VA oxides in acetic acid processing
US6552221B1 (en) 1998-12-18 2003-04-22 Millenium Petrochemicals, Inc. Process control for acetic acid manufacture
DE19923118A1 (en) * 1999-05-19 2000-11-23 Henkel Kgaa Polymerizable composition for the anticorrosion coating of metallic substrates contains an organic titanium, silicon or zirconium compound
SG186330A1 (en) 2010-06-14 2013-01-30 Celanese Int Corp Carbonylation process
US8785684B2 (en) 2010-06-14 2014-07-22 Celanese International Corporation Methanol carbonylation process with rhodium catalyst, an iodide salt and a metallic co-catalyst selected from transition metals, indium, strontium, barium, zinc, tin and heteropoly acids
US8835681B2 (en) 2010-06-14 2014-09-16 Celanese International Corporation Methanol carbonylation process with rhodium catalyst and a lanthanide metal co-catalyst
US8519182B2 (en) * 2010-10-18 2013-08-27 Lyondell Chemical Technology, L.P. Acetic acid production process
US9475746B2 (en) * 2014-09-22 2016-10-25 Lyondellbasell Acetyls, Llc Catalyst stability and corrosion prevention in acetic acid production process

Also Published As

Publication number Publication date
KR20170072875A (en) 2017-06-27
US9790159B2 (en) 2017-10-17
WO2016048889A1 (en) 2016-03-31
EP3197855B1 (en) 2019-10-23
KR101823845B1 (en) 2018-01-30
US20170008827A1 (en) 2017-01-12
CN106715378A (en) 2017-05-24
BR112017005347A2 (en) 2017-12-12
BR112017005347B1 (en) 2020-10-20
US9475746B2 (en) 2016-10-25
US20160083324A1 (en) 2016-03-24
CN106715378B (en) 2018-02-09
EP3197855A1 (en) 2017-08-02

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