BR112015022952B1 - processo de cura de pré-impregnados para preparar compósitos com superior acabamento de suas superfícies e alta consolidação das fibras - Google Patents
processo de cura de pré-impregnados para preparar compósitos com superior acabamento de suas superfícies e alta consolidação das fibras Download PDFInfo
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- BR112015022952B1 BR112015022952B1 BR112015022952A BR112015022952A BR112015022952B1 BR 112015022952 B1 BR112015022952 B1 BR 112015022952B1 BR 112015022952 A BR112015022952 A BR 112015022952A BR 112015022952 A BR112015022952 A BR 112015022952A BR 112015022952 B1 BR112015022952 B1 BR 112015022952B1
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- process according
- prepreg
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- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 1
- XPFRXWCVYUEORT-UHFFFAOYSA-N Phenacemide Chemical compound NC(=O)NC(=O)CC1=CC=CC=C1 XPFRXWCVYUEORT-UHFFFAOYSA-N 0.000 description 1
- 229920003006 Polybutadiene acrylonitrile Polymers 0.000 description 1
- 239000004697 Polyetherimide Substances 0.000 description 1
- 239000004734 Polyphenylene sulfide Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 125000002015 acyclic group Chemical group 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000005741 alkyl alkenyl group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000011951 cationic catalyst Substances 0.000 description 1
- IKZDMJSZEMDIMC-UHFFFAOYSA-N chembl389656 Chemical compound OC1=CC=CC=C1C1=NC(C=2C=CC=CC=2)=C(C=2C=CC=CC=2)N1 IKZDMJSZEMDIMC-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- GKIPXFAANLTWBM-UHFFFAOYSA-N epibromohydrin Chemical compound BrCC1CO1 GKIPXFAANLTWBM-UHFFFAOYSA-N 0.000 description 1
- 238000006735 epoxidation reaction Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- XXOYNJXVWVNOOJ-UHFFFAOYSA-N fenuron Chemical compound CN(C)C(=O)NC1=CC=CC=C1 XXOYNJXVWVNOOJ-UHFFFAOYSA-N 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000004850 liquid epoxy resins (LERs) Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- VUQUOGPMUUJORT-UHFFFAOYSA-N methyl 4-methylbenzenesulfonate Chemical compound COS(=O)(=O)C1=CC=C(C)C=C1 VUQUOGPMUUJORT-UHFFFAOYSA-N 0.000 description 1
- OIRDBPQYVWXNSJ-UHFFFAOYSA-N methyl trifluoromethansulfonate Chemical compound COS(=O)(=O)C(F)(F)F OIRDBPQYVWXNSJ-UHFFFAOYSA-N 0.000 description 1
- QOHMWDJIBGVPIF-UHFFFAOYSA-N n',n'-diethylpropane-1,3-diamine Chemical compound CCN(CC)CCCN QOHMWDJIBGVPIF-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 150000004893 oxazines Chemical class 0.000 description 1
- 150000002924 oxiranes Chemical class 0.000 description 1
- 229960003396 phenacemide Drugs 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001601 polyetherimide Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 229960004063 propylene glycol Drugs 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000003335 secondary amines Chemical group 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000005017 substituted alkenyl group Chemical group 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 238000005382 thermal cycling Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/40—Shaping or impregnating by compression not applied
- B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
- B29C70/44—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using isostatic pressure, e.g. pressure difference-moulding, vacuum bag-moulding, autoclave-moulding or expanding rubber-moulding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C37/00—Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
- B29C37/005—Compensating volume or shape change during moulding, in general
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C37/00—Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
- B29C37/006—Degassing moulding material or draining off gas during moulding
- B29C37/0064—Degassing moulding material or draining off gas during moulding of reinforced material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C71/00—After-treatment of articles without altering their shape; Apparatus therefor
- B29C71/02—Thermal after-treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
- B32B37/1018—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure using only vacuum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C71/00—After-treatment of articles without altering their shape; Apparatus therefor
- B29C71/02—Thermal after-treatment
- B29C2071/022—Annealing
Landscapes
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Fluid Mechanics (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Composite Materials (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Reinforced Plastic Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/833,425 US9205633B2 (en) | 2013-03-15 | 2013-03-15 | Prepreg curing process for preparing composites having superior surface finish and high fiber consolidation |
| PCT/IB2014/000770 WO2014140803A2 (en) | 2013-03-15 | 2014-02-21 | Prepreg curing process for preparing composites having superior surface finish and high fiber consolidation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR112015022952A2 BR112015022952A2 (pt) | 2017-07-18 |
| BR112015022952B1 true BR112015022952B1 (pt) | 2020-05-19 |
Family
ID=50979810
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112015022952A BR112015022952B1 (pt) | 2013-03-15 | 2014-02-21 | processo de cura de pré-impregnados para preparar compósitos com superior acabamento de suas superfícies e alta consolidação das fibras |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9205633B2 (enExample) |
| EP (1) | EP2969446B1 (enExample) |
| JP (2) | JP6309031B2 (enExample) |
| CN (2) | CN105121112A (enExample) |
| BR (1) | BR112015022952B1 (enExample) |
| CA (1) | CA2906289C (enExample) |
| WO (1) | WO2014140803A2 (enExample) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI888344B (zh) * | 2018-03-06 | 2025-07-01 | 日商力森諾科股份有限公司 | 預浸體、積層板、多層印刷線路板、半導體封裝體及樹脂組成物、以及預浸體、積層板及多層印刷線路板的製造方法 |
| JP7563893B2 (ja) * | 2020-04-30 | 2024-10-08 | 帝人株式会社 | 複合材料の製造方法 |
| CN114872386B (zh) * | 2022-07-08 | 2022-10-18 | 北京玻钢院复合材料有限公司 | 一种非对称飞机地板及其制备方法 |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52109568A (en) * | 1976-03-10 | 1977-09-13 | Nasa | Method of manufacture of plyplate consisted of graphite and epoxy resin * from ultraathin films |
| US4357193A (en) * | 1979-05-21 | 1982-11-02 | Rockwell International Corporation | Method of fabricating a composite structure |
| JPS5751422A (en) * | 1980-09-11 | 1982-03-26 | Mitsubishi Rayon Co Ltd | Process for molding frp |
| USH559H (en) | 1987-05-12 | 1988-12-06 | The United States Of America As Represented By The Secretary Of The Air Force | Advancing gelation front cure technique |
| JP2658631B2 (ja) * | 1991-07-02 | 1997-09-30 | 三菱電機株式会社 | 強化繊維・エポキシ樹脂複合材料の製造方法 |
| JPH06344366A (ja) * | 1993-06-10 | 1994-12-20 | Mitsubishi Heavy Ind Ltd | 樹脂硬化監視方法及びその装置 |
| US6013361A (en) | 1995-10-31 | 2000-01-11 | Lockheed Martin Corporation | High performance structural laminate composite material for use to 1000° F and above, apparatus for and method of manufacturing same, and articles made with same |
| CA2332341C (en) * | 1998-05-20 | 2005-11-29 | Cytec Technology Corp. | Manufacture of void-free laminates and use thereof |
| FR2852884B1 (fr) | 2003-03-26 | 2005-05-06 | Hurel Hispano | Procede de fabrication de pieces en composite a matrice polyimide |
| JP2004330474A (ja) * | 2003-05-01 | 2004-11-25 | Kawasaki Heavy Ind Ltd | 複合材製品の製造方法 |
| US7666938B2 (en) * | 2004-12-03 | 2010-02-23 | Henkel Corporation | Nanoparticle silica filled benzoxazine compositions |
| JP2007016364A (ja) * | 2005-07-11 | 2007-01-25 | Toray Ind Inc | 炭素繊維束 |
| JP5092444B2 (ja) * | 2007-02-21 | 2012-12-05 | トヨタ自動車株式会社 | 繊維強化複合材料の製造方法 |
| JP2009173764A (ja) * | 2008-01-24 | 2009-08-06 | Toray Ind Inc | プリプレグおよび炭素繊維強化複合材料 |
| US20100196729A1 (en) | 2009-01-31 | 2010-08-05 | Stephen Mark Whiteker | Autoclave Cure Cycle Design Process and Curing Method |
| KR20100121341A (ko) * | 2009-05-08 | 2010-11-17 | 삼성전자주식회사 | 벤조옥사진계 화합물을 포함하는 기판 형성용 조성물 및 이를 이용하여 제조된 기판 |
| DE102009003033B4 (de) * | 2009-05-12 | 2013-02-21 | Henkel Ag & Co. Kgaa | Polymerisierbare Benzoxazin-Verbindungen mit grenzflächenaktiven bzw. oberflächenaktiven Eigenschaften |
| GB201009851D0 (en) * | 2010-06-14 | 2010-07-21 | Hexcel Composites Ltd | Improvements in composite materials |
| JP5686994B2 (ja) * | 2010-07-01 | 2015-03-18 | 三菱重工業株式会社 | 成形体の製造方法 |
| JP5292445B2 (ja) * | 2010-11-26 | 2013-09-18 | 株式会社芦田製作所 | オートクレーブ成形方法及びオートクレーブ成形装置 |
| US9676124B2 (en) * | 2010-12-01 | 2017-06-13 | Plasan Carbon Composites, Inc. | Method and system for forming composite articles |
| RU2013148117A (ru) * | 2011-03-30 | 2015-05-10 | Торэй Индастриз, Инк. | Препрег, армированный волокном композитный материал и способ его получения |
| US9427943B2 (en) * | 2013-03-15 | 2016-08-30 | Henkel IP & Holding GmbH | Prepreg curing process for preparing composites having superior surface finish and high fiber consolidation |
-
2013
- 2013-03-15 US US13/833,425 patent/US9205633B2/en active Active
-
2014
- 2014-02-21 CN CN201480016259.3A patent/CN105121112A/zh active Pending
- 2014-02-21 CN CN201710969728.9A patent/CN107696528A/zh active Pending
- 2014-02-21 JP JP2015562374A patent/JP6309031B2/ja active Active
- 2014-02-21 BR BR112015022952A patent/BR112015022952B1/pt active IP Right Grant
- 2014-02-21 CA CA2906289A patent/CA2906289C/en active Active
- 2014-02-21 EP EP14731773.9A patent/EP2969446B1/en active Active
- 2014-02-21 WO PCT/IB2014/000770 patent/WO2014140803A2/en not_active Ceased
-
2018
- 2018-01-10 JP JP2018002245A patent/JP2018062669A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| BR112015022952A2 (pt) | 2017-07-18 |
| JP6309031B2 (ja) | 2018-04-11 |
| CA2906289A1 (en) | 2014-09-18 |
| WO2014140803A3 (en) | 2014-12-04 |
| CN107696528A (zh) | 2018-02-16 |
| WO2014140803A2 (en) | 2014-09-18 |
| JP2016510087A (ja) | 2016-04-04 |
| JP2018062669A (ja) | 2018-04-19 |
| EP2969446B1 (en) | 2022-12-28 |
| CN105121112A (zh) | 2015-12-02 |
| CA2906289C (en) | 2021-03-30 |
| US9205633B2 (en) | 2015-12-08 |
| EP2969446A2 (en) | 2016-01-20 |
| US20140262014A1 (en) | 2014-09-18 |
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| B06F | Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette] | ||
| B06U | Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 21/02/2014, OBSERVADAS AS CONDICOES LEGAIS. |