BR112015032249A2 - copolímero heterofásico - Google Patents
copolímero heterofásicoInfo
- Publication number
- BR112015032249A2 BR112015032249A2 BR112015032249A BR112015032249A BR112015032249A2 BR 112015032249 A2 BR112015032249 A2 BR 112015032249A2 BR 112015032249 A BR112015032249 A BR 112015032249A BR 112015032249 A BR112015032249 A BR 112015032249A BR 112015032249 A2 BR112015032249 A2 BR 112015032249A2
- Authority
- BR
- Brazil
- Prior art keywords
- copolymer
- ethylene
- weight
- propylene
- heterophasic
- Prior art date
Links
- 229920001577 copolymer Polymers 0.000 title abstract 7
- 239000011159 matrix material Substances 0.000 abstract 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 2
- 239000005977 Ethylene Substances 0.000 abstract 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 2
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 abstract 2
- 239000008096 xylene Substances 0.000 abstract 2
- 229920000181 Ethylene propylene rubber Polymers 0.000 abstract 1
- 238000006555 catalytic reaction Methods 0.000 abstract 1
- 229920001384 propylene homopolymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/02—Heterophasic composition
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
a presente invenção se refere a um copolímero heterofásico de propileno etileno que tem um r2mfr2 de 0,5 até 100 g/10 minutos e que é obtido com a utilização de um único sítio de catálise, que compreende: (i) pelo menos 40% em peso de uma matriz de homopolímero de propileno ou copolímero de propileno etileno que tenha até 4% em peso de etileno; e (ii) pelo menos 10% em peso de uma borracha de etileno propileno dispersa na matriz; o referido copolímero heterofásico de propileno etileno tendo um teor de xileno solúvel a frio (xs) de 12 até 60%; em que o conteúdo de etileno da fração solúvel a frio de xileno do referido copolímero de propileno etileno está entre 18 e 70% em peso; e vem que a viscosidade intrínseca da fração xs do referido copolímero heterofásico de propileno etileno é maior do que a viscosidade intrínseca da fração da matriz do referido copolímero.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP13176366.6A EP2824142B1 (en) | 2013-07-12 | 2013-07-12 | Heterophasic copolymer |
| PCT/EP2014/064845 WO2015004251A1 (en) | 2013-07-12 | 2014-07-10 | Heterophasic copolymer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR112015032249A2 true BR112015032249A2 (pt) | 2017-07-25 |
Family
ID=48783067
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112015032249A BR112015032249A2 (pt) | 2013-07-12 | 2014-07-10 | copolímero heterofásico |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US11299610B2 (pt) |
| EP (2) | EP2824142B1 (pt) |
| JP (1) | JP6420335B2 (pt) |
| KR (1) | KR101860241B1 (pt) |
| CN (1) | CN105593287B (pt) |
| BR (1) | BR112015032249A2 (pt) |
| ES (1) | ES2569733T3 (pt) |
| PL (1) | PL2824142T3 (pt) |
| RU (1) | RU2668075C2 (pt) |
| WO (1) | WO2015004251A1 (pt) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2622299T3 (es) | 2014-01-07 | 2017-07-06 | Borealis Ag | Polímero de polipropileno heterofásico |
| EP2995629B1 (en) * | 2014-09-12 | 2018-03-07 | Borealis AG | Process for producing propylene copolymers in gas phase |
| EP3868824B1 (en) * | 2014-12-19 | 2023-12-06 | SABIC Global Technologies B.V. | Heterophasic propylene copolymer |
| MX365523B (es) * | 2015-11-17 | 2019-06-06 | Borealis Ag | Composicion de poliolefina termoplastica (tpo) de flujo elevado con excelente impacto a baja temperatura. |
| EP3170864B1 (en) * | 2015-11-17 | 2018-10-17 | Borealis AG | High flow tpo composition with excellent balance in mechanical properties for automotive interior |
| CN118126447A (zh) | 2015-11-17 | 2024-06-04 | 博里利斯股份公司 | 具有优异的断裂拉伸应变和低粉粘性的高流动性tpo组合物 |
| CN108290338B (zh) * | 2015-11-24 | 2019-08-30 | 巴塞尔聚烯烃股份有限公司 | 聚烯烃组合物及其制造的制品 |
| ES2772748T3 (es) * | 2016-01-29 | 2020-07-08 | Borealis Ag | Copolímero de propileno heterofásico con baja contracción |
| CN110248968B (zh) * | 2016-12-12 | 2022-05-27 | Sabic环球技术有限责任公司 | 制造低排放均聚物或无规聚丙烯的方法 |
| CN110198963B (zh) * | 2016-12-12 | 2022-06-24 | Sabic环球技术有限责任公司 | 制造低排放异相聚丙烯的方法 |
| EP3645588A1 (en) * | 2017-06-27 | 2020-05-06 | ExxonMobil Chemical Patents Inc. | High impact polypropylene impact copolymer |
| KR102307179B1 (ko) * | 2017-07-07 | 2021-09-30 | 보레알리스 아게 | 헤테로상 프로필렌 공중합체의 제조 방법 |
| US11613637B2 (en) | 2017-09-14 | 2023-03-28 | Basell Poliolefine Italia S.R.L. | Permeable polymer film |
| US10907036B2 (en) | 2017-10-13 | 2021-02-02 | Borealis Ag | Multimodal random heterophasic polypropylene composition |
| KR102060900B1 (ko) * | 2017-12-19 | 2020-02-11 | (주)휴이노베이션 | 반균질상의 폴리프로필렌/프로필렌공중합체 폴리머 조성물 |
| ES2909744T3 (es) | 2017-12-20 | 2022-05-10 | Borealis Ag | Composición heterofásica de polipropileno |
| EP3505566A1 (en) * | 2017-12-28 | 2019-07-03 | Borealis AG | Cable jacket |
| JP7096681B2 (ja) * | 2018-03-16 | 2022-07-06 | サンアロマー株式会社 | ポリプロピレン組成物および成形品 |
| BR112021003478A2 (pt) | 2018-09-26 | 2021-05-18 | Borealis Ag | copolímero aleatório de propileno para uso em aplicações de película |
| WO2021058742A1 (en) | 2019-09-25 | 2021-04-01 | Borealis Ag | Heterophasic polypropylene copolymers |
| KR102467790B1 (ko) * | 2021-04-15 | 2022-11-16 | 에쓰대시오일 주식회사 | 고충격 폴리프로필렌 수지 조성물 및 이에 의해 제조된 성형품 |
| KR102587753B1 (ko) * | 2021-08-31 | 2023-10-11 | 한화토탈에너지스 주식회사 | 폴리프로필렌 수지 조성물 및 이로부터 제조된 성형품 |
Family Cites Families (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FI86867C (fi) | 1990-12-28 | 1992-10-26 | Neste Oy | Flerstegsprocess foer framstaellning av polyeten |
| DE4317655A1 (de) | 1993-05-27 | 1994-12-01 | Basf Ag | Mehrphasige Blockcopolymerisate des Propylens |
| FI111848B (fi) | 1997-06-24 | 2003-09-30 | Borealis Tech Oy | Menetelmä ja laitteisto propeenin homo- ja kopolymeerien valmistamiseksi |
| EP1236769A1 (en) * | 2001-02-21 | 2002-09-04 | Borealis Technology Oy | Heterophasic propylene polymer |
| US7595103B2 (en) * | 2001-10-30 | 2009-09-29 | Basell Poliolefine Italia S.P.A. | Pipe systems of polypropylene compositions |
| JP2004027212A (ja) * | 2002-05-10 | 2004-01-29 | Sunallomer Ltd | キャストフィルム及びその製造方法並びにキャストフィルムからなる容器 |
| RU2337114C2 (ru) | 2002-06-12 | 2008-10-27 | Базелль Полиолефине Гмбх | Композиции на основе сополимеров пропилена, имеющие хорошую ударную вязкость при низких температурах и высокую степень прозрачности |
| US7572860B2 (en) * | 2003-08-05 | 2009-08-11 | Basell Poliolefine Italia S.R.L. | Polyolefin articles |
| DE602005009648D1 (de) * | 2005-01-14 | 2008-10-23 | Borealis Polymers Oy | Heterophasische Polymerzusammensetzung und Verfahren zu ihrer Herstellung |
| RU2410388C2 (ru) | 2005-03-18 | 2011-01-27 | Базелль Полиолефине Гмбх | Металлоценовые соединения |
| EP1801156B1 (en) * | 2005-12-22 | 2009-12-02 | Borealis Technology Oy | Polyolefin compositions |
| JP2009533382A (ja) | 2006-04-12 | 2009-09-17 | バーゼル・ポリオレフィン・ゲーエムベーハー | メタロセン化合物 |
| WO2008018409A1 (fr) | 2006-08-11 | 2008-02-14 | Mitsui Chemicals, Inc. | Composition de résine de propylène pour un matériau d'emballage |
| JP4875954B2 (ja) | 2006-09-28 | 2012-02-15 | 日本ポリプロ株式会社 | プロピレン系共重合体、その製造方法及び成形体 |
| JP2008115262A (ja) * | 2006-11-02 | 2008-05-22 | Mitsui Chemicals Inc | プロピレン系樹脂組成物からなる自動車部品 |
| EP1935938A1 (en) * | 2006-12-18 | 2008-06-25 | Borealis Technology Oy | Improved high melt flow heterophasic polypropylene copolymers |
| MX2010004418A (es) | 2007-10-25 | 2010-08-09 | Lummus Novolen Technology Gmbh | Compuestos de metaloceno, catalizadores que comprenden los mismos, proceso para producir un polimero de olefina mediante el uso de los catalizadores y homo- y copolimeros de olefina. |
| EP2075284B1 (en) * | 2007-12-17 | 2013-05-29 | Borealis Technology OY | Heterophasic polypropylene with high flowability and excellent low temperature impact properties |
| EP2072546B2 (en) * | 2007-12-18 | 2012-12-26 | Borealis Technology Oy | Heterophasic polypropylene with high impact properties |
| JP5559954B2 (ja) * | 2008-02-26 | 2014-07-23 | 日本ポリプロ株式会社 | プロピレン系共重合体、その製造方法及び成形体 |
| BRPI0822601B1 (pt) * | 2008-04-24 | 2020-12-01 | Borealis Ag | copolímeros de polipropileno heterofásico com elevada pureza, seu processo de produção, e artigo |
| PL2174980T5 (pl) * | 2008-10-07 | 2019-04-30 | Borealis Ag | Polipropylen heterofazowy o dużej płynności |
| EP2361267B1 (en) | 2008-11-07 | 2015-03-04 | Borealis AG | Process to prepare a solid catalyst composition |
| WO2010052263A1 (en) | 2008-11-07 | 2010-05-14 | Borealis Ag | Solid catalyst composition |
| WO2010052264A1 (en) | 2008-11-07 | 2010-05-14 | Borealis Ag | Solid catalyst composition |
| KR101281912B1 (ko) * | 2008-12-22 | 2013-07-03 | 가부시키가이샤 프라임 폴리머 | 프로필렌계 수지 조성물, 성형체 및 용기 |
| ES2365797T3 (es) * | 2009-06-22 | 2011-10-11 | Borealis Ag | Composición copolímera de polipropileno heterofásico. |
| EP2316882A1 (en) * | 2009-10-29 | 2011-05-04 | Borealis AG | Heterophasic polypropylene resin |
| US8729206B2 (en) | 2010-04-28 | 2014-05-20 | Borealis Ag | Solid particulate catalysts comprising bridged metallocenes |
| JP5785609B2 (ja) | 2010-04-28 | 2015-09-30 | ボレアリス エージー | 触媒 |
| EP2415831A1 (en) * | 2010-08-06 | 2012-02-08 | Borealis AG | Heterophasic propylene copolymer with excellent impact/stiffness balance |
| EP2452976A1 (en) * | 2010-11-12 | 2012-05-16 | Borealis AG | Heterophasic propylene copolymers with improved stiffness/impact/flowability balance |
| EP2495280A1 (en) * | 2011-03-03 | 2012-09-05 | Borealis AG | Polyolefin composition with low CLTE and reduced occurrence of flow marks |
| WO2013007664A1 (en) | 2011-07-08 | 2013-01-17 | Borealis Ag | Heterophasic copolymers |
| SG11201402870VA (en) * | 2011-12-23 | 2014-10-30 | Borealis Ag | Propylene copolymer for injection molded articles or films |
-
2013
- 2013-07-12 PL PL13176366T patent/PL2824142T3/pl unknown
- 2013-07-12 ES ES13176366.6T patent/ES2569733T3/es active Active
- 2013-07-12 EP EP13176366.6A patent/EP2824142B1/en active Active
-
2014
- 2014-07-10 WO PCT/EP2014/064845 patent/WO2015004251A1/en active Application Filing
- 2014-07-10 JP JP2016524830A patent/JP6420335B2/ja not_active Expired - Fee Related
- 2014-07-10 RU RU2016102535A patent/RU2668075C2/ru active
- 2014-07-10 KR KR1020167003617A patent/KR101860241B1/ko active IP Right Grant
- 2014-07-10 BR BR112015032249A patent/BR112015032249A2/pt not_active Application Discontinuation
- 2014-07-10 CN CN201480039616.8A patent/CN105593287B/zh active Active
- 2014-07-10 EP EP14739131.2A patent/EP3019555A1/en not_active Withdrawn
- 2014-07-10 US US14/904,150 patent/US11299610B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| KR20160030992A (ko) | 2016-03-21 |
| PL2824142T3 (pl) | 2016-08-31 |
| EP3019555A1 (en) | 2016-05-18 |
| US11299610B2 (en) | 2022-04-12 |
| RU2668075C2 (ru) | 2018-09-26 |
| EP2824142A1 (en) | 2015-01-14 |
| RU2016102535A3 (pt) | 2018-05-07 |
| KR101860241B1 (ko) | 2018-06-27 |
| JP6420335B2 (ja) | 2018-11-07 |
| EP2824142B1 (en) | 2016-04-13 |
| CN105593287A (zh) | 2016-05-18 |
| ES2569733T3 (es) | 2016-05-12 |
| RU2016102535A (ru) | 2017-08-16 |
| US20160152810A1 (en) | 2016-06-02 |
| JP2016524028A (ja) | 2016-08-12 |
| CN105593287B (zh) | 2019-02-22 |
| WO2015004251A1 (en) | 2015-01-15 |
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Legal Events
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|---|---|---|---|
| B06U | Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette] | ||
| B11B | Dismissal acc. art. 36, par 1 of ipl - no reply within 90 days to fullfil the necessary requirements | ||
| B350 | Update of information on the portal [chapter 15.35 patent gazette] |